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1. 发明授权

US5830844A Dye transfer inhibitors for detergents 失效
标题翻译：用于洗涤剂的染料转移抑制剂
公开(公告)号：US5830844A
公开(公告)日：1998-11-03
申请号：US750478
申请日：1996-12-17
申请人： Jurgen Detering , Christian Schade , Johannes Perner , Hans-Ulrich Jager
发明人： Jurgen Detering , Christian Schade , Johannes Perner , Hans-Ulrich Jager
IPC分类号： C11D3/00 , C11D3/37
CPC分类号： C11D3/0021 , C11D3/3776
摘要： Water-insoluble, crosslinked polymers containing polymerized units of 1-vinylpyrrolidone and/or 1-vinylimidazoles of the formula ##STR1## where R, R.sup.1 and R.sup.2 are identical or different and each is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl, or of 4-vinylpyridine N-oxide, in finely divided form, at least 90% by weight of the polymers having a particle size from 0.1 to 500 .mu.m, are useful as detergent additives for inhibiting the transfer of dye during the wash.
摘要翻译： PCT No.PCT / EP95 / 02111 Sec。 371日期：1996年12月17日 102（e）日期1996年12月17日PCT提交1995年6月3日PCT公布。出版物WO95 / 35360 日期1995年12月28日含有式（I）的1-乙烯基吡咯烷酮和/或1-乙烯基咪唑的聚合单元的水不溶性交联聚合物，其中R，R 1和R 2相同或不同，各自为氢，C1- C4-烷基或苯基，或4-乙烯基吡啶N-氧化物，以细碎形式，至少90重量％的粒径为0.1至500μm的聚合物可用作抑制转移的洗涤剂添加剂洗涤期间染色。

2. 发明授权

US06756471B1 Process for the preparation of water-soluble polymers containing polyalkylene glycol ether side chains 失效
标题翻译：制备含聚亚烷基二醇醚侧链的水溶性聚合物的方法
公开(公告)号：US06756471B1
公开(公告)日：2004-06-29
申请号：US10129110
申请日：2002-05-13
申请人： Matthias Kroner , Karl-Heinz Büchner , Johannes Perner
发明人： Matthias Kroner , Karl-Heinz Büchner , Johannes Perner
IPC分类号： C08G6300
CPC分类号： C04B24/2647 , C04B2103/30 , C08F2/06 , C08F8/44 , C08F220/28 , C08F290/06 , C08F290/061 , C08F290/062 , C08F290/14 , C08G65/3322 , C08L71/02 , C08F290/00 , C08L2666/04
摘要： The invention relates to a process for the preparation of water-soluble polymers containing polyalkylene glycol ether side chains and having molecular weights of from 15,000 to 65,000 by solution polymerization of esters of ethylenically unsaturated carboxylic acids and polyalkylene glycols which are masked on the end groups at one end, if desired together with another monomer in at least one hydrocarbon at monomer concentrations of from 70 to 95% by weight in the presence of free-radical-forming polymerization initiators and, if desired, polymerization regulators at temperatures of up to 200° C., removal of the solvent used in the solution polymerization, and dissolution of the polymers in water to give from 50 to 80% strength by weight solutions, with polymers containing acid groups being neutralized if desired.
摘要翻译：本发明涉及一种制备含聚亚烷基二醇醚侧链的水溶性聚合物的方法，其分子量为15,000至65,000，通过在末端基上被掩蔽的烯属不饱和羧酸和聚亚烷基二醇的酯的溶液聚合一方面，如果需要，在形成自由基的聚合引发剂的存在下，在70至95重量％的单体浓度下，在至少一种烃中与另一种单体一起使用，如果需要，聚合调节剂的温度高达200° C.去除溶液聚合中使用的溶剂，并将聚合物溶解在水中，得到50-80％重量的强度溶液，如果需要，含有酸基团的聚合物被中和。

