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    • 2. 发明授权
    • Fusing-station roller
    • 定影辊
    • US07001653B2
    • 2006-02-21
    • US10668014
    • 2003-09-22
    • Jiann-Hsing ChenJoseph A. PavliskoPo-Jen ShihRobert A. Lancaster
    • Jiann-Hsing ChenJoseph A. PavliskoPo-Jen ShihRobert A. Lancaster
    • B32B1/08B32B27/20B32B27/30G03G15/20
    • G03G15/2057Y10T428/1393Y10T428/249972Y10T428/256Y10T428/26Y10T428/3154
    • A controlled modulus fusing-station member inclusive of a durable, tough, elastically deformable layer incorporating hollow flexible filler particles. The elastically deformable layer is preferably a single layer on a substrate, the substrate preferably a core member of a fuser roller or a pressure roller. The elastically deformable layer is made from a dry formulation inclusive of: a fluoro-thermoplastic polymer powder; microspheres in the form of unexpanded microspheres or expanded microballoons; and solid filler particles including strength-enhancing filler particles and thermal-conductivity-enhancing filler particles. The dry formulation can be thermally cured or electron-beam cured. Preferably, the dry formulation is thermally cured and further includes a curing catalyst, preferably a peroxide catalyst. Alternatively, the curing catalyst can be a bisphenol residue.
    • 一种受控模量定影站构件,包括耐用,坚韧,可弹性变形的层,其中包含中空柔性填料颗粒。 可弹性变形层优选地是在基底上的单层,该基底优选地是定影辊或加压辊的芯构件。 弹性变形层由干式制剂制成,包括:氟 - 热塑性聚合物粉末; 未膨胀微球或膨胀微球形式的微球; 以及固体填料颗粒,包括强度增强填料颗粒和导热性增强填料颗粒。 干燥制剂可以热固化或电子束固化。 优选地,干燥制剂被热固化,并且还包括固化催化剂,优选过氧化物催化剂。 或者,固化催化剂可以是双酚残基。
    • 3. 发明授权
    • Fuser member
    • 定影器成员
    • US07534492B2
    • 2009-05-19
    • US11472888
    • 2006-06-22
    • Jiann-Hsing ChenJoseph A. PavliskoShyh-Hua E. JaoPo-Jen Shih
    • Jiann-Hsing ChenJoseph A. PavliskoShyh-Hua E. JaoPo-Jen Shih
    • B32B25/08B32B25/20B32B27/08G03G15/20
    • G03G15/2057Y10T428/24355Y10T428/265Y10T428/269Y10T428/3154Y10T428/31544Y10T428/31663
    • The fuser members of this invention include a core member that includes a rigid outer surface. An adhesion promoter layer comprising silane or epoxy silane coupling is disposed on the outer surface of the core member. A resilient layer comprising an elastomer is disposed on the adhesion promoter layer. A tie layer is disposed on the resilient layer, the tie layer being made of fluoropolymers, fluoroelastomers, fluorocarbon thermoplastic copolymers and mixtures thereof. A primer layer, disposed on the tie layer, comprising perfluoroalkoxy resin and trifluoroethylene-perfluoroethyl vinyl ether-perfluoroethylene vinyl phosphate or a mixture of perfluoroalkoxy resin and trifluoroethylene-perfluoroethylvinyl ether; and an outer layer of fluoropolymer resin made from polytetrafluoroethylene, polyperfluoroalkoxy-tetrafluoroethylene, polyfluorinated ethylene-propylene and blends thereof is disposed on the primer layer.
    • 本发明的定影器构件包括包括刚性外表面的芯构件。 包含硅烷或环氧硅烷偶联剂的粘合促进剂层设置在芯构件的外表面上。 包含弹性体的弹性层设置在粘合促进剂层上。 粘结层设置在弹性层上,粘结层由含氟聚合物,含氟弹性体,碳氟化合物热塑性共聚物及其混合物制成。 布置在连接层上的底漆层,包括全氟烷氧基树脂和三氟乙烯 - 全氟乙基乙烯基醚 - 全氟乙烯基磷酸酯或全氟烷氧基树脂和三氟乙烯 - 全氟乙基乙烯基醚的混合物; 由聚四氟乙烯制成的氟聚合物树脂外层,全氟氟烷氧基四氟乙烯,多氟乙烯 - 丙烯及其共混物。
    • 4. 发明申请
    • Fuser member
    • 定影器成员
    • US20070298217A1
    • 2007-12-27
    • US11472888
    • 2006-06-22
    • Jiann-Hsing ChenJoseph A. PavliskoShyh-Hua E. JaoPo-Jen Shih
    • Jiann-Hsing ChenJoseph A. PavliskoShyh-Hua E. JaoPo-Jen Shih
    • B32B25/02B32B27/20B32B25/20G03G15/20
    • G03G15/2057Y10T428/24355Y10T428/265Y10T428/269Y10T428/3154Y10T428/31544Y10T428/31663
    • The fuser members of this invention include a core member that includes a rigid outer surface. An adhesion promoter layer comprising silane or epoxy silane coupling is disposed on the outer surface of the core member. A resilient layer comprising an elastomer is disposed on the adhesion promoter layer. A tie layer is disposed on the resilient layer, the tie layer being made of fluoropolymers, fluoroelastomers, fluorocarbon thermoplastic copolymers and mixtures thereof. A primer layer, disposed on the tie layer, comprising perfluoroalkoxy resin and trifluoroethylene-perfluoroethyl vinyl ether-perfluoroethylene vinyl phosphate or a mixture of perfluoroalkoxy resin and trifluoroethylene-perfluoroethylvinyl ether; and an outer layer of fluoropolymer resin made from polytetrafluoroethylene, polyperfluoroalkoxy-tetrafluoroethylene, polyfluorinated ethylene-propylene and blends thereof is disposed on the primer layer.
