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1. 发明授权

US4069828A Flavored tobacco article 失效
标题翻译：调味烟草制品
公开(公告)号：US4069828A
公开(公告)日：1978-01-24
申请号：US683302
申请日：1976-05-05
申请人： John B. Hall , Denis E. Hruza , Manfred Hugo Vock , Joaquin Vinals , Edward J. Shuster
发明人： John B. Hall , Denis E. Hruza , Manfred Hugo Vock , Joaquin Vinals , Edward J. Shuster
IPC分类号： A24B15/32 , C07C17/16 , C07C57/03 , C11B9/00 , A24B3/12
CPC分类号： C11B9/0019 , A24B15/32 , C07C17/16 , C07C57/03
摘要： A tobacco article comprising tobacco Tobacco and C.sub.1 -C.sub.6 alkyl-2-methyl-3,4-pentadienoates as a flavor adjuvant.
摘要翻译：一种烟草制品，其包含烟草烟草和C1-C6烷基-2-甲基-3,4-戊二烯酸酯作为风味佐剂。

2. 发明授权

US3978239A Foodstuff and flavoring containing C.sub.1 -C.sub.6 alkyl-2-methyl-3,4-pentadienoates 失效
标题翻译：含有C 1'-C 6'亚烷基-2-甲基-3,4-二戊酸酯的食品和香料
公开(公告)号：US3978239A
公开(公告)日：1976-08-31
申请号：US566118
申请日：1975-04-08
申请人： John B. Hall , Denis E. Hruza , Manfred Hugo Vock , Joaquin Vinals , Edward J. Shuster
发明人： John B. Hall , Denis E. Hruza , Manfred Hugo Vock , Joaquin Vinals , Edward J. Shuster
IPC分类号： C07C17/16 , C07C57/03 , C11B9/00 , A23L1/235
CPC分类号： C11B9/0019 , C07C17/16 , C07C57/03
摘要： Described are methods for preparing foodstuffs, flavoring compositions for foodstuffs, tobacco compositions, flavoring compositions for tobacco, perfume compositions, ingredients for perfume compositions, perfumed articles and ingredients for perfumed articles by including therein one or more C.sub.1 -C.sub.6 alkyl-2-methyl-3,4-pentadienoates in order to produce:A. In food flavorings, sweet, fruity, strawberry, tagette oil-like, pear and/or apple-like aromas and sweet, fruity, winey, creamy, strawberry, tagette oil-like, pear and/or apple tastes;B. In perfumes, berry, chamomile, wormwood, apple and/or pineapple notes; andC. In tobaccos, sweet, woody and/or fruity notes;As well as the novel compounds, isobutyl-2-methyl-3,4-pentadienoate and n-hexyl-2-methyl-3,4-pentadienoate.

3. 发明授权

US4094823A Ethyl-2-methyl-3,4-pentadienoate perfume compositions 失效
标题翻译：乙基-2-甲基-3,4-戊二烯酸乙酯香料组合物
公开(公告)号：US4094823A
公开(公告)日：1978-06-13
申请号：US683330
申请日：1976-05-05
申请人： John B. Hall , Denis E. Hruza , Manfred Hugo Vock , Joaquin Vinals , Edward J. Shuster
发明人： John B. Hall , Denis E. Hruza , Manfred Hugo Vock , Joaquin Vinals , Edward J. Shuster
IPC分类号： C07C17/16 , C07C57/03 , C11B9/00
CPC分类号： C11B9/0019 , C07C17/16 , C07C57/03
摘要： Described are methods for preparing foodstuffs, flavoring compositions for foodstuffs, tobacco compositions, flavoring compositions for tobacco, perfume compositions, ingredients for perfume compositions, perfumed articles and ingredients for perfumed articles by including therein one or more C.sub.1 -C.sub.6 alkyl-2-methyl-3,4-pentadienoates in order to produce:(a) In food flavorings, sweet, fruity, winey, strawberry, tagette oil-like, pear and/or apple-like aromas and sweet, fruity, winey, creamy, strawberry, tagette oil-like, pear and/or apple tastes;(b) In perfumes, berry, chamomile, wormwood, apple and/or pineapple notes; and(c) In tobaccos, sweet, woody and/or fruity notes;As well as the novel compounds, isobutyl-2-methyl-3,4-pentadienoate and n-hexyl-2-methyl-3,4-pentadienoate.
摘要翻译：描述了制备食品的方法，用于食品的调味组合物，烟草组合物，烟草调味组合物，香料组合物，用于香料组合物的成分，香料制品和用于香料制品的成分，其中包含一个或多个C 1 -C 6烷基-2-甲基 - 3,4-pentadienoates为了生产：