3. 发明授权

US5143840A Substantially purified proteolytic enzyme from Bacillus spec. USNI 4828 method of making and using it 失效
标题翻译：来自BACILLUS SPEC的大量纯化的蛋白酶。 USNI 4828制造和使用它的方法
公开(公告)号：US5143840A
公开(公告)日：1992-09-01
申请号：US499376
申请日：1990-05-29
申请人： Hansjoerg Rettenmaier , Andreas Kreimeyer , Johannes Perner , Paul Diessel
发明人： Hansjoerg Rettenmaier , Andreas Kreimeyer , Johannes Perner , Paul Diessel
IPC分类号： C11D3/386 , C12N9/54
CPC分类号： C12R1/07 , C11D3/386 , C12N9/54 , Y10S435/832
摘要： A substantially purified proteolytic enzyme isolated from a culture of Bacillus spec. DSM 4828 which has a molecular weight of 27,000 daltons, an optimum pH of 12, an optimal temperature of 60.degree. C. and which can be used in a detergent composition.
摘要翻译： PCT No.PCT / EP89 / 01163 Sec。 371日期1990年5月29日第 102（e）日期1990年5月29日PCT提交1989年10月4日PCT公布。出版物WO90 / 0402200 1990年04月19日。从Bacillus Spec。的培养物中分离出的基本纯化的蛋白水解酶。 DSM 4828的分子量为27,000道尔顿，最适pH为12，最适温度为60℃，可用于洗涤剂组合物。

4. 发明授权

US5008032A Use of partially esterified copolymers in liquid detergents 失效
标题翻译：在液体洗涤剂中使用部分酯化的共聚物
公开(公告)号：US5008032A
公开(公告)日：1991-04-16
申请号：US417474
申请日：1989-10-05
申请人： Paul Diessel , Johannes Perner , Walter Denzinger , Heinrich Hartmann , Hans-Juergen Raubenheimer
发明人： Paul Diessel , Johannes Perner , Walter Denzinger , Heinrich Hartmann , Hans-Juergen Raubenheimer
IPC分类号： C08L67/00 , C11D3/37
CPC分类号： C11D3/3765
摘要： Liquid, alkaline detergent formulations which contain as essential constituents a surfactant, water and 0.1-20% by weight of partially esterified copolymers are obtainable by the copolymerization of(a) one or more C.sub.4 -C.sub.28 -olefins and(b) ethylenically unsaturated dicarboxylic anhydrides of from 4 to 8 carbon atomsin a molar ratio of 1:1 and subsequent partial esterification of the copolymers of the reaction products(A) C.sub.1 -C.sub.30 -alcohols, C.sub.8 -C.sub.22 fatty acids, C.sub.1 -C.sub.12 -alkylphenols or secondary C.sub.2 -C.sub.30 -amines with(B) one or more C.sub.2 -C.sub.4 -alkylene oxides or tetrahydrofuranin a molar ratio of (A):(B) of from 1:2 to 1:50 and hydrolysis of the anhydride groups of the copolymer to carboxyl groups, the partial esterification of the copolymers being carried on until more than 5 to 50% of the carboxyl groups of the copolymers have been esterified.
摘要翻译：通过（a）一种或多种C 4 -C 28 - 烯烃和（b）烯属不饱和二羧酸酐共聚获得含有作为表面活性剂，水和0.1-20重量％部分酯化共聚物的基本组分的液体，碱性洗涤剂制剂 4至8个碳原子，摩尔比为1:1，随后反应产物（A）C 1 -C 30醇，C 8 -C 22脂肪酸，C 1 -C 12烷基酚或仲C2-C30的共聚物的部分酯化 - 胺与（B）一种或多种C 2 -C 4 - 烯化氧或四氢呋喃的摩尔比为（A）：（B）为1:2至1:50，并将共聚物的酸酐基水解成羧基，承载共聚物的部分酯化直到共聚物的羧基的5至50％已被酯化。

