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1. 发明授权

US09493673B2 Manganese complex as drier for coating compositions 有权
标题翻译：锰复合物作为涂料组合物的干燥剂
公开(公告)号：US09493673B2
公开(公告)日：2016-11-15
申请号：US13578026
申请日：2011-02-11
申请人： Johan Franz Gradus Antonius Jansen , Franciscus Adrianus Cornelis Bergman , Engelina Catharina Kleuskens
发明人： Johan Franz Gradus Antonius Jansen , Franciscus Adrianus Cornelis Bergman , Engelina Catharina Kleuskens
IPC分类号： C08K5/34 , C08K5/3435 , B05D3/02 , C09D167/03 , C08G18/08 , C09D167/06 , C09D175/14 , C09D7/12
CPC分类号： C09D167/03 , C08G18/0804 , C09D7/63 , C09D167/06 , C09D175/14
摘要： An air drying auto-oxidizable resin composition comprising components: a) a drier comprising a manganese carboxylate complex, and b) a polymer comprising unsaturated fatty acid residues, wherein the manganese carboxylate complex a) has the following structure I: wherein R1═H, C1-C20 alkyl optionally substituted with heteroatoms, or C6-C20 aryl optionally substituted with heteroatoms; X and Y are independently selected from O and OC(R3)O, in which a=4 when X═O, and a=3 when X═OC(R3)O, and in which b=4 when Y═O, and b=3 when Y═OC(R3)O; R2=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; and R3═C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue.

2. 发明授权

US09534139B2 Manganese salt complex as drier for coating compositions 有权
标题翻译：锰盐复合物作为涂料组合物的干燥剂
公开(公告)号：US09534139B2
公开(公告)日：2017-01-03
申请号：US13577976
申请日：2011-02-11
申请人： Johan Franz Gradus Antonius Jansen , Franciscus Adrianus Cornelis Bergman , Engelina Catharina Kleuskens , Ronald Hage
发明人： Johan Franz Gradus Antonius Jansen , Franciscus Adrianus Cornelis Bergman , Engelina Catharina Kleuskens , Ronald Hage
IPC分类号： C08K5/34 , C08K5/3435 , B05D3/02 , C09D167/03 , C08G18/08 , C09D167/06 , C09D175/14 , C09D7/12
CPC分类号： C09D167/03 , C08G18/0804 , C09D7/63 , C09D167/06 , C09D175/14
摘要： An air drying auto-oxidizable resin composition comprising components: a) a drier comprising a manganese salt complex, and b) a polymer comprising unsaturated fatty acid residues, wherein the manganese salt complex has the following structure I: wherein the anion is selected from Cl−, NO3− or R2COO−, in which case n=2; or the anion is SO42−, in which case n=1; wherein X,Y,Z are independently selected from O, OH, OH2, OC(R3)O, and R4BO2 and wherein a and b are independently an integer of value 2, 3 or 4; R1═H, C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms; R2=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; and R3=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue. R4═C1-C20 alkyl optionally substituted with heteroatoms, or C6-C20 aryl optionally substituted with heteroatoms.
摘要翻译：一种空气干燥自氧化树脂组合物，其包含以下组分：a）包含锰盐络合物的干燥器，和b）包含不饱和脂肪酸残基的聚合物，其中所述锰盐络合物具有以下结构I：其中所述阴离子选自Cl - ，NO 3 - 或R 2 COO-，在这种情况下n = 2; 或阴离子为SO42-，在这种情况下n = 1; 其中X，Y，Z独立地选自O，OH，OH2，OC（R3）O和R4BO2，并且其中a和b独立地是数值2,3或4的整数; R1 = H，任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基; R2 =任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基; 和R3 =任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基。 R4 =任选被杂原子取代的C 1 -C 20烷基，或任选被杂原子取代的C 6 -C 20芳基。

