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1. 发明授权

US07645835B2 High density ethylene homopolymers and blend compositions 失效
标题翻译：高密度乙烯均聚物和共混组合物
公开(公告)号：US07645835B2
公开(公告)日：2010-01-12
申请号：US11472071
申请日：2006-06-21
申请人： Jozef J. Van Dun , Akira Miyamoto , Grant B. Jacobsen , Fumio Matsushita , Patrick J. Schouterden , Lee Spencer , Pak-Wing S. Chum , Larry A. Meiske , Peter L. Wauteraerts
发明人： Jozef J. Van Dun , Akira Miyamoto , Grant B. Jacobsen , Fumio Matsushita , Patrick J. Schouterden , Lee Spencer , Pak-Wing S. Chum , Larry A. Meiske , Peter L. Wauteraerts
IPC分类号： C08L23/06 , C08L23/08 , C08F4/6592
CPC分类号： C08F10/00 , C07F17/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2203/202 , C08L2308/00 , C08L2314/06 , C08F4/6592 , C08L2666/06 , C08F2500/18 , C08F2500/08 , C08F2500/03 , C08F210/14 , C08F210/08
摘要： Blend compositions containing a novel homopolymer, the use of which allows the incorporation of more comonomer in the additional components of the blend (for the same overall density) resulting in increased tie molecule formation and improvement in properties such as ESCR, toughness and impact strength are disclosed. The homopolymers are important for applications where a high density is needed to ensure certain mechanical properties like abrasion resistance, indentation resistance, pressure resistance, topload resistance, modulus of elasticity, or morphology (for the chlorination of PE to CPE) and additional advantages such as melt processability. The blend can be obtained by dry or melt mixing the already produced components, or through in-situ production by in parallel and/or in series arranged reactors. These resins can be used in applications such as films, blow molded, injection molded, and rotomolded articles, fibers, and cable and wire coatings and jacketings and, various forms of pipe.
摘要翻译：包含新型均聚物的共混组合物，其使用允许在共混物的另外的组分中引入更多的共聚单体（相同的总体密度），导致分子形成增加，并且性能如ESCR，韧性和冲击强度的改善是披露均聚物对于需要高密度以确保某些机械性能如耐磨性，耐压缩性，耐压性，耐负载性，弹性模量或形态（用于氯化PE至CPE）的某些机械性能以及其他优点，例如熔化加工性。共混物可以通过干燥或熔融混合已经生产的组分，或通过平行和/或串联排列的反应器的原位生产来获得。这些树脂可以用于薄膜，吹塑成型，注射成型和滚塑制品，纤维，电缆和线材涂层和护套以及各种形式的管子。

2. 发明授权

US07153909B2 High density ethylene homopolymers and blend compositions 失效
公开(公告)号：US07153909B2
公开(公告)日：2006-12-26
申请号：US10173256
申请日：2002-06-13
申请人： Jozef J. Van Dun , Akira Miyamoto , Grant B. Jacobsen , Fumio Matsushita , Patrick J. Schouterden , Lee Spencer , Pak-Wing S. Chum , Larry A. Meiski , Peter L. Wauteraerts
发明人： Jozef J. Van Dun , Akira Miyamoto , Grant B. Jacobsen , Fumio Matsushita , Patrick J. Schouterden , Lee Spencer , Pak-Wing S. Chum , Larry A. Meiski , Peter L. Wauteraerts
IPC分类号： C08F110/02 , C08L23/04
CPC分类号： C08F10/00 , C07F17/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2203/202 , C08L2308/00 , C08L2314/06 , C08F4/6592 , C08L2666/06 , C08F2500/18 , C08F2500/08 , C08F2500/03 , C08F210/14 , C08F210/08
摘要： Blend compositions containing a novel homopolymer, the use of which allows the incorporation of more comonomer in the additional components of the blend (for the same overall density) resulting in increased tie molecule formation and improvement in properties such as ESCR, toughness and impact strength are disclosed. The homopolymers are important for applications where a high density is needed to ensure certain mechanical properties like abrasion resistance, indentation resistance, pressure resistance, topload resistance, modulus of elasticity, or morphology (for the chlorination of PE to CPE) and additional advantages such as melt processability. The blend can be obtained by dry or melt mixing the already produced components, or through in-situ production by in parallel and/or in series arranged reactors. These resins can be used in applications such as films, blow molded, injection molded, and rotomolded articles, fibres, and cable and wire coatings and jacketings and, various forms of pipe.

