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1. 发明授权

US06552217B2 Process for the preparation of alkyl 1-methylcyclopropanecarboxylate 失效
公开(公告)号：US06552217B2
公开(公告)日：2003-04-22
申请号：US09897872
申请日：2001-07-02
申请人： John Clark Hubbs , David Carl Attride , Neil Warren Boaz , James Charles Ciula , John Thorton Maddox , Thomas Nabih , William Dell Nottingham , David Chris Spencer
发明人： John Clark Hubbs , David Carl Attride , Neil Warren Boaz , James Charles Ciula , John Thorton Maddox , Thomas Nabih , William Dell Nottingham , David Chris Spencer
IPC分类号： C07C6974
CPC分类号： C07C209/56 , C07C67/00 , C07C67/307 , C07C67/317 , C07C2601/02 , C07C69/74 , C07C69/63 , C07C211/35
摘要： Disclosed is a 4-step process for the preparation of alkyl esters of 1-methylcyclopropanecarboxylic acid which comprises the steps of (1) converting &ggr;-butyrolactone to &agr;-methyl-&ggr;-butyrolactone; (2) converting the &agr;-methyl-&ggr;-butyrolactone from step (1) to an alkyl 4-halo-2-methylbutyrate; (3) producing a xylene solution of the alkyl 4-halo-2-methylbutyrate; and (4) contacting the xylene solution of an alkyl 4-halo-2-methylbutyrate from step (3) with an alkali metal alkoxide under conditions of temperature and pressure which causes vaporization of (i) an alkanol as it is formed and (ii) an alkyl 1-methylcyclopropanecarboxylate as it is formed from the alkyl 4-halo-2-methylbutyrate. Also disclosed are processes whereby the alkyl 1-methylcyclopropanecarboxylate, prepared as described above, is converted to 1-methylcyclopropylamine.

2. 发明授权

US06710206B2 Poly(3-cyclopropyl-3-hydroxypropionate) and processes for its preparation and derivatives thereof 失效
标题翻译：聚（3-环丙基-3-羟基丙酸酯）及其制备方法及其衍生物
公开(公告)号：US06710206B2
公开(公告)日：2004-03-23
申请号：US10414885
申请日：2003-04-16
申请人： John Clark Hubbs , Theresa Sims Barnette , Neil Warren Boaz
发明人： John Clark Hubbs , Theresa Sims Barnette , Neil Warren Boaz
IPC分类号： C07C6104
CPC分类号： C08G63/005 , C07C1/2078 , C07C1/213 , C07C13/04 , C07C17/02 , C07C51/09 , C07C51/363 , C07C51/367 , C07C51/377 , C07C51/412 , C07C67/03 , C07C67/313 , C07C69/708 , C07C2601/02 , C07D305/12 , C08G63/06 , C07C22/00 , C07C59/11 , C07C65/21 , C07C57/26 , C07C69/675 , C07C69/716
摘要： Poly(3-cyclopropyl-3-hydroxypropionates) (I) which are useful for the preparation of vinylcyclopropane and cyclopropylacetylene are disclosed. Methods for the preparation of a variety of intermediates obtained from (I) such as 3-cyclopropyl-3-hydroxypropionic acid and esters and salts thereof, 3-cyclopropylacrylic acids and vinylcyclopropane also are disclosed.
摘要翻译：公开了可用于制备乙烯基环丙烷和环丙基乙炔的聚（3-环丙基-3-羟基丙酸酯）（I）。还公开了制备从（I）得到的各种中间体如3-环丙基-3-羟基丙酸及其酯和盐，3-环丙基丙烯酸和乙烯基环丙烷的方法。

