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    • 9. 发明授权
    • Method for detecting oxygen partial pressure using a
phase-transformation sensor
    • 使用相变传感器检测氧分压的方法
    • US5942674A
    • 1999-08-24
    • US906237
    • 1997-08-04
    • Eleftherios Miltiadis LogothetisRichard E. Soltis
    • Eleftherios Miltiadis LogothetisRichard E. Soltis
    • G01N27/12G01N27/416
    • G01N27/12Y10T436/208339
    • The invention is a sensing method and an oxygen sensor for detecting a change of oxygen partial pressure in an ambient atmosphere through a change of a measurable physical property of a sensing material. The sensor includes a sensing material selected from metal or its oxides which, when at an elevated temperature and exposed to a gas containing a changing partial pressures of oxygen, is capable of changing from one metal or metal oxide phase to another such oxide phase and vice versa. Associated with such phase change is a change in a measurable physical property of the material. The sensor also includes heating means, connectable to a power source, maintaining a temperature gradient across the sensing material since it is critical that the sensing material exist in at least two phases during active sensing. An output signal is furnished in response to the change in a physical property, like electrical resistance, of a portion of or of the entire material in response to change in oxygen partial pressure.
    • 本发明是一种感测方法和氧传感器,用于通过改变感测材料的可测量物理特性来检测环境大气中氧分压的变化。 传感器包括选自金属或其氧化物的感测材料,当处于升高的温度并暴露于含有氧的分压变化的气体时,能够从一个金属或金属氧化物相变为另一个这样的氧化物相和副 反之亦然。 与这种相变有关的是材料的可测量物理性质的变化。 传感器还包括可连接到电源的加热装置,保持感测材料两端的温度梯度,因为传感材料在主动感测期间至少存在两相是至关重要的。 输出信号响应于氧分压变化而响应于物料的一部分或整个材料的物理性能(如电阻)的变化而提供。
    • 10. 发明授权
    • Method for detecting change in oxygen partial pressure based on
metal/metal oxide phase transformations
    • 用于检测基于金属/金属氧化物相变的氧分压变化的方法
    • US5798269A
    • 1998-08-25
    • US905662
    • 1997-08-04
    • Eleftherios Miltiadis LogothetisRichard E. Soltis
    • Eleftherios Miltiadis LogothetisRichard E. Soltis
    • G01N27/12
    • G01N27/12Y10T436/207497Y10T436/208339
    • The invention is a sensing method and an oxygen sensor for detecting a change of oxygen partial pressure in an ambient atmosphere. The sensor includes a sensing material selected from metal or its oxides which, when at an elevated temperature and exposed to a gas containing E a changing partial pressures of oxygen, is capable of changing from one metal or metal oxide phase to another such oxide phase and vice versa. Associated with such phase change is a change in a measurable physical property of the material. Heating elements, connectable to a power source, able to maintain a temperature gradient across said sensing material are necessary to maintain the material, during active sensing operation, in at least two of the phases defining a boundary line therebetween which is generally perpendicular to the longitudinal axis of the temperature gradient. The boundary line traverses longitudinally along the axis in response to changes in the oxygen partial pressure of the ambient atmosphere to which the sensing material is exposed. The sensor also includes a device for furnishing an output signal in response to the traversal of the boundary line across a fixed detecting location of the sensing material. Hence, the invention senses the passage of the boundary line at some specific location in the material to detect a specific P.sub.02,c.
    • 本发明是用于检测环境大气中的氧分压变化的感测方法和氧传感器。 传感器包括选自金属或其氧化物的感测材料,当在高温下暴露于含有氧的变化分压的气体时,能够从一个金属或金属氧化物相变为另一个这样的氧化物相,并且 反之亦然。 与这种相变有关的是材料的可测量物理性质的变化。 可连接到电源的加热元件能够保持穿过所述检测材料的温度梯度是必要的,以在主动感测操作期间在限定其间的边界线的至少两个相中保持材料,其中所述界限通常垂直于纵向 轴的温度梯度。 响应于感测材料暴露于的环境大气的氧分压的变化,边界线沿轴线纵向移动。 传感器还包括用于响应于穿过感测材料的固定检测位置的边界线的遍历而提供输出信号的装置。 因此,本发明感测在材料中的某个特定位置处的边界线的通过以检测特定的P02,c。