    • 本发明的定影器构件包括包括刚性外表面的芯构件。 包含硅烷或环氧硅烷偶联剂的粘合促进剂层设置在芯构件的外表面上。 包含弹性体的弹性层设置在粘合促进剂层上。 粘结层设置在弹性层上,粘结层由含氟聚合物,含氟弹性体,碳氟化合物热塑性共聚物及其混合物制成。 布置在连接层上的底漆层,包括全氟烷氧基树脂和三氟乙烯 - 全氟乙基乙烯基醚 - 全氟乙烯基磷酸酯或全氟烷氧基树脂和三氟乙烯 - 全氟乙基乙烯基醚的混合物; 由聚四氟乙烯制成的氟聚合物树脂外层,全氟氟烷氧基四氟乙烯,多氟乙烯 - 丙烯及其共混物。
    • 9. 发明申请
    • FUSER MEMBER WITH FLUOROPOLYMER OUTER LAYER
    • 具有氟聚合物外层的熔融部件
    • US20110159276A1
    • 2011-06-30
    • US12647573
    • 2009-12-28
    • Jiann-Hsing ChenJerry A. PickeringPo-Jen Shih
    • Jiann-Hsing ChenJerry A. PickeringPo-Jen Shih
    • B32B27/00B32B5/00
    • G03G15/2057G03G2215/2048Y10T428/264Y10T428/265Y10T428/269Y10T428/31544
    • A fuser member comprising: a substrate comprising an outer substrate surface; and an outer layer comprising compatible first and second fluorothermoplastics disposed over the outer substrate surface, wherein the first fluorothermoplastic is a crosslinked polymer and the second fluorothermoplastic is a linear polymer and wherein the compatible first and second fluorothermoplastics form a semi-interpenetrating polymer network (SIPN). The SIPN provides a relatively compliant layer in comparison to use of the crosslinked polymer alone, and avoids the need for sintering of a layer formed from the linear polymer alone. The SIPN may be formed from an aqueous coated composition of polyperfluoroalkoxy-tetrafluoroethylene (PFA) and THV Fluoroplastics (FLC) polymers along with a soluble organic primary amine for crosslinking the THV Fluoroplastics (FLC).
    • 一种定影器构件,包括:衬底,其包括外部衬底表面; 以及外层,其包含设置在所述外基材表面上的相容的第一和第二含氟热塑性塑料,其中所述第一含氟热塑性材料为交联聚合物,所述第二氟热塑性塑料为线性聚合物,并且其中所述相容的第一和第二含氟热塑性塑料形成半互穿聚合物网络 )。 与单独使用交联聚合物相比,SIPN提供了相对顺应性的层,并且避免了单独由线性聚合物形成的层的烧结的需要。 SIPN可以由聚氟全氟烷氧基四氟乙烯(PFA)和THV氟塑料(FLC)聚合物的水性涂料组合物以及用于交联THV氟塑料(FLC)的可溶性有机伯胺形成。
    • 10. 发明授权
    • Method of making fuser member
    • 制造定影器构件的方法
    • US08304016B2
    • 2012-11-06
    • US12647569
    • 2009-12-28
    • Jiann-Hsing ChenJerry A. PickeringPo-Jen Shih
    • Jiann-Hsing ChenJerry A. PickeringPo-Jen Shih
    • B41L7/00B41L9/00B41L23/00B41L25/00
    • G03G15/2057G03G2215/2019
    • A method of making a fuser member having an annealed outer surface comprising: providing an outer layer comprising compatible first and second fluorothermoplastics over an outer substrate surface, wherein the first fluorothermoplastic is a crosslinkable polymer and the second fluorothermoplastic is a linear polymer; curing the outer layer to crosslink the first fluorothermoplastic whereby the resulting crosslinked first fluorothermoplastic and the linear polymer second fluorothermoplastic form a semi-interpenetrating polymer network (SIPN); and annealing an outer surface of the outer layer by contacting the fuser member with applied pressure against a heated surface, without first sintering the second fluorothermoplastic linear polymer through application of heat alone.
    • 一种制造具有退火外表面的定影器构件的方法,包括:在外基材表面上提供包含相容的第一和第二含氟热塑性塑料的外层,其中所述第一荧光热塑性塑料为可交联聚合物,所述第二氟热塑性塑料为线性聚合物; 固化外层以交联第一荧光热塑性,由此所得交联的第一荧光热塑性和线性聚合物第二氟热塑性形成半互穿聚合物网络(SIPN); 以及通过使所述定影器构件与加热表面接触而使所述外层的外表面退火,而不通过单独施加热来首先烧结所述第二氟热塑性线性聚合物。