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1. 发明授权

US4602038A Insecticidal cyclopropane carboxylates 失效
标题翻译：杀虫环丙烷羧酸盐
公开(公告)号：US4602038A
公开(公告)日：1986-07-22
申请号：US618596
申请日：1984-06-08
申请人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
发明人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
IPC分类号： A61K31/275 , A01N53/00 , A01N53/02 , A01N53/08 , A23K1/16 , A61P33/00 , C07C67/00 , C07C253/00 , C07C253/30 , C07C255/31 , C07C255/39 , C07C255/45 , C07C255/53 , C07C313/00 , C07C317/00 , C07C317/44 , C07C323/60 , C07D213/64 , C07D213/647 , C07D233/74 , C07D307/45 , C07D307/93 , C07F9/40 , C07F9/535 , C07F9/6571 , C07C121/75
CPC分类号： C07D213/647 , A01N53/00 , A23K20/00 , C07C255/00 , C07D233/74 , C07F9/657181
摘要： Novel cyclopropane carboxylates in all isomeric forms of the formula ##STR1## wherein A is selected from the group consisting of --O--, --S--, ##STR2## and --SO.sub.2 --, R.sub.1 is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms optionally containing at least one heteroatom in the carbon chain and optionally substituted with at least one halogen, aryl of 6 to 18 carbon atoms and aralkyl of 7 to 18 carbon atoms and R.sub.2 is selected from the group consisting of hydrogen, optionally unsaturated alkyl of 1 to 12 carbon atoms, optionally unsaturated cycloalkyl of 3 to 12 carbon atoms and residue of other alcohols used in pyrethrinoids having pesticidal activity for combatting insects, acariens of vegetables and warm-blooded animals and nematodes and novel intermediates.
摘要翻译：新型环丙烷羧酸盐，其分子式为：其中A选自-O - ， - S-，IMA和-SO 2 - ，R 1选自任选不饱和的烷基任选地在碳链中含有至少一个杂原子且任选地被至少一个卤素，6至18个碳原子的芳基和7至18个碳原子的芳烷基取代的1至18个碳原子，R 2选自氢，任选不饱和的1至12个碳原子的烷基，任选具有3至12个碳原子的不饱和环烷基，以及用于具有杀虫昆虫的杀虫活性的拟除虫菊酯，蔬菜和温血动物以及线虫的新型中间体的其它醇的残基。

