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1. 发明授权

US5180399A Process for dyeing keratinous fibres with oxidation bases combined with an iodide and dyeing composition employed 失效
标题翻译：用氧化碱与碘化物和染色组合物结合染色角质纤维的方法
公开(公告)号：US5180399A
公开(公告)日：1993-01-19
申请号：US717253
申请日：1991-06-18
申请人： Jean F. Grollier , Jean Cotteret , Didier Garoche
发明人： Jean F. Grollier , Jean Cotteret , Didier Garoche
IPC分类号： A61K8/20 , A61K8/41 , A61K8/49 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/20 , A61K8/411 , A61K8/415 , A61K8/492 , A61K8/4926
摘要： A process for dyeing keratinous fibers employs a dye composition containing an oxidation base selected from a paraphenylenediamine, an N,N'-diphenylalkylene diamine, a para-aminophenol, an ortho-aminophenol, an ortho-phenylenediamine or a heterocyclic oxidation base, in combination with iodide ions. The application of this dyeing composition to the keratinous fibers is preceded or followed by the application to the fibers of a composition containing hydrogen peroxide.
摘要翻译：用于染色角质纤维的方法使用含有选自对苯二胺，N，N'-二苯基亚烷基二胺，对氨基苯酚，邻氨基苯酚，邻苯二胺或杂环氧化碱的氧化碱的组合物的染料组合物与碘离子。这种染色组合物在角质纤维中的应用在含有过氧化氢的组合物的纤维之前或之后。

2. 发明授权

US4888027A Process for dyeing keratinous fibers with 5,6-dihydroxyindole in combination with an iodide and a hydrogen peroxide composition at alkaline pH 失效
标题翻译：用5,6-二羟基吲哚在碱性pH下与碘化物和过氧化氢组合物组合染色角质纤维的方法
公开(公告)号：US4888027A
公开(公告)日：1989-12-19
申请号：US177323
申请日：1988-04-04
申请人： Jean F. Grollier , Didier Garoche
发明人： Jean F. Grollier , Didier Garoche
IPC分类号： A61K8/00 , A45D19/00 , A61K8/20 , A61K8/22 , A61K8/49 , A61Q5/10 , D06P1/32 , D06P1/673 , D06P3/08
CPC分类号： D06P3/08 , A45D19/00 , A61K8/492 , A61Q5/10 , A45D2019/0066
摘要： Process for dyeing keratinous fibres, characterized in that there is applied to these fibres at least one composition (A) containing, in an appropriate medium for dyeing, 5,6-dihydroxyindole in combination with iodide ions, the application of this composition (A) being preceded or followed by the application of a composition (B) which contains, in an appropriate medium for dyeing, hydrogen peroxide at an alkaline pH of less than 12.
摘要翻译：染色角质纤维的方法，其特征在于向这些纤维施用至少一种组合物（A），该组合物（A）在与碘离子组合的适当培养基中含有5,6-二羟基吲哚，该组合物（A）的应用在施用组合物（B）之前或之后，在组合物（B）中，所述组合物（B）在碱性pH低于12的适当的培养基中含有过氧化氢。

3. 发明授权

US5180397A Process for dyeing keratinous fibres with couplers and/or "rapid" oxidation dyes combined with an iodide and dyeing composition employed 失效
标题翻译：用成色剂和/或“快速”氧化染料与所用碘化物和染色组合物组合染色角质纤维的方法
公开(公告)号：US5180397A
公开(公告)日：1993-01-19
申请号：US599113
申请日：1990-10-17
申请人： Jean F. Grollier , Jean Cotteret , Didier Garoche
发明人： Jean F. Grollier , Jean Cotteret , Didier Garoche
IPC分类号： A61K8/20 , A61K8/34 , A61K8/41 , A61K8/49 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/20 , A61K8/347 , A61K8/415
摘要： A process for dyeing keratinous fibers involves applying to the fibers a dye composition (A) containing an oxidation dye which is a mixture of a coupler and a "rapid" oxidation dye or a "rapid" oxidation dye, in combination with iodide ions. Also applied to the fibers, preceding or following the application of composition (A) is a composition (B) containing hydrogen peroxide having a pH ranging from 2 to 12.
摘要翻译：用于染色角质纤维的方法包括向染色组合物（A）施加含有作为偶联剂和“快速”氧化染料或“快速”氧化染料的混合物的氧化染料与碘离子组合的染料组合物（A）。组合物（A）的应用前后也适用于纤维，是含有pH为2〜12的过氧化氢的组合物（B）。

