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    • 6. 发明授权
    • Novel halogenated organic compounds, process for the production of same,
and polyurethanes containing same
    • 新型卤化有机化合物,其制备方法和含有其的聚氨酯
    • US4110379A
    • 1978-08-29
    • US776899
    • 1977-03-11
    • David AelonyDavid Vofsi
    • David AelonyDavid Vofsi
    • C08G18/00C07C67/00C07C213/00C07C213/04C07C215/06C07C217/04C08G18/30C08G18/38C08G18/50C07C91/06C07C91/08C07C93/04
    • C08G18/5066C08G18/3802
    • Compounds are disclosed of the formula ##STR1## wherein R designates hydrogen or an alkyl group of 1 to 6 carbon atoms, inclusive;R' designates an alkylene group of 2 to 10 carbon atoms, inclusive, or alkylene substituted by a methyl or by a halomethyl group;R" designates hydrogen, an alkyl group of 1 to 4 carbon atoms, inclusive;--R"Z, ##STR2## or C(CH.sub.2 OH).sub.3 X designates chlorine or bromine;Z designates -OH, ##STR3## n is an integer from 1 to 5; and P IS AN INTEGER FROM 0 TO 4.A process for the production of such compounds is also disclosed which comprises reacting one mole or a slight excess of a trihalogenated alkylene oxide of the formula ##STR4## wherein X, R, and p are as defined above, per mole of an alkanolamine or polyamine of the formula ##STR5## wherein R', R", Z, are as defined above, at a temperature between 30.degree. to 90.degree. C and separating the resulting halogenated nitrogen containing polyol.Fire retardant polyurethane foam compositions may be prepared by reacting an organic polyisocyanate, a polyhalogenated nitrogen containing polyol of the formula defined above, an effective quantity of a catalyst for promoting the reaction between the polyisocyanate and the polyols, and a foaming agent.
    • 公开了下式的化合物,其中R表示氢或1至6个碳原子的烷基,包括端值; R'表示2〜10个碳原子的亚烷基,或被甲基或卤代甲基取代的亚烷基; R“表示氢,含1至4个碳原子的烷基,包括端值; -R''Z,或C(CH2OH)3X表示氯或溴; Z表示-OH,n表示1至5的整数; 并且P是从0到4的整数。