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1. 发明申请

US20060199728A1 Enantioselective amination and etherification 失效
标题翻译：对映选择性胺化和醚化
公开(公告)号：US20060199728A1
公开(公告)日：2006-09-07
申请号：US10527899
申请日：2003-09-12
申请人： John Hartwig , Chutian Shu , Toshimichi Ohmura , Christoph Kiener , Fernando Lopez
发明人： John Hartwig , Chutian Shu , Toshimichi Ohmura , Christoph Kiener , Fernando Lopez
IPC分类号： B01J31/00
CPC分类号： C07B53/00 , B01J31/122 , B01J31/186 , B01J2231/44 , B01J2531/0266 , B01J2531/64 , B01J2531/66 , B01J2531/827 , C07B2200/07 , C07C209/08 , C07C209/16 , C07F9/657154 , C07F15/0033
摘要： The present invention is directed to a catalyst composition, comprising: (1) a catalyst precursor having the general structure MSXn wherein M is a transition metal selected from the group consisting of iridium, molybdenum, and tungsten; S is a coordinating ligand; X is a counterion; and n is an integer from 0 to 5; and (2) a phosphoramidite ligand having the structure wherein O—Cn—O is an aliphatic or aromatic diolate and wherein R1, R2, R3 and R4 are selected from the group consisting of substituted or unsubstituted aryl groups, substituted or unsubstituted heteroaryl groups, substituted or unsubstituted aliphatic groups, and combinations thereof, with the proviso that at least one of R1, R2, R3, or R4 must be a substituted or unsubstituted aryl or heteroaryl group. The present invention is also directed to activated catalysts made from the above catalyst composition, as well as methods of allylic amination and etherification using the above catalysts.
摘要翻译：本发明涉及一种催化剂组合物，其包含：（1）具有一般结构MSX N的催化剂前体，其中M是选自铱，钼和钨的过渡金属; S是配位配体; X是抗衡离子 n为0〜5的整数。和（2）具有以下结构的亚磷酰胺配体，其中OC n-O是脂族或芳族二醇酯，并且其中R 1，R 2， R 3和R 4选自取代或未取代的芳基，取代或未取代的杂芳基，取代或未取代的脂族基团及其组合，与条件是R 1，R 2，R 3或R 4中的至少一个必须是取代的或未取代的芳基或杂芳基。本发明还涉及由上述催化剂组合物制备的活化催化剂，以及使用上述催化剂的烯丙基胺化和醚化的方法。

2. 发明授权

US07732365B2 Enantioselective amination and etherification 失效
标题翻译：对映选择性胺化和醚化
公开(公告)号：US07732365B2
公开(公告)日：2010-06-08
申请号：US10527899
申请日：2003-09-12
申请人： John F. Hartwig , Chutian Shu , Toshimichi Ohmura , Christoph Kiener , Fernando Garcia Lopez
发明人： John F. Hartwig , Chutian Shu , Toshimichi Ohmura , Christoph Kiener , Fernando Garcia Lopez
IPC分类号： B01J31/00 , B01J27/24 , B01J27/00 , B01J27/185
CPC分类号： C07B53/00 , B01J31/122 , B01J31/186 , B01J2231/44 , B01J2531/0266 , B01J2531/64 , B01J2531/66 , B01J2531/827 , C07B2200/07 , C07C209/08 , C07C209/16 , C07F9/657154 , C07F15/0033
摘要： The present invention is directed to a catalyst composition, comprising: (1) a catalyst precursor having the general structure MSXn wherein M is a transition metal selected from the group consisting of iridium, molybdenum, and tungsten; S is a coordinating ligand; X is a counterion; and n is an integer from 0 to 5; and (2) a phosphoramidite ligand having the structure wherein O—Cn—O is an aliphatic or aromatic diolate and wherein R1, R2, R3 and R4 are selected from the group consisting of substituted or unsubstituted aryl groups, substituted or unsubstituted heteroaryl groups, substituted or unsubstituted aliphatic groups, and combinations thereof, with the proviso that at least one of R1, R2, R3, or R4 must be a substituted or unsubstituted aryl or heteroaryl group. The present invention is also directed to activated catalysts made from the above catalyst composition, as well as methods of allylic amination and etherification using the above catalysts.
摘要翻译：本发明涉及一种催化剂组合物，其包括：（1）具有一般结构MSXn的催化剂前体，其中M是选自铱，钼和钨的过渡金属; S是配位配体; X是抗衡离子 n为0〜5的整数。和（2）具有以下结构的亚磷酰胺配体，其中O-Cn-O是脂族或芳族二醇酯，并且其中R 1，R 2，R 3和R 4选自取代或未取代的芳基，取代或未取代的杂芳基，取代或未取代的脂族基团及其组合，条件是R 1，R 2，R 3或R 4中的至少一个必须是取代或未取代的芳基或杂芳基。本发明还涉及由上述催化剂组合物制备的活化催化剂，以及使用上述催化剂的烯丙基胺化和醚化的方法。

