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1. 发明授权

US4801717A Hydroxylamine derivative of 5-nitro-8-hydroxy quinoline 失效
公开(公告)号：US4801717A
公开(公告)日：1989-01-31
申请号：US877884
申请日：1986-06-24
申请人： Jean Tessier , Pierre Girault , Jean-Jacques Herve , Charles-Jacques Van Assche
发明人： Jean Tessier , Pierre Girault , Jean-Jacques Herve , Charles-Jacques Van Assche
IPC分类号： C07D209/48 , A01N33/24 , A01N35/04 , A01N37/24 , A01N37/34 , A01N37/36 , A01N37/38 , A01N37/40 , A01N37/50 , A01N41/10 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/78 , C07C67/00 , C07C205/12 , C07C205/37 , C07C205/58 , C07C213/00 , C07C231/00 , C07C231/12 , C07C235/46 , C07C239/00 , C07C239/08 , C07C239/20 , C07C253/00 , C07C255/54 , C07C301/00 , C07C303/34 , C07C309/75 , C07C311/29 , C07C313/00 , C07C317/22 , C07D213/64 , C07D215/18 , C07D215/20 , C07D215/24 , C07D277/68 , C07D401/12
CPC分类号： C07D213/64 , A01N33/24 , A01N35/04 , A01N37/24 , A01N37/36 , A01N37/38 , A01N37/40 , A01N37/50 , A01N41/10 , A01N43/40 , A01N43/42 , A01N43/78 , C07C205/12 , C07C205/37 , C07C205/58 , C07D215/18 , C07D215/20 , C07D215/24 , C07D277/68
摘要： Novel hydroxylamino derivatives of the formulaAr--ONH.sub.2 Iwherein Ar is selected from the group consisting of mono- and polycyclic aromatics and hetero-aromatics, both optionally substituted with at least one member of the group consisting of --OH, halogen, --NO.sub.2, --CN, ##STR1## --R.sub.7, --OR.sub.8, ##STR2## --SO.sub.2 R.sub.12, --SO.sub.3 R.sub.13, --COOR.sub.14, aryl of 6 to 14 carbon atoms, --OR.sub.16, --CH.sub.2 --CN and --CH.sub.2 SO.sub.2 --R.sub.15, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, R.sub.7 and R.sub.8 are optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen and cyano, R.sub.9, R.sub.10, R.sub.11, R.sub.12 and R.sub.13 are alkyl of 1 to 8 carbon atoms, Z is selected from the group consisting of hydrogen, optionally unsaturated alkyl of 1 to 8 carbon atoms and acyl of an organic carboxylic acid of 2 to 18 carbon atoms, R.sub.14 is selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, R.sub.15 is selected from the group consisting of alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms optionally substituted with an alkyl of 1 to 8 carbon atoms, R.sub.16 is aryl of 6 to 14 carbon atoms optionally substituted with a member of the group consisting of alkyl of 1 to 8 carbon atoms, halogen and --NO.sub.2, the substituents of Ar being able to form rings containing at least one heteroatom selected from the group consisting of oxygen, nitrogen and sulfur and their non-toxic agriculturally acceptable acid addition salts with the proviso Ar is not phenyl nor phenyl with one methyl in the 2,3 or 4 position, a nitro in the 2- or 4-position, a chlorine in the 3- or 4-position, a bromine in the 4-position or a --CF.sub.3 in the 4-position nor 2,4-dinitrophenyl nor 2-nitro-4-trifluoromethylphenyl nor 2,6-dinitrophenyl nor 2,4,6-trinitrophenyl nor 2,4-dinitro-6-trifluoromethylphenyl useful for increasing vegetation growth and increasing crop yields and their preparation.

