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1. 发明授权

US4297325A Method of producing pseudoboehmite from aluminum salt solutions 失效
标题翻译：从铝盐溶液中制备假勃姆石的方法
公开(公告)号：US4297325A
公开(公告)日：1981-10-27
申请号：US214215
申请日：1980-12-08
申请人： Julius Scherzer , Anh-Thu Liu , Yih-Yau Sun
发明人： Julius Scherzer , Anh-Thu Liu , Yih-Yau Sun
IPC分类号： B01J21/04 , B01J29/08 , B01J37/00 , C01F7/26 , C01F7/34
CPC分类号： B01J29/08 , B01J21/04 , C01F7/26 , C01F7/34 , B01J2229/42 , B01J37/0045
摘要： The production process for pseudoboehmite from leach liquors produced in the acid treatment of clays, which liquors contain Fe and alkaline earth ions.
摘要翻译：在酸处理粘土中产生的浸出液中的假勃姆石的生产方法，该液体含有Fe和碱土离子。

2. 发明授权

US4332782A Method of producing pseudoboehmite 失效
标题翻译：制造假勃姆石的方法
公开(公告)号：US4332782A
公开(公告)日：1982-06-01
申请号：US173064
申请日：1980-07-28
申请人： Julius Scherzer , Anh-Thu Liu
发明人： Julius Scherzer , Anh-Thu Liu
IPC分类号： B01J21/04 , B01J29/04 , B01J29/08 , C01F7/34
CPC分类号： B01J21/04 , B01J29/04 , B01J29/088 , C01F7/34 , B01J2229/42 , C01P2006/12 , C01P2006/14 , C01P2006/16
摘要： A pseudoboehmite having properties suitable for incorporation into a matrix for a zeolite containing catalyst and the process for producing the same from an aluminum sulfate derived gel.
摘要翻译：具有适于掺入含沸石催化剂的基质中的性能的假勃姆石及其由硫酸铝衍生凝胶制备的方法。

3. 发明授权

US5298153A Cracking process using an attrition resistant catalyst 失效
标题翻译：使用耐磨耗催化剂的开裂过程
公开(公告)号：US5298153A
公开(公告)日：1994-03-29
申请号：US606180
申请日：1990-10-31
申请人： Julius Scherzer
发明人： Julius Scherzer
IPC分类号： B01J29/08 , C10G11/05 , C10G11/18
CPC分类号： B01J29/084 , C10G11/05 , B01J2229/42 , B01J37/0045
摘要： An attrition resistant catalytic cracking catalyst is prepared by spray drying an aqueous slurry containing a molecular sieve having cracking activity, a clay such as kaolin, a silica sol and aluminum chlorhydroxide. The resultant catalyst has a high attrition resistance as compared to commercially available cracking catalysts.
摘要翻译：通过喷雾干燥含有具有裂解活性的分子筛的水性浆料，高岭土等粘土，二氧化硅溶胶和氢氧化铝铝，制备耐磨耗催化裂化催化剂。与市售的裂化催化剂相比，所得催化剂具有高耐磨性。

4. 发明授权

US4880521A Process for the cracking of feedstocks containing high levels of nitrogen 失效
标题翻译：含有高含量氮气的原料开裂的方法
公开(公告)号：US4880521A
公开(公告)日：1989-11-14
申请号：US312625
申请日：1989-02-17
申请人： Julius Scherzer
发明人： Julius Scherzer
IPC分类号： B01J29/08 , C10G11/05
CPC分类号： B01J29/084 , C10G11/05
摘要： Hydrocarbon feedstocks containing relatively high levels of nitrogen contaminants are converted by catalytic cracking to products of lower average molecular weight by contacting the feedstock under cracking conditions with a cracking catalyst having a surface area of at least 150 m.sup.2 /gm and comprising greater than about 25 weight percent of a Y zeolite dispersed in a matrix containing a synthetic silica-alumina component in which the weight ratio of silica-to-alumina is preferably equal to or greater than about 0.10.
摘要翻译：含有相对高水平的氮污染物的烃原料通过催化裂解转化为具有较低平均分子量的产物，通过使裂化条件下的原料与表面积至少为150m 2 / gm并包含大于约25重量％的裂化催化剂接触分散在含有二氧化硅 - 氧化铝的重量比优选等于或大于约0.10的合成二氧化硅 - 氧化铝组分的基质中的Y沸石的百分比。

