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    • 2. 发明授权
    • Manufacture of aliphatic calcium carboxylate
    • 脂肪酸钙的制造
    • US5783714A
    • 1998-07-21
    • US818412
    • 1997-03-17
    • Arthur L. McKennaOscar KnottNina M. McConnell
    • Arthur L. McKennaOscar KnottNina M. McConnell
    • C07C51/41C07C51/00
    • C07C51/412
    • A process is disclosed for manufacturing a substantially grit-free calcium salt of an aliphatic carboxylic acid having twelve to twenty-two carbon atoms comprising the steps of (1) conveying into a mixing zone at least one aliphatic carboxylic acid having twelve to twenty-two carbon atoms and a calcium hydroxide product having a maximum particle size of 22 microns, (2) applying heat as necessary, (3) mixing until the reaction has progressed to the desired end point, and (4) discharging calcium carboxylate salt from the mixing zone. The disclosed process affords a novel calcium salt of a carboxylic acid such as one comprising a calcium stearate substantially free of grit, characterized by a melting range from 131.degree. C. to 159.degree. C., an ash content in the range from 9 to 12% by weight as calcuim oxide, a free fatty acid content not exceeding 1% by weight, a water soluble salt content in the range from 0.001% to 0.1% by weight, and an apparent density in the range from 15 to 25 pounds per cubic foot. The disclosed process further affords a novel calcium salt of a carboxylic acid substantially free of grit which can be incorporated in polypropylene without excessive extrusion screen pack pressure buildup.
    • 公开了一种用于制造具有十二至二十二个碳原子的脂肪族羧酸的基本上无砂的钙盐的方法,包括以下步骤:(1)将混合区输送至少一种具有十二至二十二个 碳原子和最大粒度为22微米的氢氧化钙产物,(2)根据需要加热,(3)混合直到反应进行到所需的终点,和(4)从混合物中排出羧酸钙盐 区。 所公开的方法提供了一种新颖的羧酸钙盐,例如包含基本不含砂粒的硬脂酸钙的新型钙盐,其特征在于熔点在131℃至159℃,灰分范围为9至12 重量百分比为氧化钙,游离脂肪酸含量不超过1重量%,水溶性盐含量为0.001重量%至0.1重量%,表观密度为15至25磅/立方厘米 脚丫子。 所公开的方法进一步提供了一种基本上不含砂粒的新颖的羧酸钙盐,其可以并入聚丙烯中而不会产生过大的挤出丝网组合压力。