3. 发明授权

US09151491B2 Burner insertion aid for a burner, and method for inserting a burner 有权
标题翻译：用于燃烧器的燃烧器插入辅助装置和用于插入燃烧器的方法
公开(公告)号：US09151491B2
公开(公告)日：2015-10-06
申请号：US13699034
申请日：2010-12-21
申请人： Christoph Kiener , Matthias Köhler
发明人： Christoph Kiener , Matthias Köhler
IPC分类号： F23D11/36 , F23C5/02 , F23M5/02
CPC分类号： F23C5/02 , F23D2900/00018 , F23M5/025 , Y10T137/0402
摘要： A burner insertion aid for a burner includes a funnel-shaped component, wherein the funnel-shaped component has foamed polymer and an outer edge for mounting on a burner fastening device and also has an inner funnel region for the insertion of a burner mouth.
摘要翻译：用于燃烧器的燃烧器插入辅助件包括漏斗形部件，其中漏斗形部件具有泡沫聚合物和用于安装在燃烧器紧固装置上的外边缘，并且还具有用于插入燃烧嘴的内漏斗区域。

4. 发明授权

US09005762B2 Use of aqueous polyurethane dispersions for composite foil lamination 有权
标题翻译：水性聚氨酯分散体用于复合箔层压
公开(公告)号：US09005762B2
公开(公告)日：2015-04-14
申请号：US13705883
申请日：2012-12-05
申请人： Axel Meyer , Karl-Heinz Schumacher , Christoph Kiener
发明人： Axel Meyer , Karl-Heinz Schumacher , Christoph Kiener
IPC分类号： C09J175/06 , C08G18/12 , B32B15/095 , B32B3/10 , B32B15/04 , B32B15/08 , B32B27/08 , C08G18/08 , C08G18/34 , C08G18/40 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/66 , C08G18/70 , C08G18/73 , C08G18/76 , C09J175/04
CPC分类号： C09J175/06 , B32B3/10 , B32B7/12 , B32B15/043 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/702 , C08G18/0823 , C08G18/12 , C08G18/348 , C08G18/4018 , C08G18/4216 , C08G18/44 , C08G18/4854 , C08G18/6625 , C08G18/6659 , C08G18/706 , C08G18/73 , C08G18/7621 , C09J175/04 , Y10T428/24802 , Y10T428/24917 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31587 , Y10T428/31605
摘要： The use of aqueous polyurethane dispersions is described for composite foil lamination, where at least 10% by weight of the polyurethane derives from at least one amorphous polyester polyol.
摘要翻译：描述了用于复合箔层压的水性聚氨酯分散体的使用，其中至少10重量％的聚氨酯衍生自至少一种无定形聚酯多元醇。

5. 发明申请

US20130149510A1 USE OF AQUEOUS POLYURETHANE DISPERSIONS FOR COMPOSITE FOIL LAMINATION 有权
标题翻译：使用水性聚氨酯分散体用于复合材料层压
公开(公告)号：US20130149510A1
公开(公告)日：2013-06-13
申请号：US13705883
申请日：2012-12-05
申请人： Axel MEYER , Karl-Heinz Schumacher , Christoph Kiener
发明人： Axel MEYER , Karl-Heinz Schumacher , Christoph Kiener
IPC分类号： C09J175/06 , B32B15/08 , B32B3/10 , B32B27/08 , B32B15/04
CPC分类号： C09J175/06 , B32B3/10 , B32B7/12 , B32B15/043 , B32B15/08 , B32B15/20 , B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2307/702 , C08G18/0823 , C08G18/12 , C08G18/348 , C08G18/4018 , C08G18/4216 , C08G18/44 , C08G18/4854 , C08G18/6625 , C08G18/6659 , C08G18/706 , C08G18/73 , C08G18/7621 , C09J175/04 , Y10T428/24802 , Y10T428/24917 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31587 , Y10T428/31605
摘要： The use of aqueous polyurethane dispersions is described for composite foil lamination, where at least 10% by weight of the polyurethane derives from at least one amorphous polyester polyol.
摘要翻译：描述了用于复合箔层压的水性聚氨酯分散体的使用，其中至少10重量％的聚氨酯衍生自至少一种无定形聚酯多元醇。