5. 发明授权

US4987110A Attrition resistant cracking catalyst 失效
标题翻译：耐磨裂化催化剂
公开(公告)号：US4987110A
公开(公告)日：1991-01-22
申请号：US359112
申请日：1989-05-31
申请人： Julius Scherzer
发明人： Julius Scherzer
IPC分类号： B01J29/08 , C10G11/05
CPC分类号： C10G11/05 , B01J29/084
摘要： An attrition resistant catalytic cracking catalyst is prepared by spray drying an aqueous slurry containing a molecular sieve having cracking activity, a clay such as kaolin, a silica sol and aluminum chlorhydroxide. The resultant catalyst has a high attrition resistance as compared to commercially available cracking catalysts.
摘要翻译：通过喷雾干燥含有具有裂解活性的分子筛的水性浆料，高岭土等粘土，二氧化硅溶胶和氢氧化铝铝，制备耐磨耗催化裂化催化剂。与市售的裂化催化剂相比，所得催化剂具有高耐磨性。

6. 发明授权

US4476239A Production of fluid catalytic cracking catalysts 失效
标题翻译：流化催化裂化催化剂的生产
公开(公告)号：US4476239A
公开(公告)日：1984-10-09
申请号：US491466
申请日：1983-05-04
申请人： Robert L. Chiang , Julius Scherzer
发明人： Robert L. Chiang , Julius Scherzer
IPC分类号： B01J29/08 , C10G11/05
CPC分类号： B01J29/084 , B01J29/088 , C10G11/05
摘要： Preparation of fluid catalytic cracking catalysts is improved by incorporating a viscosity-reducing agent, having the general formula of Al.sub.2 (OH).sub.5 NO.sub.3, in the aqueous slurry containing the catalyst components of zeolite, clay, aluminous binder, and a silica source, prior to drying of the slurry. The viscosity-reducing additive allows an increase in the solids content of the aqueous slurry and thus improves the efficiency of the drying operation.
摘要翻译：流化催化裂化催化剂的制备通过在含有沸石，粘土，铝粘合剂和二氧化硅源的催化剂组分的含水浆料中引入具有通式Al 2（OH）5 NO 3的粘度降低剂，在干燥浆料。降粘添加剂允许增加含水浆料的固体含量，从而提高干燥操作的效率。

7. 发明授权

US4443553A Production of fluid catalytic cracking catalysts 失效
标题翻译：流化催化裂化催化剂的生产
公开(公告)号：US4443553A
公开(公告)日：1984-04-17
申请号：US420439
申请日：1982-09-20
申请人： Robert L. Chiang , Julius Scherzer
发明人： Robert L. Chiang , Julius Scherzer
IPC分类号： B01J29/08 , B01J29/06
CPC分类号： B01J29/084
摘要： In the process of preparing fluid catalytic cracking catalysts where an aqueous slurry, containing a zeolite, or zeolites, an alumina-containing binder, a clay and a silica source, is subjected to drying to form essentially water-free solid catalyst particles, the viscosity of the aqueous slurry can be significantly reduced by incorporation of a small but effective amount of [Al.sub.2 (OH).sub.6-y Cl.sub.y ].sub.x additive. Due to this decrease in viscosity, the solids content of the slurry can be raised until the original, additive-free viscosity level, is reached, which, in turn, results in increased solids throughput rate in the drying step with corresponding savings of thermal energy and improved catalyst production efficiency.
摘要翻译：在制备流体催化裂化催化剂的过程中，其中含有沸石或沸石，含氧化铝的粘合剂，粘土和二氧化硅源的含水浆料经受干燥以形成基本上无水的固体催化剂颗粒，粘度的含水浆料可以通过加入少量但有效量的[Al 2（OH）6-yCly] x添加剂而显着降低。由于这种粘度降低，可以提高浆料的固体含量，直到达到原始的无添加剂粘度水平，这反过来又导致干燥步骤中固体产量的增加速度提高，同时节省了热能并提高催化剂生产效率。