2. 发明授权

US5082832A Novel cyclopropane carboxylates 失效
标题翻译：新型环丙基羧酸酯
公开(公告)号：US5082832A
公开(公告)日：1992-01-21
申请号：US423803
申请日：1989-10-18
申请人： Joseph Cadiergue , Jean-Pierre Demoute , Jean Tessier
发明人： Joseph Cadiergue , Jean-Pierre Demoute , Jean Tessier
IPC分类号： C07C69/74 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/06 , A01N53/08 , A01N55/00 , A01N57/12 , A01N57/14 , A01N57/36 , A23K1/16 , A61K31/215 , A61K31/23 , C07C51/377 , C07C61/40 , C07C62/02 , C07C67/00 , C07C67/317 , C07C69/63 , C07C69/65 , C07C69/743 , C07C69/757 , C07C69/76 , C07C253/00 , C07C253/30 , C07C255/10 , C07C255/31 , C07C255/53 , C07C301/00 , C07C303/28 , C07C303/30 , C07C309/63 , C07C309/64 , C07C309/65 , C07C309/66 , C07C309/70 , C07C309/72 , C07C309/73 , C07C317/04 , C07C317/14 , C07D209/48 , C07D209/49 , C07D213/30 , C07D213/57 , C07D213/64 , C07D213/647 , C07D213/65 , C07D213/68 , C07D233/64 , C07D233/72 , C07D307/42 , C07D307/45 , C07D309/38 , C07D317/24 , C07F9/09 , C07F9/117 , C07F9/177 , C07F9/38 , C07F9/40 , C07F9/58 , C07F9/655 , C07F9/6574
CPC分类号： C07D213/647 , A01N53/00 , A01N55/00 , A01N57/14 , A01N57/36 , A23K20/00 , C07C309/00 , C07C309/65 , C07C309/66 , C07C309/72 , C07C61/40 , C07C69/757 , C07D317/24 , C07F9/117 , C07F9/177 , C07F9/581 , C07F9/65502 , C07F9/65742 , C07C2101/02
摘要： Novel 2,2-dimethyl-cyclopropane carboxylic acid derivatives of the formula ##STR1## wherein X.sub.1 and X.sub.2 are individually halogen, R.sub.1 is selected from the group consisting of halogen, alkyl of 1 to 8 carbon atoms, optionally substituted aryl of 6 to 14 carbon atoms, perfluoroalkyl of 1 to 8 carbon atoms, --CN and ##STR2## R' is alkyl of 1 to 8 carbon atoms, Y is selected from the group consisting of ##STR3## Alk.sub.1 is optionally unsaturated alkyl of 1 to 8 carbon atoms no substituted or substituted with at least one functional group, Ar is aryl of 6 to 14 carbon atoms no substituted or substituted with at least one functional group, Alk.sub.2 and Alk.sub.3 and Alk.sub.2 ' and Alk.sub.3 ' are optionally unsaturated alkyl of 1 to 8 carbon atoms no substituted or substituted with at least one functional group or together with ##STR4## form the rings ##STR5## wherein A is optionally unsaturated alkyl of 1 to 6 carbon atoms optionally substituted with at least one functional group, R" is alkyl of 1 to 6 carbon atoms no substituted or substituted with at least one functional group or aryl of 6 to 14 carbon atoms no substituted or substituted with at least one functional group and R is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms and residue of an alcohol used in pyrethrinoid esters having pestioidal activity.

3. 发明授权

US4537897A 3-(1,2-Propadienyl)-cyclopropane-carboxylates 失效
标题翻译： 3-（1,2-丙二烯基） - 环丙烷羧酸酯
公开(公告)号：US4537897A
公开(公告)日：1985-08-27
申请号：US532825
申请日：1983-09-15
申请人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
发明人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
IPC分类号： C07C69/747 , A01N53/00 , A01N53/02 , A01N53/10 , C07C51/09 , C07C51/367 , C07C67/00 , C07C69/743 , C07C231/00 , C07C231/12 , C07C233/10 , C07C253/00 , C07C255/31 , C07C255/39 , C07C313/00 , C07C319/20 , C07C323/19 , C07C323/62 , C07C325/00 , C07C327/44 , C07D213/64 , C07D213/647 , C07D233/72 , C07D233/74 , C07D307/45 , C07D309/40 , C07D213/68
CPC分类号： C07D213/647 , A01N53/00 , C07C51/09 , C07C51/367 , C07D233/74 , C07D307/42
摘要： Novel 3-(1,2-propadienyl)-cyclopropane-carboxylates of the formula ##STR1## wherein R is alcohol used in pyrethrinoid synthesis, X and Y are both hydrogen or individually halogen or X is hydrogen or halogen and Y is alkyl of 1 to 18 carbon atoms or halogen or X is hydrogen or halogen or alkyl of 1 to 18 carbon atoms and Y is --COOR' or --CN or ##STR2## R' is alkyl of 1 to 18 carbon atoms, R.sub.2 and R.sub.3 are individually hydrogen or alkyl of 1 to 18 carbon atoms or R.sub.2 and R.sub.3 together with the nitrogen atom form a heterocycle having pesticidal properties.
摘要翻译：其中R是用于拟除虫菊酯合成的醇的新型3-（1,2-丙二烯基） - 环丙烷羧酸盐，X和Y都是氢或单独的卤素或X是氢或卤素，Y是 1至18个碳原子或卤素或X为氢或卤素或1至18个碳原子的烷基，Y为-COOR'或-CN或R 1为具有1至18个碳原子的烷基，R 2和R 3分别为氢或1至18个碳原子的烷基或R2和R3与氮原子一起形成具有杀虫性质的杂环。

