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    • 1. 发明授权
    • Method for the CVD deposition of a low residual halogen content multi-layered titanium nitride film having a combined thickness greater than 1000 Å
    • 用于沉积具有大于1000的组合厚度的低残留卤素含量多层氮化钛膜的CVD沉积的方法
    • US06436820B1
    • 2002-08-20
    • US09497787
    • 2000-02-03
    • Jianhua HuYin LinFufa ChenYehuda DemayoMing Xi
    • Jianhua HuYin LinFufa ChenYehuda DemayoMing Xi
    • H01L21324
    • H01L21/28568C23C16/34C23C16/56
    • The present disclosure pertains to the discovery that TiN films having a thickness of greater than about 400 Å and, particularly greater than 1000 Å, and a resistivity of less than about 175 &mgr;&OHgr;cm, can be produced by a CVD technique in which a series of TiN layers are deposited to form a desired TiN film thickness. Each layer is deposited employing a CVD deposition/treatment step. During a treatment step, residual halogen (typically chlorine) was removed from the CVD deposited film. Specifically, a TiN film having a thickness of greater than about 400 Å was prepared by a multi deposition/treatment step process where individual TiN layers having a thickness of less than 400 Å were produced in series to provide a finished TiN layer having a combined desired thickness. Each individual TiN layer was CVD deposited and then treated by exposing the TiN surface to ammonia in an annealing step carried out in an ammonia ambient. The TiN film formed in this manner not only had a resistivity of less than about 175 &mgr;&OHgr;cm, but was substantially free of micro cracks as well, including films having a thickness greater than 1,000 Å.
    • 本公开涉及通过CVD技术产生厚度大于约400埃,特别是大于1000埃,电阻率小于约175微米/厘米3的TiN膜的发现,其中一系列TiN 沉积层以形成期望的TiN膜厚度。 使用CVD沉积/处理步骤沉积各层。 在处理步骤中,从CVD沉积膜去除残留的卤素(通常为氯)。 具体地,通过多次沉积/处理步骤工艺制备具有大于约400埃厚度的TiN膜,其中制备具有小于400的厚度的单独TiN层以提供具有组合所需的成品TiN层 厚度。 每个单独的TiN层被CVD沉积,然后通过在氨环境中进行的退火步骤中将TiN表面暴露于氨进行处理。 以这种方式形成的TiN膜不仅具有小于约175μOMEGA·cm的电阻率,而且基本上没有微裂纹,包括厚度大于的的膜。