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    • 6. 发明授权
    • Fluidized bed apparatus having spray chamber with pivotal slats
    • 流化床设备具有带有枢转板条的喷雾室
    • US06203761B1
    • 2001-03-20
    • US09284758
    • 1999-04-20
    • Kathleen PaatzWerner PichlerWilfried RaehseHans Raker
    • Kathleen PaatzWerner PichlerWilfried RaehseHans Raker
    • F27B1514
    • B01J2/16
    • A fluidized bed apparatus for the production and treatment of granules and a method for its operation is provided. The fluidized bed apparatus includes an entry chamber through which a gas is designed to flow upwards; a fluidization chamber for fluidizing the material located above the entry chamber; pivotal slats located between the entry chamber and the fluidization chamber; and a nozzle arm located in the chamber below the slats with a nozzle line ending in a nozzle which is directed into the fluidization chamber through cutouts in the slats and extends partly into the fluidization chamber. The fluidized bed apparatus has rigid nozzle arms and lines which are easily jacketed for heating and cooling applications.
    • 提供了一种用于生产和处理颗粒的流化床装置及其操作方法。 流化床装置包括入口室,气体通过该入口室向上流动; 用于使位于入口室上方的材料流化的流化室; 位于进入室和流化室之间的枢轴板条; 以及喷嘴臂,其位于板条下方的腔室中,喷嘴线终止于喷嘴,喷嘴线通过板条中的切口被引导到流化室中,并部分地延伸到流化室中。 流化床装置具有刚性喷嘴臂和管线,其容易夹套用于加热和冷却应用。
    • 7. 发明授权
    • Multicomponent mixtures based on water-soluble alkali metal silicate
compounds and their use, more particularly as builders in detergents
    • 基于水溶性碱金属硅酸盐化合物的多组分混合物及其用途,更特别地作为洗涤剂中的助洗剂
    • US5814597A
    • 1998-09-29
    • US700485
    • 1996-10-10
    • Wilfried RaehseJohann F. FuesKathleen PaatzWilhelm BeckWolfgang Hlavacek
    • Wilfried RaehseJohann F. FuesKathleen PaatzWilhelm BeckWolfgang Hlavacek
    • C01B33/32C11D3/02C11D3/06C11D3/08C11D3/10C11D3/20C11D3/37C11D11/00C11D11/02
    • C11D3/046C11D11/0082C11D11/02C11D3/06C11D3/08C11D3/10C11D3/2075C11D3/3761
    • The invention relates to a solid material (primary drying product) containing alkali metal silicate with a modulus (molar ratio of SiO.sub.2 to M.sub.2 O, M=alkali metal) of 0.8 to 4 in homogeneous admixture with other inorganic and/or organic useful materials and/or auxiliaries, which has been dried from a finely sprayed aqueous preparation of mixtures of the alkali metal silicates and the inorganic and/or organic useful materials and/or auxiliaries by means of a hot gas stream. The solid material according to the invention is characterized in that, as a primary drying product in homogeneous admixture with the alkali metal silicate, it contains at least 10% by weight of water-soluble inorganic and/or organic salts, has apparent densities of at least 150 g/l, possesses a microporous absorbent internal structure and has been dried with superheated steam as the hot gas stream. The invention also relates in particular to detergent builder systems based on multicomponent systems containing this overdried alkali metal silicate and to their use for subsequent impregnation with other free-flowing useful materials and mixtures thereof from the field of detergents and to the detergents obtained.