2. 发明授权

US4401673A Pesticidal 3-(buta-1',3'-dienyl)-cyclopropane-1-carboxylic acid esters 失效
标题翻译：杀虫剂3-（buta-1'，3'-二烯基） - 环丙烷-1-羧酸酯
公开(公告)号：US4401673A
公开(公告)日：1983-08-30
申请号：US228454
申请日：1981-01-26
申请人： Jacques Martel , Jean Tessier , Pierre Girault
发明人： Jacques Martel , Jean Tessier , Pierre Girault
IPC分类号： C07C69/747 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/08 , A61K31/34 , A61K31/341 , A61K31/40 , A61K31/403 , A61K31/4035 , A61P33/00 , C07C62/30 , C07C62/32 , C07C62/38 , C07C67/00 , C07C231/00 , C07C231/12 , C07C235/34 , C07C253/00 , C07C255/31 , C07C255/39 , C07C325/00 , C07C327/44 , C07D209/49 , C07D307/36 , C07F9/655 , C11B9/00 , C07C69/743 , C07C121/75 , C07D213/57
CPC分类号： C07F9/65515 , A01N53/00 , C07C62/30 , C07C62/32 , C07C62/38 , C11B9/003 , C11B9/0061 , C11B9/0076 , C11B9/0092
摘要： Novel 3-(buta-1',3'-dienyl)-cyclopropane-1-carboxylic acid compounds of the formula ##STR1## wherein X.sub.1 and X.sub.2 are individually a halogen and A is selected from the group consisting of (A) benzyl optionally substituted (B) ##STR2## wherein R.sub.1 is selected from the group consisting of hydrogen and --CH.sub.3 and R.sub.2 is selected from the group consisting of aryl and --CH.sub.2 --C.tbd.CH, (C) ##STR3## wherein R.sub.3 is an aliphatic of 2 to 6 carbon atoms containing at least one carbon-carbon unsaturation, (D) ##STR4## wherein R'.sub.1 and R'.sub.2 are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, alkoxycarbonyl of 2 to 5 carbon atoms and cyano and R.sub.3 has the above definition, (E) ##STR5## wherein R.sub.4 is selected from the group consisting of hydrogen, --CN, --CH.sub.3, --CONH.sub.2, --CSNH.sub.2 and --C.tbd.CH, R.sub.5 is selected from the group consisting of chlorine and --CH.sub.3 and n is 0, 1 or 2, (F) .alpha.-cyano-3-phenoxy-benzyl, (G) .alpha.-cyano-3-pyridinyl-benzyl and (H) ##STR6## wherein R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are individually selected from the group consisting of hydrogen, chlorine and --CH.sub.3 and S/I indicates the ring may be aromatic or dihydro or tetrahydro useful for combatting insects, acariens and nematodes.
摘要翻译：新颖的式（Ⅰa'，3'-二烯基） - 环丙烷-1-羧酸化合物，其中X1和X2分别为卤素，A选自（A）任选取代的（B）其中R 1选自氢和-CH 3，R 2选自芳基和-CH 2 -C 3 CH 3，（C）其中R 3是脂族基含有至少一个碳 - 碳不饱和键的2至6个碳原子，（D）其中R'1和R'2分别选自氢，卤素，1至6个碳原子的烷基，芳基 2至5个碳原子的烷氧基羰基和氰基和R 3具有以上定义：（E）其中R 4选自氢，-CN，-CH 3，-CONH 2， - CSNH 2和-C 3 CH 2，R 5选自氯和-CH 3，n是0,1或2，（F）α-氰基-3-苯氧基 - 苄基，（G）α-氰基-3- 吡啶基 - 苄基和（H）其中R 6，R 7，R 8和R 9分别选自氢，氯和-CH 3，并且S / I表示环可以是用于防治昆虫，acariens的芳族或二氢或四氢和线虫。

