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1. 发明授权

US09708434B2 Multigraft copolymers as superelastomers 有权
公开(公告)号：US09708434B2
公开(公告)日：2017-07-18
申请号：US13877229
申请日：2011-09-30
申请人： Jimmy W. Mays , Samuel P. Gido , Roland Weidisch , Liane Weidisch , Christina Weidisch
发明人： Jimmy W. Mays , Samuel P. Gido , Roland Weidisch
IPC分类号： C08F299/00 , C09J151/00 , A61L31/10 , C09D151/00 , C08L51/00 , A61L31/16 , C08F279/02 , C08K3/00 , C09D151/04 , C09J151/04 , A61L29/04 , A61L31/04
CPC分类号： C08F299/00 , A61L29/04 , A61L31/04 , A61L31/10 , A61L31/16 , C08F279/02 , C08K3/013 , C08L51/003 , C09D151/003 , C09D151/04 , C09J151/003 , C09J151/04 , Y10T428/2918 , Y10T428/31645 , Y10T428/31667 , Y10T428/31692 , Y10T428/31899 , Y10T428/31938 , Y10T442/20 , C08K3/0033
摘要： Thermoplastic elastomer compositions are described comprising multigraft copolymers. The multigraft copolymers can comprise a rubbery polymeric backbone and a plurality of glassy polymeric side chains, each attached at one of a plurality of branch points randomly spaced along the backbone. The copolymer materials have high tensile strength, high strain at break, and low residual strain after elongation. The compositions can be used as adhesives and in a wide variety of high tech, medical, and commodity applications.

2. 发明申请

US20140161858A1 Multigraft Copolymers as Superelastomers 有权
标题翻译：多重共聚物作为超弹性体
公开(公告)号：US20140161858A1
公开(公告)日：2014-06-12
申请号：US13877229
申请日：2011-09-30
申请人： Jimmy W Mays , Liane Weidisch , Samuel P Gido , Christina Weidisch
发明人： Jimmy W. Mays , Samuel P. Gido , Roland Weidisch
IPC分类号： C08F299/00 , C09J151/00 , A61L31/10 , C09D151/00 , C08L51/00 , A61L31/16
CPC分类号： C08F299/00 , A61L29/04 , A61L31/04 , A61L31/10 , A61L31/16 , C08F279/02 , C08K3/013 , C08L51/003 , C09D151/003 , C09D151/04 , C09J151/003 , C09J151/04 , Y10T428/2918 , Y10T428/31645 , Y10T428/31667 , Y10T428/31692 , Y10T428/31899 , Y10T428/31938 , Y10T442/20 , C08K3/0033
摘要： Thermoplastic elastomer compositions are described comprising multigraft copolymers. The multigraft copolymers can comprise a rubbery polymeric backbone and a plurality of glassy polymeric side chains, each attached at one of a plurality of branch points randomly spaced along the backbone. The copolymer materials have high tensile strength, high strain at break, and low residual strain after elongation. The compositions can be used as adhesives and in a wide variety of high tech, medical, and commodity applications.
摘要翻译：描述了包含多接枝共聚物的热塑性弹性体组合物。多接枝共聚物可以包括橡胶状聚合物主链和多个玻璃状聚合物侧链，每个侧链在沿骨架随机分布的多个分支点中的一个上附着。共聚物材料具有高拉伸强度，高断裂应变和伸长后的低残余应变。组合物可用作粘合剂和各种高科技，医疗和商品应用。