    • PCT No.PCT / EP95 / 00604 Sec。 371日期:1996年10月10日 102(e)日期1996年10月10日PCT提交1995年2月20日PCT公布。 第WO95 / 23841号公报 日期1995年9月8日本发明涉及含有碱金属硅酸盐的固体材料(初级干燥产物),其模量(SiO 2与M 2 O的摩尔比,M =碱金属)为0.8〜4,与其它无机和/或 有机有用材料和/或辅助剂,其已经通过热气流由碱金属硅酸盐和无机和/或有机有用材料和/或助剂的混合物的精细喷雾的水性制剂干燥。 根据本发明的固体材料的特征在于,作为与碱金属硅酸盐均匀混合的初级干燥产物,其含有至少10重量%的水溶性无机和/或有机盐,其表观密度为 至少150g / l,具有微孔吸收性内部结构,并用过热蒸汽作为热气流进行干燥。 本发明还特别涉及基于含有这种过度浸渍的碱金属硅酸盐的多组分体系的洗涤剂助洗剂体系,以及其用于随后从洗涤剂领域和所得洗涤剂的其它自由流动的有用材料及其混合物浸渍的用途。
    • 8. 发明授权
    • Enzyme granules containing phosphated starch
    • 含有磷酸化淀粉的酶颗粒
    • US06380140B1
    • 2002-04-30
    • US09171501
    • 1999-03-22
    • Kathleen PaatzWilfried RaehseWerner PichlerHorst Upadek
    • Kathleen PaatzWilfried RaehseWerner PichlerHorst Upadek
    • C11D742
    • B01J2/20B01J2/28C11D3/228C11D3/38672C12N9/98
    • Enzyme granules suitable for incorporating into detergents or cleaners are provided containing an enzyme, a carrier material and a granulation auxiliary containing phosphated starch. The phosphated starch preferably has a mean degree of phosphation ranging from 1.5 to 2.5. Carrier materials include starch, cereal flour, cellulose, alkali metal aluminosilicate, layer silicate and alkali metal salts. Enzymes include proteases, lipases, amylases and cellulases. A preferred carrier material contains water-swellable starch, sucrose, cereal flour and cellulose powder. The granulation auxiliary may contain a co-granulation auxiliary selected from polyethylene glycol having an average molecular weight of from 200 to 6,000, 1,2-propylene glycol and a poly-ethoxylate having a specified formula. Preferred granules have a mean particle size of from 0.3 to 3 mm. The granules are produced by forming a mixture containing an aqueous enzyme-containing liquid such as a concentrated fermentation broth, the carrier material and the granulation auxiliary, extruding the mixture, cutting the extruded mixture to obtain granules, and optionally spheronizing and drying the granules.
    • 提供适于掺入洗涤剂或清洁剂的酶颗粒,其含有酶,载体材料和含有磷酸化淀粉的造粒助剂。 磷酸化淀粉的平均磷酸化度优选为1.5〜2.5。 载体材料包括淀粉,谷物粉,纤维素,碱金属铝硅酸盐,层状硅酸盐和碱金属盐。 酶包括蛋白酶,脂肪酶,淀粉酶和纤维素酶。 优选的载体材料含有水溶胀性淀粉,蔗糖,谷物粉和纤维素粉末。 造粒助剂可以含有选自平均分子量为200〜6000的聚乙二醇,1,2-丙二醇和具有规定式的聚乙氧基化物的共制粒助剂。 优选的颗粒具有0.3至3mm的平均粒度。 通过形成含有含水液体如浓缩发酵液,载体材料和造粒辅助剂的混合物,挤出混合物,切割挤出的混合物以获得颗粒,并任选地使球形化和干燥颗粒而制备颗粒。
    • 9. 发明授权
    • Coated enzyme preparation with an improved solubility
    • 涂层酶制剂具有改善的溶解性
    • US06350728B1
    • 2002-02-26
    • US09319714
    • 1999-06-10
    • Kathleen PaatzWilfried RaehseWerner PichlerBeatrix Kottwitz
    • Kathleen PaatzWilfried RaehseWerner PichlerBeatrix Kottwitz
    • C11D3386
    • C11D17/0039C11D3/38672C12N9/98
    • An enzyme granule and means for producing the enzyme granule is presented. The enzyme granule is composed of an enzyme, a carrier material, and a coating system of 5 to 70 percent by weight fine-particle inorganic water-insoluble pigment, 45 to 90 percent by weight of a water-soluble organic substance having a melting point of from 40 to 70° C., and 0 to 30 percent by weight of a flow improver. The granule can be produced by mixing an aqueous enzyme liquid with an inorganic or organic carrier material to form an enzyme compound, extruding the enzyme compound, spheronizing the extrudate, and applying an outer coating layer of the coating system listed above to form an enzyme granule having a mean particle size of 0.8 to 1.4 millimeters. The coated enzyme granule has increased storage stability, even coloration, reduced odor, and releases enzyme activity quickly in water. The enzyme granule is useful in solid detergents.