4. 发明授权

US5245073A Process for the preparation of certain cyclopropane carboxylates 失效
标题翻译：制备某些环丙烷羧酸盐的方法
公开(公告)号：US5245073A
公开(公告)日：1993-09-14
申请号：US747702
申请日：1991-08-20
申请人： Joseph Cadiergue , Jean-Pierre Demoute , Jean Tessier
发明人： Joseph Cadiergue , Jean-Pierre Demoute , Jean Tessier
IPC分类号： A01N53/00 , A01N55/00 , A01N57/14 , A01N57/36 , A23K1/16 , C07C61/40 , C07C69/62 , C07C69/743 , C07C69/757 , C07C255/53 , C07C309/65 , C07C309/66 , C07C309/72 , C07D213/64 , C07D213/647 , C07D317/24 , C07F9/117 , C07F9/177 , C07F9/58 , C07F9/655 , C07F9/6574
CPC分类号： C07D213/647 , A01N53/00 , A01N55/00 , A01N57/14 , A01N57/36 , A23K20/00 , C07C309/00 , C07C309/65 , C07C309/66 , C07C309/72 , C07C61/40 , C07C69/757 , C07D317/24 , C07F9/117 , C07F9/177 , C07F9/581 , C07F9/65502 , C07F9/65742 , C07C2101/02
摘要： Novel 2,2-dimethyl-cyclopropane carboxylic acid derivatives of the formula ##STR1## wherein X.sub.1 and X.sub.2 are individually halogen, R.sub.1 is selected from the group consisting of halogen, alkyl of 1 to 8 carbon atoms, optionally substituted aryl of 6 to 14 carbon atoms, perfluoroalkyl of 1 to 8 carbon atoms, --CN and ##STR2## R' is alkyl of 1 to 8 carbon atoms, Y is selected from the group consisting of --SO.sub.2 Alk.sub.1, --SO.sub.2 Ar, ##STR3## Alk.sub.1 is optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted with at least one halogen, Ar is aryl of 6 to 14 carbon atoms optionally substituted with at least one halogen Alk.sub.2 and Alk.sub.3 and Alk.sub.2 ' and Alk.sub.3 ' are optionally unsaturated alkyl of up to 8 carbon atoms optionally substituted with at least one halogen or together with ##STR4## form the rings ##STR5## wherein A is optionally unsaturated alkyl of up to 6 carbon atoms optionally substituted with at least one halogen, R" is alkyl of 1 to 6 carbon atoms no substituted or substituted with at least one functional group or aryl of 6 to 14 carbon atoms no substituted or substituted with at least one functional group and R is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms and residue of an alcohol used in pyrethrinoid esters having pestioidal activity.
摘要翻译：新颖的式Ⅰa的2,2-二甲基 - 环丙烷羧酸衍生物，其中X1和X2分别为卤素，R1选自卤素，1至8个碳原子的烷基，任选取代的6至6位的芳基 14个碳原子，1至8个碳原子的全氟烷基，-CN和R'是1至8个碳原子的烷基，Y选自-SO 2 Alk 1，-SO 2 Ar，Alk1是任选不饱和的任选被至少一个卤素取代的1至8个碳原子的烷基，Ar是任选被至少一个卤素Alk2和Alk3和Alk2'取代的6至14个碳原子的芳基，Alk3'是至多8个碳原子的任选不饱和烷基任选地被至少一个卤素取代或与“IMAGE”一起形成环，其中A是任选被至多6个碳原子任意取代的不饱和烷基，任选被至少一个卤素取代，R“是1至6个碳原子的烷基没有被取代或被替换为lea 第一官能团或未被至少一个官能团取代或取代的6至14个碳原子的芳基，R选自氢，1至8个碳原子的烷基和在除虫菊酯中使用的醇残基， pest虫活动。