3. 发明申请

US20130203903A1 MANGANESE COMPLEX DRIER FOR COATING COMPOSITIONS 有权
标题翻译：用于涂料组合物的MANGANESE复合干燥剂
公开(公告)号：US20130203903A1
公开(公告)日：2013-08-08
申请号：US13578433
申请日：2011-02-11
申请人： Johan Franz Gradus Antonius Jansen , Engelina Catharina Kleuskens , Ruben Van Summeren , Paulus Lambertus Alsters
发明人： Johan Franz Gradus Antonius Jansen , Engelina Catharina Kleuskens , Ruben Van Summeren , Paulus Lambertus Alsters
IPC分类号： C09D167/03
CPC分类号： C09D167/03 , C08G18/0804 , C09D7/63 , C09D167/06 , C09D175/14
摘要： Use of a transition metal complex a) as a drier for air drying auto-oxidative resin composition comprising a polymer b) comprising unsaturated fatty acid residues, wherein the transition metal complex a) has a cation of the following structure (I) wherein R=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; R1=H, C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms; X=O, OC(R2)O in which a=4 when X=O, and a=3 when X=OC(R2)O, R2=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue.
摘要翻译：使用过渡金属络合物a）作为用于空气干燥自动氧化树脂组合物的干燥器，其包含聚合物b）包含不饱和脂肪酸残基，其中过渡金属络合物a）具有以下结构（I）的阳离子，其中R = 任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基; R1 = H，任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基; X = O，OC（R2）O，其中当X = O时a = 4，当X = OC（R2）O时，a = 3，R2 =任选被杂原子取代的C 1 -C 20烷基，杂原子或聚合物残基。

4. 发明授权

US09228110B2 Manganese complex drier for coating compositions 有权
标题翻译：用于涂料组合物的锰复合干燥器
公开(公告)号：US09228110B2
公开(公告)日：2016-01-05
申请号：US13578433
申请日：2011-02-11
申请人： Johan Franz Gradus Antonius Jansen , Engelina Catharina Kleuskens , Ruben Van Summeren , Paulus Lambertus Alsters
发明人： Johan Franz Gradus Antonius Jansen , Engelina Catharina Kleuskens , Ruben Van Summeren , Paulus Lambertus Alsters
IPC分类号： C09D167/03 , C08G18/08 , C09D167/06 , C09D175/14 , C09D7/12
CPC分类号： C09D167/03 , C08G18/0804 , C09D7/63 , C09D167/06 , C09D175/14
摘要： Use of a transition metal complex a) as a drier for air drying auto-oxidative resin composition comprising a polymer b) comprising unsaturated fatty acid residues, wherein the transition metal complex a) has a cation of the following structure (I) wherein R═C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; R1═H, C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms; X═O, OC(R2)O in which a=4 when X═O, and a=3 when X═OC(R2)O, R2═C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue.
摘要翻译：使用过渡金属络合物a）作为用于空气干燥自动氧化树脂组合物的干燥器，其包含聚合物b）包含不饱和脂肪酸残基，其中过渡金属络合物a）具有以下结构（I）的阳离子，其中R = 任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基; 任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基; X = O，OC（R2）O，其中当X = O时a = 4，当X = OC（R2）O，R2 =任选被杂原子取代的C 1 -C 20烷基时，a = 3，杂原子或聚合物残基。

