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1. 发明授权

US09090526B2 Synergistic combination for inhibiting polymerization of vinyl monomers 有权
标题翻译：用于抑制乙烯基单体聚合的协同组合
公开(公告)号：US09090526B2
公开(公告)日：2015-07-28
申请号：US13158979
申请日：2011-06-13
申请人： Jonathan Masere
发明人： Jonathan Masere
IPC分类号： C07C7/20 , C07B63/04 , C09K15/30 , C08K5/18 , C08K5/3475 , C08K5/13 , C09K15/08 , A23L3/3463 , C08F2/40 , C07C49/603
CPC分类号： C07C7/20 , C07C49/603 , C08F2/40 , C07C15/46
摘要： The present invention provides a method for inhibiting unwanted polymerization of reactive monomers within a liquid. The method comprises the combined usage of a quinone methide with a quinone diimide to the liquid monomer. This combination has an unexpected synergistic effect. Thus, in some ratios, the combination results in practically 100% inhibition.
摘要翻译：本发明提供一种用于抑制反应性单体在液体内不期望的聚合的方法。该方法包括将醌甲基化物与醌二酰亚胺结合使用于液体单体。这种组合具有意想不到的协同效应。因此，在一些比例中，组合导致实际上100％的抑制。

2. 发明授权

US08884038B2 Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders 有权
标题翻译： 7-乙炔基醌甲基化物衍生物的合成及其作为乙烯基聚合缓凝剂的应用
公开(公告)号：US08884038B2
公开(公告)日：2014-11-11
申请号：US13158958
申请日：2011-06-13
申请人： Jonathan Masere
发明人： Jonathan Masere
IPC分类号： C07C50/02 , C07C49/553 , C07C45/51 , C07C45/69
CPC分类号： C07C7/20 , C07C45/512 , C07C45/69 , C08F2/40 , C08K5/005 , C09K15/06 , C09K15/08 , C07C49/647 , C07C49/683
摘要： The invention provides a method for synthesizing 7-Acetyleno quinone methide compounds that is safe and inexpensive. The method avoids the need for extremely cold reaction temperatures and unlike the prior art does not require any highly explosive materials. The method comprises the steps of: a) performing a condensation reaction between 3,5-di-tert-butyl-4-hydroxybenzaldehyde and a secondary amine thereby forming a secondary amine quinone methide intermediate; b) removing water from the secondary amine quinone methide intermediate by azeotropic distillation; c) adding the dehydrated secondary amine quinone methide intermediate to an organic medium containing a metal acetylide to form a Mannich base intermediate; and d) adding a release agent to the Mannich base intermediate to yield a 7-Acetyleno quinone methide.
摘要翻译：本发明提供一种安全且廉价的合成7-乙酰基醌甲基化合物的方法。该方法避免了对极冷反应温度的需要，与现有技术不同，不需要任何高度爆炸性的材料。该方法包括以下步骤：a）在3,5-二叔丁基-4-羟基苯甲醛与仲胺之间进行缩合反应，从而形成仲胺醌甲基化物中间体; b）通过共沸蒸馏从仲胺醌甲基中间体中除去水; c）将脱水的仲胺醌甲基化物中间体加入到含有金属乙炔化物的有机介质中以形成曼尼希碱中间体; 和d）向曼尼希碱中间体加入脱模剂以产生7-乙酰基醌甲基化物。

3. 发明申请

US20120313036A1 SYNTHESIS OF 7-ACETYLENO QUINONE METHIDE DERIVATIVES AND THEIR APPLICATION AS VINYLIC POLYMERIZATION RETARDERS 有权
标题翻译： 7-乙酰喹啉甲酮衍生物的合成及其作为乙烯基聚合反应的应用
公开(公告)号：US20120313036A1
公开(公告)日：2012-12-13
申请号：US13158958
申请日：2011-06-13
申请人： Jonathan Masere
发明人： Jonathan Masere
IPC分类号： C07C49/794 , C09K3/00
CPC分类号： C07C7/20 , C07C45/512 , C07C45/69 , C08F2/40 , C08K5/005 , C09K15/06 , C09K15/08 , C07C49/647 , C07C49/683
摘要： The invention provides a method for synthesizing 7-Acetyleno quinone methide compounds that is safe and inexpensive. The method avoids the need for extremely cold reaction temperatures and unlike the prior art does not require any highly explosive materials. The method comprises the steps of a) performing a condensation reaction between 3,5-di-tert-butyl-4-hydroxybenzaldehyde and a secondary amine thereby forming a secondary amine quinone methide intermediate; b) removing water from the secondary amine quinone methide intermediate by azeotropic distillation; c) adding the dehydrated secondary amine quinone methide intermediate to an organic medium containing a metal acetylide to form a Mannich base intermediate; and d) adding a release agent to the Mannich base intermediate to yield a 7-Acetyleno quinone methide.
摘要翻译：本发明提供一种安全且廉价的合成7-乙酰基醌甲基化合物的方法。该方法避免了对极冷反应温度的需要，与现有技术不同，不需要任何高度爆炸性的材料。该方法包括以下步骤：a）在3,5-二叔丁基-4-羟基苯甲醛与仲胺之间进行缩合反应，由此形成仲胺醌甲基化物中间体; b）通过共沸蒸馏从仲胺醌甲基中间体中除去水; c）将脱水的仲胺醌甲基化物中间体加入到含有金属乙炔化物的有机介质中以形成曼尼希碱中间体; 和d）向曼尼希碱中间体加入脱模剂以产生7-乙酰基醌甲基化物。

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