5. 发明授权

US4705649A Preparation of acyloxybenzenesulfonic acids and their alkali metal and alkaline earth metal salts 失效
标题翻译：酰氧基苯磺酸及其碱金属和碱土金属盐的制备
公开(公告)号：US4705649A
公开(公告)日：1987-11-10
申请号：US928696
申请日：1986-11-07
申请人： Wolf-Dieter Balzer , Hans-Heinrich Bechtolsheimer , Karl-Heinz Beyer , Rolf Fikentscher , Johannes Perner , Rudi Widder , Helmut Wolf
发明人： Wolf-Dieter Balzer , Hans-Heinrich Bechtolsheimer , Karl-Heinz Beyer , Rolf Fikentscher , Johannes Perner , Rudi Widder , Helmut Wolf
IPC分类号： C07C309/42 , C07C67/00 , C07C69/00 , C07C69/76 , C07C301/00 , C07C303/04 , C07C303/06 , C07C303/08 , C07C303/22 , C07C303/32 , C07C309/41
CPC分类号： C07C303/42 , C07C309/00
摘要： Acyloxybenzenesulfonic acids and their alkali metal and alkaline earth metal salts are prepared by sulfonation of phenol in the presence of a small amount of a complexing agent for the sulfonating agent SO.sub.3 or chlorosulfonic acid, followed by esterification and, if required, neutralization to give the alkali metal or alkaline earth metal salt.
摘要翻译：芳氧基苯磺酸及其碱金属和碱土金属盐通过在少量磺化剂SO 3或氯磺酸络合剂存在下磺化苯酚，然后进行酯化反应制备，如果需要，中和得到碱金属或碱土金属盐。

6. 发明授权

US4695412A Preparation of acyloxybenzenesulfonic acids and their alkali metal and alkaline earth metal salts 失效
标题翻译：酰氧基苯磺酸及其碱金属和碱土金属盐的制备
公开(公告)号：US4695412A
公开(公告)日：1987-09-22
申请号：US933354
申请日：1986-11-19
申请人： Wolf-Dieter Balzer , Hans-Heinrich Bechtolsheimer , Karl-Heinz Beyer , Rolf Fikentscher , Johannes Perner , Rudi Widder , Helmut Wolf
发明人： Wolf-Dieter Balzer , Hans-Heinrich Bechtolsheimer , Karl-Heinz Beyer , Rolf Fikentscher , Johannes Perner , Rudi Widder , Helmut Wolf
IPC分类号： C07C309/42 , C07C67/00 , C07C301/00 , C07C303/06 , C07C303/08 , C07C303/22 , C07C303/32 , C07C143/52
CPC分类号： C07C309/00
摘要： Acyloxybenzenesulfonic acids and their alkali metal and alkaline earth metal salts are prepared by a process comprising sulfonation of a phenyl ester in the presence or absence of a small amount of a complexing agent for the sulfonating agent SO.sub.3 or chlorosulfonic acid, subsequent acylation and, if desired, neutralization to give the alkali metal or alkaline earth metal salt, and, if required, subjecting the latter to oxidative bleaching before drying.
摘要翻译：芳氧基苯磺酸及其碱金属和碱土金属盐通过包括在存在或不存在少量用于磺化剂SO 3或氯磺酸的络合剂的情况下苯基酯磺化的方法制备，随后进行酰化，如果需要中和，得到碱金属或碱土金属盐，如果需要，在干燥前对其进行氧化漂白。