4. 发明授权

US4041069A Alkyl-2-methyl-3,4-pentadienoates 失效
标题翻译：烷基-2-甲基-3,4-戊二烯酸酯
公开(公告)号：US4041069A
公开(公告)日：1977-08-09
申请号：US683303
申请日：1976-05-05
申请人： John B. Hall , Denis E. Hruza , Manfred Hugo Vock , Joaquin Vinals , Edward J. Shuster
发明人： John B. Hall , Denis E. Hruza , Manfred Hugo Vock , Joaquin Vinals , Edward J. Shuster
IPC分类号： C07C17/16 , C07C57/03 , C11B9/00 , C07C69/54
CPC分类号： C11B9/0019 , C07C17/16 , C07C57/03
摘要： Described are methods for preparing foodstuffs, flavoring compositions for foodstuffs, tobacco compositions, flavoring compositions for tobacco, perfume compositions, ingredients for perfume compositions, perfumed articles and ingredients for perfumed articles by including therein one or more C.sub.1 -C.sub.6 alkyl-2-methyl-3,4-pentadienoates in order to produce:A. In food flavorings, sweet, fruity, winey strawberry, tagette oil-like, pear and/or apple-like aromas and sweet, fruity, winey, creamy, strawberry, tagette oil-like, pear and/or apple tastes;B. In perfumes, berry, chamomile, wormwood, apple and/or pineapple notes; andC. In tobaccos, sweet, woody and/or fruity notes;As well as the novel compounds, isobutyl-2-methyl-3,4-pentadienoate and n-hexyl-2-methyl-3,4-pentadienoate.
摘要翻译：描述了制备食品的方法，用于食品的调味组合物，烟草组合物，烟草调味组合物，香料组合物，用于香料组合物的成分，香料制品和用于香料制品的成分，其中包含一个或多个C 1 -C 6烷基-2-甲基 - 3,4-pentadienoates为了生产：

5. 发明授权

US3998873A Process for preparing one or more alkyl-2-methyl pentenoates by means of hydrogenation of one or more alkyl-2-methyl-3,4-pentadienoates 失效
标题翻译：通过氢化一种或多种烷基-2-甲基-3,4-二苯甲酸酯制备一种或多种烷基-2-甲基苯甲酸酯的方法
公开(公告)号：US3998873A
公开(公告)日：1976-12-21
申请号：US569853
申请日：1975-04-21
申请人： John B. Hall , Denis E. Hruza
发明人： John B. Hall , Denis E. Hruza
IPC分类号： C07C17/16 , C11B9/00 , C07C69/54
CPC分类号： C11B9/0019 , C07C17/16
摘要： A process for producing one or more alkyl-2-methyl pentenoates having the generic structure: ##STR1## comprising the steps of: I. Contacting with hydrogen gas one or more alkyl-2-methyl-3,4-pentadienoates having the structure: ##STR2## in the presence of a hydrogenation catalyst which may be either of: A. Raney Nickel;B. Palladium on carbon; orC. Palladium on calcium carbonateAt a temperature from about 10.degree. C up to about 100.degree. C, a hydrogen pressure from about 5 psig up to about 80 psig, the concentration of said catalyst based on the weight of the starting material, the alkyl-2-methyl-3,4-pentadienoate, being from about 0.1% up to about 10%;Ii. Recovering at least 60% by weight of one or more alkyl-2-methyl-cis-3-pentenoates having the structure: ##STR3## wherein R is alkyl having up to 6 carbon atoms; optionally III. Separating the ingredients of the resulting chemical composition to obtain ethyl-2-methyl-cis-3-pentenoate; and/or, optionally,Iv. Forming one or more carboxylic acids by means of admixing the resulting chemical composition with a basic hydrolysis agent which may be either an aqueous solution of alkali metal hydroxide, or an alcohol solution of an alkali metal hydroxide; and, optionally,V. Re-esterifying the resulting carboxylic acid(s) by reacting said carboxylic acid(s) with an esterifying agent such as an alkanol in the presence of a protonic acid catalyst.The products produced are useful in altering the organoleptic characteristics (aroma and/or taste) of foodstuffs, foodstuff flavors, chewing gum, medicinal products, tobaccos, flavoring compositions for tobaccos, perfumes, perfume compositions and perfumed articles such as soaps, colognes, cosmetic powders and detergent powders and liquids.

6. 再颁专利

USRE30370E Flavoring foodstuffs with a thioester 失效
标题翻译：用硫酯调味食品
公开(公告)号：USRE30370E
公开(公告)日：1980-08-12
申请号：US3882
申请日：1979-01-16
申请人： Alan O. Pittet , Denis E. Hruza , Ira Katz , Cynthia J. Mussinan , John V. Pascale
发明人： Alan O. Pittet , Denis E. Hruza , Ira Katz , Cynthia J. Mussinan , John V. Pascale
IPC分类号： A23L27/20 , C11B9/00
CPC分类号： C11B9/0061 , A23L27/20 , C11B9/0011 , C11B9/0026
摘要： Processes for imparting flavors and aromas to consumable materials, for example vegetable flavors to foodstuffs or perique flavors to tobacco, by adding to such materials a small amount of at least one thioester according to the formula: ##STR1## wherein R.sub.1 is alkyl, aryl, aralkyl, alkaryl, cycloalkyl, or alkenyl and R.sub.2 is alkyl, alkylthioalkyl, aralkyl, alkaryl, or aryl, R.sub.1 containing at least two carbon atoms when R.sub.2 is an alkyl group containing three or four carbon atoms, effective to alter the flavor and/or aroma of such materials, together with compositions containing such thioesters and adapted to alter the flavor and/or aroma of such materials, novel cycloalkyl and alkenyl thiopropionates useful for such purposes, and processes for producing such novel thiopropionates.