    • 提供了酶颗粒和用于生产酶颗粒的方法。 酶颗粒由酶,载体材料和5〜70重量%的微粒无机水不溶性颜料的涂布体系组成,45〜90重量%的具有熔点的水溶性有机物质 为40-70℃,和0-30重量%的流动改进剂。 可以通过将含水酶液与无机或有机载体材料混合以形成酶化合物,挤出酶化合物,使挤出物滚圆,并施加上述涂覆体系的外涂层以形成酶颗粒来制备颗粒 平均粒度为0.8至1.4毫米。 包衣的酶颗粒具有增加的储存稳定性,甚至着色,减少气味,并在水中快速释放酶活性。 酶颗粒可用于固体洗涤剂。
    • 10. 发明授权
    • Process for deodorizing fermented culture broths with superheated steam
    • 用过热蒸汽除臭发酵培养液的方法
    • US5834275A
    • 1998-11-10
    • US750657
    • 1997-01-15
    • Wilfried RaehseKathleen PaatzWerner PichlerHorst Upadek
    • Wilfried RaehseKathleen PaatzWerner PichlerHorst Upadek
    • C12N9/52B01D1/18B01D3/38C11D3/386C12N9/98C12P1/00C12N9/00C12N9/50D06M16/00
    • C12N9/98C12P1/00
    • A process is provided for deodorizing an aqueous culture broth composition by: (a) providing an aqueous culture broth composition containing odorous compounds in spray form; (b) providing a stream of superheated steam; (c) providing a spray zone in vacuo; (d) simultaneously introducing both the aqueous composition of (a) and the superheated steam into the spray zone causing the odorous compounds to be entrained in the superheated steam, thus forming a deodorized aqueous culture broth composition; (e) removing the superheated steam containing the entrained odorous compounds from the spray zone; and (f) discharging the deodorized aqueous culture broth composition from the spray zone. Preferably, the culture broth composition is maintained at a temperature of less than 50.degree. C. in the spray zone to prevent inactivation of temperature-sensitive materials such as enzymes. Pressure in the spray zone may be about 10 to 250 mbar and temperature of the superheated steam can be up to 250.degree. C. The superheated steam may be introduced into the spray zone countercurrent to the culture broth composition. The deodorized culture broth composition can be recycled to the spray zone for further deodorization.
    • PCT No.PCT / EP95 / 02142 Sec。 371日期1997年1月17日 102(e)日期1997年1月17日PCT Filed June 6,1995 PCT Pub。 公开号WO95 / 34358 日期1995年12月21日提供了一种通过以下步骤对含水培养液组合物进行除臭的方法:(a)提供含有喷雾形式的含臭味化合物的含水培养液组合物; (b)提供过热蒸汽流; (c)真空提供喷雾区; (d)同时将(a)的水性组合物和过热蒸汽两者同时引入喷雾区,使得气味化合物被夹带在过热蒸汽中,从而形成除臭的含水培养液组合物; (e)从喷雾区域除去含有夹带的有气味化合物的过热蒸汽; 和(f)从喷雾区排出除臭的含水培养液组合物。 优选地,培养液组合物在喷雾区中保持在低于50℃的温度,以防止温度敏感材料如酶的失活。 喷雾区中的压力可以为约10至250毫巴,过热蒸汽的温度可高达250℃。过热蒸汽可以与培养肉汤组合物逆流引入喷雾区。 除臭的培养肉汤组合物可以再循环到喷雾区以进一步除臭。