4. 发明授权

US5180396A Process for dyeing keratinous fibres with oxidation dyes combined with indole derivatives and dyeing composition employed 失效
标题翻译：用氧化染料与吲哚衍生物和染色组合物一起染色角质纤维的方法
公开(公告)号：US5180396A
公开(公告)日：1993-01-19
申请号：US795344
申请日：1991-11-20
申请人： Jean F. Grollier , Jean Cotteret , Didier Garoche
发明人： Jean F. Grollier , Jean Cotteret , Didier Garoche
IPC分类号： A61K8/20 , A61K8/41 , A61K8/49 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/20 , A61K8/411 , A61K8/415 , A61K8/49 , A61K8/492
摘要： Process for dyeing keratinous fibres, characterized in that at least one composition (A) containing, in a medium suitable for dyeing, at least one indole derivative and at least one oxidation dye chosen from rapid oxidation dyes and couplers in combination, either (a) with iodide ions, or (b) with hydrogen peroxide, is applied on these fibres at a pH of between 2 and 7, and preferably between 2 and 5, the application of the composition (A) being preceded or followed by the application of a composition (B) which contains, in a medium suitable for dyeing:either (a) hydrogen peroxide at a pH of between 2 and 12 and preferably between 2 and 7 when (A) contains iodide ions;or (b) iodide ions at a pH of between 3 and 11 when the composition (A) contains hydrogen peroxide.
摘要翻译：染色角质纤维的方法，其特征在于至少一种组合物（A）在适于染色的培养基中组合至少一种吲哚衍生物和至少一种选自快速氧化染料和成色剂的氧化染料的组合物，（a）用碘离子或（b）与过氧化氢一起施用于这些纤维上，pH在2至7之间，优选2至5之间，组合物（A）在施用之前或之后施用组合物（B），其在适于染色的介质中包含：（A）当（A）含有碘离子时，pH为2至12，优选2至7的过氧化氢; 或（b）当组合物（A）含有过氧化氢时，pH在3和11之间的碘离子。

5. 发明授权

US4885006A Process for dyeing keratinous fibres with indole derivatives combined with an iodide 失效
公开(公告)号：US4885006A
公开(公告)日：1989-12-05
申请号：US121890
申请日：1987-11-17
申请人： Jean F. Grollier , Didier Garoche
发明人： Jean F. Grollier , Didier Garoche
IPC分类号： A61K8/00 , A61K8/20 , A61K8/22 , A61K8/34 , A61K8/36 , A61K8/365 , A61K8/37 , A61K8/41 , A61K8/49 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/492
摘要： Process for dyeing human keratinous fibres, consisting in applying on these fibres at least least one composition (A) containing, in a cosmetically acceptable medium, one or more indole derivatives corresponding to the formula (I) ##STR1## in which: R.sub.1 denotes a hydrogen atom, a lower C.sub.1 -C.sub.6 lower akly group or a group --SiR.sub.9 R.sub.10 R.sub.11 ;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.6 lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group wherein the alkoxy moiety contains 1 to 6 carbon atoms, or a group --COOSiR.sub.9 R.sub.10 R.sub.11 ;R.sub.4 and R.sub.5, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.20 linear or branched alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O) (OR.sub.6).sub.2 or a group R.sub.6 OSO.sub.2 --, or alternatively R.sub.4 and R.sub.5, together with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group, a methylene group, a thiocarbonyl group or one of the following groups; >P(O)OR.sub.6, or >CR.sub.7 R.sub.8 ;R.sub.6 and R.sub.7 denoting a hydrogen atom or C.sub.1 -C.sub.6 lower alkyl group, R.sub.8 denoting a C.sub.1 -C.sub.6 lower alkoxy group or a mono- or di-C.sub.1 -C.sub.6 alkylamino group, R.sub.9,R.sub.10 and R.sub.11, which may be identical or different, denoting C.sub.1 -C.sub.6 linear or branched alkyl groups, and the corresponding salts of alkali metals, alkaline-earth metals and amines, at least one of the radicals R.sub.1 to R.sub.5 being other than hydrogen,in combinations:either (a) with iodide ions, or (b) with a solution of hydrogen peroxide at a pH of between 3.5 and 7, the application of the composition (A) being preceded or followed by the application of composition (B) which contains, in a cosmetically acceptable medium, either (a) hydrogen peroxide at a pH of between 2 and 7 when the composition (A) contains iodide ions, or (b) iodide ions when the composition (A) contains hydrogen peroxide.

