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1. 发明授权

US4892976A Process for the preparation of aldehydes 失效
标题翻译：醛的制备方法
公开(公告)号：US4892976A
公开(公告)日：1990-01-09
申请号：US219926
申请日：1988-07-15
申请人： Jean Cordier , Bernard Dussart , Francis Petit , Yves Castanet , Serge Melloul , Andre Mortreux
发明人： Jean Cordier , Bernard Dussart , Francis Petit , Yves Castanet , Serge Melloul , Andre Mortreux
IPC分类号： B01J27/08 , B01J27/128 , B01J31/28 , C07B61/00 , C07C45/00 , C07C45/49 , C07C47/02 , C07C47/06 , C07C67/00
CPC分类号： C07C45/49
摘要： The process for the preparation of an aldehyde of formula R--CHO in which R is an alkyl group of C.sub.1 -C.sub.7 comprises according to the invention the reaction on an alkyl formate of formula H--COOR in which R has the meaning given above, of a gas constituted mainly by CO, in the presence of(a) a catalyst based on a metal chosen from among Rh, Ru, Ir, mixtures of them or a mixture of Rh and/or Ru and/or Ir with Co, Ni or Fe,(b) a promoter chosen from among iodides and mixtures of covalent compounds of iodine and a phosphine or a tertiary amine,(c) a solvent consisting of a cyclic N-alkyl amide.
摘要翻译：制备其中R为C 1 -C 7烷基的式R-CHO的醛的方法包括根据本发明的式H-COOR烷基甲酸酯的反应，其中R具有上述含义，在（a）基于选自Rh，Ru，Ir的金属的催化剂，它们的混合物或Rh和/或Ru和/或Ir与Co，Ni或其混合物的混合物的存在下，主要由CO构成的气体 Fe，（b）选自碘化物的促进剂和碘和膦或叔胺的共价化合物的混合物，（c）由环状N-烷基酰胺组成的溶剂。

2. 发明授权

US5214205A Process for the preparation of acetic anhydride from methyl formate 失效
标题翻译：从甲基丙烯酸制备乙酸酐的方法
公开(公告)号：US5214205A
公开(公告)日：1993-05-25
申请号：US868186
申请日：1992-04-14
申请人： Yves Castanet , Bruno Seuillet , Andre Mortreux , Francis Petit
发明人： Yves Castanet , Bruno Seuillet , Andre Mortreux , Francis Petit
IPC分类号： B01J31/20 , B01J31/24 , C07B61/00 , C07C51/12 , C07C51/56 , C07C53/12
CPC分类号： C07C53/12 , C07C51/56
摘要： The invention relates to a process for the preparation of acetic anhydride, characterized in that a gas containing essentially CO, at a pressure of at least 1 MPa, is reacted with methyl formate in the presence ofa) a rhodium-based catalyst,b) two iodine-containing promoters of different kind, successively ionic and covalent, andc) an N-substituted cyclic amide as solvent.
摘要翻译：本发明涉及一种制备乙酸酐的方法，其特征在于在a）铑基催化剂存在下，使基本上含有至少1MPa压力的CO的气体与甲酸甲酯反应，b）两种不同种类的含碘促进剂，连续离子和共价，和c）N-取代的环状酰胺作为溶剂。

3. 发明授权

US5194676A Catalyst and process for the synthesis of saturated carboxylic esters 失效
标题翻译：用于饱和羧酸酯合成的催化剂和方法
公开(公告)号：US5194676A
公开(公告)日：1993-03-16
申请号：US674745
申请日：1991-03-26
申请人： Yves Castanet , Christophe Legrand , Andre Mortreux , Francis Petit
发明人： Yves Castanet , Christophe Legrand , Andre Mortreux , Francis Petit
IPC分类号： B01J27/13 , B01J31/02 , C07B61/00 , C07C67/303 , C07C67/38 , C07C69/24
CPC分类号： C07C69/24 , C07C67/38
摘要： Saturated carboxylic esters are produced from alkyl formate and an olefin, without the presence of substantial amounts of carbon monoxide, at a temperature of 120.degree. to 280.degree. C., under a pressure of 1 to 3,000 bars, in the presence of a catalyst based on ruthenium coordinated by ligands selected from carbon monoxide, halogen atoms and amines, and in the presence of an amide as a solvent. The catalyst is selected from catalysts consisting essentially of RuCl.sub.3.3H.sub.2 O; catalysts consisting essentially of the combination of an RuCl.sub.3.3H.sub.2 O together with at least one stabilizer selected from iodine, covalent iodides and quaternary ammonium halides; catalysts comprising Ru.sub.3 (CO).sub.12 together with at least one stabilizer such as is mentioned above; and catalysts selected from RuI.sub.3, [RuCl.sub.2 (CO).sub.3 ].sub.2, Ru(NH.sub.3).sub.6 Cl.sub.3 and [Ru(NH.sub.3).sub.5 Cl]Cl.sub.2, comprising, where appropriate, in addition, at least one stabilizer such as is mentioned above.
摘要翻译：在120至280℃的温度下，在1至3,000巴的压力下，在催化剂基的存在下，将饱和羧酸酯由甲酸烷基酯和烯烃生产，而不存在大量的一氧化碳在由选自一氧化碳，卤素原子和胺的配体和在作为溶剂的酰胺存在下配位的钌上。催化剂选自基本上由RuCl 3·3H 2 O组成的催化剂; 基本上由RuCl 3·3H 2 O与至少一种选自碘，共价碘化物和季铵卤化物的稳定剂的组合组成的催化剂; 包含Ru 3（CO）12的催化剂以及如上所述的至少一种稳定剂; 以及选自RuI 3，[RuCl 2（CO）3] 2，Ru（NH 3）6 Cl 3和[Ru（NH 3）5 Cl] Cl 2的催化剂，在适当的情况下还包括至少一种如上所述的稳定剂。