3. 发明授权

US4501894A Heterocyclic alcohols and their derivatives 失效
标题翻译：杂环醇及其衍生物
公开(公告)号：US4501894A
公开(公告)日：1985-02-26
申请号：US352256
申请日：1982-02-25
申请人： Francois Nezot , Pierre Girault , Jean Tessier , Jacques Martel
发明人： Francois Nezot , Pierre Girault , Jean Tessier , Jacques Martel
IPC分类号： A01N53/00 , C07D277/20 , C07D277/22 , C07D277/24 , C07D277/30 , C07D277/34 , C07D277/56 , C07D285/08
CPC分类号： C07D277/20 , A01N53/00 , C07D277/24 , C07D277/34 , C07D277/56 , C07D285/08
摘要： Novel heterocyclic compounds of the formula ##STR1## wherein X is selected from the group consisting of chlorine, bromine, iodine and --OH, W is selected from the group consisting of hydrogen and --CN, Z is selected from the group consisting of --CH.sub.2 -- and --O-- attached to the carbon atom included between a nitrogen and the sulfur atom of Y and Y is selected from the group consisting of thiazolyl or thiadiazolyl connected to ##STR2## at one of its available positions except for (2-benzyl-4 and 5-thiazolyl) methanol and .alpha.-cyano-(2-benzyl-5-thiazolyl)-methanol and the compounds wherein X is halogen when W is --CN whose esters have insecticidal activity.
摘要翻译：式（I）的新型杂环化合物其中X选自氯，溴，碘和-OH，W选自氢和-CN，Z选自 - 包含在氮和Y和Y的硫原子之间的碳原子上的CH 2 - 和-O-连接在其可用位置之一处的噻唑基或噻二唑基之间，除了（2-苄基 -4和5-噻唑基）甲醇和α-氰基 - （2-苄基-5-噻唑基） - 甲醇和其中当W是具有杀虫活性的-CN的时，X是卤素的化合物。

4. 发明授权

US4808210A Herbicidal method of using 5-pyrazolones 失效
标题翻译：使用5-吡唑啉酮的除草方法
公开(公告)号：US4808210A
公开(公告)日：1989-02-28
申请号：US096364
申请日：1987-09-11
申请人： Jean Tessier , Pierre Girault
发明人： Jean Tessier , Pierre Girault
IPC分类号： A01N43/56 , A01N43/78 , A01N47/38 , C07D231/20 , C07D231/22 , C07D401/04 , C07D403/04 , C07D417/04
CPC分类号： C07D401/04 , A01N43/56 , A01N43/78 , A01N47/38 , C07D231/20 , C07D231/22 , C07D403/04 , C07D417/04
摘要： A 5-pyrazolone of the formula ##STR1## wherein R is selected from the group consisting of mono- and polycyclic aromatic of 6 to 14 carbon atoms, heterocyclic optionally substituted with phenyl, ##STR2## and benzyl, all optionally substituted with at least one member of the group consisting of fluorine, chlorine, bromine, --CF.sub.3, optionally unsaturated alkyl of 1 to 8 carbon atoms and the radical OZ in which Z is an optionally unsaturated alkyl of 1 to 8 carbon atoms or an acyl of a carboxylic acid of 1 to 6 carbon atoms, A is selected from the group consisting of halogen, --CF.sub.3 and --CN, B and C are individually selected from the group consisting of hydrogen, halogen, --OH, --OR' and R' is optionally unsaturated alkyl of 1 to 8 carbon atoms, acyl of 1 to 6 carbon atoms, alkyl sulfonyl of 1 to 8 carbon atoms, aryl sulfonyl of 6 to 18 carbon atoms and benzyl optionally substituted with a member of the group consisting of fluorine, chlorine, bromine, --CF.sub.3, optionally unsaturated alkyl of 1 to 8 carbon atoms, optionally unsaturated alkyl and haloalkyl of 1 to 8 carbon atoms interrupted with at least one heteroatom, with the proviso that B and C can not both be fluorine or --OH having herbicidial activity.
摘要翻译：下式的5-吡唑啉酮其中R选自6至14个碳原子的单环和多环芳族化合物，任选被苯基取代的杂环基，和任选地被至少取代的苯甲基由氟，氯，溴，-CF 3，1-8个碳原子的任选不饱和烷基和Z为任选不饱和的1至8个碳原子的烷基的基团OZ或羧酸酰基组成的组中的一个成员 1至6个碳原子，A选自卤素，-CF 3和-CN，B和C分别选自氢，卤素，-OH，-OR'，R'是任选不饱和的 1至8个碳原子的烷基，1至6个碳原子的酰基，1至8个碳原子的烷基磺酰基，6至18个碳原子的芳基磺酰基和任选被氟，氯，溴成员组成的基团取代的苄基，-CF 3，1〜8的任选的不饱和烷基碳原子，任选不饱和的烷基和1至8个碳原子的卤代烷基与至少一个杂原子间隔，条件是B和C不能都是具有除草活性的氟或-OH。