5. 发明授权

US4925874A Novel cyclopropane carboxylates 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4925874A
公开(公告)日：1990-05-15
申请号：US123374
申请日：1987-11-20
申请人： Joseph Cadiergue , Jean-Pierre Demoute , Jean Tessier
发明人： Joseph Cadiergue , Jean-Pierre Demoute , Jean Tessier
IPC分类号： C07C69/74 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/06 , A01N53/08 , A01N55/00 , A01N57/12 , A01N57/14 , A01N57/36 , A23K1/16 , A61K31/215 , A61K31/23 , C07C51/377 , C07C61/40 , C07C62/02 , C07C67/00 , C07C67/317 , C07C69/63 , C07C69/65 , C07C69/743 , C07C69/757 , C07C69/76 , C07C253/00 , C07C253/30 , C07C255/10 , C07C255/31 , C07C255/53 , C07C301/00 , C07C303/28 , C07C303/30 , C07C309/63 , C07C309/64 , C07C309/65 , C07C309/66 , C07C309/70 , C07C309/72 , C07C309/73 , C07C317/04 , C07C317/14 , C07D209/48 , C07D209/49 , C07D213/30 , C07D213/57 , C07D213/64 , C07D213/647 , C07D213/65 , C07D213/68 , C07D233/64 , C07D233/72 , C07D307/42 , C07D307/45 , C07D309/38 , C07D317/24 , C07F9/09 , C07F9/117 , C07F9/177 , C07F9/38 , C07F9/40 , C07F9/58 , C07F9/655 , C07F9/6574
CPC分类号： C07D213/647 , A01N53/00 , A01N55/00 , A01N57/14 , A01N57/36 , A23K20/00 , C07C309/00 , C07C309/65 , C07C309/66 , C07C309/72 , C07C61/40 , C07C69/757 , C07D317/24 , C07F9/117 , C07F9/177 , C07F9/581 , C07F9/65502 , C07F9/65742 , C07C2101/02
摘要： Novel 2,2-dimethyl-cyclopropane carboxylic acid derivatives of the formula ##STR1## wherein X.sub.1 and X.sub.2 are individually halogen, R.sub.1 is selected from the group consisting of halogen, alkyl of 1 to 8 carbon atoms, optionally substituted aryl of 6 to 14 carbon atoms, perfluoroalkyl of 1 to 8 carbon atoms, --CN and ##STR2## R' is alkyl of 1 to 8 carbon atoms, Y is selected from the group consisting of --SO.sub.2 Alk.sub.1, --SO.sub.2 Ar, ##STR3## Alk.sub.1 is optionally unsaturated alkyl of 1 to 8 carbon atoms no substituted or substituted with at least one functional group, Ar is aryl of 6 to 14 carbon atoms no substituted or substituted with at least one functional group, Alk.sub.2 and Alk.sub.3 and Alk.sub.2 ' and Alk.sub.3 ' are optionally unsaturated alkyl of 1 to 8 carbon atoms no substituted or substituted with at least one functional group or together with ##STR4## form the rings ##STR5## wherein A is optionally unsaturated alkyl of 1 to 6 carbon atoms optionally substituted with at least one functional group, R" is alkyl of 1 to 6 carbon atoms no substituted or substituted with at least one functional group or aryl of 6 to 14 carbon atoms no substituted or substituted with at least one functional group and R is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms and residue of an alcohol used in pyrethrinoid esters having pesticidal activity.
摘要翻译：新颖的式Ⅰa的2,2-二甲基 - 环丙烷羧酸衍生物，其中X1和X2分别为卤素，R1选自卤素，1至8个碳原子的烷基，任选取代的6至6位的芳基 14个碳原子，1至8个碳原子的全氟烷基，-CN和R'是1至8个碳原子的烷基，Y选自-SO 2 Alk 1，-SO 2 Ar，Alk1是任选不饱和的未被取代或被至少一个官能团取代的1至8个碳原子的烷基，Ar是不被至少一个官能团取代或取代的6至14个碳原子的芳基，Alk2和Alk3以及Alk2'和Alk3'是任选不饱和的没有被至少一个官能团取代或取代的1至8个碳原子的烷基，或与一起形成环，其中A是任选被1至6个碳原子任选取代的不饱和烷基，任选被至少一个官能团取代， R“是1至1的烷基 6个未被至少一个未被取代或被至少一个官能团取代或被至少一个官能团取代的官能团或6至14个碳原子的芳基取代或取代的碳原子，R选自氢，1至8个碳原子的烷基和用于具有杀虫活性的拟除虫菊酯中的醇残基。

