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1. 发明授权

US5596053A High trans-1,4-polybutadiene and catalyst and process for preparing crystalline high trans-1,4-poly-butadiene 失效
标题翻译：高反式1,4-聚丁二烯及其催化剂及制备结晶高反式1,4-聚丁二烯的方法
公开(公告)号：US5596053A
公开(公告)日：1997-01-21
申请号：US455772
申请日：1995-05-31
申请人： Jung W. Kang , Jason T. Poulton
发明人： Jung W. Kang , Jason T. Poulton
IPC分类号： C08F4/70 , C08F136/06
CPC分类号： C08F4/7098 , C08F136/06
摘要： Diene polymers having a high content of trans-1,4 addition and two distinct melting points in the ranges of 30.degree. C. to 50.degree. C. and 70.degree. C. to 130.degree. C. are prepared by polymerizing a 1,3-diene monomer in a hydrocarbon solvent in the presence of a catalyst composition comprising (a) a carboxylated nickel oxy borate compound; (b) an orKanoaluminum compound; (c) a triaryloxy phosphorus compound and (d) a carboxylic acid preferably a fluorinated carboxylic acid. The resultant polymers are useful as additives to tire rubbers to improve processability by reducing compound Mooney viscosity and reducing the shrinkage of various compound stocks.
摘要翻译：具有高反式-1,4-加成含量的二烯聚合物和30℃至50℃和70℃至130℃范围内的两个不同的熔点通过聚合1,3-二二烯单体在烃溶剂中，在催化剂组合物存在下，包含（a）羧化的含硼酸镍化合物; （b）一种或二种铝化合物; （c）三芳氧基磷化合物和（d）羧酸，优选氟化羧酸。所得到的聚合物可用作轮胎橡胶的添加剂，以通过降低化合物门尼粘度和降低各种化合物料的收缩来提高加工性能。

2. 发明授权

US06329459B1 Extended syndiotactic polystyrene-elastomeric block copolymers 失效
标题翻译：扩展的间同立构聚苯乙烯弹性体嵌段共聚物
公开(公告)号：US06329459B1
公开(公告)日：2001-12-11
申请号：US08710829
申请日：1996-09-23
申请人： Jung W. Kang , Xiaorong Wang , Xiao-Liang Luo , Frank J. Clark , Jason T. Poulton , Takahiro Matsuse , Naruhiko Mashita , Hideo Takeichi , Shinichi Toyosawa
发明人： Jung W. Kang , Xiaorong Wang , Xiao-Liang Luo , Frank J. Clark , Jason T. Poulton , Takahiro Matsuse , Naruhiko Mashita , Hideo Takeichi , Shinichi Toyosawa
IPC分类号： C08J300
CPC分类号： C08L53/00 , C08F297/04 , C08L53/02 , C08L53/025 , C08L2666/02 , C08L2666/24
摘要： There are disclosed a block copolymer of at least one elastomeric block and at least one syndiotactic polystyrene block which comprises 100 parts by weight of a polymer component comprising 1 to 80% by weight of syndiotactic polystyrene (sPS) block(s) and 99 to 20% by weight of rubbery elastomeric block(s) and at least 30 parts by weight of an extender. These extended block copolymer compositions display the characteristics of thermoplastic elastomers and are useful for high temperature applications possessing unique softness.
摘要翻译：公开了至少一种弹性体嵌段和至少一个间同立构聚苯乙烯嵌段的嵌段共聚物，其包含100重量份的包含1至80重量％的间同立构聚苯乙烯（sPS）嵌段和99至20重量份的聚合物组分重量％的橡胶弹性体块和至少30重量份的增量剂。这些延伸的嵌段共聚物组合物显示出热塑性弹性体的特性，并且对于具有独特柔软性的高温应用是有用的。

3. 发明授权

US6017985A Hydrosilated crystalline high trans polybutadine with silica filler, tires having a base of said composition and method of preparing same 失效
标题翻译：具有二氧化硅填料的水溶液结晶高反式聚丁二烯，具有所述组合物的碱的轮胎及其制备方法
公开(公告)号：US6017985A
公开(公告)日：2000-01-25
申请号：US845130
申请日：1997-04-21
申请人： Jung W. Kang , Jason T. Poulton , Takashi Kitamura
发明人： Jung W. Kang , Jason T. Poulton , Takashi Kitamura
IPC分类号： B60C1/00 , C08C19/25 , C08K3/36 , C08L9/00 , C08L21/00 , C08K5/32
CPC分类号： C08C19/25 , C08L21/00
摘要： Novel silicon-containing derivatives of crystalline, high-trans-1,4 polybutadiene in which organosilicon-containing groups are bonded to the 1,2-vinyl carbon atoms along the main chain of the butadiene polymers through the carbon-silicon linkages. These derivatives of butadiene polymers are produced by the addition reaction of an organosilicon-compound having one hydrogen atom directly bonded to the silicon atom in the molecule to the double bonds in the 1,2-vinyl group butadiene polymers. These derivatives having good compatibility with siliceous fillers and when blended with filled diene rubbers are cured to elastomer compositions having excellent properties suitable for the production of tires.
摘要翻译：含有有机硅基团的结晶高反式-1,4-聚丁二烯的新型含硅衍生物通过碳 - 硅键连接到沿丁二烯聚合物主链的1,2-乙烯基碳原子上。这些丁二烯聚合物的衍生物是通过将具有一个氢原子的有机硅化合物与分子中的硅原子直接键合到1,2-乙烯基类丁二烯聚合物中的双键而进行的。这些具有与硅质填料相容性良好且与填充的二烯橡胶共混的衍生物固化成具有优良性能的适用于轮胎生产的弹性体组合物。