3. 发明申请

US20090028356A1 DIAPHONIC ACOUSTIC TRANSDUCTION COUPLER AND EAR BUD 有权
标题翻译：离子声波传感耦合器和耳机
公开(公告)号：US20090028356A1
公开(公告)日：2009-01-29
申请号：US12178236
申请日：2008-07-23
申请人： Stephen D. Ambrose , Samuel P. Gido , Jimmy W. Mays , Roland Weidisch , Robert B. Schulein
发明人： Stephen D. Ambrose , Samuel P. Gido , Jimmy W. Mays , Roland Weidisch , Robert B. Schulein
IPC分类号： G10K11/16 , H04R1/10
CPC分类号： H04R1/1016 , H04R1/1091
摘要： The disclosed methods and devices incorporate a novel expandable bubble portion which provides superior fidelity to a listener while minimizing listener fatigue. The expandable bubble portion may be expanded through the transmission of low frequency audio signals or the pumping of a gas to the expandable bubble portion. In addition, embodiments of the acoustic device may be adapted to consistently and comfortably fit to any ear, providing for a variable, impedance matching acoustic seal to both the tympanic membrane and the audio transducer, respectively, while isolating the sound-vibration chamber within the driven bubble. This reduces the effect of gross audio transducer vibration excursions on the tympanic membrane and transmits the audio content in a manner which allows the ear to utilize its full inherent capabilities.
摘要翻译：所公开的方法和装置结合了一种新颖的可膨胀气泡部分，其在使听众疲劳最小化的同时向收听者提供优良的保真度。可扩张气泡部分可以通过低频音频信号的传输或将气体泵送到可膨胀气泡部分而扩展。此外，声学装置的实施例可以适于一致地和舒适地适合于任何耳朵，分别为鼓膜和音频换能器两者提供可变的阻抗匹配声学密封，同时隔离声音振动室驱动泡沫。这减少了大量音频传感器振动偏移对鼓膜的影响，并以允许耳朵利用其完整固有能力的方式传输音频内容。

4. 发明授权

US08340310B2 Diaphonic acoustic transduction coupler and ear bud 有权
标题翻译：耳声声传导耦合器和耳芽
公开(公告)号：US08340310B2
公开(公告)日：2012-12-25
申请号：US12178236
申请日：2008-07-23
申请人： Stephen D. Ambrose , Samuel P. Gido , Jimmy W. Mays , Roland Weidisch , Robert B. Schulein
发明人： Stephen D. Ambrose , Samuel P. Gido , Jimmy W. Mays , Roland Weidisch , Robert B. Schulein
IPC分类号： G10K11/16 , H04R1/10
CPC分类号： H04R1/1016 , H04R1/1091
摘要： The disclosed methods and devices incorporate a novel expandable bubble portion which provides superior fidelity to a listener while minimizing listener fatigue. The expandable bubble portion may be expanded through the transmission of low frequency audio signals or the pumping of a gas to the expandable bubble portion. In addition, embodiments of the acoustic device may be adapted to consistently and comfortably fit to any ear, providing for a variable, impedance matching acoustic seal to both the tympanic membrane and the audio transducer, respectively, while isolating the sound-vibration chamber within the driven bubble. This reduces the effect of gross audio transducer vibration excursions on the tympanic membrane and transmits the audio content in a manner which allows the ear to utilize its full inherent capabilities.
摘要翻译：所公开的方法和装置结合了一种新颖的可膨胀气泡部分，其在使听众疲劳最小化的同时向收听者提供优良的保真度。可扩张气泡部分可以通过低频音频信号的传输或将气体泵送到可膨胀气泡部分而扩展。此外，声学装置的实施例可以适于一致地和舒适地适合于任何耳朵，分别为鼓膜和音频换能器两者提供可变的阻抗匹配声学密封，同时隔离声音振动室驱动泡沫。这减少了大量音频传感器振动偏移对鼓膜的影响，并以允许耳朵利用其完整固有能力的方式传输音频内容。

5. 发明授权

US08536279B2 Phase-separating block or graft copolymers comprising incompatible hard blocks and moulding compositions having a high stiffness 有权
标题翻译：包含不相容的硬块和具有高刚度的模塑组合物的相分离嵌段或接枝共聚物
公开(公告)号：US08536279B2
公开(公告)日：2013-09-17
申请号：US13141870
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： C08L53/02 , C08F279/00
CPC分类号： C08L25/10 , C08F257/02 , C08F279/02 , C08F297/04 , C08F297/044 , C08L25/06 , C08L51/003 , C08L51/06 , C08L53/02 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.
摘要翻译：包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

