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    • 2. 发明授权
    • Toner fuser member having release layer formed from glycidyl end-capped polymer and perfluoroalkyl glycidyl-reactive compound
    • 具有由缩水甘油基封端聚合物和全氟烷基缩水甘油基反应性化合物形成的释放层的调色剂定影器构件
    • US07273687B2
    • 2007-09-25
    • US11017485
    • 2004-12-20
    • Jiann-Hsing ChenJoseph A. PavliskoMuhammed AslamNataly Boulatnikov
    • Jiann-Hsing ChenJoseph A. PavliskoMuhammed AslamNataly Boulatnikov
    • G03G13/20C08L83/04
    • C08L63/00G03G15/2057Y10T428/265Y10T428/31507Y10T428/31511Y10T428/31529Y10T428/31721Y10T428/31725Y10T428/31786
    • A toner fuser member has a substrate, on which is formed a toner release surface layer from a composition that includes: about 95 wt. % to about 99.9 wt. % of a cross-linked, glycidyl end-capped bisphenolic polymer having the formula where R1 and R2 are each independently H or an alkyl group containing 1 to about 4 carbon atoms, and R3 and R4 are each independently H, F, or an alkyl group containing 1 to about 4 carbon atoms, Z is a carbonyl cross-linking group, and x is an integer from 1 to about 10; and about 0.01 wt. % to about 5 wt. % of a perfluoroalkylsubstituted glycidyl-reactive compound having the formula where R5 is H or F, Q is OH or SiR6R7R8, R6, R7, and R8 being independently selected from the group consisting of Cl, OH, an alkyl group containing 1 to about 4 carbon atoms, an alkoxy group containing 1 to about 4 carbon atoms, an acyloxy group containing 2 to about 4 carbon atoms, and an amino group containing 0 to about 4 carbon atoms; and n is an integer from 1 to about 15. When Q is SiR6R7R8, at least one of R6, R7, and R8 is Cl, OH, or an alkoxy, acyloxy, or amino group.
    • 调色剂定影器构件具有基底,在其上由组合物形成调色剂释放表面层,所述组合物包括:约95wt。 %至约99.9wt。 %的具有下式的交联的缩水甘油基封端的双酚聚合物,其中R 1和R 2各自独立地为H或含有1至约4个碳的烷基 原子和R 3和R 4各自独立地为H,F或含有1至约4个碳原子的烷基,Z为羰基交联基团, 且x为1至约10的整数; 和约0.01重量% %至约5wt。 %的具有下式的全氟烷基取代的缩水甘油基反应性化合物的%为H或F,Q为OH或SiR 6 R 7 R 7, S 8,R 6,R 7,R 8和R 8独立地选自Cl,OH, 含有1至约4个碳原子的烷基,含有1至约4个碳原子的烷氧基,含2至约4个碳原子的酰氧基和含有0至约4个碳原子的氨基; 并且n是1至约15的整数。当Q是SiR 6 R 7 R 8时,R 0〜 R 6,R 7和R 8是Cl,OH或烷氧基,酰氧基或氨基。