8. 发明授权

US4313923A Method of producing pseudoboehmites 失效
标题翻译：假勃起体的制备方法
公开(公告)号：US4313923A
公开(公告)日：1982-02-02
申请号：US220904
申请日：1980-12-29
申请人： Thomas E. Block , Julius Scherzer
发明人： Thomas E. Block , Julius Scherzer
IPC分类号： C01F7/34
CPC分类号： C01F7/34
摘要： Method of producing pseudoboehmite by reacting an aluminum salt with an aluminate.
摘要翻译：通过铝盐与铝酸盐反应制备假勃姆石的方法。

9. 发明授权

US4747935A Process for the catalytic cracking of feedstocks containing nitrogen 失效
标题翻译：含氮原料催化裂化的方法
公开(公告)号：US4747935A
公开(公告)日：1988-05-31
申请号：US844463
申请日：1986-03-26
申请人： Julius Scherzer
发明人： Julius Scherzer
IPC分类号： C10G11/05 , C10G11/18 , C10G17/095
CPC分类号： C10G11/05
摘要： Hydrocarbon feedstocks containing relatively high levels of nitrogen contaminants are converted by catalytic cracking to products of lower average molecular weight by contacting the feedstock with a mixture of a cracking catalyst and separate particles of a nitrogen scavenger comprising microporous solids selected from the group consisting of acid clays; hydrogen or ammonium exchanged mordenite, clinoptilolite, chabazite and erionite; mineral acids or mineral acid precursors supported on an inorganic, refractory oxide; and Catapal alumina.

10. 发明授权

US4588496A Process for the catalytic cracking of metals-containing feedstocks 失效
标题翻译：含金属原料的催化裂化方法
公开(公告)号：US4588496A
公开(公告)日：1986-05-13
申请号：US688567
申请日：1985-01-03
申请人： Julius Scherzer
发明人： Julius Scherzer
IPC分类号： C10G11/05
CPC分类号： C10G11/05
摘要： Hydrocarbon feedstocks containing relatively high levels of metal contaminants, such as nickel and vanadium, are converted via catalytic cracking into products of lower average molecular weight by contacting the feedstock with a catalyst comprising a (1) porous, inorganic refractory oxide component and (2) a dealuminated Y zeolite having a silica-to-alumina mole ratio above about 6.0. The dealuminated Y zeolite is preferably prepared by contacting an ammonium-exchanged Y zeolite having a silica-to-alumina mole ratio below about 6.0 with an aqueous solution of ammonium hexafluorosilicate. The refractory oxide component will preferably contain alumina and a clay such as kaolin. The catalyst may also contain a nondealuminated Y zeolite, preferably one that has been ion exchanged with rare earth cations. Typically, the hydrocarbon feedstock will contain contaminant metals in sufficient quantities such that their concentration exceeds about 4.0 ppmw Nickel Equivalents.
摘要翻译：通过使原料与包含（1）多孔无机耐火氧化物组分的催化剂接触，和（2）含有（1）多孔无机耐火氧化物组分的催化剂，通过催化裂解将含有相对高含量的金属污染物如镍和钒的烃原料转化为较低的平均分子量的产物，二氧化硅 - 氧化铝摩尔比高于约6.0的脱铝Y沸石。脱铝Y沸石优选通过使二氧化硅 - 氧化铝摩尔比低于约6.0的铵交换的Y沸石与六氟硅酸铵水溶液接触来制备。难熔氧化物组分优选含有氧化铝和粘土如高岭土。催化剂还可以含有未发射的Y沸石，优选与稀土离子交换的Y沸石。通常，烃原料将含有足够量的污染金属，使得其浓度超过约4.0ppmw镍当量。

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