6. 发明授权

US08313559B2 Aluminum aminocarboxylates as porous metal organic frameworks 失效
标题翻译：铝氨基羧酸铝作为多孔金属有机骨架
公开(公告)号：US08313559B2
公开(公告)日：2012-11-20
申请号：US12601022
申请日：2008-05-20
申请人： Markus Schubert , Ulrich Mueller , Christoph Kiener
发明人： Markus Schubert , Ulrich Mueller , Christoph Kiener
IPC分类号： B01J20/28 , B01J20/30 , F17C11/00
CPC分类号： B01D53/02 , B01D2253/204 , B01D2253/306 , B01D2257/108 , B01D2257/504 , B01D2257/702 , B01D2259/4525 , B01J20/226 , B01J20/28042 , B01J20/28066 , B01J20/30 , B01J31/1691 , B01J31/1805 , B01J31/2226 , B01J2531/31 , C07F5/069 , F17C11/00 , F17C11/005 , Y02C10/08 , Y02P20/152
摘要： A porous metal organic framework containing an at least bidentate organic compound coordinated to a metal ion, wherein the metal ion is AlIII and the at least bidentate organic compound is 2-aminoterephthalic acid, and wherein the framework is in powder form and has a specific surface area determined by the Langmuir method (N2, 77 K) of at least 2500 m2/g. In addition, a shaped body containing the metal organic framework, processes for preparing the metal organic framework and shaped body, and processes for storing and separating gases with the metal organic framework and shaped body.
摘要翻译：一种多孔金属有机骨架，其含有与金属离子配位的至少二齿有机化合物，其中所述金属离子为AlIII，所述至少二齿有机化合物为2-氨基对苯二甲酸，并且其中所述骨架为粉末形式并具有比表面积由Langmuir法测定的面积（N2，77K）至少为2500m2 / g。此外，含有金属有机骨架的成形体，用于制备金属有机骨架和成形体的方法，以及用金属有机骨架和成形体储存和分离气体的方法。

7. 发明申请

US20090306420A1 PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS 审中-公开
标题翻译：制备包含金属有机骨架的方法
公开(公告)号：US20090306420A1
公开(公告)日：2009-12-10
申请号：US12375218
申请日：2007-07-13
申请人： Markus Schubert , Faruk Oezkirim , Christoph Kiener , Ulrich Mueller , Markus Tonigold
发明人： Markus Schubert , Faruk Oezkirim , Christoph Kiener , Ulrich Mueller , Markus Tonigold
IPC分类号： C07F1/08
CPC分类号： C07F1/005
摘要： The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.
摘要翻译：本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种铜离子配位的第一和至少一种第二至少二齿有机化合物，其包括以下步骤：（a）将反应混合物在液体包含至少一种铜化合物和第一至少二齿有机化合物以形成包含至少一种铜离子和第一至少二齿有机化合物的中间体络合物，第一至少二齿有机化合物衍生自二羧酸并且具有作为烃的骨架，和（b）中间体络合物与至少第二至少二齿有机化合物的反应，至少第二至少二齿有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳原子被杂原子所取代由N，O和S组成，其中步骤（a）中的反应混合物包含基于所使用的铜化合物的铜少于3倍过量的甲酸。

8. 发明授权

US07598201B2 Process for preparing a support for olefin polymerization catalysts 失效
标题翻译：制备烯烃聚合催化剂载体的方法
公开(公告)号：US07598201B2
公开(公告)日：2009-10-06
申请号：US12086319
申请日：2006-12-04
申请人： Christoph Kiener , Ingo Treffkorn , Guido Funk
发明人： Christoph Kiener , Ingo Treffkorn , Guido Funk
IPC分类号： B01J21/00 , C08F4/72 , C08F4/44 , C08F4/06
CPC分类号： C08F10/00 , B01J21/08 , B01J35/08 , B01J35/1023 , B01J35/1047 , B01J37/036 , C01B33/16 , C01G9/02 , C01G23/047 , C01G25/02 , C01P2004/32 , C01P2004/61 , C01P2006/12 , C01P2006/14 , C01P2006/82 , C08F4/24 , C08F4/025
摘要： The invention relates to a process for preparing an essentially spherical support for olefin polymerization catalysts, which comprises the steps: preparation of a hydrogel comprising a cogel of silicon oxide and at least one further metal oxide, if appropriate, washing of the hydrogel until the content of alkali metal ions is less than 0.1% by weight, based on the weight of solids, extraction of the water from the hydrogel until the water content is less than 5% by weight, based on the total content of liquid, and drying of the hydrogel to form a xerogel. According to the invention, the extraction step comprises at least one first extraction with a first organic solvent which is at least partially miscible with water down to a water content of 50% by weight, followed by at least one second extraction with a second organic solvent which is at least partially miscible with water.
摘要翻译：本发明涉及一种制备用于烯烃聚合催化剂的基本上为球形的载体的方法，其包括以下步骤：制备包含氧化硅和至少一种其它金属氧化物的共凝胶的水凝胶（如果合适的话），洗涤水凝胶，直到含量的碱金属离子的含量小于0.1重量％，基于固体的重量，从水凝胶中提取水直到水含量低于5重量％，基于液体的总含量，并干燥水凝胶形成干凝胶。根据本发明，提取步骤包括至少一次首先用第一有机溶剂进行萃取，所述第一有机溶剂至少部分地与水混合至水含量为50重量％，然后用第二有机溶剂至少一次萃取其至少部分地与水混溶。