6. 发明授权

US4556666A Cyclopropane carboxylic acid derivatives 失效
标题翻译：环丙烷羧酸衍生物
公开(公告)号：US4556666A
公开(公告)日：1985-12-03
申请号：US541084
申请日：1983-10-12
申请人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
发明人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
IPC分类号： C07C67/343 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/06 , A01N53/08 , A01N53/10 , A01N53/12 , A23K1/16 , C07C67/00 , C07C69/734 , C07C69/736 , C07C69/757 , C07C253/00 , C07C255/14 , C07C255/39 , C07C313/00 , C07C317/44 , C07C323/55 , C07D213/64 , C07D213/647 , C07D233/72 , C07D233/74 , C07D233/78 , C07D307/45 , C07D307/93
CPC分类号： C07D213/647 , A01N53/00 , A23K20/105 , A23K20/116 , C07D233/74
摘要： All stereoisomeric forms and mixtures of stereoisomers of compounds of the formula ##STR1## wherein X is selected from the group consisting of oxygen, sulfur, sulfoxide and sulfone, R.sub.1 and R.sub.3 are individually selected from the group consisting of optionally unsaturated alkyl of 1 to 7 carbon atoms and optionally unsaturated cycloalkyl of 3 to 7 carbon atoms optionally substituted with at least one halogen and optionally interrupted with at least one heteroatom and aryl and aralkyl of 6 to 18 carbon atoms and R.sub.2 is the residue of a R.sub.2 OH alcohol used in pyrethrinoids synthesis having pesticidal activity and their preparation and novel intermediates.
摘要翻译：下式化合物的立体异构体形式和立体异构体的混合物其中X选自氧，硫，亚砜和砜，R1和R3分别选自任选不饱和的1至 7个碳原子和任选地具有3至7个碳原子的不饱和环烷基，任选被至少一个卤素取代并且任选地被至少一个杂原子中断并且具有6至18个碳原子的芳基和芳烷基，并且R 2是用于除虫菊酯中的R2OH醇的残基合成具有杀虫活性及其制备和新型中间体。

