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1. 发明申请

US20120010376A1 Multi-Component Catalyst Systems and Polymerization Processes for Forming Broad Composition Distribution Polymers 有权
公开(公告)号：US20120010376A1
公开(公告)日：2012-01-12
申请号：US12832237
申请日：2010-07-08
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/76 , C08F4/42
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.

2. 发明申请

US20120264894A1 Multi-Component Catalyst Systems and Polymerization Processes for Forming Broad Composition Distribution Polymers 有权
标题翻译：多组分催化剂体系和用于形成广泛组分分布聚合物的聚合方法
公开(公告)号：US20120264894A1
公开(公告)日：2012-10-18
申请号：US13525443
申请日：2012-06-18
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/76 , C08F210/06
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.
摘要翻译：本文描述了丙烯聚合方法，由其形成的聚合物和膜。丙烯聚合方法通常包括在聚合反应容器内将丙烯和一定量的乙烯与第一茂金属催化剂和第二茂金属催化剂接触以形成丙烯基聚合物，其中该量是有效形成基于丙烯的聚合物的量，包括约2重量％％至约6wt。％乙烯，第二茂金属催化剂能够比第一茂金属催化剂在丙烯基聚合物中引入更多量的乙烯，并且其中第一茂金属催化剂能够形成丙烯/乙烯无规共聚物，其表现出大于由第二茂金属催化剂形成的丙烯/乙烯无规共聚物。

3. 发明授权

US08278403B2 Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers 有权
标题翻译：多组分催化剂体系和用于形成宽分子量聚合物的聚合方法
公开(公告)号：US08278403B2
公开(公告)日：2012-10-02
申请号：US12832237
申请日：2010-07-08
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/60 , C08F4/603 , C08F4/606 , C08F4/6592 , C08L23/00 , B01J31/22
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.
摘要翻译：本文描述了丙烯聚合方法，由其形成的聚合物和膜。丙烯聚合方法通常包括在聚合反应容器内将丙烯和一定量的乙烯与第一茂金属催化剂和第二茂金属催化剂接触以形成丙烯基聚合物，其中该量是有效形成基于丙烯的聚合物的量，包括约2重量％％至约6wt。％乙烯，第二茂金属催化剂能够比第一茂金属催化剂在丙烯基聚合物中引入更多量的乙烯，并且其中第一茂金属催化剂能够形成丙烯/乙烯无规共聚物，其表现出大于由第二茂金属催化剂形成的丙烯/乙烯无规共聚物。

4. 发明授权

US08461276B2 Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers 有权
标题翻译：多组分催化剂体系和用于形成宽分子量聚合物的聚合方法
公开(公告)号：US08461276B2
公开(公告)日：2013-06-11
申请号：US13525443
申请日：2012-06-18
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/6592 , C08F4/60 , C08F4/603 , C08F4/606 , C08F4/653
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.
摘要翻译：本文描述了丙烯聚合方法，由其形成的聚合物和膜。丙烯聚合方法通常包括在聚合反应容器内将丙烯和一定量的乙烯与第一茂金属催化剂和第二茂金属催化剂接触以形成丙烯基聚合物，其中该量是有效形成基于丙烯的聚合物的量，包括约2重量％％至约6wt。％乙烯，第二茂金属催化剂能够比第一茂金属催化剂在丙烯基聚合物中引入更多量的乙烯，并且其中第一茂金属催化剂能够形成丙烯/乙烯无规共聚物，其表现出大于由第二茂金属催化剂形成的丙烯/乙烯无规共聚物。