5. 发明授权

US4618364A 3-(2-tetrahydropyranyl)-1,2,3,4 ,5,6,7-hexahydro-1-p-tolyloxycarbonyl-5H-cyclopentapyrimidine-2,4-dione and herbicidal compositions and methods using it 失效
标题翻译： 3-（2-四氢吡喃基）-1,2,3,4,5,6,7-六氢-1-对甲氧基羰基-5H-环戊并嘧啶-2,4-二酮及其使用的除草组合物和方法
公开(公告)号：US4618364A
公开(公告)日：1986-10-21
申请号：US628331
申请日：1984-07-06
申请人： Jean Tessier , Pierre Girault
发明人： Jean Tessier , Pierre Girault
IPC分类号： A01N47/38 , C07D401/04 , C07D405/04 , C07D239/70
CPC分类号： C07D405/04 , A01N47/38
摘要： Novel uracils of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms, halogen and --C(Hal).sub.3, Hal is halogen and R.sub.2 is hydrogen or R.sub.1 and R.sub.2 taken together with the benzene ring to which they are attached form a system of two coupled rings optionally containing at least one heteroatom having selective herbicidal activity.
摘要翻译：式（I）的新型尿嘧啶，其中R 1选自1至8个碳原子的烷基，1至8个碳原子的烷氧基，卤素和-C（Hal）3，Hal是卤素，R 2是氢或者R 1和R 2与它们所连接的苯环一起形成任选含有至少一个具有选择性除草活性的杂原子的两个偶联环的体系。

6. 发明授权

US4364928A Novel salts of ion exchange resins of the acid type 失效
标题翻译：酸型离子交换树脂的新型盐
公开(公告)号：US4364928A
公开(公告)日：1982-12-21
申请号：US194907
申请日：1980-10-07
申请人： Jacques Martel , Jean Tessier , Pierre Girault , Jean A. Grandadam
发明人： Jacques Martel , Jean Tessier , Pierre Girault , Jean A. Grandadam
IPC分类号： A61K9/18 , A61K47/48 , B01J39/18 , B01J47/00 , B01J39/20 , A61K31/74
CPC分类号： A61K47/48184 , B01J39/18 , B01J47/006
摘要： Ion exchange resins of the acid type at least partially salified with 7-bromo-6-chloro-febrifugin having very good coccidiostatic activity, a very good anti-leucocytozoonosis activity and a low toxicity and their preparation.
摘要翻译：具有非常好的抗球虫抑制活性的7-溴-6-氯 - 异丙酸至少部分成盐的酸型离子交换树脂，非常好的抗白细胞生成活性和低毒性及其制备。

