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1. 发明授权

US4476054A Uretidione dimer of isophorone diisocyanate and method of preparation 失效
标题翻译：异佛尔酮二异氰酸酯的尿嘧啶二聚体及其制备方法
公开(公告)号：US4476054A
公开(公告)日：1984-10-09
申请号：US292499
申请日：1981-08-13
申请人： Josef Disteldorf , Werner Hubel , Elmar Wolf
发明人： Josef Disteldorf , Werner Hubel , Elmar Wolf
IPC分类号： B01J31/02 , C07B61/00 , C07D229/00 , C08G18/79 , C09D5/46 , C09D175/00 , C09D175/04
CPC分类号： C07D229/00 , C08G18/798 , C08G2150/20
摘要： A process for producing a substantially isocyanurate-free uretidione dimer of isophorone diisocyanate, which is more than 98% decomposable by heat to isophorone diisocyanate, which comprises dimerizing isophorone diisocyanate, optionally in an inert organic solvent, in the presence of a catalyst of the formula X.sub.m P(NR.sub.2).sub.3-m wherein m=0, 1, 2; X=Cl OR of R wherein R is selected from the group consisting of the same or different aklyl radical, aralkyl radical, cycloalkyl radical, substituted cycloalkyl radical and radicals wherein two or more of the aforementioned radicals form a hererocyclic ring together with the nitrogen atom; at temperatures of 0.degree.-80.degree. C., isolating the resulting 1,3-diazacyclobutane-2,4-dione, after 5-70% conversion, without previous inactivation of the catalyst, from the reaction mixture as the residue of a thin film distillation and isolating the catalyst and monomer as the distillate.
摘要翻译：制备异佛尔酮二异氰酸酯的基本上不含异氰脲酸酯的脲基二酮二聚体的方法，其通过加热至异佛尔酮二异氰酸酯可分解98％以上，该方法包括二异丙氧基异氰酸酯，任选在惰性有机溶剂中，在式 XmP（NR2）3-m，其中m = 0,1,2; X = R的Cl OR，其中R选自相同或不同的甲酰基，芳烷基，环烷基，取代的环烷基和基团，其中两个或更多个上述基团与氮原子一起形成本环 ; 在0°-80℃的温度下，分离得到的1,3-二氮杂环丁烷-2,4-二酮，在转化5-70％之后，未反应催化剂失活，作为薄的残留物薄膜蒸馏和分离催化剂和单体作为馏出物。

2. 发明授权

US4668780A Isocyanate-uretdiones and a method for their production 失效
标题翻译：异氰酸酯 - 脲酶及其生产方法
公开(公告)号：US4668780A
公开(公告)日：1987-05-26
申请号：US822965
申请日：1986-01-28
申请人： Josef Disteldorf , Werner Hubel , Elmar Wolf
发明人： Josef Disteldorf , Werner Hubel , Elmar Wolf
IPC分类号： C07D229/00 , C08G18/00 , C08G18/79 , C08G18/80 , C09D5/03 , C09D175/00 , C07D403/06 , C07D403/14
CPC分类号： C08G18/798 , C07D229/00 , C08G18/807 , C08G2150/20
摘要： Isocyanate-uretdiones having the formula: ##STR1## wherein the R groups are identical or different and are hydrocarbon groups having the formulas: ##STR2## and n is an integral or fractional number from 1 to 5. Production of the isocyanate-uretdiones, which can be dissociated by heat up to an extent of greater than 70%, is accomplished through dimerization of aliphatic diisocyanates having the formula: ##STR3## with a phosphine catalyst having the formula:X.sub.m P(NR.sub.2).sub.3-mwherein:m is 0, 1 or 2;x is a --Cl, --OR or --R group, wherein R is identical or different alkyl-, arylalkyl-, cycloalkyl, or alkyl-substituted cycloalkyl groups. The reaction temperatures are 0.degree.-80.degree. C.The reaction product is subjected to thin-layer distillation after a conversion of 5-70%, by weight, without deactivation of the catalyst. The compounds of the present invention are useful as intermediates in the production of starting materials for the production of polyurethanes.
摘要翻译：具有下式的异氰酸酯 - uretiones：其中R基团相同或不同，并且是具有下式的烃基：＆lt; IMAGE＆gt;和n是1至5的整数或分数。产生异氰酸酯 - uretionion，其中可以通过加热分解达到大于70％的程度，这是通过用具有下式的膦催化剂二聚制得的具有下式的脂族二异氰酸酯：具有下式的化合物：XmP（NR2）3-m其中 m为0,1或2; x是-Cl，-OR或-R基团，其中R是相同或不同的烷基 - ，芳烷基 - ，环烷基或烷基取代的环烷基。反应温度为0°-80℃。反应产物在5-70％（重量）的转化率下进行薄层蒸馏，而不使催化剂失活。本发明的化合物可用作生产聚氨酯的起始原料的中间体。