3. 发明授权

US06610878B1 Poly(3-cyclopropyl-3-hydroxypropionate) and processes for its preparation and derivatives thereof 失效
标题翻译：聚（3-环丙基-3-羟基丙酸酯）及其制备方法及其衍生物
公开(公告)号：US06610878B1
公开(公告)日：2003-08-26
申请号：US09546817
申请日：2000-04-11
申请人： John Clark Hubbs , Theresa Sims Barnette , Neil Warren Boaz
发明人： John Clark Hubbs , Theresa Sims Barnette , Neil Warren Boaz
IPC分类号： C07C974
CPC分类号： C08G63/005 , C07C1/2078 , C07C1/213 , C07C13/04 , C07C17/02 , C07C51/09 , C07C51/363 , C07C51/367 , C07C51/377 , C07C51/412 , C07C67/03 , C07C67/313 , C07C69/708 , C07C2601/02 , C07D305/12 , C08G63/06 , C07C22/00 , C07C59/11 , C07C65/21 , C07C57/26 , C07C69/675 , C07C69/716
摘要： Poly(3-cyclopropyl-3-hydroxypropionates) (I) which are useful for the preparation of vinylcyclopropane and cyclopropylacetylene are disclosed. Methods for the preparation of a variety of intermediates obtained from (I) such as 3-cyclopropyl-3-hydroxypropionic acid and esters and salts thereof, 3-cyclopropylacrylic acid, and vinylcyclopropane also are disclosed.
摘要翻译：公开了可用于制备乙烯基环丙烷和环丙基乙炔的聚（3-环丙基-3-羟基丙酸酯）（I）。还公开了制备从（I）得到的各种中间体如3-环丙基-3-羟基丙酸及其酯和盐，3-环丙基丙烯酸和乙烯基环丙烷的方法。

4. 发明授权

US5817490A Enzymatic process for the manufacture of ascorbic acid 2-keto-L-gulonic acid and esters of 2-keto-L-gulonic acid 失效
标题翻译：用于制备抗坏血酸2-酮-L-古洛糖酸的酶法和2-酮-L-古洛糖酸的酯
公开(公告)号：US5817490A
公开(公告)日：1998-10-06
申请号：US845295
申请日：1997-04-25
申请人： John Clark Hubbs
发明人： John Clark Hubbs
IPC分类号： C12N9/16 , C12N9/20 , C12N9/56 , C12N9/84 , C12P7/60 , C12P7/62 , C12P17/04 , C12P7/58 , C12N1/00 , C12N1/20 , C12N9/14
CPC分类号： C12P17/04 , C12P7/60 , Y10S435/836 , Y10S435/847 , Y10S435/913 , Y10S435/921 , Y10S435/933
摘要： The present invention is directed toward efficient, high-yield processes for making ascorbic acid, 2-keto-L-gulonic acid, and esters of 2-keto-L-gulonic acid. The processes comprise reacting the appropriate starting materials with a hydrolase enzyme catalyst such as a protease, an esterase, a lipase or an amidase.
摘要翻译：本发明涉及用于制备抗坏血酸，2-酮-L-古洛糖酸和2-酮-L-古洛糖酸的酯的有效的高产率方法。该方法包括使合适的原料与水解酶催化剂如蛋白酶，酯酶，脂肪酶或酰胺酶反应。

5. 发明授权

US06670505B1 Process for the recovery of organic acids from aqueous solutions 失效
标题翻译：从水溶液中回收有机酸的方法
公开(公告)号：US06670505B1
公开(公告)日：2003-12-30
申请号：US09519936
申请日：2000-03-07
申请人： Nick Allen Collins , Mark Robert Shelton , George William Tindall , Steven Thomas Perri , Ruairi Seosamh O'Meadhra , Chester Wayne Sink , Bhaskar Krishna Arumugam , John Clark Hubbs
发明人： Nick Allen Collins , Mark Robert Shelton , George William Tindall , Steven Thomas Perri , Ruairi Seosamh O'Meadhra , Chester Wayne Sink , Bhaskar Krishna Arumugam , John Clark Hubbs
IPC分类号： C07C5142
CPC分类号： C07C51/43 , Y02P20/582 , Y10S435/803 , Y10S435/876 , Y10S435/896 , C07C59/347
摘要： A process for recovering a desired organic acid from a solution includes the steps of: providing an aqueous solution including at least one desired organic acid or its acid anion; adjusting the proton concentration in the aqueous solution to a desired level, with the desired proton concentration being selected, at least in part, by the amount of available protons needed to associate with the acid anions of the desired organic acid(s) to be recovered and/or acid anions that are weaker than the desired organic acids; and recovering at least a portion of the at least one desired organic acid from the aqueous phase. The desired proton concentration can be based on the amount of available protons being greater than, less than or substantially equal, to the amount of protons needed to associate with the anion of the desired organic acid(s) and acid anions that are weaker than the desired organic acid(s). Specific examples of suitable organic acids include, but are not limited to, ascorbic, succinic, tartaric, glyconic, gulonic, citric, lactic, hialic, maleic, acetic, formic, gluconic pyruvic, propionic, butyric, itaconic acids and mixtures thereof. One embodiment of the present invention relates to the recovery of 2-keto-L-gulonic acid (KLG) from aqueous solutions such as fermentation baths.
摘要翻译：从溶液中回收所需有机酸的方法包括以下步骤：提供包含至少一种所需有机酸或其酸阴离子的水溶液; 将所述水溶液中的质子浓度调节到所需的水平，其中所需质子浓度至少部分地被选择与需要回收的所需有机酸的酸性阴离子缔合所需的可用质子的量和/或弱于所需有机酸的酸性阴离子; 以及从所述水相中回收所述至少一种所需有机酸的至少一部分。期望的质子浓度可以基于可用质子的量大于，小于或基本上等于与所需有机酸的阴离子和酸阴离子相比所需的质子的量，其弱于合适的有机酸的具体实例包括但不限于抗坏血酸，琥珀酸，酒石酸，葡萄糖酸，古洛糖酸，柠檬酸，乳酸，唾液酸，马来酸，乙酸，甲酸，葡萄糖酸，丙酸，丙酸，丁酸，衣康酸及其混合物。本发明的一个实施方案涉及从水溶液如发酵浴中回收2-酮-L-古洛糖酸（KLG）。