7. 发明授权

US4777180A Pesticidal cyclopropanecarboxylates 失效
标题翻译：杀虫环丙烷羧酸酯
公开(公告)号：US4777180A
公开(公告)日：1988-10-11
申请号：US106143
申请日：1987-10-07
申请人： Jean Tessier , Pierre Girault
发明人： Jean Tessier , Pierre Girault
IPC分类号： C07D233/72 , A01N53/00 , A01N53/04 , A01N53/08 , A23K1/16 , C07D233/60 , C07D233/74 , A01N43/50
CPC分类号： C07D233/74 , A01N53/00 , A23K20/137
摘要： Novel esters in all stereoisomeric forms and mixtures of said isomers of the formula ##STR1## wherein one of X and Y is ##STR2## and the other is selected from the group consisting of --CH.sub.2 --, --CH.sub.2 --CH.sub.2 -- and --CH.sub.2 --CH.sub.2 --CH.sub.2 --, n is an integer from 2 to 3 and R.sub.1 is selected from the group consisting of alkyl of 1 to 3 carbon atoms and alkenyl and alkynyl of 2 to 3 carbon atoms having pesticidal activity.
摘要翻译：所有立体异构体形式的新型酯和式（I）的所述异构体的混合物，其中X和Y之一为“IMA”，另一个选自-CH 2 - ， - CH 2 -CH 2 - 和-CH 2 -CH 2 -CH 2 - ，n为2〜3的整数，R 1选自1〜3个碳原子的烷基和具有杀虫活性的2〜3个碳原子的链烯基和炔基。

8. 发明授权

US4565822A 2-Fluoro-2-cyanoethenyl cyclopropane carboxylates as pesticides 失效
标题翻译： 2-氟-2-氰基乙烯基环丙烷羧酸酯作为农药
公开(公告)号：US4565822A
公开(公告)日：1986-01-21
申请号：US637106
申请日：1984-08-02
申请人： Jean Tessier , Andre Teche , Pierre Girault
发明人： Jean Tessier , Andre Teche , Pierre Girault
IPC分类号： C07D233/70 , A01N43/40 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/08 , A01P7/04 , A23K1/16 , A61K31/275 , C07C67/00 , C07C253/00 , C07C253/30 , C07C255/31 , C07C255/39 , C07C255/53 , C07D213/57 , C07D213/64 , C07D213/647 , C07D233/72 , C07D233/74 , C07D307/45 , C07F3/10 , C07F3/12 , C07D213/65 , C07C121/48
CPC分类号： C07D213/647 , A01N53/00 , C07C255/00 , C07D233/72 , C07F3/10 , C07F3/12
摘要： Novel cyclopropanecarboxylates in all possible isomeric forms or mixtures thereof of the formula ##STR1## with a 1R,cis or 1R,trans structure and wherein X is a halogen, R is selected from the group consisting of (A) optionally unsaturated alkyl of 2 to 12 carbon atoms, (B) optionally unsaturated cycloalkyl of 3 to 12 carbon atoms, (c) ##STR2## Z is selected from the group consisting of --C.tbd.CH, --CH.sub.3 and --CN and Ar is selected from the group consisting of --C.sub.6 H.sub.5, --C.sub.6 F.sub.5, ##STR3## B is hydrogen or fluorine and X is fluorine, chlorine or bromine ##STR4## Y.sub.2 is selected from the group consisting of hydrogen, fluorine, chlorine bromine, --C.tbd.N and --C.tbd.CH, Y.sub.3, Y.sub.4, and Y.sub.5 are individually selected from the group consisting of hydrogen, fluorine, chlorine, bromine alkyl of 1 to 8 carbon atoms and cycloalkyl of 3 to 8 carbon atoms optionally substituted by one or more functional groups, alkenyl of 2 to 8 carbon atoms and alkynyl of 2 to 8 carbon atoms, and two of Y.sub.3, Y.sub.4 and Y.sub.5 can form rings between them with the proviso that if X is bromine and R is ##STR5## and Z is cyano or ethynyl and A.sub.r is ##STR6## the carbon carrying Z is in the (S) configuration and the double bond in the 3-side chain may have E or Z structure useful in combatting pests such as insects, nematodes acarids.
摘要翻译：新型环丙烷羧酸酯，其具有1R，顺式或1R，反式结构的所有可能的异构形式或其混合物，其中X为卤素，R选自（A）任选不饱和的2位烷基至12个碳原子，（B）任选的3至12个碳原子的不饱和环烷基，（c）Z选自-C 3 CH 2，-CH 3和-CN，Ar选自（D）图像（E）和图像（F），其中，C 6 H 5，-C 6 F 5， Y2选自氢，氟，氯溴，-C 3位N和-C 3位CH，Y 3，Y 4和Y 5分别选自氢，氟，氯，溴烷基1至 8个碳原子和3至8个碳原子的环烷基，任选被一个或多个官能团取代，2至8个碳原子的烯基和2个炔基的炔基至8个碳原子，并且Y 3，Y 4和Y 5中的两个可以在它们之间形成环，条件是如果X是溴且R是“Z”，Z是氰基或乙炔基，Ar是“ 3侧链中的（S）构型和双键可以具有用于对抗昆虫，线虫螨等害虫的E或Z结构。

