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    • 5. 发明授权
    • Coating compositions for marking substrates
    • 用于标记基材的涂料组合物
    • US08101545B2
    • 2012-01-24
    • US11886137
    • 2006-03-13
    • Jonathan CampbellJohn WhitworthAlan PlattIan Street
    • Jonathan CampbellJohn WhitworthAlan PlattIan Street
    • B41M5/333B41M5/337C09D11/00
    • B41M5/26B41M5/286C07F7/04C07F7/1804C09D5/024C09D11/50
    • The present invention provides coating compositions for marking substrates, which comprises a color former, an amine salt of an organic metal compound, a binder, a solvent, and optionally additional components, wherein the amine salt of the organic metal compound is of formula (I) in which X is silicon or boron, and E and F are the same or different and are selected from the group consisting of a, b, c, d, e, f, g, h in which R6 and R7 are the same or different are hydrogen, C1-4-alkyl, C1-4-alkoxy, halogen, amino or carboxy, and for X=silicon o=1 and p=0, and R1 is aryl, aralkyl or C1-4-alkyl, or o=1 and p=1, and R1 and R2 together form a one residue selected from the group consisting of a, b, c, d, e, f, g and h, and for X=boron o=0 and p=0, and R3, R4 and R5 are the same or different and are hydrogen, C1-12-alkyl, C1-6-hydroxyalkyl, allyl, aralkyl or arylsulfonyl, in which aralkyl or arylsulfonyl can be substituted with C1-4-alkyl, or R3 and R4 together with the nitrogen to which they are attached form a morpholino or piperidino ring. The present invention also provides a process for the preparation of the composition of the present invention, substrates coated with these compositions, a process for preparing coated substrates, a process for preparing a marked substrate using these compositions, a marked substrate obtainable by the latter process and amine salts of the organic metal compounds of formula I.
    • 本发明提供了用于标记基材的涂料组合物,其包含成色剂,有机金属化合物的胺盐,粘合剂,溶剂和任选的另外的组分,其中有机金属化合物的胺盐具有式(I )其中X是硅或硼,E和F相同或不同,并且选自a,b,c,d,e,f,g,h,其中R 6和R 7是相同的,或 不同的是氢,C 1-4 - 烷基,C 1-4 - 烷氧基,卤素,氨基或羧基,X =硅o = 1和p = 0,并且R 1是芳基,芳烷基或C 1-4 - 烷基,或o = 1和p = 1,并且R 1和R 2一起形成选自a,b,c,d,e,f,g和h的一个残基,对于X =硼o = 0和p = 0 ,R 3,R 4和R 5相同或不同,为氢,C 1-12-烷基,C 1-6 - 羟基烷基,烯丙基,芳烷基或芳基磺酰基,其中芳烷基或芳基磺酰基可被C 1-4 - 烷基取代,或 R3和R4与氮一起 ey形成吗啉或哌啶子环。 本发明还提供了制备本发明组合物的方法,用这些组合物涂覆的基材,涂覆基材的制备方法,使用这些组合物制备标记基材的方法,通过后一方法可获得的标记基材 和式I的有机金属化合物的胺盐。
    • 6. 发明申请
    • Coating compositions for marking substrates
    • 用于标记基材的涂料组合物
    • US20090071367A1
    • 2009-03-19
    • US11886137
    • 2006-03-13
    • Jonathan CampbellJohn WhitworthAlan PlattIan Street
    • Jonathan CampbellJohn WhitworthAlan PlattIan Street
    • C09D1/00C08K5/15C23C14/28B01J19/08
    • B41M5/26B41M5/286C07F7/04C07F7/1804C09D5/024C09D11/50
    • The present invention provides coating compositions for marking substrates, which comprises a colour former, an amine salt of an organic metal compound, a binder, a solvent, and optionally additional components, wherein the amine salt of the organic metal compound is of formula (I) in which X is silicon or boron, and E and F are the same or different and are selected from the group consisting of a, b, c, d, e, f, g, h in which R6 and R7 are the same or different are hydrogen, C1-4-alkyl, C1-4-alkoxy, halogen, amino or carboxy, and for X=silicon o=1 and p=0, and R1 is aryl, aralkyl or C1-4-alkyl, or o=1 and p=1, and R1 and R2 together form a one residue selected from the group consisting of a, b, c, d, e, f, g and h, and for X=boron o=0 and p=0, and R3, R4 and R5 are the same or different and are hydrogen, C1-12-alkyl, C1-6-hydroxyalkyl, allyl, aralkyl or arylsulfonyl, in which aralkyl or arylsulfonyl can be substituted with C1-4-alkyl, or R3 and R4 together with the nitrogen to which they are attached form a morpholino or piperidino ring. The present invention also provides a process for the preparation of the composition of the present invention, substrates coated with these compositions, a process for preparing coated substrates, a process for preparing a marked substrate using these compositions, a marked substrate obtainable by the latter process and amine salts of the organic metal compounds of formula I.
    • 本发明提供了用于标记基材的涂料组合物,其包含成色剂,有机金属化合物的胺盐,粘合剂,溶剂和任选的另外的组分,其中有机金属化合物的胺盐具有式(I )其中X是硅或硼,E和F相同或不同,并且选自a,b,c,d,e,f,g,h,其中R 6和R 7是相同的,或 不同的是氢,C 1-4 - 烷基,C 1-4 - 烷氧基,卤素,氨基或羧基,X =硅o = 1和p = 0,并且R 1是芳基,芳烷基或C 1-4 - 烷基,或o = 1和p = 1,并且R 1和R 2一起形成选自a,b,c,d,e,f,g和h的一个残基,对于X =硼o = 0和p = 0 ,R 3,R 4和R 5相同或不同,为氢,C 1-12-烷基,C 1-6 - 羟基烷基,烯丙基,芳烷基或芳基磺酰基,其中芳烷基或芳基磺酰基可被C 1-4 - 烷基取代,或 R3和R4与氮一起 嘿连接形成吗啉或哌啶子环。 本发明还提供了制备本发明组合物的方法,用这些组合物涂覆的基材,涂覆基材的制备方法,使用这些组合物制备标记基材的方法,通过后一方法可获得的标记基材 和式I的有机金属化合物的胺盐。