5. 发明授权

US09296917B2 Low temperature cure heat-curable powder coating composition comprising a crystalline polyester resin, an amorphous polyester resin, a crosslinking agent and a thermal radical initiator 有权
标题翻译：包含结晶聚酯树脂，无定形聚酯树脂，交联剂和热自由基引发剂的低温固化热固化粉末涂料组合物
公开(公告)号：US09296917B2
公开(公告)日：2016-03-29
申请号：US13696449
申请日：2011-05-06
申请人： Tosko Alexandar Misev , Leendert Jan Molhoek , Johan Franz Gradus Antonius Jansen , Nicole Van Der Werf , Sven Johan Wilbert Reijmer , Jan Pieter Drijfhout , Peter Wellenberg
发明人： Tosko Alexandar Misev , Leendert Jan Molhoek , Johan Franz Gradus Antonius Jansen , Nicole Van Der Werf , Sven Johan Wilbert Reijmer , Jan Pieter Drijfhout , Peter Wellenberg
IPC分类号： C08L67/00 , C08K5/00 , C09D167/02 , C09D167/00 , C09D167/06 , C08K3/00 , C08K5/06 , C08K5/10 , C08K5/101 , C08K5/14 , C08L67/06
CPC分类号： C09D167/02 , C08K3/011 , C08K5/0025 , C08K5/06 , C08K5/10 , C08K5/101 , C08K5/14 , C08L67/00 , C08L67/06 , C09D167/00 , C09D167/06 , C08L2666/18
摘要： The invention relates to a heat-curable powder coating composition comprising i) at least one crystalline polyester resin present in an amount of at most 90 wt %; and ii) at least one amorphous polyester resin; and iii) at least one crosslinking agent; and iv) at least one thermal radical initiator, wherein, the at least one crystalline polyester resin and/or the at least one amorphous polyester resin has di-acid ethylenic unsaturations; wherein the at least one crosslinking agent is either crystalline or amorphous; wherein the at least one crosslinking agent has reactive unsaturations that are reactable with the ethylenic unsaturations of the di-acid ethylenic unsaturations of the at least one crystalline polyester resin and/or the at least one amorphous polyester resin to be crosslinked, said unsaturations of the crosslinking agent are different from the unsaturations of the at least one crystalline polyester resin and the unsaturations of the at least amorphous polyester resin; wherein the wt % is based on the total amount of i)+ii)+iii). The compositions of the invention may be cured to an acceptable degree at low temperature of for example at most 130° C. for at most 20 minutes, said compositions may be ground, sieved and extrudable and said compositions can upon heat cure form powder coatings that may also exhibit a good balance of properties between good flexibility, good smoothness and good adhesion. In addition, the compositions of the invention can suitably be used on heat- and/or non heat-sensitive, even if the composition is highly pigmented.
摘要翻译：本发明涉及一种可热固化粉末涂料组合物，其包含i）至少一种以至多90重量％存在的结晶聚酯树脂; 和ii）至少一种无定形聚酯树脂; 和iii）至少一种交联剂; 和iv）至少一种热自由基引发剂，其中所述至少一种结晶聚酯树脂和/或所述至少一种无定形聚酯树脂具有二酸烯属不饱和度; 其中所述至少一种交联剂是结晶或无定形的; 其中所述至少一种交联剂具有可与所述至少一种结晶性聚酯树脂和/或所述至少一种待交联的至少一种无定形聚酯树脂的二酸烯属不饱和度的烯属不饱和度反应的反应性不饱和度，所述不饱和度交联剂不同于至少一种结晶聚酯树脂的不饱和度和至少非晶形聚酯树脂的不饱和度; 其中wt％基于i）+ ii）+ iii）的总量。本发明的组合物可以在低温例如最多130℃下固化至可接受的程度，最多20分钟，所述组合物可以研磨，筛分和挤出，并且所述组合物可以在热固化时形成粉末涂料，也可以在良好的柔韧性，良好的光滑度和良好的粘合性之间表现出良好的性能平衡。此外，即使组合物高度着色，本发明的组合物也可适用于热和/或非热敏感。