9. 发明授权

US4450169A Insecticidal esters 失效
标题翻译：杀虫剂
公开(公告)号：US4450169A
公开(公告)日：1984-05-22
申请号：US352257
申请日：1982-02-25
申请人： Francois Nezot , Pierre Girault , Jean Tessier , Jacques Martel
发明人： Francois Nezot , Pierre Girault , Jean Tessier , Jacques Martel
IPC分类号： A01N43/836 , A01N43/78 , A01N43/82 , A01N53/00 , A01N53/04 , A01N53/06 , A23K1/16 , A61K31/41 , A61K31/425 , A61K31/426 , A61K31/433 , A61P31/00 , A61P33/10 , C07D277/20 , C07D277/24 , C07D277/30 , C07D277/34 , C07D277/56 , C07D285/08 , C07D417/12
CPC分类号： C07D285/08 , A01N43/78 , A01N43/82 , A01N53/00 , C07D277/24 , C07D277/30 , C07D277/34 , C07D277/56
摘要： Novel esters of the formula ##STR1## wherein R is selected from the group consisting of ##STR2## W is selected from the group consisting of hydrogen and --CN, Z is selected from the group consisting of --CH.sub.2 -- and --O--, and is attached to a carbon atom included between a nitrogen and the sulfur atom of Y and Y is selected from the group consisting of thiazolyl or thiadiazolyl connected to ##STR3## at one of its available positions.
摘要翻译：其中R选自由下列组成的组成的组的下式的新颖的酯：其中R选自氢和-CN，Z选自-CH 2 - 和-O-，并且连接到包含在氮和Y的硫原子之间的碳原子上，Y选自噻唑基或噻二唑基，其在其可用位置之一处连接到“IMAGE”。

10. 发明授权

US5164409A Pyrroles possessing insecticidal activity 失效
标题翻译： PYRROLES POSSESSING INSECTICIDAL活动
公开(公告)号：US5164409A
公开(公告)日：1992-11-17
申请号：US661399
申请日：1991-02-26
申请人： Marc Benoit , Jacques Demassey , Jean-Pierre Demoute , Jean Tessier
发明人： Marc Benoit , Jacques Demassey , Jean-Pierre Demoute , Jean Tessier
IPC分类号： A01N53/00 , A01N53/04 , C07D207/32 , C07D207/333
CPC分类号： C07D207/333 , A01N53/00
摘要： All possible stereoisomers and mixtures of a compound of the formula ##STR1## wherein X and Y are different and are selected from the group consisting of hydrogen, halogen, --CN, alkyl and haloalkyl of 1 to 8 carbon atoms and phenyl optionally substituted by at least one member of the group consisting of halogen and alkyl and alkoxy of 1 to 8 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, methyl, --CN and ethynyl, ##STR2## A and B are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms and the --CF.sub.3 is in the 2-, 4- or 5-position of the pyrrole ring having pesticidal activity.
摘要翻译：式（I）化合物的所有可能的立体异构体和混合物，其中X和Y不同，并且选自氢，卤素，-CN，具有1至8个碳原子的烷基和卤代烷基，以及任选的苯基被至少一个由卤素和1至8个碳原子的烷基和烷氧基组成的组取代，R 1选自氢，甲基，-CN和乙炔基，A和B分别选自由氢，卤素，碳原子数1〜8的烷基和碳原子数为6〜14的芳基构成的基团，在具有杀虫活性的吡咯环的2-，4-或5-位。

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