5. 发明申请

US20050234198A1 Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system 审中-公开
标题翻译：异相共聚物和茂金属催化剂体系及使用茂金属催化剂体系生产多相共聚物的方法
公开(公告)号：US20050234198A1
公开(公告)日：2005-10-20
申请号：US10827959
申请日：2004-04-20
申请人： Jun Tian , William Gauthier , Kenneth Blackmon , David Rauscher
发明人： Jun Tian , William Gauthier , Kenneth Blackmon , David Rauscher
IPC分类号： A61B5/05 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F10/00 , C08F10/06 , C08F210/16 , C08L23/12 , C08L23/16
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F10/06 , C08F210/16 , C08L23/12 , C08L23/16 , C08L2207/02 , C08L2314/06 , C08F4/65916 , C08L2666/06 , C08F2/001 , C08F210/06 , C08F2500/12 , C08F2500/13 , C08F2500/05
摘要： Disclosed is a heterophasic polymer having a flowability over a broad range of xylene solubles content of the heterophasic polymer, a metallocene catalyst system (MCS) for producing such heterophasic polymer, and a method of producing such heterophasic polymer using the metallocene catalyst system. The MCS includes a support and a metallocene bound substantially throughout the support.
摘要翻译：公开了具有在多相聚合物的二甲苯可溶物含量的宽范围内的流动性的多相聚合物，用于生产这种多相聚合物的茂金属催化剂体系（MCS），以及使用茂金属催化剂体系制备这种多相聚合物的方法。 MCS包括基本上在整个载体上结合的载体和茂金属。

6. 发明申请

US20080287619A1 Supported metallocene catalysts 审中-公开
标题翻译：负载金属茂催化剂
公开(公告)号：US20080287619A1
公开(公告)日：2008-11-20
申请号：US11804483
申请日：2007-05-18
申请人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
发明人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
IPC分类号： B01J31/14 , C08F4/46
CPC分类号： C08F210/16 , B01J31/143 , B01J31/2295 , B01J2231/122 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F210/06 , C08F4/65916 , C08F2500/15 , C08F2500/12
摘要： Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m 2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′ are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
摘要翻译：在制备全同立构乙烯丙烯共聚物中使用负载型茂金属催化剂组合物的方法。组合物包含负载在平均粒度为10-40微米，孔体积为1.3-1.6毫升/克，表面积为200-400平方米/克的粒状二氧化硅载体上的金属茂组分。在载体上加入烷基铝氧烷助催化剂组分。特殊的茂金属的特征在于以下公式：<？in-line-formula description =“In-line formula”end =“lead”？> B（CpRaRb）（FlR'2 > n （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>或通过公式：<？in-line-formula description =“在线公式 “end =”lead“？> B'（Cp'R'aR'b）（Fl'）M'Q'N'（2）<？in-line-formula description =”In 在式中，Cp和Cp'是取代的环戊二烯基，Fl和Fl'是芴基，B和B'是结构桥。 R'是2和7位的取代基，Ra和R'a是桥的远端的取代基，Rb和R'b靠近桥。 M和M'是过渡金属，Q'是卤素或C 1 -C 4 -C 4烷基; 并且n'是0-4的整数。

7. 发明授权

US08436112B2 Polyolefin production with a high performance support for a metallocene catalyst system 有权
标题翻译：聚烯烃生产具有高性能支持的茂金属催化剂体系
公开(公告)号：US08436112B2
公开(公告)日：2013-05-07
申请号：US12013774
申请日：2008-01-14
申请人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
发明人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
IPC分类号： C08F4/52 , C08F4/64 , C08F4/76
CPC分类号： C08F4/76 , C08F4/65912 , C08F4/65927 , C08F10/00 , Y10T428/2982 , C08F4/65916 , C08F110/06 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F2500/15
摘要： The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.
摘要翻译：本发明涉及一种茂金属催化剂体系，其包含惰性二氧化硅载体，其具有在孔直径约250埃至约350埃之间具有大于约0.115mL / g的峰孔体积的孔，以及铝氧烷活化剂与茂金属在整个支撑体上大体上被束缚。将活化剂在甲苯的回流温度下在溶剂中接枝到载体上，得到二氧化硅上的铝氧烷，并加入金属茂组分以制备茂金属负载量为约2重量％的MCS。这促进了催化活性增加的茂金属催化剂体系的生产，其催化活性比之前所公认的高约1％（重量），其中活化剂在室温下接枝到载体上的金属茂负载量的催化活性高至少约20％。