6. 发明授权

US08716368B2 Unsaturated polyester resin or vinyl ester resin composition 有权
标题翻译：不饱和聚酯树脂或乙烯基酯树脂组合物
公开(公告)号：US08716368B2
公开(公告)日：2014-05-06
申请号：US11921646
申请日：2006-06-06
申请人： Johan Franz Gradus Antonius Jansen , Ivo Ronald Kraeger
发明人： Johan Franz Gradus Antonius Jansen , Ivo Ronald Kraeger
IPC分类号： C08L67/00 , C08K5/07 , C08L33/04 , C08L67/06 , C08K5/00 , C08K5/16 , C08K3/08
CPC分类号： C08L63/10 , C08K5/07 , C08L33/08 , C08L33/10 , C08L67/06 , C08L67/07 , C08L67/08 , C08L2666/04
摘要： This invention relates to unsaturated polyester resin or vinyl ester resin compositions comprising a polymer containing reactive unsaturations as a resin; a 1,3-dioxo-component, and optionally a reactive diluent and/or an inhibitor and/or a stabilizer; the resin compositions being curable with a peroxide component, and wherein the resin in the resin composition has an acid value=10; and the resin composition contains—while being cured—a base, which is either selected from the group of organic or inorganic oxides, hydroxides, alkoxides or carboxylates for each of which the cation has a redox potential of the metal of at most −1V, or of ammonium ions; or is selected from the group of nitrogen-containing organic compounds. The present invention also relates to objects and structural parts prepared from such resin composition by curing with a peroxide. Finally the invention also relates to methods of peroxide curing of unsaturated polyester or vinyl ester curing and its use in chemical anchoring, roof coatings etc.
摘要翻译：本发明涉及不饱和聚酯树脂或乙烯基酯树脂组合物，其包含含有作为树脂的反应性不饱和度的聚合物; 1,3-二氧代组分和任选的反应性稀释剂和/或抑制剂和/或稳定剂; 所述树脂组合物可用过氧化物组分固化，并且其中树脂组合物中的树脂的酸值= 10; 并且所述树脂组合物含有固化的碱，所述碱选自有机或无机氧化物，氢氧化物，醇盐或羧酸盐，其中阳离子的金属氧化还原电位至多为-1V，或铵离子; 或选自含氮有机化合物的组。本发明还涉及通过用过氧化物固化由这种树脂组合物制备的物体和结构部件。本发明还涉及不饱和聚酯或乙烯基酯固化的过氧化物固化方法及其在化学锚固，屋顶涂料等中的应用。

7. 发明授权

US08513343B2 Unsaturated polyester resin compositions 有权
标题翻译：不饱和聚酯树脂组合物
公开(公告)号：US08513343B2
公开(公告)日：2013-08-20
申请号：US12307395
申请日：2007-07-05
申请人： Johan Franz Gradus Antonius Jansen , Ronald Ivo Kraeger
发明人： Johan Franz Gradus Antonius Jansen , Ronald Ivo Kraeger
IPC分类号： C08K5/04 , C08G18/42 , C08L33/04
CPC分类号： C08F299/04 , C08F283/01 , C08K5/0091 , C08K5/07 , C08K5/16 , Y10T428/1362 , Y10T428/2395 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin composition comprising an unsaturated polyester resin, a manganese compound, a 1,3-dioxo compound and a base; the molar ratio between the dioxo compound and the basic functionality of the base is from 170:1 to 1:30 and the resin composition being curable with a peroxide. The present invention further relates to a process for radically curing such a resin composition wherein a peroxide is added to the resin composition and the curing is effected in the absence of cobalt.
摘要翻译：本发明涉及不饱和聚酯树脂组合物，其包含不饱和聚酯树脂，锰化合物，1,3-二氧化合物和碱; 二氧化合物与碱的官能度之间的摩尔比为170:1至1:30，树脂组合物可用过氧化物固化。本发明还涉及一种使这种树脂组合物自由基固化的方法，其中在树脂组合物中加入过氧化物，并且在没有钴的情况下进行固化。

8. 发明申请

US20130190452A1 MULTICOMPONENT RESIN SYSTEM 有权
标题翻译：多元树脂系统
公开(公告)号：US20130190452A1
公开(公告)日：2013-07-25
申请号：US13577752
申请日：2011-02-11
申请人： Arie Boer Den , Johan Franz Gradus Antonius Jansen , Daniel Raimann
发明人： Arie Boer Den , Johan Franz Gradus Antonius Jansen , Daniel Raimann
IPC分类号： C08L35/02
CPC分类号： C08L35/02 , C08F299/0492 , C08G59/5006 , C08G59/68 , C08G59/681 , C08K5/005 , C08K5/0091 , C08K5/32 , C08K5/3432 , C08L63/00 , C08L63/10 , C08L67/06 , C08L2205/02 , C08L2666/22 , C08L33/068
摘要： The present invention relates to a multicomponent resin system comprising a. a compound capable of undergoing a radical copolymerization selected from the group consisting of unsaturated polyester resins, vinyl ester resins and mixtures thereof b. an epoxide functional resin as compound capable of reacting with a primary and/or secondary aliphatic amine, c. a transition metal compound, d. a primary and/or secondary aliphatic amine characterized in that the transition metal is selected from the group consisting of Cu, Mn, Fe and mixtures thereof.
摘要翻译：本发明涉及一种多组分树脂体系，其包含a。能够进行自由基共聚的化合物，其选自不饱和聚酯树脂，乙烯基酯树脂及其混合物。作为能够与伯和/或仲脂族胺反应的化合物的环氧官能树脂，c。过渡金属化合物，d。其特征在于所述过渡金属选自Cu，Mn，Fe及其混合物。