6. 发明授权

US4808190A Process for dyeing keratinous fibres with 5,6-dihydroxy-indole and hydrogen peroxide, preceded or followed by a treatment with an iodide 失效
标题翻译：用5,6-二羟基 - 吲哚和过氧化氢染色角质纤维的方法，之前或之后用碘化物
公开(公告)号：US4808190A
公开(公告)日：1989-02-28
申请号：US4497
申请日：1987-01-20
申请人： Jean F. Grollier , Didier Garoche
发明人： Jean F. Grollier , Didier Garoche
IPC分类号： A61K8/00 , A61K8/20 , A61K8/22 , A61K8/34 , A61K8/37 , A61K8/42 , A61K8/49 , A61K8/86 , A61Q5/10 , C09B53/00 , C09B67/02 , D06P1/32 , D06P1/673 , D06P3/08 , A61K7/13
CPC分类号： D06P3/08 , A61K8/20 , A61K8/492 , A61Q5/10
摘要： The invention relates to a process for dyeing keratinous fibers characterized in that at least one composition comprising, in a medium suitable for dyeing, 5,6-dihydroxyindole in combination with hydrogen peroxide at a pH of between 2 and 7 is applied to these fibers, the application of said composition being preceded or followed by the application of a composition comprising iodide ions in a medium suitable for dyeing.
摘要翻译：本发明涉及一种染色角质纤维的方法，其特征在于至少一种组合物包含在适于染色5至2羟基吲哚与过氧化氢组合的培养基中，pH2至7之间的培养基适用于这些纤维，所述组合物的应用在包含碘离子的组合物在适于染色的介质中之前或之后。

7. 发明授权

US4804385A Process for dyeing keratinous fibres with 5,6-dihydroxy-indole combined with an iodide and dyeing composition employed 失效
标题翻译：用5,6-二羟基 - 吲哚染色角质纤维与碘化物和染色组合物结合的方法
公开(公告)号：US4804385A
公开(公告)日：1989-02-14
申请号：US4496
申请日：1987-01-20
申请人： Jean F. Grollier , Didier Garoche
发明人： Jean F. Grollier , Didier Garoche
IPC分类号： A61K8/00 , A61K8/20 , A61K8/22 , A61K8/34 , A61K8/37 , A61K8/42 , A61K8/49 , A61K8/86 , A61Q5/10 , C09B53/00 , C09B67/02 , D06P1/32 , D06P1/673 , D06P3/08 , A61K7/13
CPC分类号： D06P3/08 , A61K8/20 , A61K8/492 , A61Q5/10
摘要： The invention relates to a plural stage process for dyeing keratinous fibers wherein a composition (A) comprising, in a medium suitable for dyeing, 5,6-dihydroxyindole and iodide ions, is applied to the hair, the application of said composition (A) being preceded or followed by the application of a composition (B) comprising hydrogen peroxide.
摘要翻译：本发明涉及一种用于染色角质纤维的多级方法，其中在适合于染色5,6-二羟基吲哚和碘离子的培养基中包含施用于毛发的组合物（A），所述组合物（A）的应用，在施用包含过氧化氢的组合物（B）之前或之后。

