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1. 发明申请

US20140329333A1 MICRO-SAMPLING-SYSTEM FOR SMALL AMOUNTS OF FLUID SAMPLES FOR ANALYSIS IN THE VAPOUR PHASE 审中-公开
标题翻译：用于微波分析的液体样品微量采样系统
公开(公告)号：US20140329333A1
公开(公告)日：2014-11-06
申请号：US14239174
申请日：2012-08-14
申请人： Károly Nagy , Bernd Schilling , Alexander Plum
发明人： Károly Nagy , Bernd Schilling , Alexander Plum
IPC分类号： G01N1/22
CPC分类号： G01N1/2205 , G01N1/28 , G01N1/40 , G01N2030/126 , Y10T436/2575
摘要： Microsampling system for small amounts of fluid samples for analysis in the vapour phase, which comprises a plurality of integrated functional units and is suitable for small sample quantities with fast reaction times.
摘要翻译：微量采样系统用于少量用于气相分析的流体样品，其包含多个集成的功能单元，适用于具有快速反应时间的小样品量。

2. 发明授权

US4242276A Process for the manufacture of .beta.-isobutyrylaminocrotonic acid amide 失效
标题翻译：制备β-异丁酰氨基巴豆酸酰胺的方法
公开(公告)号：US4242276A
公开(公告)日：1980-12-30
申请号：US99778
申请日：1979-12-03
申请人： Bernd Schilling
发明人： Bernd Schilling
IPC分类号： C07C67/00 , C07C231/00 , C07C231/04 , C07C231/12 , C07C237/16 , C07C237/22 , C07C97/16
CPC分类号： C07C231/00
摘要： A process for the manufacture of .beta.-isobutyrylaminocrotonic acid amide by reacting .beta.-aminocrotonic acid amide with dimethylketene in the liquid or gaseous state without the application of external heat at temperatures in the range of from room temperature to 70.degree. C. The dispersion medium used is an organic solvent having a boiling point above 40.degree. C. that may contain up to 0.1 mole of water and 0.2 to 2 moles of a carboxylic acid having 1 to 4 carbon atoms per mole of .beta.-aminocrotonic acid amide. If the dimethylketene is added undiluted the reaction is carried out in the absence of oxygen and in the presence of a protective gas atmosphere. The .beta.-isobutyrylaminocrotonic acid amide is obtained in the form of two stereoisomers (Z- and E-forms), which differ as regards their melting point and their solubility in organic solvents. On heating to 40.degree. C., the E-form is converted into the Z-form.
摘要翻译：通过使β-氨基巴豆酸酰胺与液体或气态的二甲基烯酮反应制备β-异丁酰氨基巴豆酸酰胺的方法，而不需要在室温至70℃的温度范围内施加外界热。使用的分散介质是沸点高于40℃的有机溶剂，其可含有至多0.1摩尔水和0.2至2摩尔每摩尔β-氨基巴豆酸酰胺具有1至4个碳原子的羧酸。如果未稀释地加入二甲基烯酮，则反应在不存在氧的情况下和在保护气体气氛存在下进行。 β-二异丁酰氨基巴豆酸酰胺以两种立体异构体（Z-和E-型）的形式获得，它们的熔点和它们在有机溶剂中的溶解度不同。加热至40℃时，将E型转化成Z型。

3. 发明授权

US4959249A Self-crosslinking vinyl ester dispersions having a reduced formaldehyde content or containing no formaldehyde for strengthening textile fiber structures 失效
标题翻译：具有降低甲醛含量或不含甲醛的自交联乙烯基酯分散体用于加强纺织纤维结构
公开(公告)号：US4959249A
公开(公告)日：1990-09-25
申请号：US423002
申请日：1989-10-18
申请人： Bernd Schilling , Gerhard Brink , Ingo Harder , Hubert Wiest
发明人： Bernd Schilling , Gerhard Brink , Ingo Harder , Hubert Wiest
IPC分类号： D06M15/643 , C08L31/04 , C08L43/00 , C08L43/04 , C09J131/04 , D06M15/227 , D06M15/263 , D06M15/285 , D06M15/29 , D06M15/327 , D06M15/333 , D06M15/356 , D06M101/08
CPC分类号： D06M15/285 , D06M15/227 , D06M15/263 , D06M15/29 , D06M15/333 , D06M15/3568 , Y10T442/2566
摘要： Binders for strengthening textile fiber structures and based on aqueous, self-crosslinking vinyl ester dispersions having a reduced formaldehyde content or containing no formaldehyde. The low content of free formaldehyde in the dispersion is achieved by partial or complete substitution of the crosslinking comonomers containing N-methylol groups by vinylalkoxysilanes as crosslinking agents. Non-woven treated with these formaldehyde-free or low formaldehyde binder systems are distinguished by high strength values and excellent solvent resistance.
摘要翻译：用于加强纺织纤维结构并基于具有降低的甲醛含量或不含甲醛的水性，自交联乙烯基酯分散体的粘合剂。分散体中游离甲醛的含量低是通过乙烯基烷氧基硅烷作为交联剂部分或完全取代含有N-羟甲基的交联共聚单体来实现的。用这些无甲醛或低甲醛粘合剂体系处理的无纺织物具有高强度值和优异的耐溶剂性。

