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1. 发明授权

US09444110B2 System and method for reducing fuel cell power plant emissions 有权
标题翻译：减少燃料电池发电厂的系统和方法
公开(公告)号：US09444110B2
公开(公告)日：2016-09-13
申请号：US13144713
申请日：2009-01-15
申请人： John L. Preston , Peter F. Foley , Paul R. Hanrahan , Joshua D. Isom
发明人： John L. Preston , Peter F. Foley , Paul R. Hanrahan , Joshua D. Isom
IPC分类号： H01M8/04 , H01M8/06 , H01M2/02
CPC分类号： H01M8/04104 , H01M2/0242 , H01M8/04097 , H01M8/04201 , H01M8/04208 , H01M8/0687 , Y02E60/50
摘要： A system and method for operating fuel cell power plant 10 includes enclosing fuel bearing components, such as fuel cell stack 28 and reformer 24, into a fuel compartment 12 separate from motorized components in a motor compartment 14, and consuming leaked fuel in the fuel compartment 12 using a fuel bearing component such as cell stack 28 and/or burner 26, thereby reducing fuel emissions from the plant.
摘要翻译：用于操作燃料电池发电设备10的系统和方法包括将诸如燃料电池堆28和重整器24的燃料轴承部件包围到与电动机室14中的电动部件分离的燃料室12中，并且消耗燃料室中的泄漏燃料 12使用燃料轴承部件如电池组28和/或燃烧器26，从而减少来自工厂的燃料排放。

2. 发明申请

US20110281187A1 SYSTEM AND METHOD FOR REDUCING FUEL CELL POWER PLANT EMISSIONS 有权
标题翻译：用于减少燃料电池发电厂排放的系统和方法
公开(公告)号：US20110281187A1
公开(公告)日：2011-11-17
申请号：US13144713
申请日：2009-01-15
申请人： John L. Preston , Peter F. Foley , Paul R. Hanrahan , Joshua D. Isom
发明人： John L. Preston , Peter F. Foley , Paul R. Hanrahan , Joshua D. Isom
IPC分类号： H01M8/06
CPC分类号： H01M8/04104 , H01M2/0242 , H01M8/04097 , H01M8/04201 , H01M8/04208 , H01M8/0687 , Y02E60/50
摘要： A system and method for operating fuel cell power plant 10 includes enclosing fuel bearing components, such as fuel cell stack 28 and reformer 24, into a fuel compartment 12 separate from motorized components in a motor compartment 14, and consuming leaked fuel in the fuel compartment 12 using a fuel bearing component such as cell stack 28 and/or burner 26, thereby reducing fuel emissions from the plant.
摘要翻译：用于操作燃料电池发电设备10的系统和方法包括将诸如燃料电池堆28和重整器24的燃料轴承部件包围到与电动机室14中的电动部件分离的燃料室12中，并且消耗燃料室中的泄漏燃料 12使用燃料轴承部件如电池组28和/或燃烧器26，从而减少来自工厂的燃料排放。

3. 发明申请

US20110003214A1 HYDRODESULFURIZER RECYCLE APPLIED UPSTREAM OF PROCESSOR FEEDSTOCK PRESSURIZATION 有权
标题翻译：加氢器回收再生应用上料加料机进料加压
公开(公告)号：US20110003214A1
公开(公告)日：2011-01-06
申请号：US12736137
申请日：2008-05-22
申请人： Peter F. Foley , Joshua D. Isom , John L. Preston
发明人： Peter F. Foley , Joshua D. Isom , John L. Preston
IPC分类号： H01M8/06 , B01J19/00
CPC分类号： C10G45/02 , C01B3/34 , C01B3/38 , C01B3/48 , C01B2203/0216 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/1241 , C01B2203/1258 , C01B2203/148 , C01B2203/1638 , C01B2203/169 , C10G59/02 , C10G63/02
摘要： Fuel processing by a reformer (42) and a shift reactor (44) converts hydrocarbon feedstock (12) and steam (36) to hydrogen-rich reformate (11), such as for use in a fuel cell power plant (47). Some of the reformate is recycled through a restriction (18) to the inlet (15) of a feedstock pump (14), thereby increasing its pressure sufficiently to cause recycle flow through a hydrodesulfurizer (21) and the secondary inlet (26) of an ejector (28) driven by the steam (36). Recycle pressure (48) is maintained by steam pressure through a valve (34) regulated by a controller (17).
摘要翻译：通过重整器（42）和换档反应器（44）的燃料处理将烃原料（12）和蒸汽（36）转化为富氢重整产物（11），例如用于燃料电池发电厂（47）中。一些重整产物通过限制（18）再循环到原料泵（14）的入口（15），从而增加其压力以使再循环流通过加氢脱硫剂（21）和次级进料口（26）由蒸汽（36）驱动的喷射器（28）。循环压力（48）通过蒸汽压力通过由控制器（17）调节的阀（34）来维持。