8. 发明授权

US5112360A Processes for dyeing keratinous fibres based on 5,6 dihydroxyindole or an indole derivative and at least one rare earth salt and compositions for implementation thereof 失效
公开(公告)号：US5112360A
公开(公告)日：1992-05-12
申请号：US369344
申请日：1989-06-21
申请人： Didier Garoche , Jean F. Grollier
发明人： Didier Garoche , Jean F. Grollier
IPC分类号： A61K8/00 , A61K8/19 , A61K8/34 , A61K8/36 , A61K8/37 , A61K8/39 , A61K8/42 , A61K8/49 , A61K8/58 , A61Q5/10 , C09B9/04 , D06P3/24
CPC分类号： A61K8/19 , A61K8/492 , A61Q5/10
摘要： Process for dyeing keratinous fibres, comprising the application of:(a) a component (A) containing at least one rare earth salt in a medium suitable for dyeing, and(b) a component (b) containing, in a medium suitable for dyeing, at least one indole derivative of formula (I): ##STR1## in which: R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.4 -alkyl group, a carboxyl group or a (C.sub.1 -C.sub.4 alkoxy)carbonyl group;R.sub.4, R.sub.5, R.sub.6 and R.sub.7, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.4 alkyl, carboxyl, C.sub.1 -C.sub.4 carboxyalkyl, (C.sub.1 -C.sub.4 alkoxy) carbonyl, (C.sub.1 -C.sub.4 alkoxy)carbonyl(C.sub.1 -C.sub.4 alkyl), carbamyl, halogen, mono- or polyhydroxy(C.sub.1 -C.sub.4 alkyl) or C.sub.1 -C.sub.4 aminoalkyl radical, a group OZ in which Z denotes hydrogen or C.sub.1 -C.sub.20 linear or branched alkyl, an aryl(C.sub.1 -C.sub.4 alkyl) group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.11 R.sub.12 R.sub.13, a group --P(O)(OR.sub.8).sub.2 or a group R.sub.6 OSO.sub.2 --; it being possible for the radicals R.sub.4 and R.sub.5, or alternatively R.sub.5 and R.sub.6, or alternatively R.sub.6 and R.sub.7 to form, together with the carbon atoms to which they are attached, a ring optionally containing a carbonyl group, a thiocarbonyl group, a group >P(O)(OR.sub.8) or a group >CR.sub.9 R.sub.10 ;with the proviso that at least one of the radicals R.sub.4 to R.sub.7 denotes a group OZ or alternatively that R.sub.4 and R.sub.5, or alternatively R.sub.5 and R.sub.6, or alternatively R.sub.6 and R.sub.7 form a ring, R.sub.8 and R.sub.9 denote a hydrogen atom or a C.sub.1 -C.sub.4 lower alkyl group, R.sub.10 denotes a C.sub.1 -C.sub.4 alkoxy group or a mono- or di(C.sub.1 -C.sub.4 alkyl)amino group, and R.sub.11, R.sub.12 and R.sub.13, which may be identical or different, denote linear or branched C.sub.1 -C.sub.4 alkyl groups,and the corresponding salts of alkali metals and alkaline-earth metals, ammonium salts and amine salts, or the addition salts of inorganic or organic acids.the components (A) and (B) being applied on the fibres using a single composition, or the component (A) being applied on the fibres prior or subsequent to the application of the component (B).