3. 发明授权

US07714073B2 Ethylene copolymers and blend compositions 有权
标题翻译：乙烯共聚物和共混组合物
公开(公告)号：US07714073B2
公开(公告)日：2010-05-11
申请号：US11477198
申请日：2006-06-28
申请人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
发明人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
IPC分类号： C08L23/08 , C08F4/6592
CPC分类号： C08L23/04 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , D01F6/46 , C08F2/14 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08L2666/06
摘要： The invention provides blends comprising an ethylene copolymer formed from ethylene with at least one comonomer selected from (a) the group comprising compounds represented by the formula H2C═CHR wherein R represents a C1-C20 linear, branched or cyclic alkyl group or a C6-C20 aryl group, and (b) a C4-C20 linear, branched or cyclic diene. Each copolymer has a specific density, a specific molecular weight distribution, and a specific comonomer content distribution characteristic.
摘要翻译：本发明提供了包含由乙烯与至少一种共聚单体形成的共聚物的共混物，所述共聚单体选自（a）由式H2C = CHR表示的化合物的组，其中R表示C1-C20直链，支链或环状烷基或C6- C20芳基，和（b）C 4 -C 20直链，支链或环状二烯。每种共聚物具有特定的密度，特定的分子量分布和特定的共聚单体含量分布特征。

4. 发明申请

US20100292407A1 PROCESS FOR PREPARING COPOLYMERS AND BLEND COMPOSITIONS CONTAINING THE SAME 审中-公开
标题翻译：制备共聚物的方法和含有该共聚物的混合组合物
公开(公告)号：US20100292407A1
公开(公告)日：2010-11-18
申请号：US12724487
申请日：2010-03-16
申请人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
发明人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
IPC分类号： C08L23/08
CPC分类号： C08L23/04 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , D01F6/46 , C08F2/14 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08L2666/06
摘要： Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is, for example, an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
摘要翻译：公开了一种新型乙烯共聚物，其通过将淤浆聚合方法通过共聚合乙烯和至少一种选自式H2C = CHR表示的化合物，其中R为例如烷基或芳基和二烯的共聚单体存在固体催化剂体系，其包括载体，过渡金属化合物和能够将过渡金属化合物转化为催化活性的过渡金属络合物的活化剂。

5. 发明授权

US07166676B2 Process for preparing copolymers and blend compositions containing the same 有权
标题翻译：制备含有它们的共聚物和共混组合物的方法
公开(公告)号：US07166676B2
公开(公告)日：2007-01-23
申请号：US10165815
申请日：2002-06-07
申请人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
发明人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
IPC分类号： C08L23/08
CPC分类号： C08L23/04 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , D01F6/46 , C08F2/14 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08L2666/06
摘要： A process for the preparation of blends including an ethylene copolymer by copolymerizing ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
摘要翻译：一种制备包括乙烯共聚物的共混物的方法，该共聚物通过共聚乙烯和至少一种选自式H 2 C-CHR表示的化合物的共聚单体，其中R是烷基或芳基，和二烯，在包含载体，过渡金属化合物和能够将过渡金属化合物转化为催化活性的过渡金属络合物的活化剂的固体催化剂体系存在下进行。

6. 发明授权

US07521518B2 Ethylene copolymer compositions 失效
标题翻译：乙烯共聚物组合物
公开(公告)号：US07521518B2
公开(公告)日：2009-04-21
申请号：US10341235
申请日：2003-01-13
申请人： Grant B. Jacobsen , Fumio Matsushita , Lee Spencer , Peter L. Wauteraerts
发明人： Grant B. Jacobsen , Fumio Matsushita , Lee Spencer , Peter L. Wauteraerts
IPC分类号： C08F4/6592 , C08F210/16 , C08L23/08
CPC分类号： C08F210/16 , C07F17/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F10/02 , C08F110/02 , Y10T428/2913 , C08F4/6592 , C08F210/08 , C08F2500/08 , C08F2500/17 , C08F2500/12 , C08F2500/13 , C08F2500/18 , C08F2500/03 , C08F210/14
摘要： Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
摘要翻译：公开了一种新型乙烯共聚物，其通过在存在下通过淤浆聚合方法将乙烯和至少一种选自式H2C-CHR表示的化合物（其中R为烷基或芳基）和二烯的共聚单体共聚固体催化剂体系，其包括载体，过渡金属化合物和能够将过渡金属化合物转化为催化活性的过渡金属络合物的活化剂。