3. 发明授权

US4483798A Polyaddition products containing uretidione groups and process for their preparation 失效
标题翻译：含有脲基二酮基团的加成产物及其制备方法
公开(公告)号：US4483798A
公开(公告)日：1984-11-20
申请号：US292500
申请日：1981-08-13
申请人： Josef Disteldorf , Rainer Gras , Werner Hubel , Elmar Wolf , Horst Schnurbusch
发明人： Josef Disteldorf , Rainer Gras , Werner Hubel , Elmar Wolf , Horst Schnurbusch
IPC分类号： C07D229/00 , C08G18/79 , C08G18/80
CPC分类号： C08G18/8012 , C07D229/00 , C08G18/798 , C08G18/8061 , C08G2150/20
摘要： A method for producing a polyaddition product of isophorone diisocyanate and diols which comprises, reacting a uretidione group-containing dimer of isophoronediisocyanate, which is decomposable by heat into 98% isophorone diisocyanate, with a diol, wherein the ratio of NCO to OH groups is such that the final polyaddition product has free terminal NCO groups, or free terminal OH groups.
摘要翻译：一种异佛尔酮二异氰酸酯和二醇的加成产物的制造方法，其特征在于，将含有能够通过热分解的异佛尔酮二异氰酸酯的异脲体系二异氰酸酯与98％异佛尔酮二异氰酸酯与二醇反应，其中NCO与OH基的比例为最终的加聚产物具有游离的末端NCO基团或游离的末端OH基团。

4. 发明授权

US4454317A Process for the trimerization of diisocyanates 失效
标题翻译：二异氰酸酯三聚的方法
公开(公告)号：US4454317A
公开(公告)日：1984-06-12
申请号：US400992
申请日：1982-07-23
申请人： Josef Disteldorf , Werner Hubel , Elmar Wolf
发明人： Josef Disteldorf , Werner Hubel , Elmar Wolf
IPC分类号： C07B61/00 , C07D251/34 , C08G18/79
CPC分类号： C08G18/791 , C07D251/34
摘要： In a process for the trimerization of diisocyanates in the presence of a catalyst comprising quaternary ammonium salts of organic acids having the formula: ##STR1## wherein X represents the same or different radicals selected from the group consisting of C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.8 cycloalkyl, and C.sub.2 -C.sub.20 aralkyl; two X radicals taken together with at least one other heteroatom forming a hetero-ring and three X radicals taken together with the quaternary nitrogen atoms forming a hetero-ring through a common hetero-atom such that said heterocyclic ring structure is selected from the group consisting of triethylene diamine, methyl triethylene diamine, quinuclidine, N-methylmorpholine, N-ethylmorpholine, and N,N'-dimethylpiperazine; R is alkyl, cycloalkyl or aralkyl, R" is R or hydrogen; R+R" together form a C.sub.1 -C.sub.12 alkyl radical; R' is hydrogen, hydroxyl or a C.sub.1 -C.sub.12 alkyl radical, optionally containing a CH.sub.(3-b) Z.sub.b group, wherein b=1 to 3 and Z is OH, the improvement comprising: reacting said diisocyanate with said catalyst in an amount of 0.02 to 0.1% by weight calculated on the weight of the compound to be trimerized at a temperature ranging from 40.degree. to 120.degree. C.
摘要翻译：在含有下式的有机酸季铵盐的催化剂存在下使二异氰酸酯三聚的方法：其中X代表相同或不同的选自C 1 -C 20烷基，C 3 -C 8的基团环烷基和C 2 -C 20芳烷基; 两个X基团与至少一个其它杂原子一起形成杂环，三个X基团与季氮原子一起通过共同杂原子形成杂环，使得所述杂环结构选自的三亚乙基二胺，甲基三亚乙基二胺，奎宁环，N-甲基吗啉，N-乙基吗啉和N，N'-二甲基哌嗪; R是烷基，环烷基或芳烷基，R“是R或氢; R + R“一起形成C 1 -C 12烷基; R'是氢，羟基或任选含有CH（3-b）Zb基团的C 1 -C 12烷基，其中b = 1至3，Z是OH，其改进包括：使所述二异氰酸酯与所述催化剂反应，按40至120℃的温度下待三元化合物的重量计算为0.02至0.1重量％