9. 发明申请

US20120157618A1 UNSATURATED POLYESTER RESIN 审中-公开
标题翻译：不饱和聚酯树脂
公开(公告)号：US20120157618A1
公开(公告)日：2012-06-21
申请号：US13202163
申请日：2010-03-24
申请人： Marian Henryk Szkudlarek , Johan Franz Gradus Antonius Jansen
发明人： Marian Henryk Szkudlarek , Johan Franz Gradus Antonius Jansen
IPC分类号： C08L67/02 , B32B1/08 , B32B1/02 , C08G18/42
CPC分类号： C08G63/52 , C08F283/01 , C09D5/03 , C09D167/06 , Y10T428/1352 , Y10T428/139 , Y10T428/1393
摘要： The present invention relates to a resin composition comprising an unsaturated polyester resin comprising 1,3-propane diol building blocks and C5-C10 unsaturated dicarboxylic acid building blocks and further comprising a reactive diluent. Preferably, at least part of the 1,3-propane diol is derived from a non-fossil source. Preferably, itaconic acid or anhydride is used as the C5 unsaturated dicarboxylic acid.
摘要翻译：本发明涉及包含不饱和聚酯树脂的树脂组合物，其包含1,3-丙二醇结构单元和C5-C10不饱和二羧酸结构单元，并且还包含反应性稀释剂。优选地，1,3-丙二醇的至少一部分来源于非化石源。优选地，衣康酸或酸酐用作C5不饱和二羧酸。

10. 发明申请

US20120094136A1 PROCESS FOR PREPARING ORGANIC NANOPARTICLES 审中-公开
标题翻译：制备有机纳米颗粒的方法
公开(公告)号：US20120094136A1
公开(公告)日：2012-04-19
申请号：US13313923
申请日：2011-12-07
申请人： Matthias Jozef Gertruda BROUNS , Joseph Petronella Friederichs , Johan Franz Gradus Antonius Jansen , Marco Marcus Matheus Driessen
发明人： Matthias Jozef Gertruda BROUNS , Joseph Petronella Friederichs , Johan Franz Gradus Antonius Jansen , Marco Marcus Matheus Driessen
IPC分类号： B32B29/04 , C08F2/22 , C08F283/01 , B82Y30/00 , B82B3/00
CPC分类号： C08F267/06 , C08F263/00 , C08F263/02 , C08F283/01 , C08L51/003 , C08L51/08 , C09D151/003 , C09D151/08 , Y10T428/3179 , Y10T428/31906 , C08L2666/02
摘要： The invention provides a process for preparing organic nanoparticles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin, an initiator and a hydrophobic monomer; (b) emulsifying the solution obtained in step (a) in an aqueous phase; and thereafter (c) curing the emulsified solution. The invention further provides organic nanoparticles obtainable by the process according to the invention; various uses of said nanoparticles; and paper, dye compositions and toner compositions comprising said nanoparticles.
摘要翻译：本发明提供一种制备有机纳米颗粒的方法，包括以下步骤：（a）制备包含不饱和聚酯和/或乙烯基酯树脂，引发剂和疏水性单体的溶液; （b）在水相中乳化步骤（a）中获得的溶液; 然后（c）固化乳化溶液。本发明还提供可通过本发明方法获得的有机纳米颗粒; 所述纳米颗粒的各种用途; 以及包含所述纳米颗粒的纸，染料组合物和调色剂组合物。

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