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1. 发明授权

US07595413B2 Phosphine-substituted vinyl containing metallocene catalyst, preparation process and the application of the same 有权
标题翻译：膦取代的含乙烯基茂金属催化剂，制备方法及其应用
公开(公告)号：US07595413B2
公开(公告)日：2009-09-29
申请号：US12068662
申请日：2008-02-08
申请人： Jianjun Yi , Wenhua Sun , Peng Hao , Shu Zhang
发明人： Jianjun Yi , Wenhua Sun , Peng Hao , Shu Zhang
IPC分类号： C07F17/00 , B01J31/00 , C07F7/00 , C08F4/44
CPC分类号： C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2420/03 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： The invention relates to a phosphine-substituted vinyl containing metallocene catalyst, and also to the preparation process of the same as well as to the application of the catalyst. The catalyst has the general formula of Cp2(CR1═CR2(P(R3)2))MX, wherein Cp is a ligand containing cyclopentadiene having 1˜5 substitutions, of which two neighbors connecting to each other to form fused rings having more than two members; R1-R3 is selected from the groups consisting of hydrogen, C1˜C18 alkyl or perfluoro-alkyl, C6˜C24 aralkyl or alkaryl; M is selected from the groups consisting of metals of the IVB group; and X is selected from the groups consisting of halogens, C1˜C24 alkyl alkoxyl, silicone or alkaryl. With aluminoxane or modified aluminoxane, aluminum alkyl, halogenated aluminum alkyl or their mixture as the catalyst promoter the phosphine-substituted vinyl containing metallocene catalyst may be employed as the major catalyst for the polymerization or copolymerization of alpha-olefin. Due to its high activity, the polymerization may occur at both high and low temperatures with the polymer having higher molecular weight and broader molecular weight distribution.
摘要翻译：本发明涉及一种膦取代的含乙烯基茂金属催化剂，以及其制备方法以及催化剂的应用。催化剂具有通式Cp2（CR1-CR2（P（R3）2））MX，其中Cp是含有1〜5个取代基的含环戊二烯的配体，其中两个相邻的相互连接形成具有多于两名成员 R1-R3选自氢，C1〜C18烷基或全氟烷基，C6〜C24芳烷基或烷芳基; M选自IVB族金属组成的组; X选自卤素，C 1 -C 24烷基烷氧基，硅氧烷或烷芳基。使用铝氧烷或改性的铝氧烷，可以使用烷基铝，卤代烷基铝或它们作为催化剂助催化剂的混合物，其中膦取代的含乙烯基的茂金属催化剂可用作α-烯烃聚合或共聚的主要催化剂。由于其高活性，聚合可以在高温和低温下发生，聚合物具有较高的分子量和较宽的分子量分布。

2. 发明申请

US20080194854A1 Phosphine-substituted vinyl containing metallocene catlyst, preparation process and the application of the same 有权
标题翻译：膦取代的含乙烯基茂金属catlyst，其制备方法及其应用
公开(公告)号：US20080194854A1
公开(公告)日：2008-08-14
申请号：US12068662
申请日：2008-02-08
申请人： Jianjun Yi , Wenhua Sun , Peng Hao , Shu Zhang
发明人： Jianjun Yi , Wenhua Sun , Peng Hao , Shu Zhang
IPC分类号： C07F7/28 , C07F7/00
CPC分类号： C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2420/03 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： The invention relates to a phosphine-substituted vinyl containing metallocene catalyst, and also to the preparation process of the same as well as to the application of the catalyst. The catalyst has the general formula of Cp2(CR1═CR2(P(R3)2))MX, wherein Cp is a ligand containing cyclopentadiene having 1˜5 substitutions, of which two neighbors connecting to each other to form fused rings having more than two members; R1-R3 is selected from the groups consisting of hydrogen, C1˜C18 alkyl or perfluoro-alkyl, C6˜C24 aralkyl or alkaryl; M is selected from the groups consisting of metals of the IVB group; and X is selected from the groups consisting of halogens, C1˜C24 alkyl alkoxyl, silicone or alkaryl. With aluminoxane or modified aluminoxane, aluminum alkyl, halogenated aluminum alkyl or their mixture as the catalyst promoter the phosphine-substituted vinyl containing metallocene catalyst may be employed as the major catalyst for the polymerization or copolymerization of alpha-olefin. Due to its high activity, the polymerization may occur at both high and low temperatures with the polymer having higher molecular weight and broader molecular weight distribution.
摘要翻译：本发明涉及一种膦取代的含乙烯基茂金属催化剂，以及其制备方法以及催化剂的应用。催化剂具有通式Cp 2（CR 1）-CR 2 2（P（R 3）3）其中Cp是含有1〜5个取代基的含环戊二烯的配体，其中两个相邻的相互连接形成具有多于两个成员的稠环; R 1〜Z 3选自氢，C 1 -C 18烷基或全氟（C 1 -C 18）烷基或全氟 - 烷基，C 6 -C 24芳烷基或烷芳基; M选自IVB族金属组成的组; 并且X选自卤素，C 1 -C 24烷基烷氧基，硅氧烷或烷芳基。使用铝氧烷或改性的铝氧烷，可以使用烷基铝，卤代烷基铝或它们作为催化剂助催化剂的混合物，其中膦取代的含乙烯基的茂金属催化剂可用作α-烯烃聚合或共聚的主要催化剂。由于其高活性，聚合可以在高温和低温下发生，聚合物具有较高的分子量和较宽的分子量分布。