8. 发明申请

US20060247395A1 Process for increasing ethylene incorporation into random copolymers 有权
标题翻译：增加乙烯掺入无规共聚物的方法
公开(公告)号：US20060247395A1
公开(公告)日：2006-11-02
申请号：US11119243
申请日：2005-04-29
申请人： William Gauthier , Jun Tian , David Rauscher , Constance Patrick , Shady Henry , Nathan Williams
发明人： William Gauthier , Jun Tian , David Rauscher , Constance Patrick , Shady Henry , Nathan Williams
IPC分类号： C08F2/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F2500/03 , C08F2500/20 , C08F4/65927
摘要： A process for preparing low melting copolymers comprising contacting a mixture of olefin monomers with a CpFlu-type metallocene catalyst under reaction conditions sufficient to form a copolymer. The copolymers thus prepared desirably display melt temperatures from about 100° C. to about 140° C. and may be produced with reduced amounts of ethylene. The copolymers may also exhibit reduced levels of undesirable xylene solubles, relatively narrow molecular weight distribution, and other improved optical and physical properties.
摘要翻译：一种制备低熔点共聚物的方法，包括使烯烃单体的混合物与CpFlu型金属茂催化剂在足以形成共聚物的反应条件下接触。如此制备的共聚物理想地显示约100℃至约140℃的熔融温度，并且可以用减少量的乙烯制备。共聚物也可以表现出不希望的二甲苯可溶物的水平降低，分子量分布相对窄，以及其他改进的光学和物理性能。

9. 发明授权

US08299188B2 Supported metallocene catalysts 有权
标题翻译：负载金属茂催化剂
公开(公告)号：US08299188B2
公开(公告)日：2012-10-30
申请号：US12882268
申请日：2010-09-15
申请人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
发明人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
IPC分类号： C08F4/6592 , C08F4/642 , C08F210/02 , C08F210/06 , B01J31/22
CPC分类号： C08F210/06 , B01J31/143 , B01J31/2295 , B01J2231/122 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F4/65916 , C08F2500/15 , C08F2500/12 , C08F2500/18
摘要： Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′ are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
摘要翻译：在制备全同立构乙烯丙烯共聚物中使用负载型茂金属催化剂组合物的方法。组合物包含负载在平均粒度为10-40微米，孔体积为1.3-1.6ml / g，表面积为200-400m2 / g的颗粒状二氧化硅载体上的金属茂组分。在载体上加入烷基铝氧烷助催化剂组分。特异性金属茂的特征是：B（CpRaRb）（FlR'2）MQn（1）或式：B'（Cp'R'aR'b）（Fl'）M'Q'n'（2 ）式中Cp和Cp'是取代的环戊二烯基，Fl和Fl'是芴基，B和B'是结构桥。 R'是2和7位的取代基，Ra和R'a是桥的远端的取代基，Rb和R'b靠近桥。 M和M'是过渡金属，Q'是卤素或C 1 -C 4烷基; 并且n'是0-4的整数。

10. 发明申请

US20080194399A1 Polyolefin Production with a High Performance Support for a Metallocene Catalyst System 有权
标题翻译：具有高性能支撑金属茂催化剂体系的聚烯烃生产
公开(公告)号：US20080194399A1
公开(公告)日：2008-08-14
申请号：US12013774
申请日：2008-01-14
申请人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
发明人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
IPC分类号： B01J31/00
CPC分类号： C08F4/76 , C08F4/65912 , C08F4/65927 , C08F10/00 , Y10T428/2982 , C08F4/65916 , C08F110/06 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F2500/15
摘要： The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.
摘要翻译：本发明涉及一种茂金属催化剂体系，其包含惰性二氧化硅载体，其具有在孔直径约250埃至约350埃之间具有大于约0.115mL / g的峰孔体积的孔，以及铝氧烷活化剂与茂金属在整个支撑体上大体上被束缚。将活化剂在甲苯的回流温度下在溶剂中接枝到载体上，得到二氧化硅上的铝氧烷，并加入金属茂组分以制备茂金属负载量为约2重量％的MCS。这促进了催化活性增加的茂金属催化剂体系的生产，其催化活性比之前所公认的高约1％（重量），其中活化剂在室温下接枝到载体上的金属茂负载量的催化活性高至少约20％。

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