6. 发明申请

US20120061287A1 PHASE-SEPARATING BLOCK OR GRAFT COPOLYMERS COMPRISING INCOMPATIBLE HARD BLOCKS AND MOULDING COMPOSITIONS HAVING A HIGH STIFFNESS 有权
标题翻译：包含不合适硬块的相分离块或共聚物和具有高刚度的成型组合物
公开(公告)号：US20120061287A1
公开(公告)日：2012-03-15
申请号：US13141870
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： B65D85/86 , C08L53/02 , C08F12/08
CPC分类号： C08L25/10 , C08F257/02 , C08F279/02 , C08F297/04 , C08F297/044 , C08L25/06 , C08L51/003 , C08L51/06 , C08L53/02 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.
摘要翻译：包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％的组分的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

7. 发明申请

US20050215723A1 Blends of styrene/butadiene block copolymers 失效
标题翻译：苯乙烯/丁二烯嵌段共聚物的共混物
公开(公告)号：US20050215723A1
公开(公告)日：2005-09-29
申请号：US11085473
申请日：2005-03-22
申请人： Konrad Knoll , Roland Weidisch
发明人： Konrad Knoll , Roland Weidisch
IPC分类号： C08L53/02 , C08F293/00
CPC分类号： C08L53/02 , C08L2205/02 , C08L2666/24
摘要： A blend comprising a) from 5 to 40% by weight of a linear block copolymer of vinylaromatic monomers and dienes of the structure (I) S1—(B/S)1—S2 having a flexible phase fraction (B/S)1 of not more than 55% by weight, based on the block copolymer (I) and b) from 95 to 60% by weight of a linear block copolymer of vinylaromatic monomers and dienes of the structure (II) S3—(B/S)2—S4 having a flexible phase fraction (B/S)2 of at least 65% by weight, based on the block copolymer (II), where S1 is a block of vinylaromatic monomers having a number average molar mass Mn in the range from 40 000 to 100 000 g/mol, S2, S3 and S4 are in each case blocks of vinylaromatic monomers having a number average molar mass Mn in the range from 5000 to 20 000 g/mol, (B/S)1 and (B/S)2 are in each case copolymer blocks of dienes and vinylaromatic monomers having a number average molar mass Mn in the range from 15 000 to 40 000 g/mol.
摘要翻译：一种共混物，其包含a）5至40重量％的乙烯基芳族单体和结构（I）S 1 - （B / S）1 95至60重量％的乙烯基芳族单体和结构（II）的二烯的线性嵌段共聚物S 3 - （B / S）2 -S < 基于嵌段共聚物（II），具有至少65重量％的柔性相分数（B / S）2 的4 是一种乙烯基芳族单体，其数均摩尔质量M n n在40 000至100 000g / mol的范围内，S 2，S 3，在每种情况下，数均分子量为5000〜200000g / mol的乙烯基芳族单体的嵌段（B / S）＆lt; 1＆gt;和（B / S）2＆lt; 2＆gt;在各种情况下是二烯和乙烯基的共聚物嵌段具有15000至40000g / mol的数均摩尔质量M n n N的芳族单体。