6. 发明授权

US06271006B1 Enzymatic process for the manufacture of ascorbic acid, 2-keto-L-gulonic acid and esters of 2-keto-L-gulonic acid 失效
标题翻译：用于制备抗坏血酸，2-酮-L-古洛糖酸和2-酮-L-古洛糖酸的酯的酶法
公开(公告)号：US06271006B1
公开(公告)日：2001-08-07
申请号：US09150515
申请日：1998-09-09
申请人： John Clark Hubbs
发明人： John Clark Hubbs
IPC分类号： C12P762
CPC分类号： C12P17/04 , C12P7/60 , Y10S435/836 , Y10S435/847 , Y10S435/913 , Y10S435/921 , Y10S435/933
摘要： The present invention is directed toward efficient, high-yield processes for making ascorbic acid, 2-keto-L-gulonic acid, and esters of 2-keto-L-gulonic acid. The processes comprise reacting the appropriate starting materials with a hydrolase enzyme catalyst such as a protease, an esterase, a lipase or an amidase.
摘要翻译：本发明涉及用于制备抗坏血酸，2-酮-L-古洛糖酸和2-酮-L-古洛糖酸的酯的有效的高产率方法。该方法包括使合适的原料与水解酶催化剂如蛋白酶，酯酶，脂肪酶或酰胺酶反应。

7. 发明申请

US20080135059A1 Tobacco smoke filter material and process for the preparation thereof 审中-公开
标题翻译：烟草烟雾过滤材料及其制备方法
公开(公告)号：US20080135059A1
公开(公告)日：2008-06-12
申请号：US11636255
申请日：2006-12-08
申请人： Ted Calvin Germroth , Steven Anthony Wilson , Thauming Kuo , John Clark Hubbs
发明人： Ted Calvin Germroth , Steven Anthony Wilson , Thauming Kuo , John Clark Hubbs
IPC分类号： A24D1/04 , A24D3/06 , A24D3/02
CPC分类号： B01J20/26 , A24D3/08 , A24D3/10 , A24D3/14
摘要： Disclosed are materials and compositions effective for the selective removal of gaseous aldehydes from tobacco smoke. The materials and compositions comprise tobacco smoke filters comprising a fibrous material or fibers of a polymeric material containing covalently-bonded acetoacetoxy residues. The fibrous material or fibers are capable of reacting with and removing aldehydes present in tobacco smoke. Also disclosed are processes for the preparation of fibrous materials and fibers of a polymeric material containing covalently-bonded acetoacetoxy residues and methods for the removal of a gaseous aldehyde from tobacco smoke by contacting tobacco smoke with the aforesaid fibrous materials or fibers containing covalently-bonded acetoacetoxy residues.
摘要翻译：公开了对从烟草烟雾中选择性除去气态醛有效的材料和组合物。该材料和组合物包括烟草烟雾过滤器，其包括纤维材料或含有共价键合的乙酰乙酰氧基残基的聚合材料的纤维。纤维材料或纤维能够与烟草烟雾中存在的醛反应和除去。还公开了制备含有共价键合的乙酰乙酸基残基的聚合材料的纤维材料和纤维的方法以及通过使烟草烟与前述纤维材料或含有共价键合的乙酰乙酰氧基的纤维接触而从烟草烟中除去气态醛的方法残留物。