4. 发明授权

US08557452B2 Hydrodesulfurizer recycle applied upstream of processor feedstock pressurization 有权
标题翻译：加氢脱硫剂回收应用于处理器原料加压上游
公开(公告)号：US08557452B2
公开(公告)日：2013-10-15
申请号：US12736137
申请日：2008-05-22
申请人： Peter F. Foley , Joshua D. Isom , John L. Preston
发明人： Peter F. Foley , Joshua D. Isom , John L. Preston
IPC分类号： H01M8/06 , H01M8/04 , H01M8/22 , B01J19/00 , B01J8/00 , C01B3/24
CPC分类号： C10G45/02 , C01B3/34 , C01B3/38 , C01B3/48 , C01B2203/0216 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/1241 , C01B2203/1258 , C01B2203/148 , C01B2203/1638 , C01B2203/169 , C10G59/02 , C10G63/02
摘要： Fuel processing by a reformer (42) and a shift reactor (44) converts hydrocarbon feedstock (12) and steam (36) to hydrogen-rich reformate (11), such as for use in a fuel cell power plant (47). Some of the reformate is recycled through a restriction (18) to the inlet (15) of a feedstock pump (14), thereby increasing its pressure sufficiently to cause recycle flow through a hydrodesulfurizer (21) and the secondary inlet (26) of an ejector (28) driven by the steam (36). Recycle pressure (48) is maintained by steam pressure through a valve (34) regulated by a controller (17).
摘要翻译：通过重整器（42）和换档反应器（44）的燃料处理将烃原料（12）和蒸汽（36）转化为富氢重整产物（11），例如用于燃料电池发电厂（47）中。一些重整产物通过限制（18）再循环到原料泵（14）的入口（15），从而增加其压力以使再循环流通过加氢脱硫剂（21）和次级进料口（26）由蒸汽（36）驱动的喷射器（28）。循环压力（48）通过蒸汽压力通过由控制器（17）调节的阀（34）来维持。

5. 发明授权

US09745526B2 Fuel processing of feedstocks having components harmful to hydrodesulfurization 有权
公开(公告)号：US09745526B2
公开(公告)日：2017-08-29
申请号：US13416744
申请日：2012-03-09
申请人： Antonio M. Vincitore , Peter F. Foley , Nancy P. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , James A. Davies
发明人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , James A. Davies
IPC分类号： B01J8/00 , C10G45/00 , C10G65/04 , C10G45/02 , C10L3/10 , C10G3/00 , C01B3/38 , C01B3/48
CPC分类号： C10G65/04 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/065 , C01B2203/1058 , C01B2203/1064 , C01B2203/127 , C01B2203/1276 , C10G3/42 , C10G3/50 , C10G45/00 , C10G45/02 , C10G2300/1025 , C10G2300/202 , C10L3/101 , C10L3/103 , Y10T137/0318
摘要： A reformer system (11) having a hydrodesulfurizer (12) provides desulfurized natural gas feedstock to a catalytic steam reformer (16), the outflow of which is treated by a water gas shift reactor (20) and optionally a preferential CO oxidizer (58) to provide reformate gas (28, 28a) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock (35) are reacted (38) with hydrogen (28, 28a; 71) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor (38) having no sulfide sorbent, and cooled (46), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water (42). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate (28, 28a) or from a mini-CPO (67), or from other sources.

6. 发明申请

US20110195326A1 CLOSED LOOP, FUEL CELL POWERED PRODUCTION OF SODIUM CHLORATE 有权
标题翻译：封闭环，燃料电池产生氯酸钠
公开(公告)号：US20110195326A1
公开(公告)日：2011-08-11
申请号：US12998327
申请日：2008-11-17
申请人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston
发明人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston
IPC分类号： H01M8/06
CPC分类号： H01M8/086 , C01B3/56 , C01B3/58 , C01B5/00 , C01B2203/042 , C01B2203/0435 , C01B2203/0465 , C01B2203/048 , C01B2203/0883 , C01B2203/146 , C25B1/04 , C25B1/265 , H01M8/0656 , H01M8/0662 , Y02E60/366 , Y02P70/56
摘要： A sodium chlorate electrolysis cell (9) receives a portion of its electrical power (47, 48; 50, 51) from a phosphoric acid fuel cell (45) which receives fuel at its anode inlet (43) from a water cooled catalytic reactor (26) that converts oxygen in the byproduct output (21) of the sodium chlorate electrolysis cell to hydrogen and water. A utility grid (53) may provide through a converter (55) power to support the electrochemical process in the sodium chlorate electrolysis cell. Temperature of the water cooled catalytic reactor is determined by the vaporization of pressurized hot water, the pressure of which may be adjusted by a controller (36) and a valve (38) in response to temperature (40).
摘要翻译：氯酸钠电解池（9）从磷酸燃料电池（45）接收一部分电力（47,48; 50,51），磷酸燃料电池在其阳极入口（43）从水冷催化反应器（43）接收燃料 26）将氯酸钠电解池的副产物输出（21）中的氧转化为氢和水。公用电网（53）可以通过转换器（55）提供电力来支持氯酸钠电解池中的电化学过程。水冷催化反应器的温度由加压热水的蒸发决定，其压力可以通过控制器（36）和阀（38）根据温度（40）调节。

