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    • 2. 发明授权
    • Coating composition comprising hydroxylamine esters
    • 包含羟胺酯的涂料组合物
    • US07820248B2
    • 2010-10-26
    • US10545755
    • 2004-03-03
    • Jean-Pierre WolfLjubomir MisevPeter NesvadbaSevgi Zeren
    • Jean-Pierre WolfLjubomir MisevPeter NesvadbaSevgi Zeren
    • B05D3/00B29C71/02
    • C09D4/00C08K5/3435
    • The invention relates to a dual thermal and ultraviolet radiation curable coating composition, comprising a) at least an ethylenically unsaturated compound; b) a hydroxylamine ester effective to enable IR-curing or NIR-curing of the ethylenically unsaturated compound; c) a photoinitiator effective to enable UV-curing of the ethylenically unsaturated compound; wherein the thermal initiator is a hydroxylamine ester which has a structural element of formula (1) or formula (1) or a polymeric hydroxylamine ester which has a repetitive structural unit of formula (11) or (I[′) of formula (11) Furthermore, the invention relates to a process for curing a thermal curable coating composition composing hydroxylamine esters as thermal initiators using NIR-curing.
    • 本发明涉及双重热和紫外线辐射固化涂料组合物,其包含a)至少一种烯属不饱和化合物; b)有效地使烯属不饱和化合物进行IR固化或NIR固化的羟胺; c)有效使烯属不饱和化合物进行UV固化的光引发剂; 其中所述热引发剂是具有式(1)或式(1)的结构元件的羟胺酯或具有式(11)或式(11)的(I [')的重复结构单元的聚羟胺, 此外,本发明涉及使用NIR固化固化构成羟胺酯作为热引发剂的热固化性涂料组合物的方法。
    • 4. 发明授权
    • Photoresist compositions
    • 光刻胶组合物
    • US08507569B2
    • 2013-08-13
    • US13255543
    • 2010-03-17
    • Hisatoshi KuraKaori SameshimaKazuhiko KunimotoPeter NesvadbaMasaki Ohwa
    • Hisatoshi KuraKaori SameshimaKazuhiko KunimotoPeter NesvadbaMasaki Ohwa
    • H05B6/68C08G61/04
    • G03F7/028C07D211/94C07D491/113C08F110/02C08F110/06C08F265/02C08K5/3435G03F7/0007G03F7/031G03F7/40C08L33/06
    • The present invention relates to a radically polymerizable composition comprising a hydroxylamine ester used to manufacture color filters. The invention further relates to novel hydroxylamine esters. The invention further relates to the use of hydroxylamine esters in all liquid crystal display components requiring post-baking. The present invention relates to a radically polymerizable composition comprising: (a) at least one alkaline developable resin; (b) at least one acrylate monomer; (c) at least a photoinitiator; (d) at least one hydroxylamine ester compound of formula (I) wherein Ra represents an acyl radical; one of Rb and Rc represents hydrogen and the other one represents a substituent; or Rb and Rc both represent hydrogen or identical or different substituents; or Rb and Rc together represent oxygen; or Rb and Rc together form a ring; R1-R4 each represent C1-C6 alkyl; and R5 and R6 each represent independently of one another hydrogen, C1-C6 alkyl or C6-C10 aryl; or R5 and R6 together represent oxygen.
    • 本发明涉及一种可自由基聚合的组合物,其包含用于制造滤色器的羟胺酯。 本发明还涉及新的羟胺酯。 本发明还涉及在需要后烘烤的所有液晶显示组件中使用羟胺酯。 本发明涉及可自由基聚合的组合物,其包含:(a)至少一种碱性显影树脂; (b)至少一种丙烯酸酯单体; (c)至少一种光引发剂; (d)至少一种式(I)的羟胺酯化合物,其中R a表示酰基; Rb和Rc之一表示氢,另一个表示取代基; 或Rb和Rc都表示氢或相同或不同的取代基; 或Rb和Rc一起代表氧; 或Rb和Rc一起形成环; R1-R4各自表示C1-C6烷基; R 5和R 6各自独立地表示氢,C 1 -C 6烷基或C 6 -C 10芳基; 或R5和R6一起表示氧。
    • 10. 发明授权
    • N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith
    • N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物,它们相应的N-氧化物和受控自由基聚合
    • US07288613B2
    • 2007-10-30
    • US11364537
    • 2006-02-28
    • Peter NesvadbaMarie-Odile ZinkWiebke Wunderlich
    • Peter NesvadbaMarie-Odile ZinkWiebke Wunderlich
    • C08F2/38C08F4/00
    • C07D211/94C07D491/113C07D491/22C07D519/00C08F2/46C08F4/00
    • The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
    • 本发明涉及选择的1-烷氧基-2,2,6,6四甲基哌啶,1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-二甲基 哌啶衍生物,其在4位被两个形成开链或环状缩酮结构的氧原子取代,所述可聚合组合物包含a)至少一种烯属不饱和单体和b)所述哌啶衍生物。 本发明的另外的方面是使烯键式不饱和单体聚合的方法,以及使用1-烷氧基-2,2,6,6四甲基哌啶,1-烷氧基-2,2二乙基-6,6二甲基哌啶和1- 烷氧基-2,6-二乙基-2,3,6二甲基哌啶衍生物,其在4位被两个氧原子取代,形成用于受控聚合的开链或环状缩酮结构。 中间体N-氧基衍生物,具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。