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    • 1. 发明授权
    • Sulphonium salt initiators
    • 锍盐引发剂
    • US07901867B2
    • 2011-03-08
    • US11922444
    • 2006-06-21
    • Jean-Pierre WolfAttila LatikaJean-Luc BirbaumStephan IlgPascal Hayoz
    • Jean-Pierre WolfAttila LatikaJean-Luc BirbaumStephan IlgPascal Hayoz
    • G03F7/004G03F7/30C07C381/12
    • C07D209/88B33Y70/00C07C309/06C07C381/12G03F7/0045G03F7/038Y10S430/122
    • Compounds of the formula (I), (II), (III), (IV) and wherein, R is hydrogen, C1-C20alkyl; C2-C20alkyl interrupted by one or more O; is -L-X—R2 or -L-R2; R1 has for example one of the meanings as given for R; R2 is a monovalent sensitizer or photoinitiator moiety; Ar1 and Ar2 for example independently of one another are phenyl substituted by C1-C20alkyl, halogen or OR3; or are unsubstituted naphthyl, anthryl, phenanthryl or biphenylyl; or are naphthyl, anthryl, phenanthryl or biphenylyl substituted by C1-C20alkyl, OH or OR3; or are —Ar4-A-Ar3; Ar3 is unsubstituted phenyl naphthyl, anthryl, phenanthryl or biphenylyl; or is phenyl, naphthyl, anthryl, phenanthryl or biphenylyl substituted by C1-C20alkyl, OR3 or benzoyl; Ar4 is phenylene, naphthylene, anthrylene or phenanthrylene; A is a direct bond, S, O or C1-C20alkylene; X is CO, C(O)O, OC(O), O, S or NR3; L is C1-C20alkylene or C2-C20alkylene interrupted by one or more O; R3 is C1-C20alkyl or C1-C20hydroxyalkyl; and Y is an anion, are suitable as photolatent acid generators.
    • 式(I),(II),(III),(IV)的化合物,其中R是氢,C 1 -C 20烷基; 被一个或多个O中断的C 2 -C 20烷基; 是-L-X-R2或-L-R2; R1具有例如R给出的含义之一; R2是单价敏化剂或光引发剂部分; Ar 1和Ar 2例如彼此独立地是被C 1 -C 20烷基,卤素或OR 3取代的苯基; 或未取代的萘基,蒽基,菲基或联苯基; 或被C 1 -C 20烷基,OH或OR 3取代的萘基,蒽基,菲基或联苯基; 或为-Ar4-A-Ar3; Ar 3是未取代的苯基萘基,蒽基,菲基或联苯基; 或由C 1 -C 20烷基,OR 3或苯甲酰基取代的苯基,萘基,蒽基,菲基或联苯基; Ar4是亚苯基,亚萘基,亚蒽基或菲基; A是直接键合,S,O或C1-C20亚烷基; X是CO,C(O)O,OC(O),O,S或NR 3; L是被一个或多个O中断的C 1 -C 20亚烷基或C 2 -C 20亚烷基; R3是C1-C20烷基或C1-C20羟烷基; 并且Y是阴离子,适合作为光潜酸产生剂。
    • 2. 发明申请
    • Sulphonium Salt Initiators
    • 锍盐引发剂
    • US20090208872A1
    • 2009-08-20
    • US11922444
    • 2006-06-21
    • Jean-Pierre WolfAttila LatikaJean-Luc BirbaumStephan IlgPascal Hayoz
    • Jean-Pierre WolfAttila LatikaJean-Luc BirbaumStephan IlgPascal Hayoz
    • G03F7/20G03F7/004C07D209/88C07C321/30
    • C07D209/88B33Y70/00C07C309/06C07C381/12G03F7/0045G03F7/038Y10S430/122
    • Compounds of the formula (I), (II), (III), (IV) and wherein, R is hydrogen, C1-C20alkyl; C2-C20alkyl interrupted by one or more O; is -L-X—R2 or -L-R2; R1 has for example one of the meanings as given for R; R2 is a monovalent sensitizer or photoinitiator moiety; Ar1 and Ar2 for example independently of one another are phenyl substituted by C1-C20alkyl, halogen or OR3; or are unsubstituted naphthyl, anthryl, phenanthryl or biphenylyl; or are naphthyl, anthryl, phenanthryl or biphenylyl substituted by C1-C20alkyl, OH or OR3; or are —Ar4-A-Ar3; Ar3 is unsubstituted phenyl naphthyl, anthryl, phenanthryl or biphenylyl; or is phenyl, naphthyl, anthryl, phenanthryl or biphenylyl substituted by C1-C20alkyl, OR3 or benzoyl; Ar4 is phenylene, naphthylene, anthrylene or phenanthrylene; A is a direct bond, S, O or C1-C20alkylene; X is CO, C(O)O, OC(O), O, S or NR3; L is C1-C20alkylene or C2-C20alkylene interrupted by one or more O; R3 is C1-C20alkyl or C1-C20hydroxyalkyl; and Y is an anion, are suitable as photolatent acid generators.
