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    • 7. 发明授权
    • Color-stabilized electrochromic devices
    • 颜色稳定的电致变色装置
    • US06433914B1
    • 2002-08-13
    • US09650870
    • 2000-08-30
    • Jeffrey R. LompreyThomas F. GuarrKelvin L. Baumann
    • Jeffrey R. LompreyThomas F. GuarrKelvin L. Baumann
    • G02F115
    • G02F1/1525C09K9/02G02F1/15G02F1/1521G02F2001/1502G02F2001/1512
    • An electrochromic device comprising: (a) at least one substantially transparent substrate having an electrically conductive material associated therewith; and (b) an electrochromic medium having a predetermined color while in a high transmission state, wherein the electrochromic medium comprises: (1) an anodic material and a cathodic material, wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic; (2) a redox buffer; and (3) means associated with the redox buffer for controllably maintaining the predetermined color of the electrochromic medium while in the high transmission state relative to an electrochromic medium without the redox buffer.
    • 一种电致变色装置,包括:(a)至少一个基本上透明的基底,其具有与之相关联的导电材料; 和(b)在高透射状态下具有预定颜色的电致变色介质,其中所述电致变色介质包括:(1)阳极材料和阴极材料,其中阳极和阴极材料都是电活性的,并且至少一种 阳极和阴极材料是电致变色的; (2)氧化还原缓冲液; 和(3)与氧化还原缓冲液相关联的装置,用于相对于没有氧化还原缓冲液的电致变色介质,在高透射状态下可控地保持电致变色介质的预定颜色。
    • 8. 发明授权
    • Tristate electrochromic device
    • 三态电致变色装置
    • US07075697B2
    • 2006-07-11
    • US11236071
    • 2005-09-27
    • Punam GiriThomas F. Guarr
    • Punam GiriThomas F. Guarr
    • G02F1/15G02F1/153
    • G02F1/153G02F1/1521G02F1/163G02F2203/11
    • An electrochromic medium for use in a tristate electrochromic device, comprising: (a) at least one solvent; (b) at least one anodic material; (c) at least one cathodic material, wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic; (d) wherein, in a first state, the electrochromic medium exhibits a maximum light transmission; (e) wherein, in a second state, variable attenuation occurs to a significant extent in one of visible radiation or near-infrared radiation without significant attenuation in the other; and (f) wherein, in a third state, variable attenuation occurs to a significant extent in the other spectral region.
    • 一种用于三级电致变色装置的电致变色介质,包括:(a)至少一种溶剂; (b)至少一种阳极材料; (c)至少一种阴极材料,其中阳极和阴极材料都是电活性的,阳极和阴极材料中的至少一种是电致变色的; (d)其中,在第一状态下,所述电致变色介质表现出最大光透射率; (e)其中,在第二状态下,在可见辐射或近红外辐射之一中显着地发生可变衰减,而在另一个状态下没有显着的衰减; 和(f)其中,在第三状态下,可变衰减在另一光谱区域中显着地发生。
    • 9. 发明授权
    • Substituted metallocenes and electrochromic media and devices comprising the same
    • 取代的金属茂和电致变色介质以及包含其的装置
    • US06594066B2
    • 2003-07-15
    • US10121760
    • 2002-04-22
    • Jeffrey R. LompreyThomas F. Guarr
    • Jeffrey R. LompreyThomas F. Guarr
    • G02F101
    • G02F1/1521C07F17/02C09K9/02
    • An electrochromic device comprising at least one substantially transparent substrate having an electrically conductive material associated therewith, and an electrochromic medium which comprises a solvent, a cathodic material, and an anodic electrochromic material represented by the formula: wherein R1-R10 are the same or different and at least three of R1-R10 are the same or different and comprise a straight or branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 40 carbon atom(s), and/or a silyl or siloxyl group containing approximately 1 to approximately 40 silicon atom(s), wherein the carbon or silicon atom(s) may be a linking group to, or part of, one or more functional groups comprising nitrites; nitro constituents; sulfoxides; sulfonates; phosphonium constituents; phosphonates; phosphonites; ammonium constituents; viologens, including bipyridinyl constituents; carbonyls, including carbonates, carbamates; ketones; esters; and amides; ethers, including polyethers; amines, including tertiary amines; alkenes; alkynes; and mixtures thereof; wherein any remainder of R1-R10 comprise H; and wherein M comprises a transition metal.
    • 一种电致变色装置,包括至少一个具有与之相关的导电材料的基本上透明的基底,以及电致变色介质,其包含溶剂,阴极材料和由下式表示的阳极电致变色材料:其中R1-R10相同或不同 并且R1-R10中的至少三个相同或不同,并且包含含有约1至约40个碳原子的直链或支链烷基,芳基,烷芳基或芳烷基,和/或含有约1至约40个碳原子的甲硅烷基或硅氧烷基 1至约40个硅原子,其中碳或硅原子可以是与一个或多个包含亚硝酸根的官能团的一部分或部分的连接基团; 硝基成分; 亚砜 磺酸盐; 鏻成分; 膦酸盐 亚膦酸盐 铵成分; 紫罗兰,包括联吡啶成分; 羰基,包括碳酸酯,氨基甲酸酯; 酮类 酯类 和酰胺; 醚,包括聚醚; 胺,包括叔胺; 烯烃 炔烃 及其混合物; 其中R 1 -R 10的任何其余部分包括H; 并且其中M包含过渡金属。