7. 发明授权

US06506866B2 Ethylene copolymer compositions 失效
标题翻译：乙烯共聚物组合物
公开(公告)号：US06506866B2
公开(公告)日：2003-01-14
申请号：US08857816
申请日：1997-05-16
申请人： Grant B. Jacobsen , Fumio Matsushita , Lee Spencer , Peter L. Wauteraerts
发明人： Grant B. Jacobsen , Fumio Matsushita , Lee Spencer , Peter L. Wauteraerts
IPC分类号： C08F21002
CPC分类号： C08F210/16 , C07F17/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F10/02 , C08F110/02 , Y10T428/2913 , C08F4/6592 , C08F210/08 , C08F2500/08 , C08F2500/17 , C08F2500/12 , C08F2500/13 , C08F2500/18 , C08F2500/03 , C08F210/14
摘要： Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex. The produced copolymer has a density of from 0.870 to 0.980 and a molecular weight distribution (Mw/Mn) of from 3 to 10, and exhibiting GPC/FT-IR characteristics and CFC characteristics, both of which define a comonomer content distribution, wherein, in one aspect, the lower the molecular weight of a copolymer fraction in a molecular weight distribution of an ethylene copolymer, the lower the comonomer content of the copolymer fraction; and, in the other aspect, the higher the molecular weight of a copolymer fraction, the higher the comonomer content of the copolymer fraction, so that ethylene copolymer exhibits high impact strength and excellent ESCR properties. Further, the ethylene copolymer contains substantially no impurites such as a wax, a gel and the like. Thus, the ethylene copolymer and blend compositions therefrom can be advantageously used for the production of film, fibers, foams or sheets including blown film, cast films, laminate films, blow-molded articles, injection molded articles, pipes, coating materials for cables, and the like.
摘要翻译：公开了一种新型乙烯共聚物，其通过在存在下通过淤浆聚合方法将乙烯和至少一种选自式H2C = CHR表示的化合物（其中R为烷基或芳基）和二烯的共聚单体共聚固体催化剂体系，其包括载体，过渡金属化合物和能够将过渡金属化合物转化为催化活性的过渡金属络合物的活化剂。制得的共聚物的密度为0.870〜0.980，分子量分布（Mw / Mn）为3〜10，表现出GPC / FT-IR特性和CFC特性，均为共聚单体含量分布，在一个方面，共聚物部分在乙烯共聚物的分子量分布中的分子量越低，共聚物部分的共聚单体含量越低; 而在另一方面，共聚物部分的分子量越高，共聚物部分的共聚单体含量越高，使得乙烯共聚物表现出高的冲击强度和优异的ESCR性能。此外，乙烯共聚物基本上不含蜡，凝胶等等。因此，乙烯共聚物及其共混组合物可有利地用于制造膜，纤维，泡沫或片材，包括吹塑薄膜，流延薄膜，层压薄膜，吹塑制品，注塑制品，管道，电缆用涂料，等等。