3. 发明授权

US08470941B2 Catalyst for homopolymerizing and copolymerizing propylene and its preparation and use 有权
标题翻译：用于丙烯均聚和共聚的催化剂及其制备和用途
公开(公告)号：US08470941B2
公开(公告)日：2013-06-25
申请号：US13127591
申请日：2008-12-02
申请人： Jianjun Yi , Baozuo Yin , Chunming Cui , Zhifei Li , Liang Cui , Huashu Li , Weihuan Huang , Jianying Zhang , Li Wang
发明人： Jianjun Yi , Baozuo Yin , Chunming Cui , Zhifei Li , Liang Cui , Huashu Li , Weihuan Huang , Jianying Zhang , Li Wang
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/6545 , C08F4/651 , C08F4/6543 , C08F2500/15 , C08F210/16 , C08F2500/12
摘要： A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl2.nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl2.nROH is 0.01-1, based on the amount of MgCl2.nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl2.nROH is 1-200. The catalyst has high activity, high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.
摘要翻译：丙烯均聚和共聚的催化剂及其制备和用途。催化剂组分包括含有至少一个Ti-卤素键的钛化合物和负载在MgCl 2·nROH加合物上的至少两种电子给体化合物A和B，其中电子给体化合物A是式（I）化合物，给体化合物B是酯或醚化合物; 化合物A与化合物B的摩尔比为0.1-5; 基于MgCl 2·nROH的量，两种电子给体和MgCl 2·nROH的总量之间的摩尔比为0.01-1。含Ti-卤键的钛化合物与MgCl 2·nROH之间的摩尔比为1-200。该催化剂具有高活性，高立体定向性和良好的共聚性能。此外，由其获得的聚合物的形态是良好的。

4. 外观设计

USD884498S1 Food thermometer 有权
公开(公告)号：USD884498S1
公开(公告)日：2020-05-19
申请号：US29711800
申请日：2019-11-03
申请人： Jianjun Yi
设计人： Jianjun Yi
摘要： FIG. 1 is a perspective view of a food thermometer showing my new design;
FIG. 2 is another perspective view thereof;
FIG. 3 is a front view thereof;
FIG. 4 is a rear view thereof;
FIG. 5 is a left side view thereof;
FIG. 6 is a right side view thereof;
FIG. 7 is a top plan view thereof; and,
FIG. 8 is a bottom plan view thereof.
The broken lines are for the purposes of illustrating portions of the food thermometer and form no part of the claimed design.

5. 发明申请

US20130131292A1 CATALYST FOR POLYMERIZATION OF OLEFINS COMPRISING THIENYL-SUBSTITUTED SILANES 有权
标题翻译：用于聚合烯丙基取代的硅烷的烯烃的聚合催化剂
公开(公告)号：US20130131292A1
公开(公告)日：2013-05-23
申请号：US13813479
申请日：2011-06-03
申请人： Zhifei Li , Kuilong Tan , Hao Wang , Jianjun Yi , Qinghong Xu , Weisong Cui , Wei Bai , Xinyuan Liu , Pu Xu , Wanqing Ju
发明人： Zhifei Li , Kuilong Tan , Hao Wang , Jianjun Yi , Qinghong Xu , Weisong Cui , Wei Bai , Xinyuan Liu , Pu Xu , Wanqing Ju
IPC分类号： C08F110/00
CPC分类号： C08F110/00 , C08F110/06 , C08F4/6465 , C08F2500/12 , C08F2500/15
摘要： Disclosed is a catalyst for the polymerization of olefins comprising thienyl-substituted silanes, which comprises a solid titanium catalyst component containing titanium, magnesium and a halogen as the main components, an alkylaluminum compound, and a component of organosiloxane compound comprising two thienyl as substituents represented by general formula (I). The molar ratio of each catalyst component is 1:50-150:5-50 based on titanium:aluminum:silicon. When the catalyst is used in the polymerization of propylene, the polymerisate obtained has very high degree of isotacticity, and the yield is high.
摘要翻译：公开了包含噻吩基取代的硅烷的烯烃聚合催化剂，其包含含有钛，镁和卤素作为主要成分的固体钛催化剂组分，烷基铝化合物和包含两个噻吩基作为取代基的有机硅氧烷化合物的组分由通式（I）表示。每个催化剂组分的摩尔比基于钛：铝：硅为1:50-150:5-50。当催化剂用于丙烯聚合时，所得聚合物具有非常高的全同立构规整度，产率高。