9. 发明授权

US4985955A Process for dyeing keratinous fibres with couplers and/or "rapid" oxidation dyes combined with an iodide and dyeing composition employed 失效
标题翻译：用成色剂和/或“快速”氧化染料与所用碘化物和染色组合物组合染色角质纤维的方法
公开(公告)号：US4985955A
公开(公告)日：1991-01-22
申请号：US198806
申请日：1988-05-25
申请人： Jean F. Grollier , Jean Cotteret , Didier Garoche
发明人： Jean F. Grollier , Jean Cotteret , Didier Garoche
IPC分类号： A61K8/00 , A61K8/20 , A61K8/22 , A61K8/33 , A61K8/34 , A61K8/36 , A61K8/41 , A61K8/49 , A61Q5/10 , C09B53/00 , C09B53/02 , D06P1/32 , D06P3/04 , D06P3/14
CPC分类号： A61Q5/10 , A61K8/20 , A61K8/347 , A61K8/411 , A61K8/415
摘要： The invention relates to process, composition, and kit for the oxidative dyeing of keratinous fibers with couplers and/or rapid oxidation dyes combined with iodide ions.
摘要翻译：本发明涉及用耦合剂和/或与碘离子结合的快速氧化染料对角质纤维进行氧化染色的方法，组合物和试剂盒。

10. 发明授权

US5567701A Alkylpolyglycoside and pyrimidine derivative based composition for inducing and stimulating hair growth and/or reducing hair loss 失效
标题翻译：用于诱导和刺激毛发生长和/或减少脱发的基于烷基多糖苷和嘧啶衍生物的组合物
公开(公告)号：US5567701A
公开(公告)日：1996-10-22
申请号：US214668
申请日：1994-03-18
申请人： Jean F. Grollier
发明人： Jean F. Grollier
IPC分类号： C07D239/22 , A61K8/00 , A61K8/49 , A61K8/60 , A61K8/73 , A61Q5/00 , A61Q5/02 , A61Q7/00 , A61K31/505 , A61K7/06 , A61K31/70
CPC分类号： A61K8/4953 , A61K8/604 , A61Q7/00 , Y10S514/88 , Y10S514/881 , Y10S514/888
摘要： A composition for inducing and stimulating hair growth and/or reducing hair loss comprises at least one alkylpolyglycoside and at least one compound having formula (I) in a physiologically acceptable medium. ##STR1## In compound (I) , R.sub.1 represents the group ##STR2## where in R.sub.3 and R.sub.4 may be selected from hydrogen, alkyl, alkenyl or cycloalkyl. R.sub.3 and R.sub.4 may also form a heterocycle with the nitrogen atom to which they are bonded. The heterocycle may be an aziridinyl, azetidinyl, pyrrolidinyl, piperidinyl, hexahydroazepinyl, heptamethyleneimine, octamethyleneimine, morpholine or 4-low alkylpiperazidinyl group. These heterocycles may be substituted at the carbon atoms by one to three alkyl, hydroxy or alkoxy groups. R.sub.2 is selected from hydrogen, alkyl, alkenyl, alkylalkoxy, cycloalkyl, aryl, alkylaryl, arylalkyl, alkylarylalkyl, alkoxyarylalkyl and/or haloarylalkyl. The physiologically acceptable acid addition salts of the compound may also be used.
摘要翻译：用于诱导和刺激毛发生长和/或减少脱发的组合物包含至少一种烷基多糖苷和至少一种在生理学上可接受的培养基中具有式（I）的化合物。（I）在化合物（I）中，R 1表示基团，其中R 3和R 4可以选自氢，烷基，链烯基或环烷基。 R3和R4也可以与它们所键合的氮原子形成杂环。杂环可以是氮丙啶基，氮杂环丁烷基，吡咯烷基，哌啶基，六氢氮杂基，七亚甲基亚胺，八亚甲基亚胺，吗啉或4-低级烷基哌嗪基。这些杂环可以在碳原子上被一至三个烷基，羟基或烷氧基取代。 R2选自氢，烷基，烯基，烷基烷氧基，环烷基，芳基，烷基芳基，芳基烷基，烷基芳基烷基，烷氧基芳基烷基和/或卤代芳烷基。也可以使用该化合物的生理上可接受的酸加成盐。

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