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    • 3. 发明授权
    • Preparing a crystalline, stable sodium percarbonate
    • 制备结晶稳定的过碳酸钠
    • US5603911A
    • 1997-02-18
    • US397171
    • 1995-04-25
    • Timo KorvelaJonni AhlgrenBo HedenasIlkka Renwall
    • Timo KorvelaJonni AhlgrenBo HedenasIlkka Renwall
    • C01B15/10C11D3/39C01B31/24
    • C01B15/106C11D3/394
    • The object of the invention is a process for preparing a crystalline, stable sodium percarbonate, in which polymers of gross formulas (I or II) are added in the preparation process to control the crystal form of the sodium percarbonate and to coat the crystals, the molecular weight of the polymers varying in the range from 500 to 1,000,000 g/mol, or salts of these polymers or mixtures of polymers of formulas (I and It) or of their salts are added. Formula (I) denotes (I) and formula (II) denotes (II): HO--(--CH.sub.2 --CH.sub.2 --O).sub.r --(CHCH.sub.3 --CH.sub.2 --O).sub.s --(--CH.sub.2 --CH.sub.2 --O).sub.t --H and X 0%, R.sub.1 is --H or --CH.sub.3, R.sub.2 is --COOM, in which M may be H.sup.+ or a cation, in particular Na.sup.+, K.sup.+ or NH.sup.+.sub.4, R.sub.7 and R.sub.8 may be identical or different, being --COOM, --CONR.sub.5 R.sub.6, H, --OH or --COO(--CH.sub.2 --CH.sub.2 --O).sub.r --(CHCH.sub.3 --CH.sub.2 --O).sub.s --(--CH.sub.2 --CH.sub.2 --O).sub.t --H and R.sub.5 and R.sub.6 are --H or an alkyl group, in particular C.sub.1 --C.sub.4 and may be mutually identical or different groups and r, t and s may vary respectively in the range from 0 to 100%, their sum being 100%.
    • PCT No.PCT / FI93 / 00356 Sec。 371日期1995年04月26日 102(e)日期1995年4月26日PCT 1993年9月7日PCT公布。 出版物WO94 / 05594 日期:1994年3月17日本发明的目的是制备结晶稳定的过碳酸钠的方法,其中在制备过程中加入总配方(I或II)的聚合物以控制过碳酸钠的晶型, 涂覆晶体,聚合物的分子量在500至1,000,000g / mol范围内变化,或这些聚合物的盐或式(I和It)或其盐的聚合物的混合物。 式(I)表示(I),式(II)表示(II):HO - ( - CH 2 -CH 2 -O)r - (CHCH 3 -CH 2 -O)s - ( - CH 2 -CH 2 -O)t H和X 其中M可以是H +或阳离子,特别是Na +,K +或NH + 4,R 7和R 8可以相同或不同, 是-COOM,-CONR 5 R 6,H,-OH或-COO(-CH 2 -CH 2 -O)r - (CHCH 3 -CH 2 -O)s - ( - CH 2 -CH 2 -O)t H,R 5和R 6是-H 或烷基,特别是C 1 -C 4并且可以相互相同或不同的基团,并且r,t和s可以分别在0至100%的范围内变化,它们的和为100%。
    • 9. 发明授权
    • Process for preparing a cationically modified (meth)acrylamide polymer and use of the polymer
    • 制备阳离子改性(甲基)丙烯酰胺聚合物的方法和该聚合物的用途
    • US06387998B1
    • 2002-05-14
    • US09529627
    • 2000-04-13
    • Jonni AhlgrenLars PetanderJussi Nikkarinen
    • Jonni AhlgrenLars PetanderJussi Nikkarinen
    • C07C22100
    • C02F1/56C08F8/30C08F20/54
    • The invention relates to a process for preparing a cationically modified (meth)acrylamide polymer by the Mannich reaction. There is prepared in advance a stable aldehyde-secondary amine adduct, which is obtained as a reaction product of an aqueous solution of the secondary amine and an aqueous solution of the aldehyde, and which, after the formation of the adduct, is stabilized to endure storage, by lowering the pH of the mixture of 7 or below and/or by adding methanol, and the adduct thus prepared is added to an aqueous solution of the (meth)acrylamide polymer and the pH is adjusted to an alkaline level, whereupon modification occurs. The invention also relates to the use of the modified (meth)acrylamide polymer as a flocculation, retention or dewatering agent.
    • 本发明涉及通过曼尼希反应制备阳离子改性(甲基)丙烯酰胺聚合物的方法。 预先制备稳定的醛 - 仲胺加合物,其作为仲胺的水溶液和醛的水溶液的反应产物获得,并且在形成加合物之后,其稳定化以耐受 通过降低7或更低的混合物的pH和/或通过加入甲醇来储存,并将如此制备的加合物加入到(甲基)丙烯酰胺聚合物的水溶液中,并将pH调节至碱性水平, 发生。 本发明还涉及改性(甲基)丙烯酰胺聚合物作为絮凝,保留或脱水剂的用途。