    • 式(I),(II),(III),(IV)的化合物,其中R是氢,C 1 -C 20烷基; 被一个或多个O中断的C 2 -C 20烷基; 是-L-X-R2或-L-R2; R1具有例如R给出的含义之一; R2是单价敏化剂或光引发剂部分; Ar 1和Ar 2例如彼此独立地是被C 1 -C 20烷基,卤素或OR 3取代的苯基; 或未取代的萘基,蒽基,菲基或联苯基; 或被C 1 -C 20烷基,OH或OR 3取代的萘基,蒽基,菲基或联苯基; 或为-Ar4-A-Ar3; Ar 3是未取代的苯基萘基,蒽基,菲基或联苯基; 或由C 1 -C 20烷基,OR 3或苯甲酰基取代的苯基,萘基,蒽基,菲基或联苯基; Ar4是亚苯基,亚萘基,亚蒽基或菲基; A是直接键合,S,O或C1-C20亚烷基; X是CO,C(O)O,OC(O),O,S或NR 3; L是被一个或多个O中断的C1-C20亚烷基或C2-C20亚烷基; R3是C1-C20烷基或C1-C20羟烷基; 并且Y是阴离子,适合作为光潜酸产生剂。
    • 3. 发明授权
    • Iodonium salts as latent acid donors
    • 碘盐作为潜酸供体
    • US06306555B1
    • 2001-10-23
    • US09740205
    • 2000-12-18
    • Reinhard SchulzJean-Luc BirbaumJean-Pierre WolfStephan IlgHitoshi YamatoToshikage Asakura
    • Reinhard SchulzJean-Luc BirbaumJean-Pierre WolfStephan IlgHitoshi YamatoToshikage Asakura
    • G03F7004
    • G03F7/0382B33Y70/00C07C17/00C07C25/18C07C2601/14C08G59/68C08G65/105G03F7/0045G03F7/038G03F7/0392Y10S430/115
    • Radiation-sensitive compositions comprising (a1) a cationically or acid-catalytically polymerisable or crosslinkable compound or (a2) a compound that increases its solubility in a developer under the action of acid; and (b) at least one diaryliodonium salt of formula I X is branched C3-C20alkyl or C3-C8cycloalkyl; X1 is hydrogen, linear C1-C20alkyl, branched C3-C20alkyl or C3-C8cycloalkyl; with the proviso that the sum of the carbon atoms in X and X1 is at least 4; Y is linear C1-C10alkyl, branched C3-C10alkyl or C3-C8cycloalkyl; A− is a non-nucleophilic anion, selected from the group (BF4)−, (SbF6)−, (PF6)−, (B(C6F5))4−, C1-C20alkylsulfonate, C2-C20haloalkylsulfonate, unsubstituted C6-C10arylsulfonate, camphorsulfonate, and C6-C10arylsulfonate substituted by halogen, NO2, C1-C12alkyl, C1-C12halo-alkyl, C1-C12alkoxy or by COOR1; and R1 is C1-C20alkyl, phenyl, benzyl; or phenyl mono- or poly-substituted by C1-C12alkyl, C1-C12alkoxy or by halogen; with the proviso that the two phenyl rings on the iodine atom are not identically substituted.