7. 发明授权

US4939172A Novel cyclopropane carboxylates 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4939172A
公开(公告)日：1990-07-03
申请号：US153157
申请日：1988-02-08
申请人： Joseph Cadiergue , Jacques Demassey , Jean-Pierre Demoute , Jean Tessier
发明人： Joseph Cadiergue , Jacques Demassey , Jean-Pierre Demoute , Jean Tessier
IPC分类号： C07C69/743 , A01N53/00 , A01N53/06 , A01N55/00 , A01N55/10 , A61K31/215 , C07C33/46 , C07C43/23 , C07C67/00 , C07C67/08 , C07C69/73 , C07C69/747 , C07C69/757 , C07C213/08 , C07C219/32 , C07C253/00 , C07C253/30 , C07C255/38 , C07C255/39 , C07C255/41 , C07C255/53 , C07C255/55 , C07C319/20 , C07C323/16 , C07C323/18 , C07C323/19 , C07C323/60 , C07C323/62 , C07D309/12 , C07F7/08 , C07F7/18
CPC分类号： C07C255/00 , A01N53/00 , C07C43/23 , C07D309/12 , C07F7/1852
摘要： Novel cyclopropane carboxylic acid esters of all possible stereoisomeric forms and mixtures thereof of the formula ##STR1## wherein X is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, R is selected from the group consisting of optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted, optionally unsaturated cycloalkyl of 3 to 8 carbon atoms optionally substituted, optionally substituted aryl of 6 to 14 carbon atoms and optionally substituted heterocycle, Z is selected from the group consisting of hydrogen, --CH.sub.3, --CN and --C.tbd.CH and Y is selected from the group consisting of hydrogen, --OH, optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted, --CN, --(CH.sub.2).sub.m --OAlk, --(CH.sub.2).sub.m --S--Alk, ##STR2## m is 0,1,2,3 or 4, Alk is alkyl of 1 to 12 carbon atoms, --Si(Alk').sub.3, Alk' is optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted, --O--Ar and --(CH.sub.2).sub.m --Ar and Ar is aryl of 6 to 14 carbon atoms having excellent pesticidal activities and novel intermediates.
摘要翻译：所有可能的立体异构体形式的新型环丙烷羧酸酯及其混合物，其中X选自氢，氟，氯和溴，R选自任选不饱和的1位烷基至8个碳原子任选取代，任选取代的3至8个碳原子的任意不饱和环烷基，任选取代的6至14个碳原子的任选取代的芳基和任选取代的杂环，Z选自氢，-CH 3，-CN和 - C 3 CH 3和Y选自氢，-OH，任选取代的具有1至8个碳原子的任选不饱和烷基，-CN， - （CH 2）m -OAlk， - （CH 2）m S-Alk， > m为0,1,2,3或4，Alk为1〜12个碳原子的烷基，-Si（Alk'）3，Alk'为任选取代的1〜8个碳原子的任意不饱和烷基，-O-Ar 和 - （CH 2）m -Ar，Ar是具有优异p的6至14个碳原子的芳基杀虫活动和新颖的中间体。

8. 发明授权

US4879302A Certain oximino-cyclopropane carboxylates having insecticidal activity 失效
标题翻译：某些具有杀虫活性的肟基 - 环丙烷羧酸盐
公开(公告)号：US4879302A
公开(公告)日：1989-11-07
申请号：US114534
申请日：1987-10-29
申请人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
发明人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
IPC分类号： C07D209/49 , A01N53/00 , A01N53/02 , A23K1/16 , A61K31/35 , A61K31/351 , A61K31/40 , A61K31/403 , A61K31/4035 , A61K31/415 , A61K31/4166 , A61K31/44 , A61K31/4402 , A61K31/4418 , A61P33/10 , C07C67/00 , C07C239/00 , C07C251/36 , C07C251/38 , C07C251/40 , C07D213/64 , C07D213/647 , C07D213/68 , C07D213/70 , C07D233/72 , C07D307/42 , C07D309/38
CPC分类号： C07D213/647 , A01N53/00 , A23K20/00
摘要： All possible stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein A is selected from the group consisting of hydrogen, optionally unsaturated alkyl and haloalkyl of 1 to 18 carbon atoms, optionally substituted with aryl or a heterocyclic and optionally interrupted by --O-- or --S--, optionally unsaturated cycloalkyl of 3 to 18 carbon atoms, aryl of 6 to 14 carbon atoms and heterocyclic, B is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms optionally interrupted by --S-- or --O-- and optionally substituted with at least one member of the group consisting of halogen, --OH, alkoxy of 1 to 8 carbon atoms, --SH, thioalkoxy of 1 to 8 carbon atoms, --NO.sub.2 and --CN and R is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms and residue of an alcohol used in the synthesis of pyrethrinoid esters having pesticidal activity.
摘要翻译：式I化合物的所有可能的立体异构形式及其混合物，其中A选自氢，任选不饱和的烷基和具有1至18个碳原子的卤代烷基，任选被芳基或杂环取代，并任选地中断 3至18个碳原子的任选不饱和环烷基，6至14个碳原子的芳基和杂环基，B选自氢，1至18个碳原子的烷基，任意地被 - 任选被至少一个卤素，-OH，1-8个碳原子的烷氧基，-SH，1至8个碳原子的硫代烷氧基，-NO 2和-CN和R 选自具有1至18个碳原子的任选不饱和的烷基和用于合成具有杀虫活性的拟除虫菊酯的醇的残基。