4. 发明授权

US4585863A Process for the manufacture of 2-isopropyl-4-methyl-6-hydroxypyrimidine 失效
标题翻译：制备2-异丙基-4-甲基-6-羟基嘧啶的方法
公开(公告)号：US4585863A
公开(公告)日：1986-04-29
申请号：US641329
申请日：1984-08-16
申请人： Wolfgang Deinhammer , Bernd Schilling
发明人： Wolfgang Deinhammer , Bernd Schilling
IPC分类号： C07D239/34 , C07D239/36 , C07D239/02
CPC分类号： C07D239/36
摘要： An improved process for the manufacture of 2-isopropyl-4-methyl-6-hydroxypyrimidine, starting from 3-aminocrotonic acid amide and an acylating agent, without isolating the intermediately formed 3-isobutyrylaminocrotonic acid amide. In a first process step, the acylation is carried out with excess isobutyric acid anhydride in the presence of an alkali metal salt of isobutyric acid at temperatures of from 50.degree. to 120.degree. C. and in the absence of a solvent. In a second process step, the cyclization is carried out in the resulting reaction mixture by the addition of an aqueous alkali metal hydroxide solution at temperatures of from 80.degree. to 105.degree. C., and then the hydroxypyrimidine is isolated in known manner. The total quantities of alkali metal hydroxide added in the second process step are such that they are sufficient both for the neutralization of the isobutyric acid present in the reaction mixture and also for the cyclization. Less than 1 mole of alkali metal hydroxide per mole of the 3-aminocrotonic acid amide originally used is used for the cyclization itself.
摘要翻译：从3-氨基巴豆酸酰胺和酰化剂制备2-异丙基-4-甲基-6-羟基嘧啶的改进方法，而不分离中间形成的3-异丁酰氨基巴豆酸酰胺。在第一工艺步骤中，在50-120℃的温度和不存在溶剂的条件下，在异丁酸的碱金属盐存在下，用过量的异丁酸酐进行酰化。在第二个工艺步骤中，通过在80℃至105℃的温度下加入碱金属氢氧化物水溶液在所得反应混合物中进行环化，然后以已知的方式分离出羟基嘧啶。在第二工艺步骤中加入的碱金属氢氧化物的总量使得它们对于中和反应混合物中存在的异丁酸以及环化都是足够的。最初使用的每摩尔3-氨基巴豆酸酰胺少于1摩尔碱金属氢氧化物用于环化本身。

5. 发明申请

US20110259136A1 SHAFT WITH A GEAR CAST ON ITS FRONT SIDE AND METHOD FOR PRODUCING SUCH A SHAFT 有权
标题翻译：具有齿轮的轴在其前端和用于生产这样的轴的方法
公开(公告)号：US20110259136A1
公开(公告)日：2011-10-27
申请号：US13070083
申请日：2011-03-23
申请人： STEPHAN OBERLE , Bernd Schilling , Uwe Probst , Markus Bernhard
发明人： STEPHAN OBERLE , Bernd Schilling , Uwe Probst , Markus Bernhard
IPC分类号： F16H55/17 , B22D25/02 , B22D19/00
CPC分类号： F16H55/06 , B29C45/0025 , B29C45/14491 , B29C45/2669 , B29C47/0009 , B29C47/025 , B29C2045/0027 , B29C2045/2671 , B29D15/00 , B29L2015/003 , F16H55/17 , F16H2055/065 , Y10T74/1987
摘要： The present invention is directed to a shaft with two front sides and an axis of rotation, whereby the shaft comprises at least one gear with the same axis of rotation, which gear borders at least a first one of the front sides in an axial area. Viewed from radially inside toward radially outside, the gear comprises a connection part with a central receptacle for the shaft, and an outer part with teeth. The connection part is cast directly between the shaft and the outer part. The connection part extends over the shaft in axial direction and covers the first front side.
摘要翻译：本发明涉及具有两个前侧和一个旋转轴线的轴，由此该轴包括具有相同旋转轴线的至少一个齿轮，该齿轮在轴向区域中与至少第一个前侧边界。从径向内侧向径向外侧观察，齿轮包括具有用于轴的中心插座的连接部分和具有齿的外部部分。连接部分直接铸在轴和外部之间。连接部在轴向上延伸穿过轴并覆盖第一前侧。