4. 发明授权

US5580930A Rubber composition for tires 失效
标题翻译：轮胎橡胶组合物
公开(公告)号：US5580930A
公开(公告)日：1996-12-03
申请号：US470559
申请日：1995-06-06
申请人： Jung W. Kang , Thomas J. Lynch , Jason T. Poulton
发明人： Jung W. Kang , Thomas J. Lynch , Jason T. Poulton
IPC分类号： B60C1/00 , C08F136/06 , C08L9/00 , C08L21/00 , C08L9/06 , C08L7/00 , C08L47/00
CPC分类号： C08L7/00 , C08L9/00 , C08L9/06 , C08L2205/02 , Y10T152/10
摘要： Diene polymers having a high content of trans-1,4 addition and two distinct melting points in the ranges of 30.degree. C. to 60.degree. C. and 70.degree. C. to 130.degree. C. are useful as additives to tire rubbers to improve processability by reducing compound Mooney viscosity and reducing the shrinkage of various compound stocks.
摘要翻译：在30℃至60℃和70℃至130℃范围内具有高反式-1,4-加成量和两个不同熔点的二烯聚合物可用作轮胎橡胶的添加剂以改善通过降低复合门尼粘度和减少各种复合材料的收缩来提高加工性能。

5. 发明授权

US08372925B2 Nickel-based catalyst composition 有权
标题翻译：镍基催化剂组成
公开(公告)号：US08372925B2
公开(公告)日：2013-02-12
申请号：US12098825
申请日：2008-04-07
申请人： Zengquan Qin , Jason T. Poulton , David M. Roggeman , Shigeaki Matsuo
发明人： Zengquan Qin , Jason T. Poulton , David M. Roggeman , Shigeaki Matsuo
IPC分类号： C08F4/14 , C08F4/52
CPC分类号： C08F136/06 , C08F36/04 , C08F236/06 , C08F4/7098
摘要： In general the present invention provides a process for forming conjugated diene polymer, the process comprising the step of polymerizing conjugated diene monomer in the presence of a catalytically effective amount of a catalyst composition formed by combining (a) a nickel-containing compound, (b) an alkylating agent, (c) a fluorine-containing compound, (d) a carboxylic acid, and (e) an alcohol.
摘要翻译：通常本发明提供一种形成共轭二烯聚合物的方法，该方法包括在催化有效量的催化剂组合物的存在下，使（C）含镍化合物（b））烷基化剂，（c）含氟化合物，（d）羧酸和（e）醇。

6. 发明申请

US20100160542A1 HYBRID POLYMER AND METHOD FOR MAKING 有权
标题翻译：混合聚合物和制备方法
公开(公告)号：US20100160542A1
公开(公告)日：2010-06-24
申请号：US12519549
申请日：2007-12-17
申请人： Jason T. Poulton , Yan Yuan-Yong , Wang Hao
发明人： Jason T. Poulton , Yan Yuan-Yong , Wang Hao
IPC分类号： C08G77/00 , C08L83/00
CPC分类号： C08C19/44 , C08K3/013 , C08L15/00
摘要： A macromolecule includes a polymer directly tethered or bonded to a polyatomic functionality. The polyatomic functionality can be located at a terminus of the polymer and can be generated concurrent with or soon after formation of the polymer. The macro-molecule can be prepared from a functionalized polymer by hydrolyzing and condensing (e.g., by a sol-gel process) functionalities in which one or more alkoxy groups are bound to a silica atom in the presence of an excess of a compound that includes a Si, Ti, Zr, Sn, Al, or Fe atom. Such macromolecules can be used in the manufacture of vulcanizates and tire components, either alone or blended with other polymers and/or other particulate fillers.
摘要翻译：大分子包括直接键合或键合到多原子官能团的聚合物。多原子官能团可以位于聚合物的末端，并且可以在聚合物形成之后或之后同时产生。大分子可以通过水解和缩合（例如，通过溶胶 - 凝胶法）官能化的聚合物制备，其中一个或多个烷氧基在过量的化合物的存在下与二氧化硅原子结合，所述化合物包括 Si，Ti，Zr，Sn，Al或Fe原子。这种大分子可以单独使用或与其它聚合物和/或其它颗粒填料共混制成硫化橡胶和轮胎组分。