7. 发明申请

US20090194459A1 Fuel processing of feedstocks having components harmful to hydrodesulfurization 审中-公开
标题翻译：具有对加氢脱硫有害的成分的原料的燃料加工
公开(公告)号：US20090194459A1
公开(公告)日：2009-08-06
申请号：US12321261
申请日：2009-01-16
申请人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , Nancy P. Foley
发明人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , Nancy P. Foley
IPC分类号： C10G67/00 , B01J19/00
CPC分类号： C10G65/04 , C10L3/101 , C10L3/103
摘要： A reformer system (11) having a hydrodesulfurizer (12) provides desulfurized natural gas feedstock to a catalytic steam reformer (16), the outflow of which is treated by a water gas shift reactor (20) and optionally a preferential CO oxidizer (58) to provide reformate gas (28, 28a) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock (35) are reacted (38) with hydrogen (28, 28a; 71) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor (38) cooled (46), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water (42). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate (28, 28a) or from a mini-CPO (67), or from other sources.
摘要翻译：具有加氢脱硫剂（12）的重整器系统（11）向催化蒸汽重整器（16）提供脱硫天然气原料，其流出物由水煤气变换反应器（20）和任选的优先CO氧化器（58）处理，以提供具有高氢和适度二氧化碳含量的重整气体（28,28a）。为了避免加氢脱硫剂由于过热而损坏，非脱硫天然气原料（35）中任何有害的氢反应物（例如峰值刮削气体或烯烃中的氧）与氢（28,28a; 71）反应（38）将它们转化为烷烃（例如乙烯和丙烯至乙烷和丙烷），并在冷却（46）的催化反应器（38）中将氧转化为水，低于会损坏反应器的温度，通过用加压热水蒸发冷却（42）。用于脱硫剂的氢气和氢气反应可以作为循环重整油（28,28a）或来自小型CPO（67）或其它来源提供。

8. 发明授权

US5792572A System for treatment of acid fuel cell fuel gas stream 失效
标题翻译：酸性燃料电池燃料气流处理系统
公开(公告)号：US5792572A
公开(公告)日：1998-08-11
申请号：US656569
申请日：1996-05-31
申请人： Peter F. Foley , Francis J. Luczak , John L. Preston, Jr. , Christopher R. Teeling , Richard D. Breault , Robert R. Fredley , Glenn W. Scheffler
发明人： Peter F. Foley , Francis J. Luczak , John L. Preston, Jr. , Christopher R. Teeling , Richard D. Breault , Robert R. Fredley , Glenn W. Scheffler
IPC分类号： B01D53/58 , C01B25/28 , H01M8/02 , H01M8/04 , H01M8/06
CPC分类号： B01D53/58 , H01M8/0662 , H01M2300/0008 , H01M8/04014 , H01M8/0612
摘要： Ammonia which is found in fuel cell fuel gases is removed therefrom by passing the fuel gas stream through a scrubber bed of porous carbon pellets containing phosphoric acid. The ammonia reacts with the phosphoric acid in the scrubber bed to form ammonium phosphate compounds which remain in the scrubber bed. The ammonia content of the fuel gas stream is thus lowered to a concentration of about one ppm or less. By maintaining the temperature of the fuel gas stream passing through the scrubber bed in a range of about 400.degree. F. to about 450.degree. F. sufficient phosphoric acid will also be evaporated from the scrubber bed to replace acid electrolyte lost during operation of the power plant. Adjustments in the temperature of the fuel gas flowing through the scrubber may be made in order to match electrolyte losses which occur during different operating phases of the power plant. The scrubber formed in accordance with this invention thus serves two functions, one being to remove ammonia from the fuel gas stream, and the other being to replenish electrolyte lost in the power plant during normal operation thereof.
摘要翻译：在燃料电池燃料气体中发现的氨通过使燃料气流通过含有磷酸的多孔碳粒料的洗涤床而被除去。氨与洗涤床中的磷酸反应形成残留在洗涤床中的磷酸铵化合物。因此，燃料气流的氨含量降低至约1ppm或更低的浓度。通过将通过洗涤器床的燃料气体流的温度保持在约400°F至约450°F的范围内。足够的磷酸也将从洗涤床中蒸发以代替在功率运行期间损失的酸性电解质厂。可以对流过洗涤器的燃料气体的温度进行调节，以便匹配在发电厂的不同运行阶段期间发生的电解质损失。因此，根据本发明形成的洗涤器具有两个功能，一个是从燃料气流中除去氨，另一个是在正常操作期间补充在发电厂中损失的电解质。