7. 发明授权

US3981987A Hair setting compositions containing easily removable neutralized copolymers 失效
标题翻译：包含容易去除的中和的共聚物的固化组合物
公开(公告)号：US3981987A
公开(公告)日：1976-09-21
申请号：US539417
申请日：1975-01-08
申请人： Wolfgang Linke , Karl Herrle , Wolfgang Schwarz , Johannes Perner
发明人： Wolfgang Linke , Karl Herrle , Wolfgang Schwarz , Johannes Perner
IPC分类号： A61K8/81 , A61Q5/06 , A61K7/11
CPC分类号： A61K8/8164 , A61Q5/06 , Y10S424/01 , Y10S424/02
摘要： Copolymers obtained by copolymerization of vinyl esters of aliphatic carboxylic acids and/or acrylic or methacrylic acid esters of aliphatic alcohols, with half-esters of ethylenically unsaturated dibasic carboxylic acids, followed by neutralization with bases, are used in hair setting compositions.
摘要翻译：通过将脂族羧酸的乙烯基酯和/或脂族醇的丙烯酸或甲基丙烯酸酯与烯键式不饱和二元羧酸的半酯共聚合得到的共聚物，随后用碱中和，用于头发定型组合物中。

8. 发明授权

US06855762B1 Method for producing water soluble polymer of esters from ethylenically unsaturated carboxylic acids and polyalkylene glycols 有权
标题翻译：从烯键式不饱和羧酸和聚亚烷基二醇生产酯的水溶性聚合物的方法
公开(公告)号：US06855762B1
公开(公告)日：2005-02-15
申请号：US10130611
申请日：2000-11-16
申请人： Matthias Kroner , Karl-Heinz Büchner , Johannes Perner , Hans-Jürgen Raubenheimer , Dieter Faul
发明人： Matthias Kroner , Karl-Heinz Büchner , Johannes Perner , Hans-Jürgen Raubenheimer , Dieter Faul
IPC分类号： C08F2/06 , C08F8/44 , C08F220/28 , C08F290/06 , C08F290/14 , C08G65/332 , C08L71/02 , C08L33/00
CPC分类号： C08G65/3322 , C08F8/44 , C08F290/06 , C08F290/061 , C08F290/14 , C08L71/02 , C08F290/00 , C08L2666/04
摘要： A process for the preparation of water-soluble polymers of esters of ethylenically unsaturated carboxylic acids and polyalkylene glycols by azeotropic esterification, in the presence of organic solvents which form an azeotrope with water, of ethylenically unsaturated carboxylic acids with polyalkylene oxides which are capped at one end by end groups, to a degree of at least 85 wt %, followed by free-radical polymerization of the resulting esters optionally together with other ethylenically unsaturated monomers, in aqueous medium, wherein the organic solvents are removed by azeotropic distillation from the reaction mixture during polymerization and the water that is removed by distillation is recycled or the quantity of water removed by distillation from the reaction mixture is replaced by a feed of fresh water.
摘要翻译：烯键式不饱和羧酸与聚亚烷基二醇的水溶性聚合物的制备方法，在有机溶剂与水形成共沸物的情况下通过共沸酯化制备烯键式不饱和羧酸与聚合环氧烷封端的聚烯烃末端以达到至少85重量％的程度，然后将所得酯任选地与其它烯属不饱和单体一起在水性介质中进行自由基聚合，其中通过共沸蒸馏从反应混合物中除去有机溶剂并且通过蒸馏除去的水被再循环，或者通过蒸馏从反应混合物中除去的水量被淡水的进料代替。