5. 发明授权

US4463154A Polyurethane powder enamels free of cleavage products as well as enamel coatings produced from such powders 失效
标题翻译：不含裂解产物的聚氨酯粉末搪瓷以及由此类粉末制成的搪瓷涂层
公开(公告)号：US4463154A
公开(公告)日：1984-07-31
申请号：US460942
申请日：1983-01-25
申请人： Josef Disteldorf , Rainer Gras , Horst Schnurbusch , Werner Hubel , Elmar Wolf
发明人： Josef Disteldorf , Rainer Gras , Horst Schnurbusch , Werner Hubel , Elmar Wolf
IPC分类号： C09D5/03 , C08G18/00 , C08G18/79 , C08G18/80 , C09D5/46 , C09D175/00 , C09D175/04
CPC分类号： C08G18/8012 , C08G18/798 , C08G18/8061 , C08G2150/20
摘要： A polyurethane powder enamel free of volatile cleavage products comprising an adduct of the uretidinedione dimer of isophorone diisocyanate with a diol, wherein the adduct has the formula ##STR1## wherein R= ##STR2## X=NCO or ##STR3## R"=a divalent aliphatic, cycloaliphatic, aromatic or araliphatic hydrocarbon radical or a diol, n>1, andR'=a monoalcohol radical or primary or secondary monoamine radical with 1-30 C-atoms, wherein the NCO/OH ratio of the dimer to the diol is from 1:0.5 to 1:0.9, the dimer/diol molar ratio is from 2:1 to 6:5, the average molecular weight is between 550 and 4300, and the melting point is .gtoreq.70.degree. C. and .ltoreq.130.degree. C., and wherein the uretidinedione groups present in the adduct are cleavable with heat into .gtoreq.98% --NCO groups, and a polyol having an OH functionality .gtoreq.3.4 to .ltoreq.7, an average molecular weight of 2000 to 5000, an OH number between 30 and 100 mg KOH/g, a viscosity of
摘要翻译：一种不含挥发性裂解产物的聚氨酯粉末搪瓷，其包含异佛尔酮二异氰酸酯的脲基二酮二聚体与二醇的加合物，其中加合物具有下式：其中R = X = NCO或 R“=二价脂族，脂环族，芳族或芳脂族烃基或二醇，n> 1，R'=具有1-30个C原子的一元醇基或伯或仲单胺基，其中NCO / OH比的二聚体为1:0.5至1:0.9，二聚体/二醇的摩尔比为2:1至6:5，平均分子量为550至4300，熔点> 并且其中存在于加合物中的脲基二酮基团可以通过加热切割成≥/ = 98％-NCO基团，并且具有OH官能度> = 3.4至 = 7，平均分子量为2000〜5000，OH值在30〜100mg KOH / g之间，160℃下的粘度<100,000mpa.s，熔点> 70℃。 d <120℃，并且其中加合物与多元醇的摩尔比选择为使多元醇中加合物中的NCO基与OH基的比例为0.8:1至1.2:1。

