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    • 2. 发明授权
    • Column system process for polyester plants
    • 聚酯工厂的柱系统工艺
    • US4254246A
    • 1981-03-03
    • US23831
    • 1979-03-26
    • Ovidiu DicoiHans Wewer
    • Ovidiu DicoiHans Wewer
    • C07C29/80C07C69/82
    • C07C29/80Y10S203/06
    • A new process for use with continuously operated plants for the production of polyester polymers suitable for producing fibers, bottles and film, by reacting ethylene glycol and terephthalic acid in the presence of a catalyst so that the vapour by-products from the esterification, prepolycondensation and polycondensation stages are continuously rectified in two in-line columns yielding ethylene glycol of high purity (99.85%) which is returned to the process, waste water with 400 ppm ethylene glycol, and a heavy fraction containing oligomers, diethylene glycol, etc.Moreover, an improvement in the quality of the esterified product is attained as it contains less than 0.6% diethylene glycol without the use of diisopropylamine, a poisonous additive.
    • 一种用于生产适用于生产纤维,瓶和薄膜的聚酯聚合物的连续操作设备的新方法,通过使乙二醇和对苯二甲酸在催化剂存在下反应,使得来自酯化,预缩聚的蒸气副产物和 缩聚阶段在两个直列柱中连续精馏,得到高纯度(99.85%)的乙二醇,并返回该方法,含有400ppm乙二醇的废水和含低聚物,二甘醇等的重馏分。此外, 得到酯化产物质量的改善,因为它含有少于0.6%的二甘醇,而不使用二异丙胺(一种有毒添加剂)。