7. 发明申请

US20080255327A1 NICKEL-BASED CATALYST COMPOSITION 有权
标题翻译：镍基催化剂组合物
公开(公告)号：US20080255327A1
公开(公告)日：2008-10-16
申请号：US12098825
申请日：2008-04-07
申请人： Zenquan Qin , Jason T. Poulton , David M. Roggeman , Shigeaki Matsuo
发明人： Zenquan Qin , Jason T. Poulton , David M. Roggeman , Shigeaki Matsuo
IPC分类号： C08F4/42 , C08F4/06 , B01J31/04
CPC分类号： C08F136/06 , C08F36/04 , C08F236/06 , C08F4/7098
摘要： In general the present invention provides a process for forming conjugated diene polymer, the process comprising the step of polymerizing conjugated diene monomer in the presence of a catalytically effective amount of a catalyst composition formed by combining (a) a nickel-containing compound, (b) an alkylating agent, (c) a fluorine-containing compound, (d) a carboxylic acid, and (e) an alcohol.
摘要翻译：通常本发明提供一种形成共轭二烯聚合物的方法，该方法包括在催化有效量的催化剂组合物的存在下，使（C）含镍化合物（b））烷基化剂，（c）含氟化合物，（d）羧酸和（e）醇。

8. 发明授权

US08623975B2 Process for producing polydienes 有权
标题翻译：聚二烯生产工艺
公开(公告)号：US08623975B2
公开(公告)日：2014-01-07
申请号：US13380938
申请日：2010-06-24
申请人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
发明人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
IPC分类号： C08F4/44 , C08F2/00
CPC分类号： C08F36/04 , C08L9/00 , C08F4/545 , C08F2/06
摘要： A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.
摘要翻译：一种制备聚二烯的方法，该方法包括在二烃基醚存在下聚合共轭二烯单体的步骤，其中所述聚合步骤在聚合混合物内进行，所述聚合混合物包含基于所述二烯烃醚的少于20重量％的有机溶剂聚合混合物的总重量，并且在所述聚合步骤中使用镧系元素的催化剂体系，其包括（a）镧系元素化合物，（b）铝氧烷，（c）有机铝化合物除了铝氧烷外，还有（d）选自元素溴，含溴混合卤素和有机溴化物的含溴化合物。

9. 发明授权

US08541509B2 Polymers functionalized with protected oxime compounds 有权
标题翻译：用保护的肟化合物官能化的聚合物
公开(公告)号：US08541509B2
公开(公告)日：2013-09-24
申请号：US13309958
申请日：2011-12-02
申请人： Steven Luo , Yuan-Yong Yan , Jason T. Poulton , Eiju Suzuki
发明人： Steven Luo , Yuan-Yong Yan , Jason T. Poulton , Eiju Suzuki
IPC分类号： C08F4/12 , C08F4/52 , C08F36/04 , C08C19/22 , C08C4/00
CPC分类号： C08C19/44 , C08L9/00 , C08L19/006 , C08L2666/08
摘要： A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing conjugated diene monomer by employing a lanthanide-based catalyst to form a reactive polymer, and (ii) reacting the reactive polymer with a protected oxime compound.
摘要翻译：一种制备官能化聚合物的方法，所述方法包括以下步骤：（i）通过使用镧系元素基催化剂聚合共轭二烯单体以形成反应性聚合物，和（ii）使反应性聚合物与受保护的肟化合物反应。

10. 发明申请

US20120172553A1 Process For Producing Polydienes 有权
标题翻译：生产聚二烯的方法
公开(公告)号：US20120172553A1
公开(公告)日：2012-07-05
申请号：US13380938
申请日：2010-06-24
申请人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
发明人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
IPC分类号： C08F2/06
CPC分类号： C08F36/04 , C08L9/00 , C08F4/545 , C08F2/06
摘要： A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.
摘要翻译：一种制备聚二烯的方法，该方法包括在二烃基醚存在下聚合共轭二烯单体的步骤，其中所述聚合步骤在聚合混合物内进行，所述聚合混合物包含基于所述二烯烃醚的少于20重量％的有机溶剂聚合混合物的总重量，并且在所述聚合步骤中使用镧系元素的催化剂体系，其包括（a）镧系元素化合物，（b）铝氧烷，（c）有机铝化合物除了铝氧烷外，还有（d）选自元素溴，含溴混合卤素和有机溴化物的含溴化合物。

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