6. 发明授权

US08404789B2 Olefin polymerization catalyst and preparation method and use thereof 有权
标题翻译：烯烃聚合催化剂及其制备方法及用途
公开(公告)号：US08404789B2
公开(公告)日：2013-03-26
申请号：US12664517
申请日：2008-05-15
申请人： Jianjun Yi , Chunming Cui , Huashu Li , Baozuo Yin , Jianying Zhang , Xiaomei Lang , Linmei Wu
发明人： Jianjun Yi , Chunming Cui , Huashu Li , Baozuo Yin , Jianying Zhang , Xiaomei Lang , Linmei Wu
IPC分类号： C08F4/44
CPC分类号： C08F110/06 , C08F4/6465 , C08F4/6567 , C08F4/6543 , C08F4/651 , C08F2500/15
摘要： An olefin polymerization catalyst and preparation method and use thereof are provided. The catalyst component comprises (1) an active magnesium halide, (2) a titanium compound containing at least one Ti-halide bond supported thereon, and (3) an electron donor selected from the group consisting of one or more sulfonyl-containing compounds having the following formula. There are two methods for preparing such solid catalyst component: I) treating the active magnesium halide (1) particles with alkylaluminum, subsequently adding the electron donor (3), treating it with the solution of titanium compound (2) one or more times; II) adding spherical magnesium chloride alcoholate particles to the solution of titanium compound (2), subsequently adding the electron donor (3), treating it with the solution of titanium compound (2) one or more times. The catalyst system comprises such solid catalyst component, a co-catalyst (alkylaluminum compound) and an external electron donor.
摘要翻译：提供烯烃聚合催化剂及其制备方法和用途。催化剂组分包括（1）活性卤化镁，（2）载有至少一种Ti卤化物键的钛化合物，和（3）选自一种或多种含磺酰基化合物的电子给体，所述化合物具有以下公式。制备这种固体催化剂组分有两种方法：I）用烷基铝处理活性卤化镁（1）颗粒，随后加入电子给体（3），用钛化合物（2）的溶液处理一次或多次; II）向钛化合物（2）的溶液中加入球形氯化镁醇盐颗粒，随后加入电子给体（3），用钛化合物（2）的溶液处理一次或多次。催化剂体系包括这样的固体催化剂组分，助催化剂（烷基铝化合物）和外电子给体。

7. 发明申请

US20110207900A1 CATALYST FOR HOMOPOLYMERIZING AND COPOLYMERIZING PROPYLENE AND ITS PREPARATION AND USE 有权
标题翻译：用于丙烯共聚和共聚合催化剂及其制备和使用
公开(公告)号：US20110207900A1
公开(公告)日：2011-08-25
申请号：US13127591
申请日：2008-12-02
申请人： Jianjun Yi , Baozuo Yin , Chunming Cui , Zhifei Li , Liang Cui , Huashu Li , Weihuan Huang , Jianying Zhang , Li Wang
发明人： Jianjun Yi , Baozuo Yin , Chunming Cui , Zhifei Li , Liang Cui , Huashu Li , Weihuan Huang , Jianying Zhang , Li Wang
IPC分类号： C08F4/76 , B01J31/02 , B01J37/08 , B01J37/06
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/6545 , C08F4/651 , C08F4/6543 , C08F2500/15 , C08F210/16 , C08F2500/12
摘要： A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl2.nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl2.nROH is 0.01-1, based on the amount of MgCl2.nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl2.nROH is 1-200. The catalyst has high activity, high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.
摘要翻译：丙烯均聚和共聚的催化剂及其制备和用途。催化剂组分包括含有至少一个Ti-卤素键的钛化合物和负载在MgCl 2·nROH加合物上的至少两种电子给体化合物A和B，其中电子给体化合物A是式（I）化合物，给体化合物B是酯或醚化合物; 化合物A与化合物B之间的摩尔比为0.1-5; 基于MgCl 2·nROH的量，两种电子给体和MgCl 2·nROH的总量之间的摩尔比为0.01-1。含Ti-卤键的钛化合物与MgCl 2·nROH之间的摩尔比为1-200。该催化剂具有高活性，高立体定向性和良好的共聚性能。此外，由其获得的聚合物的形态是良好的。

