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    • 4. 发明申请
    • ARTICLES COMPRISING A WEATHER RESISTANT SILICONE COATING
    • 包含耐候硅胶涂层的文章
    • US20110143148A1
    • 2011-06-16
    • US12636750
    • 2009-12-13
    • Matthew David ButtsJohn Matthew BablinDavid Gilles GascoyneJudith SteinWilliam David Richards
    • Matthew David ButtsJohn Matthew BablinDavid Gilles GascoyneJudith SteinWilliam David Richards
    • B32B33/00B32B9/04C08K5/05C08K5/17C08K5/11C08K5/5419C08K5/13C08L83/04
    • C09D183/12C08K3/013C08K5/005Y10T428/31663
    • An article comprises a weatherable surface exposed to precipitation or airborne debris; and a weather resistant coating disposed on the weatherable surface, wherein the coating comprises component A, a one- or two-part room temperature vulcanizable polyorganosiloxane composition; and component B, an ice release-enhancing proportion of at least one polyorganosiloxane comprising one or more silanol or alkoxy-silyl groups and comprising from about 10 weight percent to about 85 weight percent of at least one hydroxy-terminated or alkoxy-terminated polyoxyalkylenealkyl radical; and any reaction products thereof. In another embodiment, an article comprises a weatherable surface exposed to precipitation or airborne debris; and a weather resistant coating disposed on the weatherable surface, wherein the coating includes a one- or two-part addition curable polyorganosiloxane composition comprising a resin polymer and a crosslinker, wherein the resin polymer and/or crosslinker comprises an ice release-enhancing proportion of covalently bound hydrophilic functionality that contributes from about 0.5 weight percent to about 40 weight percent of the coating composition; and any reaction products thereof.
    • 一件物品包括暴露于沉淀物或气载碎片的耐候性表面; 以及设置在耐候性表面上的耐候性涂层,其中所述涂层包含组分A,一份或两份室温可硫化聚有机硅氧烷组合物; 和组分B,至少一种包含一个或多个硅烷醇或烷氧基 - 甲硅烷基的聚有机硅氧烷的冰释放增强比例,包含约10重量%至约85重量%的至少一个羟基封端或烷氧基封端的聚氧化烯烷基 ; 及其任何反应产物。 在另一个实施方案中,制品包括暴露于沉淀或气载碎片的耐候性表面; 以及设置在耐候性表面上的耐候性涂层,其中所述涂层包括包含树脂聚合物和交联剂的一部分或两部分可加成固化的聚有机硅氧烷组合物,其中所述树脂聚合物和/或交联剂包含冰释放增强比例 共价结合的亲水性官能度,其占涂料组合物的约0.5重量%至约40重量% 及其任何反应产物。
    • 5. 发明授权
    • Method for improving selectivity for dialkyldichlorosilane
    • 提高二烷基二氯硅烷选择性的方法
    • US06407276B1
    • 2002-06-18
    • US09820025
    • 2001-03-29
    • Larry Neil LewisRobert Edgar ColbornJohn Matthew Bablin
    • Larry Neil LewisRobert Edgar ColbornJohn Matthew Bablin
    • C07F716
    • C07F7/16
    • A method for forming a dialkyldichlorosilane, comprising reacting elemental silicon with an alkyl chloride using copper as a catalyst together with promoters zinc, tin, and a special promoter. The special promoter is silver, a silver compound, gold, a gold compound, or combinations thereof. The alkyl may be methyl such that the dialkyldichlorosilane is dimethyldichlorosilane and the alkyl chloride is methyl chloride. The reacting generates the dialkyldichlorosilane in accordance with a first selectivity for the dialkyldichlorosilane that exceeds a second selectivity for the dialkyldichlorosilane. The second selectivity is a selectivity for the dialkyldichlorosilane that would have existed had the special promoter been absent.
    • 一种形成二烷基二氯硅烷的方法,包括使用铜作为催化剂与促进剂锌,锡和特殊的促进剂一起使元素硅与烷基氯反应。 特殊促进剂是银,银化合物,金,金化合物或其组合。 烷基可以是甲基,使得二烷基二氯硅烷是二甲基二氯硅烷,并且烷基氯是甲基氯。 该反应根据对二烷基二氯硅烷的第二选择性的二烷基二氯硅烷的第一选择性产生二烷基二氯硅烷。 第二选择性是对于二烷基二氯硅烷的选择性,如果没有特殊促进剂,那么它将存在。