8. 发明申请

US20060276593A1 High density ethylene homopolymers and blend compositions 失效
标题翻译：高密度乙烯均聚物和共混组合物
公开(公告)号：US20060276593A1
公开(公告)日：2006-12-07
申请号：US11472071
申请日：2006-06-21
申请人： Jozef Van Dun , Akira Miyamoto , Grant Jacobsen , Fumio Matsushita , Patrick Schouterden , Lee Spencer , Pak-Wing Chum , Larry Meiske , Peter Wauteraerts
发明人： Jozef Van Dun , Akira Miyamoto , Grant Jacobsen , Fumio Matsushita , Patrick Schouterden , Lee Spencer , Pak-Wing Chum , Larry Meiske , Peter Wauteraerts
IPC分类号： C08F110/02 , C08L23/04 , C08L23/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2203/202 , C08L2308/00 , C08L2314/06 , C08F4/6592 , C08L2666/06 , C08F2500/18 , C08F2500/08 , C08F2500/03 , C08F210/14 , C08F210/08
摘要： This invention relates to novel homopolymers important for applications where a high density is needed to ensure certain mechanical properties like abrasion resistance, indentation resistance, pressure resistance, topload resistance, modulus of elasticity, or morphology (for the chlorination of PE to CPE) and additional advantages such as melt processability. This invention also relates to blend compositions containing the novel homopolymer, the use of which allows the incorporation of more comonomer in the additional components of the blend (for the same overall density) resulting in increased tie molecule formation and improvement in properties such as ESCR, toughness and impact strength. The blend can be obtained by dry or melt mixing the already produced components, or through in-situ production by in parallel and/or in series arranged reactors. These resins can be used in applications such as films, blow molded, injection molded, and rotomolded articles, fibres, and cable and wire coatings and jacketings and, various forms of pipe.
摘要翻译：本发明涉及对于需要高密度以确保某些机械性能如耐磨性，耐压缩性，耐压性，耐负载性，弹性模量或形态（用于将聚氯乙烯与聚氯乙烯进行氯化）等附加的重要的新型均聚物）优点如熔融加工性。本发明还涉及含有新型均聚物的共混组合物，其用途允许在共混物的另外的组分中引入更多的共聚单体（相同的总体密度），导致连接分子的形成和性能的提高，例如ESCR，韧性和冲击强度。共混物可以通过干燥或熔融混合已经生产的组分，或通过平行和/或串联排列的反应器的原位生产来获得。这些树脂可以用于薄膜，吹塑成型，注射成型和滚塑制品，纤维，电缆和线材涂层和护套以及各种形式的管子。

9. 发明申请

US20070088129A1 Process for preparing copolymers and blend compositions containing the same 有权
标题翻译：制备含有它们的共聚物和共混组合物的方法
公开(公告)号：US20070088129A1
公开(公告)日：2007-04-19
申请号：US11477198
申请日：2006-06-28
申请人： Grant Jacobsen , Jozef Van Dun , Pak-Wing Chum , Larry Meiske , Fumio Matsushita , Akira Miyamoto
发明人： Grant Jacobsen , Jozef Van Dun , Pak-Wing Chum , Larry Meiske , Fumio Matsushita , Akira Miyamoto
IPC分类号： C08L23/04
CPC分类号： C08L23/04 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , D01F6/46 , C08F2/14 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08L2666/06
摘要： A process for the preparation of blends comprising an ethylene copolymer, which is prepared by polymerizing ethylene and at least one comonomer selected from (a) a compound represented by the formula H2C═CHR, wherein R is an alkyl group, an aryl group, or (b) a diene. The polymerization takes place in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
摘要翻译：一种制备包含乙烯共聚物的共混物的方法，其通过聚合乙烯和至少一种选自（a）由式H 2 C-CHR表示的化合物的共聚单体制备，其中R为烷基，芳基或（b）二烯。聚合反应在包含载体，过渡金属化合物和能够将过渡金属化合物转化为催化活性的过渡金属络合物的活化剂的固体催化剂体系存在下进行。

10. 发明授权

US08137892B2 Photobase generator and photocurable resin composition 有权
标题翻译：光碱发生剂和光固化树脂组合物
公开(公告)号：US08137892B2
公开(公告)日：2012-03-20
申请号：US12518313
申请日：2007-12-12
申请人： Katsuya Shimizu , Fumio Matsushita
发明人： Katsuya Shimizu , Fumio Matsushita
IPC分类号： G03F7/00 , G03F7/004 , G03F7/028 , G03F7/032
CPC分类号： G03F7/0045 , C08K5/29 , C08L61/00 , C08L63/00 , C09D7/63 , Y10S430/106 , Y10S430/111 , Y10S430/114 , Y10S430/12
摘要： Disclosed is a photobase generator comprising a compound having a nitrogen atom and a conjugated multiple bond.
摘要翻译：公开了一种光碱产生剂，其包含具有氮原子和共轭多重键的化合物。

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