7. 发明授权

US3966989A Flavoring methods and compositions 失效
标题翻译：调味方法和组合物
公开(公告)号：US3966989A
公开(公告)日：1976-06-29
申请号：US582861
申请日：1975-06-02
申请人： Alan O. Pittet , John V. Pascale , Denis E. Hruza
发明人： Alan O. Pittet , John V. Pascale , Denis E. Hruza
IPC分类号： A23L27/20 , A24B15/30 , A24B15/32 , A23L1/235
CPC分类号： A24B15/301 , A23L27/2022 , A23L27/203 , A23L27/204 , A24B15/32
摘要： Processes for imparting fruity flavors to foodstuffs by adding to foodstuffs a small amount of at least one sulfinate according to the formula: ##EQU1## wherein R.sub.1 is selected from the group consisting of methyl, n-hexyl and n-decyl and R.sub.2 is selected from the group consisting of methyl, n-hexyl and n-propyl, provided that when R.sub.1 is methyl, R.sub.2 is n-propyl, or n-hexyl; and provided that when R.sub.2 is methyl, R.sub.1 is n-decyl or n-hexyl, effective to alter the flavor and/or aroma of foodstuffs, together with compositions containing such sulfinates and adapted to alter the flavor and/or aroma of foodstuffs.
摘要翻译：通过向食品中加入少量至少一种下式的亚磺酸盐来赋予食品水果香料的方法：O PARALLEL R1-OS-R2其中R1选自甲基，正己基和正癸基， R2选自甲基，正己基和正丙基，条件是当R 1为甲基时，R 2为正丙基或正己基; 并且条件是当R 2为甲基时，R 1为正癸基或正己基，有效地改变食品的风味和/或香气，以及含有这些亚硫酸盐的组合物，并适于改变食品的风味和/或香气。

8. 发明授权

US3980089A Novel heterocyclic flavoring compositions and processes 失效
标题翻译：新型杂环调味料组合物和方法
公开(公告)号：US3980089A
公开(公告)日：1976-09-14
申请号：US468180
申请日：1974-05-08
申请人： Alan O. Pittet , John V. Pascale , Denis E. Hruza
发明人： Alan O. Pittet , John V. Pascale , Denis E. Hruza
IPC分类号： A23L27/20 , A24B15/38 , C07D207/32 , C07D207/323 , A24B15/04
CPC分类号： C07D207/323 , A23L27/205 , A23L27/2054 , A24B15/385
摘要： The flavor and aroma of tobacco products are altered by adding thereto an effective amount of at least one N-substituted pyrrole having the formula: ##SPC1##Wherein R.sub.1 and R.sub.2 are hydrogen or alkyl and are the same or different and R.sub.3 is alkyl containing eight to fourteen carbon atoms, alkenyl containing three or four carbon atoms, cycloalkyl containing from three to twelve carbon atoms, phenalkyl containing seven to eleven carbon atoms, carboalkoxyalkyl having three to seven carbon atoms, alkoxyphenylalkyl having eight to twelve carbon atoms, hydroxyalkyl having two to five carbon atoms, alkoxyalkyl having two to six carbon atoms, (alkylthio)-alkyl having two to six carbon atoms, mercaptoalkyl having from two to six carbon atoms, mercaptophenyl, pyrazinyl, pyridinyl, or thiazolyl.
摘要翻译：通过向其中加入有效量的至少一种具有下式的N-取代吡咯来改变烟草产品的风味和香气：

9. 再颁专利

USRE29843E Substituted thiazoles and flavoring processes and products produced thereby 失效
标题翻译：由此生产的取代的噻唑和调味过程和产物
公开(公告)号：USRE29843E
公开(公告)日：1978-11-21
申请号：US807054
申请日：1977-06-16
申请人： Alan O. Pittet , Denis E. Hruza
发明人： Alan O. Pittet , Denis E. Hruza
IPC分类号： A23L27/20 , A24B15/36 , C07D277/22 , C07D277/24 , C07D277/34 , C07D277/36 , C11B9/00
CPC分类号： C07D277/22 , A23L27/2056 , A24B15/36 , A24B15/365 , C07D277/24 , C07D277/36 , C11B9/0096
摘要： Processes for altering the flavors and/or fragrances of materials which comprise adding thereto effective amounts of at least one thiazole having the formula: ##STR1## wherein R is hydrogen, alkyl, or acyl; X is .Iadd.alkyl, .Iaddend.alkoxy, .Iadd.or .Iaddend.hydrogen, .[.or when R and Y are alkyl, alkyl;.]. and Y is alkyl, acyl, alkoxy or hydrogen, no more than two of R, X and Y being hydrogen; .Iadd.with the proviso that X is alkyl only when either (i) R and Y are each alkyl or (ii) Y is alkoxy; .Iaddend.compositions containing such thiazoles and compositions; perfumed materials containing such thiazoles and compositions; and novel thiazoles and processes for producing same.

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