6. 发明授权

US4283535A Method for the production of 2,4,6-triketohexahydrotriazines 失效
标题翻译：生产2,4,6-三酮六氢三嗪的方法
公开(公告)号：US4283535A
公开(公告)日：1981-08-11
申请号：US38692
申请日：1979-05-14
申请人： Josef Disteldorf , Werner Hubel , Elmar Wolf
发明人： Josef Disteldorf , Werner Hubel , Elmar Wolf
IPC分类号： C07D251/34
CPC分类号： C07D251/34
摘要： A method of preparing 2,4,6-triketohexahydrotriazines which comprises catalytically trimerizing an organic isocyanate at 60.degree.-150.degree. C. in an inert, polar solvent present in an amount of 5-40 weight % with respect to the quantity of said isocyanate, in the presence of 0.1-5 weight % of a catalyst of the formula ##STR1## or hydrated derivatives of said catalyst, wherein R is selected from the group consisting of hydrogen and C.sub.1 -C.sub.4 alkyl, and Me.sup.+2 is a bivalent metal cation; interrupting the trimerization at a conversion of about 50% by cooling; and then isolating the 2,4,6-triketohexahydrotriazine.
摘要翻译：一种制备2,4,6-三酮六氢三嗪的方法，该方法包括在惰性极性溶剂中以60〜150℃催化三聚化有机异氰酸酯，其量为5-40重量％，相对于所述异氰酸酯的量在0.1-5重量％的下式催化剂或所述催化剂的水合衍生物存在下，其中R选自氢和C 1 -C 4烷基，Me + 2是二价金属阳离子; 通过冷却中断转化率约50％的三聚作用; 然后分离出2,4,6-三酮六氢三嗪。

7. 发明授权

US4469867A Isocyanatoisocyanurates 失效
标题翻译：异氰酸酯异氰脲酸酯
公开(公告)号：US4469867A
公开(公告)日：1984-09-04
申请号：US454633
申请日：1982-12-30
申请人： Josef Disteldorf , Werner Hubel , Elmar Wolf
发明人： Josef Disteldorf , Werner Hubel , Elmar Wolf
IPC分类号： C07D251/34 , C08G18/00 , C08G18/79
CPC分类号： C08G18/792 , C07D251/34
摘要： Polyisocyanatoisocyanurates of the formula ##STR1## wherein the R groups may be the same or different and are aliphatic divalent radicals selected from the group consisting of divalent aliphatic radicals having the formulas ##STR2## and n is a whole or fractional number from 1 to 5, are useful as isocyanate hardeners in polyurethane resin coatings.
摘要翻译：其中R基团可以相同或不同，并且是选自具有式“IMAGE”的二价脂族基团和n为1至5的整数或分数的脂族二价基团，可用作聚氨酯树脂涂料中的异氰酸酯硬化剂。

8. 发明授权

US4430474A Stoving enamel containing blocked isocyanates 失效
标题翻译：含有阻塞异氰酸酯的搪瓷
公开(公告)号：US4430474A
公开(公告)日：1984-02-07
申请号：US292689
申请日：1981-08-13
申请人： Horst Schnurbusch , Rainer Gras , Elmar Wolf , Josef Disteldorf , Werner Hubel
发明人： Horst Schnurbusch , Rainer Gras , Elmar Wolf , Josef Disteldorf , Werner Hubel
IPC分类号： C08G18/00 , C08G18/79 , C08G18/80 , C09D5/46 , C09D175/00 , C08L67/02
CPC分类号： C08G18/798 , C08G18/8012 , C08G18/8061
摘要： A stoving enamel comprising (a) 30-70% by weight of a mixture of a polymer containing hydroxyl groups having a hydroxyl number between 40 and 240 mg KOH/g with an isocyanurate-free derivative of isophorone diisocyanate containing uretidinedione groups and blocked isocyanate groups, (b) 0-3% by weight of a cross-linking catalyst, (c) 30-60% by weight of an organic solvent, (d) 0-65% by weight of a filler or pigment, (e) 0-5% by weight of a dye, and (f) optionally 0.1-3% by weight of leveling agents, gloss improvers, antioxidants, and/or stabilizers, has improved storage stability, reduced curing time and reduced liberation of blocking agent during cure.
摘要翻译：一种烘烤搪瓷，其包含（a）30-70重量％的羟值为40-240mg KOH / g的羟基的聚合物与含异脲酸酯的异佛尔酮二异氰酸酯的衍生物的混合物，其中含有脲基二ione基和封端的异氰酸酯基，（b）0-3重量％的交联催化剂，（c）30-60重量％的有机溶剂，（d）0-65重量％的填料或颜料，（e）0 -5重量％的染料，和（f）任选的0.1-3重量％的流平剂，光泽改进剂，抗氧化剂和/或稳定剂，具有改善的储存稳定性，降低固化时间和减少固化期间封闭剂的释放。