    • 辐射敏感性组合物,其包含(a1)阳离子或酸可催化聚合或交联的化合物或(a2)在酸的作用下增加其在显影剂中的溶解度的化合物; 和(b)式IX的至少一种二芳基碘鎓盐是支链C 3 -C 20烷基或C 3 -C 8环烷基; X 1是氢,直链C 1 -C 20烷基,支链C 3 -C 20烷基或C 3 -C 8环烷基; 条件是X和X 1中的碳原子总数至少为4; Y为直链C 1 -C 10烷基,支链C 3 -C 10烷基或C 3 -C 8环烷基; A-为非亲核阴离子,选自(BF 4 ) - ,(SbF 6) - ,(PF 6) - ,(B(C 6 F 5))4-,C 1 -C 20烷基磺酸酯,C 2 -C 20卤代烷基磺酸酯,未取代的C 6 -C 10芳基磺酸酯,樟脑磺酸酯和C 6 -C 10芳基磺酸酯,被卤素, ,C 1 -C 12卤代烷基,C 1 -C 12烷氧基或COOR 1; 并且R 1是C 1 -C 20烷基,苯基,苄基; 或被C 1 -C 12烷基,C 1 -C 12烷氧基或卤素单取代或多取代的苯基;条件是碘原子上的两个苯环不同等取代。
    • 9. 发明申请
    • METHOD OF OPTICAL TELEDETECTION OF COMPOUNDS IN A MEDIUM
    • 中等化合物的光学检测方法
    • US20100283992A1
    • 2010-11-11
    • US12602245
    • 2008-05-26
    • Jérôme KasparianJean-Pierre Wolf
    • Jérôme KasparianJean-Pierre Wolf
    • G01J3/00G01N21/49
    • G01J3/42F21S41/675G01J3/457G01N21/31G01N21/538G01N2021/1795G01N2021/4709G01S7/4802G01S17/95Y02A90/19
    • The invention relates to a method of optical teledetection of compounds in a medium in which: a detection measurement is carried out by emitting into the medium, short pulses of light at least 3 nm wide, and detecting a part of the light back-scattered by the medium by means of a detection unit with temporal resolution, a reference measurement in which the light emitted or the light back-scattered is filtered by virtue of addressable filtering means, simulating the optical spectrum of the light at the working wavelengths of at least one given compound to be searched for, a comparison of a detection measurement and of a reference measurement, so as to deduce therefrom the possible presence of the compound or compound(s) searched for in the medium, the addressable filtering means are modified dynamically, and a series of reference measurements and a series of corresponding comparisons are performed for a series of various compounds liable to be present in the medium, as well as a device adapted for implementing such a method.
    • 本发明涉及一种在介质中对化合物进行光电检测的方法,其中:通过向介质中发射检测测量,至少3nm宽的短脉冲光,并通过以下步骤检测部分光反向散射 通过具有时间分辨率的检测单元的介质,借助于可寻址滤波装置对发射的光或光反向散射进行滤波的参考测量,模拟在至少一个工作波长处的光的光谱 给定化合物进行检索,检测测量和参考测量的比较,从而推断出在介质中搜索的化合物或化合物的可能存在,可寻址过滤装置被动态修改,以及 对一系列易于存在于介质中的各种化合物进行一系列参考测量和一系列相应的比较,以及一种装置 适于实施这种方法。
    • 10. 发明授权
    • Incorporable photoinitiator
    • 可并入的光引发剂
    • US07588880B2
    • 2009-09-15
    • US10512300
    • 2003-04-17
    • Jean-Pierre WolfRinaldo HüslerWolfgang PeterReinhard H. SommerladeSouâd Boulmaâz
    • Jean-Pierre WolfRinaldo HüslerWolfgang PeterReinhard H. SommerladeSouâd Boulmaâz
    • G03C1/73G03C1/735G03F7/028C08F2/50C07C49/12
    • C08F2/50B33Y70/00
    • Compounds of formula I Y is, for example, C3-C12alkylene, butenylene, butynylene, or C4-C12alkylene interrupted one or more times by non-consecutive —O— or —NR2—; R1 is a reactive group selected from OH, SH, NR3R4, —(CO)—OH, —(CO)—NH2, SO3H, —C(R5)═CR6R7, oxiranyl, —O—(CO)—NH—R8—NCO and —O—(CO)—R9—(CO)—X; R2 is hydrogen, C1-C4alkyl or C2-C4hydroxyalkyl; R3 and R4 are each independently of the other hydrogen, C1-C4alkyl or C2-C4hydroxyalkyl; R5, R6 and R7 are each independently of the others hydrogen or methyl; R8 is, for example, linear or branched C4-C12alkylene, or phenylene; R9 is, for example, linear or branched C1-C16alkylene, —CH═CH—, —CH═CH—CH2—, C6-cycloalkylene, phenylene or naphthylene; and X, X1 and X2 are each independently of the others OH, Cl, OCH3 or OC2H5; are suitable as photoinitiators that can be incorporated in a formulation to be cured.
    • 式I Y的化合物是例如C 3 -C 12亚烷基,亚丁烯基,亚丁炔基或C 4 -C 12亚烷基被非连续的-O-或-NR 2 - 间隔一次或多次; R1是选自OH,SH,NR3R4, - (CO)-OH, - (CO)-NH2,SO3H,-C(R5)-CR6R7,环氧乙烷基,-O-(CO)-NH-R8- NCO和-O-(CO)-R9-(CO)-X; R2是氢,C1-C4烷基或C2-C4羟烷基; R 3和R 4各自独立地为氢,C 1 -C 4烷基或C 2 -C 4羟烷基; R5,R6和R7各自独立地为氢或甲基; R8是例如直链或支链C 4 -C 12亚烷基或亚苯基; R 9为例如直链或支链C 1 -C 16亚烷基,-CH-CH-,-CH-CH-CH 2 - ,C 6 - 亚环烷基,亚苯基或亚萘基; X,X 1和X 2各自独立地为OH,Cl,OCH 3或OC 2 H 5; 适合作为可引入待固化制剂中的光引发剂。