8. 外观设计

USD891949S1 Wireless food thermometer 有权
公开(公告)号：USD891949S1
公开(公告)日：2020-08-04
申请号：US29711802
申请日：2019-11-03
申请人： Jianjun Yi
设计人： Jianjun Yi
摘要： FIG. 1 is a perspective view of a wireless food thermometer showing my new design;
FIG. 2 is another perspective view thereof;
FIG. 3 is a front view thereof;
FIG. 4 is a rear view thereof;
FIG. 5 is a left side view thereof;
FIG. 6 is a right side view thereof;
FIG. 7 is a top plan view thereof; and,
FIG. 8 is a bottom plan view thereof.
The broken lines are for the purposes of illustrating portions of the wireless food thermometer and form no part of the claimed design.

9. 外观设计

USD884499S1 Food thermometer 有权
公开(公告)号：USD884499S1
公开(公告)日：2020-05-19
申请号：US29711801
申请日：2019-11-03
申请人： Jianjun Yi
设计人： Jianjun Yi
摘要： FIG. 1 is a perspective view of a food thermometer showing my new design;
FIG. 2 is another perspective view thereof;
FIG. 3 is a front view thereof;
FIG. 4 is a rear view thereof;
FIG. 5 is a left side view thereof;
FIG. 6 is a right side view thereof;
FIG. 7 is a top plan view thereof;
FIG. 8 is a bottom plan view thereof;
FIG. 9 is an enlarged view of FIG. 5; and,
FIG. 10 is an enlarged view of FIG. 6.
The broken lines are for the purposes of illustrating portions of the food thermometer and form no part of the claimed design.

10. 发明授权

US08716417B2 Olefin polymerization catalyst and preparation method and use thereof 有权
标题翻译：烯烃聚合催化剂及其制备方法及用途
公开(公告)号：US08716417B2
公开(公告)日：2014-05-06
申请号：US13702209
申请日：2011-06-03
申请人： Jianjun Yi , Chunming Cui , Huashu Li , Zhifei Li , Baozuo Yin , Liang Cui , Jianying Zhang , Liang Wang
发明人： Jianjun Yi , Chunming Cui , Huashu Li , Zhifei Li , Baozuo Yin , Liang Cui , Jianying Zhang , Liang Wang
IPC分类号： C08F4/44 , B01J35/08 , B01J31/00
CPC分类号： C08F4/16 , C08F10/06 , C08F110/06 , C08F4/6565 , C08F4/6465 , C08F2500/15
摘要： An olefin polymerization catalyst and preparation method and use thereof are provided. The components of the catalyst comprise an active magnesium halide, a titanium compound containing at least one Ti-halide bond loaded on the active magnesium halide, and an internal electron donor selected from one or more silicon esters compounds having formula (I). The method for preparing the catalyst components is that: adding spherical magnesium chloride alcoholate particles and the electron donor into the solution of titanium compound in sequence, and processing with the titanium compound for one or more times to obtain the catalyst. The catalyst system used for the olefin polymerization comprises the catalyst components, a cocatalyst and an external electron donor. The catalyst has high activity for the propylene polymerization, and the activity is 4399 gPP/gTi·h(50° C., 1 h, slurry polymerization at atmospheric pressure), and the isotacticity of the polymer is 98%.
摘要翻译：提供烯烃聚合催化剂及其制备方法和用途。催化剂的组分包括活性卤化镁，含有负载在活性卤化镁上的至少一种Ti-卤化物键的钛化合物和选自一种或多种具有式（I）的硅酯化合物的内部电子给体。制备催化剂组分的方法是：将球形氯化镁醇盐颗粒和电子给体依次加入钛化合物溶液中，并用钛化合物处理一次或多次以获得催化剂。用于烯烃聚合的催化剂体系包括催化剂组分，助催化剂和外部电子给体。该催化剂对丙烯聚合具有高活性，活性为4399gPP / gTi·h（50℃，1小时，常压下淤浆聚合），聚合物的全同立构规整度为98％。

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