6. 发明授权

US06489391B1 Process for preparing aqueous, protective colloid stabilized vinyl ester homopolymer and copolymer dispersions 失效
标题翻译：制备水性，保护胶体稳定的乙烯基酯均聚物和共聚物分散体的方法
公开(公告)号：US06489391B1
公开(公告)日：2002-12-03
申请号：US09509285
申请日：2000-05-22
申请人： Bernd Schilling , Georg Riepl
发明人： Bernd Schilling , Georg Riepl
IPC分类号： C08L2904
CPC分类号： C08J3/005 , C08J2331/04 , C08L31/02 , C08L2201/50 , C08L2205/02 , C08L2205/18 , C09J131/02 , C08L2666/04
摘要： The invention provides a method of producing aqueous, protective colloid stabilized vinyl ester homo- and co-polymer dispersions with a defined solids content by emulsion polymerization in the presence of a protective colloid. The method specifies that a dispersion with a solids content lower than the defined solids content is produced and then thickened to the defined solids content after the polymerization has been completed. The dispersion is thickened by adding a polymer powder which is of the same polymer composition as the emulsion polymerizate and which can be redispersed in water.
摘要翻译：本发明提供了一种通过在保护胶体存在下通过乳液聚合制备具有确定的固体含量的水性，保护胶体稳定的乙烯基酯均聚物和共聚物分散体的方法。该方法规定了固体含量低于定义的固体含量的分散体，然后在聚合完成之后增稠至所定义的固体含量。通过加入与乳液聚合物具有相同聚合物组成并可再分散在水中的聚合物粉末来增稠分散体。

7. 发明授权

US4323678A Process for the manufacture of diazinon 失效
标题翻译：二嗪农的制备方法
公开(公告)号：US4323678A
公开(公告)日：1982-04-06
申请号：US120411
申请日：1980-02-11
申请人： Bernd Schilling
发明人： Bernd Schilling
IPC分类号： A01N43/54 , C07F9/6512 , C07F9/65
CPC分类号： C07F9/65125
摘要： The invention provides an improved process for the manufacture of the insecticide diazinon. The process uses .beta.-isobutyrylaminocrotonic acid amide as starting material and, by reaction with sodium hydroxide solution or alcoholate and phosphorylation with diethylthiophosphoryl chloride, diazinon (0,0-diethyl-0-(2-isopropyl-4-methyl-6-pyrimidinyl)thiono -phosphate) is obtained directly in a high yield without isolating any intermediates.
摘要翻译：本发明提供了用于制造杀虫剂二嗪农的改进方法。该方法使用β-异丁酰氨基巴豆酸酰胺作为原料，通过与氢氧化钠溶液或醇化物反应并用二乙基硫代磷酰氯磷酸化，二嗪农（0-二乙基-O-（2-异丙基-4-甲基-6-嘧啶基）硫代磷酸盐）直接以高产率获得，而不分离任何中间体。

8. 发明授权

US06656983B1 Vinylaromatic/1,3-diene copolymer stabilized with protective colloids as adhesives for porous substrates 失效
标题翻译：用保护胶体稳定的乙烯基芳烃/ 1,3-二烯共聚物作为多孔基材的粘合剂
公开(公告)号：US06656983B1
公开(公告)日：2003-12-02
申请号：US09856538
申请日：2001-08-01
申请人： Theo Mayer , Thomas Kohler , Reinhard Harzschel , Hans-Peter Weitzel , Bernd Schilling
发明人： Theo Mayer , Thomas Kohler , Reinhard Harzschel , Hans-Peter Weitzel , Bernd Schilling
IPC分类号： C08L100
CPC分类号： C09J125/10 , C08F236/10 , C08L2666/02 , C09J109/06
摘要： The invention provides mixed aromatic vinyl-1,3-diene polymers stabilized by a protective colloid and present in the form of aqueous polymer dispersions or polymer powders redispersible in water as adhesives for porous substrates. The polymer dispersions and the polymer powders are obtained by emulsion polymerization of a mixture containing: a) 20 to 80 percent by weight of one or more vinylaromatics; b) 19.9 to 79.9 percent by weight of one or more 1,3-dienes; c) 0.1 to 15 percent by weight of one or more comonomers from the group consisting of N-methylolacrylamide, N-methylolmethacrylamide and the N-(alkoxymethyl)-acrylamides and N-(alkoxymethyl)-methacrylamides with a C1 to C6-alkyl radical. The sum of the above percentages adds up to 100% by weight. Emulsion polymerization is carried out in the presence of one or more protective colloids and without emulsifiers, optionally followed by drying of the resulting aqueous polymer dispersion.
摘要翻译：本发明提供了由保护胶体稳定并以聚合物水分散体形式存在的混合芳族乙烯基-1,3-二烯聚合物或可再分散在水中的聚合物粉末作为多孔基材的粘合剂。聚合物分散体和聚合物粉末通过混合物的乳液聚合获得，所述混合物包含：a）20至80重量％的一种或多种乙烯基芳烃; b）19.9至79.9重量％的一种或多种1,3-二烯; c）0.1至15重量％的来自由N-羟甲基丙烯酰胺，N-羟甲基甲基丙烯酰胺和N-（烷氧基甲基） - 丙烯酰胺和具有C 1至C 6 - 烷基的N-（烷氧基甲基） - 甲基丙烯酰胺组成的组中的一种或多种共聚单体。上述百分比的总和高达100重量％。乳液聚合在一种或多种保护胶体和不含乳化剂的存在下进行，任选然后干燥所得的聚合物水分散体。

