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    • 1. 发明授权
    • Topical viscosity control for light hydrocarbon displacing fluids in
petroleum recovery and in fracturing fluids for well stimulation
    • 石油回收中的轻碳氢化合物置换液体和用于油井刺激的压裂液中的局部粘度控制
    • US4607696A
    • 1986-08-26
    • US771504
    • 1985-08-30
    • John P. HellerDileep K. Dandge
    • John P. HellerDileep K. Dandge
    • C09K8/58E21B43/22
    • C09K8/58Y10S507/922Y10S507/936
    • Solvent-type flooding fluids comprising light hydrocarbons in the range of ethane to hexane (and mixtures thereof) are used to displace crude oil in formations having temperatures of about 20 degrees to about 150 degrees Centigrade and pressures above about 650 psi, the light hydrocarbons having dissolved therein from about 0.05% to about 3% of an organotin compound of the formula R.sub.3 SnF where each R is independently an alkyl, aryl or alkyaryl group from 3 to 12 carbon atoms. Under the pressures and temperatures described, the organotin compounds become pentacoordinated and linked through the electronegative bridges, forming polymers within the light hydrocarbon flooding media to render them highly viscous. Under ambient conditions, the viscosity control agents will not readily be produced from the formation with either crude oil or water, since they are insoluble in the former and only sparingly soluble in the latter.
    • 使用包含乙烷至己烷范围内的轻质烃(及其混合物)的溶剂型淹没流体替代具有约20摄氏度至约150摄氏度的温度和高于约650psi的压力的地层中的原油,轻烃具有 溶解在其中约0.05%至约3%的式R 3 SnF的有机锡化合物,其中每个R独立地为3至12个碳原子的烷基,芳基或烷芳基。 在所述的压力和温度下,有机锡化合物变成五配位并通过电负性桥连接,在轻质烃驱油介质中形成聚合物,使它们高度粘稠。 在环境条件下,粘度控制剂不容易从原油或水的形成中产生,因为它们不溶于前者,仅在微溶于后者中。
    • 6. 发明授权
    • Fiber optic refractive index sensor using metal cladding
    • 使用金属包层的光纤折射率传感器
    • US5026139A
    • 1991-06-25
    • US501144
    • 1990-03-28
    • Stanley M. KlainerDileep K. DandgeMarcus ButlerKisholoy Goswami
    • Stanley M. KlainerDileep K. DandgeMarcus ButlerKisholoy Goswami
    • G01N21/27G01N21/41G01N21/43G02B6/02
    • G01N21/431G02B6/02G01N2021/432
    • A refractive index FOCS has a fiber optic core with a partly light transmissive thin metal film clad of an effective thickness and light transmissivity so that transmission through the core is strongly affected by the refractive index of a surrounding liquid or vapor medium. The metal clad and surrounding medium produce a localized refractive index at the core interface which modulates light transmission through the core as a function of the medium refractive index. The clad is made of platinum, or also of gold, rhodium, palladium, nickel, iron, cobalt, ruthenium, iridium, osmium, zinc, copper, silver, chronium, molybdenum, tungsten, vanadium, niobium, tantalum, titanium, zirconium or hafnium. The clad is also made of oxides of these metals, or metal compounds or alloys. With a fluorescent tip, the changes in the fluorescent signal are a measure of the medium refractive index. With a reflective tip, the changes in the reflected signal are measured. In a linear configuration, source and detector are placed at opposite ends of the fiber and changes in the transmitted signal are measured as a function of refractive index. Multiple measurements with multiple clads of different specificity can be made. The multiple clads can be on a single fiber or on separate fibers.
    • 折射率FOCS具有具有有效厚度和透光率的部分透光的薄金属薄膜包层的光纤芯,使得通过芯的透射受到周围液体或蒸气介质的折射率的强烈影响。 金属包层和周围介质在核心界面处产生局部折射率,其作为介质折射率的函数调制通过芯的光透射。 包层由铂,或金,铑,钯,镍,铁,钴,钌,铱,锇,锌,铜,银,时代,钼,钨,钒,铌,钽,钛,锆或 铪。 包层也由这些金属的氧化物或金属化合物或合金制成。 使用荧光尖端,荧光信号的变化是介质折射率的量度。 使用反射尖端,测量反射信号的变化。 在线性配置中,源和检测器被放置在光纤的相对端,并且传输信号的变化被测量为折射率的函数。 可以进行具有不同特异性的多个囊的多个测量。 多个包层可以在单个纤维上或在单独的纤维上。