9. 发明授权

US08673511B2 Apparatus including sodium chlorate electrolysis cell connected by water cooled catalytic reactor to phosphoric acid fuel cell 有权
标题翻译：装置包括用水冷催化反应器连接到磷酸燃料电池的氯酸钠电解槽
公开(公告)号：US08673511B2
公开(公告)日：2014-03-18
申请号：US12998327
申请日：2008-11-17
申请人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston
发明人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston
IPC分类号： H01M8/06 , H01M16/00
CPC分类号： H01M8/086 , C01B3/56 , C01B3/58 , C01B5/00 , C01B2203/042 , C01B2203/0435 , C01B2203/0465 , C01B2203/048 , C01B2203/0883 , C01B2203/146 , C25B1/04 , C25B1/265 , H01M8/0656 , H01M8/0662 , Y02E60/366 , Y02P70/56
摘要： A sodium chloride electrolysis cell (9) receives a portion of its electrical power (47, 48: 50, 51) from a phosphoric acid fuel cell (44) which receives fuel at its anode inlet (43) from a water cooled catalytic reactor (26) that converts oxygen in the byproduct output (19) of the sodium chlorate electrolysis cell to hydrogen and water. A utility grid (53) may provide through a converter (55) power to support the electrochemical process in the sodium chlorate electrolysis cell. Temperature of the water cooled catalytic reactor is determined by the vaporization of pressurized hot water, the pressure of which may be adjusted by a controller (36) and a valve (38) in response to temperature (40).
摘要翻译：氯化钠电解槽（9）从其水阳极入口（43）从水冷催化反应器（43）接收燃料的磷酸燃料电池（44）接收其一部分电力（47,48：50,51） 26）将氯酸钠电解池的副产物输出（19）中的氧转化为氢和水。公用电网（53）可以通过转换器（55）提供电力来支持氯酸钠电解池中的电化学过程。水冷催化反应器的温度由加压热水的蒸发决定，其压力可以通过控制器（36）和阀（38）根据温度（40）调节。

10. 发明申请

US20120288412A1 Fuel Processing of Feedstocks Having Components Harmful to Hydrodesulfurization 有权
标题翻译：具有加氢脱硫有害成分的原料的燃料加工
公开(公告)号：US20120288412A1
公开(公告)日：2012-11-15
申请号：US13416744
申请日：2012-03-09
申请人： Antonio M. Vincitore , Peter F. Foley , Nancy P. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , James A. Davies
发明人： Antonio M. Vincitore , Peter F. Foley , Nancy P. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , James A. Davies
IPC分类号： B01J8/00 , F17D3/00 , G05D7/00
CPC分类号： C10G65/04 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/065 , C01B2203/1058 , C01B2203/1064 , C01B2203/127 , C01B2203/1276 , C10G3/42 , C10G3/50 , C10G45/00 , C10G45/02 , C10G2300/1025 , C10G2300/202 , C10L3/101 , C10L3/103 , Y10T137/0318
摘要： A reformer system (11) having a hydrodesulfurizer (12) provides desulfurized natural gas feedstock to a catalytic steam reformer (16), the outflow of which is treated by a water gas shift reactor (20) and optionally a preferential CO oxidizer (58) to provide reformate gas (28, 28a) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock (35) are reacted (38) with hydrogen (28, 28a; 71) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor (38) having no sulfide sorbent, and cooled (46), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water (42). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate (28, 28a) or from a mini-CPO (67), or from other sources.
摘要翻译：具有加氢脱硫剂（12）的重整器系统（11）向催化蒸汽重整器（16）提供脱硫天然气原料，其流出物由水煤气变换反应器（20）和任选的优先CO氧化器（58）处理，以提供具有高氢和适度二氧化碳含量的重整气体（28,28a）。为了避免加氢脱硫剂由于过热而损坏，非脱硫天然气原料（35）中任何有害的氢反应物（例如峰值刮削气体或烯烃中的氧）与氢（28,28a; 71）反应（38）将它们转化为烷烃（例如乙烯和丙烯至乙烷和丙烷），并在不具有硫化物吸附剂的催化反应器（38）中将氧转化为水，并在低于将破坏反应器的温度下冷却（46），由用加压热水蒸发冷却（42）。用于脱硫剂的氢气和氢气反应可以作为循环重整油（28,28a）或来自小型CPO（67）或其它来源提供。

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