8. 发明申请

US20110257335A1 PHASE-SEPARATING BLOCK COPOLYMERS COMPOSED OF INCOMPATIBLE HARD BLOCKS AND MOLDING MATERIALS WITH HIGH STIFFNESS 审中-公开
标题翻译：组成不可分割硬块的相分离块状共聚物和具有高刚度的成型材料
公开(公告)号：US20110257335A1
公开(公告)日：2011-10-20
申请号：US13141840
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： C08L53/02 , C08F279/00
CPC分类号： C08F297/04 , C08L25/06 , C08L25/10 , C08L51/04 , C08L51/06 , C08L53/02 , C08L2205/02 , C08L2205/03 , C08L2666/02 , C08L2666/24 , C08L2666/04
摘要： A block copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprisinga) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, andb) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., andc) at least one copolymer block (S/B)B composed of from 20 to 60% by weight of vinylaromatic monomers and from 40 to 80% by weight of dienes, with glass transition temperature TgB in the range from 0 to −80° C.,where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, and the proportion by weight of the entirety of all of the blocks (S/B)A and (S/B)B is in the range from 30 to 50% by weight, based in each case on the block copolymer A, and also mixtures thereof, and their use.
摘要翻译：一种重均摩尔质量Mw至少为100000g / mol的嵌段共聚物，包含a）至少一种由95-100％（重量）乙烯基芳族单体和0-5％（重量）二烯组成的嵌段S，和b）由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的至少一种共聚物嵌段（S / B）A，玻璃化转变温度TgA在5至30℃的范围内 C）和c）由20至60重量％的乙烯基芳族单体和40至80重量％的二烯组成的至少一种共聚物嵌段（S / B）B，玻璃化转变温度TgB为0 至-80℃，其中全部块S的重量比例在50至70重量％的范围内，并且全部块的重量比（S / B ）A和（S / B）B在30至50重量％的范围内，基于嵌段共聚物A的每种情况，以及它们的混合物及其用途。

9. 发明授权

US07524899B2 Blends of styrene/butadiene block copolymers 失效
标题翻译：苯乙烯/丁二烯嵌段共聚物的共混物
公开(公告)号：US07524899B2
公开(公告)日：2009-04-28
申请号：US11085473
申请日：2005-03-22
申请人： Konrad Knoll , Roland Weidisch
发明人： Konrad Knoll , Roland Weidisch
IPC分类号： C08L53/02
CPC分类号： C08L53/02 , C08L2205/02 , C08L2666/24
摘要： A blend comprising a) from 5 to 40% by weight of a linear block copolymer of vinylaromatic monomers and dienes of the structure (I) S1—(B/S)1—S2 having a flexible phase fraction (B/S)1 of not more than 55% by weight, based on the block copolymer (I) and b) from 95 to 60% by weight of a linear block copolymer of vinylaromatic monomers and dienes of the structure (II) S3—(B/S)2—S4 having a flexible phase fraction (B/S)2 of at least 65% by weight, based on the block copolymer (II), where S1 is a block of vinylaromatic monomers having a number average molar mass Mn in the range from 40 000 to 100 000 g/mol, S2, S3 and S4 are in each case blocks of vinylaromatic monomers having a number average molar mass Mn in the range from 5000 to 20 000 g/mol, (B/S)1 and (B/S)2 are in each case copolymer blocks of dienes and vinylaromatic monomers having a number average molar mass Mn in the range from 15 000 to 40 000 g/mol.
摘要翻译：一种共混物，其包含a）5至40重量％的乙烯基芳族单体和结构（I）S1-（B / S）1-S2的二烯的线性嵌段共聚物，其具有柔性相分数（B / S）1 不超过55重量％，基于嵌段共聚物（I）和b）95至60重量％的乙烯基芳族单体和结构（II）S3-（B / S）2的二烯的线型嵌段共聚物 -S4具有基于嵌段共聚物（II）至少65重量％的柔性相分数（B / S）2，其中S1是数均摩尔质量Mn在40的范围内的乙烯基芳族单体的嵌段 000〜100 000g / mol，S2，S3和S4分别为数均摩尔质量Mn为5000〜200000g / mol，（B / S）1和（B / S）2分别为数均摩尔质量Mn在15000至40000g / mol范围内的二烯和乙烯基芳族单体的共聚物嵌段。

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