9. 发明授权

US4879336A Novel coating slips 失效
标题翻译：新型涂层滑
公开(公告)号：US4879336A
公开(公告)日：1989-11-07
申请号：US272634
申请日：1988-11-17
申请人： Bernd Schilling , Karl-Ernst Fickert
发明人： Bernd Schilling , Karl-Ernst Fickert
IPC分类号： C08F216/06 , C08F8/12 , C08F16/02 , C08L29/02 , C09D5/00 , C09D129/04 , D21H19/60
CPC分类号： D21H19/60
摘要： In a coating slip for coating flat surfaces comprising an aqueous dispersion, with a solids content of 8 to 65% by weight, of 100 parts by weight of a pigment, 3 to 30 parts by weight of synthetic high-molecular-weight binder based on copolymers of acrylates, styrene, butadiene and unsaturated carboxylic acid esters and 0.5 to 2 parts by weight of a cobinder the improvement comprising using a cobinder polymer containing a large degree of hydroxyl groups comprising (a) 50 to 95% by weight of vinyl alcohol units, (b) 5 to 50% by weight of 1-alkylvinyl alcohol units of 1 to 4 alkyl carbon atoms, (c) 0 to 20% by weight of vinyl acylate units, (d) 0 to 20% by weight of allyl alcohol units and (e) 0 to 5% by weight of other polymerizable monomers having improved pigment shock behavior and very good activity as an optical brightener support.
摘要翻译：在用于涂覆平坦表面的涂层滑动剂中，其包含含水分散体，固含量为8至65重量％，100重量份颜料，3至30重量份的合成高分子量粘合剂，基于丙烯酸酯，苯乙烯，丁二烯和不饱和羧酸酯的共聚物和0.5至2重量份的椰子料，其改进包括使用含有大量羟基的椰子树脂聚合物，其包含（a）50至95重量％的乙烯醇单元，（b）5〜50重量％的1〜4个烷基碳原子的1-烷基乙烯醇单元，（c）0〜20重量％的乙烯基酰化物单元，（d）0〜20重量％的烯丙基醇单元和（e）0至5重量％的具有改进的颜料冲击行为和作为荧光增白剂载体的非常好的活性的其它可聚合单体。

10. 发明授权

US09464706B2 Shaft with a gear cast on its front side and method for producing such a shaft 有权
标题翻译：其前侧具有齿轮的轴和用于制造这种轴的方法
公开(公告)号：US09464706B2
公开(公告)日：2016-10-11
申请号：US13070083
申请日：2011-03-23
申请人： Stephan Oberle , Bernd Schilling , Uwe Probst , Markus Bernhard
发明人： Stephan Oberle , Bernd Schilling , Uwe Probst , Markus Bernhard
IPC分类号： F16H55/17 , F16H55/06 , B29C45/00 , B29C45/14 , B29D15/00 , B29C45/26 , B29C47/02 , B29L15/00 , B29C47/00
CPC分类号： F16H55/06 , B29C45/0025 , B29C45/14491 , B29C45/2669 , B29C47/0009 , B29C47/025 , B29C2045/0027 , B29C2045/2671 , B29D15/00 , B29L2015/003 , F16H55/17 , F16H2055/065 , Y10T74/1987
摘要： The present invention is directed to a shaft with two front sides and an axis of rotation, whereby the shaft comprises at least one gear with the same axis of rotation, which gear borders at least a first one of the front sides in an axial area. Viewed from radially inside toward radially outside, the gear comprises a connection part with a central receptacle for the shaft, and an outer part with teeth. The connection part is cast directly between the shaft and the outer part. The connection part extends over the shaft in axial direction and covers the first front side.
摘要翻译：本发明涉及具有两个前侧和一个旋转轴线的轴，由此该轴包括具有相同旋转轴线的至少一个齿轮，该齿轮在轴向区域中与至少第一个前侧边界。从径向内侧向径向外侧观察，齿轮包括具有用于轴的中心插座的连接部分和具有齿的外部部分。连接部分直接铸在轴和外部之间。连接部在轴向上延伸穿过轴并覆盖第一前侧。

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