9. 发明授权

US5149805A Process for the production of monoblocked diisocyanates 失效
标题翻译：生产单嵌段二异氰酸酯的方法
公开(公告)号：US5149805A
公开(公告)日：1992-09-22
申请号：US243605
申请日：1988-09-13
申请人： Rainer Gras , Elmar Wolf , Josef Disteldorf , Werner Huebel , Horst Schnurbusch
发明人： Rainer Gras , Elmar Wolf , Josef Disteldorf , Werner Huebel , Horst Schnurbusch
IPC分类号： C07C263/16 , C07C67/00 , C07C241/00 , C07C263/18 , C07C265/00 , C07C265/14 , C07D223/10 , C07D227/087 , C08G18/80 , C09D5/44
CPC分类号： C07D223/10 , C07D227/087 , C08G18/8061 , C08G18/807 , C09D5/4465
摘要： Monoblocked diisocyanates which contain little free and diblocked diisocyanate are obtained by a process which involves adding 1 mole of a blocking agent to a diisocyanate which is present in excess and subsequently removing the excess diisocyanate by thin film evaporation. The compounds produced are useful for the production of cataphoresis resins.
摘要翻译：含有少量游离和二嵌段二异氰酸酯的单嵌段二异氰酸酯是通过一种方法获得的，该方法包括向过量存在的二异氰酸酯中加入1摩尔封闭剂，然后通过薄膜蒸发除去过量的二异氰酸酯。所生产的化合物可用于生产电泳树脂。

10. 发明授权

US5919568A Powder coating and its use for coating heat-resistant substrates 失效
标题翻译：粉末涂料及其在耐热基材上的应用
公开(公告)号：US5919568A
公开(公告)日：1999-07-06
申请号：US764442
申请日：1996-12-12
申请人： Elmar Wolf
发明人： Elmar Wolf
IPC分类号： C08G18/32 , C08G18/42 , C08G18/58 , C08G18/60 , C08G18/72 , C08G18/79 , C08G18/80 , C09D5/03 , C09D5/46 , C09D175/00 , C09D175/04 , C09J175/00 , C09J175/04 , B32B27/38 , B32B27/40 , C08G18/00
CPC分类号： C08G18/8038 , C08G18/4219 , C08G18/58 , C08G18/603 , C08G18/791 , C08G18/8009 , C08G2150/20 , C08G2170/20 , Y10S524/904 , Y10T428/31511 , Y10T428/31551
摘要： A power coating and a substrate coated with the coating are provided, wherein the coating contains a mixture ofA) a pulverulent polyisocyanate component which is a solid at temperatures of less than 50.degree. C. and a liquid at temperatures above 160.degree. C., of the formula I ##STR1## where R, R.sup.1 and n are as described herein, and B) a pulverulent, organic polyhydroxy component which is a solid at temperatures of less than 50.degree. C. and a liquid at temperatures above 160.degree. C. and having a ratio of secondary to primary OH groups of at least 3.1,wherein components A and B are present in a ratio of equivalents of NCO:OH groups of from 0.5:1 to 1.3:1,and wherein component B is selected from the group consisting of bisphenol A-containing epoxy resin, oligoamides containing secondary hydroxyl groups, and mixtures thereof.
摘要翻译：提供了涂覆有涂层的电源涂层和基材，其中涂层含有A）在低于50℃的温度下为固体的粉末多异氰酸酯组分和温度高于160℃的液体的混合物，其中R，R 1和n如本文所述，和B）粉末状有机多羟基组分，其在低于50℃的温度下为固体，在高于160℃的温度下为液体，并且具有次要至主要OH基团的比例至少为3.1，其中组分A和B以0.5：1至1.3：1的NCO:OH基当量的比例存在，其中组分B选自含有双酚A的环氧树脂，含有仲羟基的低聚酰胺及其混合物。

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