9. 发明授权

US4849449A Novel cyclopropane carboxylates 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4849449A
公开(公告)日：1989-07-18
申请号：US939635
申请日：1986-12-09
申请人： Jean Tessier , Jean-Pierre DeMoute , Joseph Cadiergue
发明人： Jean Tessier , Jean-Pierre DeMoute , Joseph Cadiergue
IPC分类号： A01N53/00 , A01N53/02 , A23K1/16 , C07D213/64 , C07D213/647
CPC分类号： C07D213/647 , A01N53/00 , A23K20/00
摘要： Novel stereoisomers or mixtures of stereoisomers of compounds of the formula ##STR1## wherein R is the residue of an alcohol used in the pyrethrinoid field having remarkable pesticidal properties and being surprisingly stable.
摘要翻译：新颖的立体异构体或下式化合物的立体异构体的混合物其中R是拟除虫菊酯类中使用的具有显着杀虫性能并令人惊奇稳定的醇的残基。

10. 发明授权

US5329017A Vinylsulfone nor-pyrethric compounds 失效
标题翻译：乙烯基砜除虫菊酯化合物
公开(公告)号：US5329017A
公开(公告)日：1994-07-12
申请号：US51177
申请日：1993-04-22
申请人： Didier Babin , Jean-Pierre Demoute , Jean Tessier
发明人： Didier Babin , Jean-Pierre Demoute , Jean Tessier
IPC分类号： C07C69/743 , C07D327/04
CPC分类号： C07C69/743
摘要： Novel all possible stereoisomers and mixtures thereof of vinylsulfone nor-pyrethric compounds of the formula ##STR1## wherein R.sub.a is selected from the group consisting of alkyl of 1 to 18 carbon atoms, alkenyl and alkynyl of 2 to 18 carbon atoms, cycloalkyl of 3 to 18 carbon atoms, cycloalkylalkyl of 4 to 18 carbon atoms and aryl of 6 to 14 carbon atoms unsubstituted or substituted with at least one functional group, n is 0, 1 or 2, R.sub.b is selected from the group consisting of alkyl of 1 to 18 carbon atoms, alkenyl and alkynyl of 2 to 18 carbon atoms, cycloalkyl of 3 to 18 carbon atoms, cycloalkylalkyl of 4 to 18 carbon atoms and aryl of 6 to 14 carbon atoms, all unsubstituted or unsubstituted with at least one functional group or R.sub.a and R.sub.b together with the C-S-C to which they are attached form ##STR2##
摘要翻译：其中R a选自1至18个碳原子的烷基，2至18个碳原子的烯基和炔基，3个环烷基的全部可能的立体异构体及其混合物，至18个碳原子，4至18个碳原子的环烷基烷基和未被取代或被至少一个官能团取代的6至14个碳原子的芳基，n为0,1或2，Rb选自1至 2至18个碳原子的烯基和炔基，3至18个碳原子的环烷基，4至18个碳原子的环烷基烷基和6至14个碳原子的芳基，全部未取代或未取代，至少有一个官能团或Ra 和Rb与它们所连接的CSC一起形成

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