9. 发明授权

US08603225B2 Aluminum naphthalenedicarboxylate as porous metal-organic framework material 失效
标题翻译：铝萘二羧酸铝作为多孔金属 - 有机骨架材料
公开(公告)号：US08603225B2
公开(公告)日：2013-12-10
申请号：US12447671
申请日：2007-10-24
申请人： Markus Schubert , Ulrich Mueller , Stefan Marx , Christoph Kiener , James Reuben Brown , Gerhard Krennrich
发明人： Markus Schubert , Ulrich Mueller , Stefan Marx , Christoph Kiener , James Reuben Brown , Gerhard Krennrich
IPC分类号： B01D53/02
CPC分类号： B01J20/226 , B01J20/28014 , B01J20/28042 , B01J20/28057 , B01J31/1691 , B01J31/2239 , B01J35/002 , B01J2231/48 , B01J2531/31 , C01B3/001 , C07C63/38 , F17C11/005 , F17C11/007 , Y02C10/08 , Y02E60/321 , Y02E60/327 , Y02E60/328 , Y10T428/249953
摘要： The present invention relates to a porous metal-organic framework material comprising a bidentate organic compound bound by coordination to a metal ion, the metal ion being AlIII and the bidentate organic compound being 2,6-naphthalenedicarboxylate, wherein the X-ray diffractogram (XRD) of the framework material has a first reflection in the range from 6.5°
摘要翻译：本发明涉及多孔金属 - 有机骨架材料，其包含与金属离子配位结合的二齿有机化合物，金属离子为AlIII，二齿有机化合物为2,6-萘二甲酸酯，其中X射线衍射图）的框架材料具有在6.5°<2θ<7.5°的范围内的第一反射和在13.8°<2θ<15.0°的范围内的第二反射，第一反射的面积相对于所有反射范围为2°<2°<70°，第二反射面积为第二大，第一和第二反射面积的总和相对于所有反射的总面积至少提供50％在2°<2°<70°的范围内。本发明还涉及包括这种框架材料的成形体，用于生产骨架材料的方法以及框架材料或所提出的成形体的使用。

10. 发明授权

US08518264B2 Method of using a metal organic frameworks based on aluminum fumarate 有权
标题翻译：使用富马酸铝的金属有机骨架的方法
公开(公告)号：US08518264B2
公开(公告)日：2013-08-27
申请号：US13347212
申请日：2012-01-10
申请人： Christoph Kiener , Ulrich Müller , Markus Schubert
发明人： Christoph Kiener , Ulrich Müller , Markus Schubert
IPC分类号： B01D15/00
CPC分类号： B01J20/0211 , B01J20/226 , B01J20/28042 , B01J20/28066 , B01J20/3085 , B01J31/1691 , B01J31/2239 , B01J2231/48 , B01J2231/72 , B01J2531/31 , C01B3/001 , C01B3/508 , C07C51/418 , Y02C10/08 , Y02E60/324 , Y10T428/249953 , C07C63/38 , C07C57/15 , C07C63/26
摘要： A method comprising (i) providing a metal organic framework formed by AlIII ions to which fumarate ions are coordinated to produce a porous framework structure, (ii) bringing a substance into contact with the metal organic framework such that the substance is uptaken by the porous metal organic framework to provide storage of or controlled release of, the substance.
摘要翻译：一种方法，包括（i）提供由AlIII离子形成的金属有机骨架，其中富马酸根离子被配位以产生多孔骨架结构，（ii）使物质与金属有机骨架接触，使得物质被多孔金属有机骨架提供物质的储存或控制释放。

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