8. 发明申请

US20080135058A1 Tobacco smoke filter and method for removal of aldehydes from tobacco smoke 审中-公开
标题翻译：烟草烟雾过滤器和从烟草中去除醛的方法
公开(公告)号：US20080135058A1
公开(公告)日：2008-06-12
申请号：US11635993
申请日：2006-12-08
申请人： Ted Calvin Germroth , Steven Anthony Wilson , Thauming Kuo , John Clark Hubbs
发明人： Ted Calvin Germroth , Steven Anthony Wilson , Thauming Kuo , John Clark Hubbs
IPC分类号： A24F7/04 , A24D3/06
CPC分类号： A24D3/14 , A24D3/08
摘要： Disclosed are filter materials which are effective for the selective removal of gaseous aldehydes from a cigarette smoke stream. The filter materials comprise a tobacco smoke filter comprising a filter support material and an alkyl acetoacetate that is capable of reacting with and removing aldehydes present in tobacco smoke. Also disclosed are a method of removing gaseous aldehydes from tobacco smoke by contacting tobacco smoke with a filter comprising a filter support material and an alkyl acetoacetate and a smoking article such as a cigarette comprising the tobacco smoke filter described herein.
摘要翻译：公开了对于从香烟烟雾流中选择性除去气态醛有效的过滤材料。过滤材料包括烟草烟雾过滤器，其包括过滤器支撑材料和乙酰乙酸烷基酯，其能够与烟草烟雾中存在的醛反应并除去其中的醛。还公开了一种通过使烟草烟与包含过滤器支撑材料和乙酰乙酸烷基酯的过滤器以及吸烟制品（例如包含本文所述的烟草烟雾过滤器）的香烟接触而从烟草烟气中除去气态醛的方法。

9. 发明授权

US6136575A Enzymatic process for the manufacture of ascorbic acid, 2-keto-L-gulonic acid and esters of 2-keto-L-gulonic acid 失效
公开(公告)号：US6136575A
公开(公告)日：2000-10-24
申请号：US146661
申请日：1998-09-03
申请人： John Clark Hubbs
发明人： John Clark Hubbs
IPC分类号： C12N9/16 , C12N9/20 , C12N9/56 , C12N9/84 , C12P7/60 , C12P7/62 , C12P17/04 , C12N9/14
CPC分类号： C12P17/04 , C12P7/60 , Y10S435/836 , Y10S435/847 , Y10S435/913 , Y10S435/921 , Y10S435/933
摘要： The present invention is directed toward efficient, high-yield processes for making ascorbic acid, 2-keto-L-gulonic acid, and esters of 2-keto-L-gulonic acid. The processes comprise reacting the appropriate starting materials with a hydrolase enzyme catalyst such as a protease, an esterase, a lipase or an amidase.

10. 发明授权

US6022719A Enzymatic process for the manufacture of ascorbic acid, 2-keto-L-gulonic acid and esters of 2-keto-L-gulonic acid 失效
标题翻译：用于制备抗坏血酸，2-酮-L-古洛糖酸和2-酮-L-古洛糖酸的酯的酶法
公开(公告)号：US6022719A
公开(公告)日：2000-02-08
申请号：US140933
申请日：1998-08-27
申请人： John Clark Hubbs
发明人： John Clark Hubbs
IPC分类号： C12N9/16 , C12N9/20 , C12N9/56 , C12N9/84 , C12P7/60 , C12P7/62 , C12P17/04
CPC分类号： C12P17/04 , C12P7/60 , Y10S435/836 , Y10S435/847 , Y10S435/913 , Y10S435/921 , Y10S435/933
摘要： The present invention is directed toward efficient, high-yield processes for making ascorbic acid, 2-keto-L-gulonic acid, and esters of 2-keto-L-gulonic acid. The processes comprise reacting the appropriate starting materials with a hydrolase enzyme catalyst such as a protease, an esterase, a lipase or an amidase.
摘要翻译：本发明涉及用于制备抗坏血酸，2-酮-L-古洛糖酸和2-酮-L-古洛糖酸的酯的有效的高产率方法。该方法包括使合适的原料与水解酶催化剂如蛋白酶，酯酶，脂肪酶或酰胺酶反应。

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