9. 发明授权

US06846882B2 Method for modifying acid group containing polymers 有权
标题翻译：改性含酸基聚合物的方法
公开(公告)号：US06846882B2
公开(公告)日：2005-01-25
申请号：US10239053
申请日：2001-03-27
申请人： Matthias Kroner , Johannes Perner , Karl-Heinz Büchner , Jochen Wild , Jürgen Pfister
发明人： Matthias Kroner , Johannes Perner , Karl-Heinz Büchner , Jochen Wild , Jürgen Pfister
IPC分类号： C08G81/02 , C04B24/26 , C08F8/14 , C08F8/30
CPC分类号： C04B24/2658 , C04B2103/408 , C08G81/025
摘要： Polymers containing acid groups are modified by reaction of (a) polymers which comprise at least 5% by weight of a copolymerized monoethylenically unsaturated monomer containing acid groups, have molar masses of from 200 to 100,000 and are obtainable by free-radical polymerization of monoethylenically unsaturated acids in aqueous solution in the presence or absence of other monoethylenically unsaturated monomers and in the presence of at least 4% by weight, based on the monomers used in the polymerization, of a water-soluble sulfur compound in which the sulfur is in the oxidation state +4, with (b) polyalkylene glycols which are end-capped at one end, alkylpolyalkylene glycol amines or mixtures thereof, or mixtures of at least one of the two compounds specified with up to 30% by weight, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acids at up to 250° C.
摘要翻译：含有酸基的聚合物通过（a）包含至少5重量％的含酸基团的共聚单烯属不饱和单体的聚合物的反应进行改性，摩尔质量为200至100,000，可通过单烯键不饱和的自由基聚合获得在存在或不存在其它单烯键式不饱和单体的情况下，在基于聚合中使用的单体的至少4重量％存在下，在水溶液中的硫在其中氧化的水溶性硫化合物状态+4，其中（b）在一端被封端的聚亚烷基二醇，烷基聚亚烷基二醇胺或其混合物，或基于混合物，至多30重量％指定的两种化合物中的至少一种的混合物，的氨，胺，醇，羟基羧酸或至多250℃的氨基羧酸

10. 发明授权

US5766612A Use of endgroup-capped fatty amide alkoxylates 失效
标题翻译：使用端基封端的脂肪酰胺烷氧基化物
公开(公告)号：US5766612A
公开(公告)日：1998-06-16
申请号：US632436
申请日：1996-04-22
申请人： Beate Strecker , Gunter Oetter , Alfred Oftring , Johannes Perner , Richard Baur , Volker Schwendemann , Martin aus dem Kahmen , Wolfgang Reif
发明人： Beate Strecker , Gunter Oetter , Alfred Oftring , Johannes Perner , Richard Baur , Volker Schwendemann , Martin aus dem Kahmen , Wolfgang Reif
IPC分类号： C11D1/72 , A01N25/30 , A61K47/18 , B01F17/00 , B01F17/42 , C07C231/02 , C07C233/18 , C07C233/20 , C09D17/00 , C09K8/035 , C09K8/28 , C11D1/52 , C23G5/00
CPC分类号： A61K8/45 , A01N25/30 , A61K47/18 , B01F17/0042 , C07C233/18 , C07C233/20 , C09D17/00 , C09K8/035 , C09K8/28 , C11D1/526 , A61Q19/10 , A61Q5/02
摘要： The use of endgroup-capped fatty amide alkoxylates I R.sup.1 --CO--NH--(CH.sub.2).sub.n --O--(AO).sub.x --R.sup.2(I) where R.sup.1 is C.sub.5 -C.sub.21 -alkyl or -alkenyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl, A is C.sub.2 -C.sub.4 -alkylene, n is 2 or 3, and x has a value from 1 to 6, as nonionic surfactants or emulsifiers in detergents, cleaners or body care compositions, as surface-active substances for industrial applications in electroplating, in the photographic industry, in petroleum production, in the pharmaceutical industry, in plant feeding and in crop protection formulations, and as surface-active substances in the production of emulsions and pigment and plastic dispersions.
摘要翻译： PCT No.PCT / EP94 / 03354 Sec。 371日期：1996年4月22日 102（e）日期1996年4月22日PCT 1994年10月12日PCT PCT。出版物WO95 / 11225 日期1995年04月27日使用端基封端的脂肪酰胺烷氧基化物IR1-CO-NH-（CH2）nO-（AO）x-R2（I）其中R1是C5-C21-烷基或 - 烯基，R2是C1- C 4 - 烷基，A为C 2 -C 4亚烷基，n为2或3，x为1至6的值，作为洗涤剂，清洁剂或身体护理组合物中的非离子表面活性剂或乳化剂，作为工业应用的表面活性物质在电镀，照相工业，石油生产，制药工业，植物饲料和作物保护制剂中，以及作为生产乳液和颜料和塑料分散体的表面活性物质。

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