4. 发明授权

US5574116A Process for the preparation of a catalyst for the polymerization of olefins 失效
标题翻译：制备烯烃聚合催化剂的方法
公开(公告)号：US5574116A
公开(公告)日：1996-11-12
申请号：US214691
申请日：1994-03-18
申请人： Karel Bujadoux , Jean-Michel Brusson , Francis Petit , Andre Mortreux
发明人： Karel Bujadoux , Jean-Michel Brusson , Francis Petit , Andre Mortreux
IPC分类号： C08F4/654 , C08F10/00
CPC分类号： C08F10/00
摘要： A process is disclosed for the polymerization of olefins, using (i) a catalyst and (ii) an organometallic activator from Groups I, II or III of the Periodic Table at temperatures between 20.degree. and 250.degree. C., and pressure up to 200 bar, in solution, or in suspension in an inert liquid hydrocarbon, at temperatures between 160.degree. and 350.degree. C., under pressures of between 400 and 3000 bar, in a continuous manner in a reactor where the mean residence time of the catalyst is between 1 and 150 seconds. The catalyst comprises at least one titanium compound, at least one halogen-containing organoaluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihaloalkane. The titanium compound is essentially a titanium (III) compound, the total content of titanium (II) and titanium (IV) being less than or equal to 15% of the total content of titanium. The catalyst is obtained by a process comprising, in a first step, the reduction of a titanium (IV) compound in an .alpha.,.omega.-dihaloalkane by means of a molar excess of at least one halogen-containing organoaluminum compound, in the absence of an ether, and, in a second step, the addition to the reaction mixture of a compound which forms a magnesium halide in situ without supplementary reduction of the titanium compound obtained in the first step. Molar ratios of the .alpha.,.omega.-dihaloalkane, the titanium compound, halogen-containing organoaluminum, and the compound which forms a magnesium halide in situ are also described.
摘要翻译：公开了一种用于烯烃聚合的方法，其使用（i）催化剂和（ii）在20℃至250℃之间的元素周期表第I，II或III族的有机金属活化剂，压力高达200 在惰性液体烃中，160-150℃的温度下，在400-3000巴的压力下，在反应器中连续地在惰性液体烃中悬浮或悬浮，其中催化剂的平均停留时间为 1到150秒之间。催化剂包含至少一种钛化合物，至少一种含卤素的有机铝化合物和至少一种α，ω-二卤代烷烃中的悬浮液中的至少一种无机镁化合物。钛化合物基本上是钛（III）化合物，钛（II）和钛（IV）的总含量小于或等于钛总含量的15％。该催化剂是通过一种方法获得的，该方法包括在第一步骤中，通过摩尔过量的至少一种含卤素的有机铝化合物在α，ω-二卤代烷烃中还原钛（IV）化合物，醚，并且在第二步中，在没有补充还原第一步中获得的钛化合物的情况下向原位形成镁卤化物的化合物的反应混合物加入。还描述了α，ω-二卤代烷烃，钛化合物，含卤素的有机铝和原位形成卤化镁的化合物的摩尔比。

5. 发明授权

US5068014A Catalytic composition for the polymerization of olefins and its process of preparation 失效
标题翻译：用于烯烃聚合的催化组合物及其制备方法
公开(公告)号：US5068014A
公开(公告)日：1991-11-26
申请号：US369229
申请日：1989-06-22
申请人： Jean M. Brusson , Karel Bujadoux , Francis Petit , Jean M. Fuchs , Andre Mortreux
发明人： Jean M. Brusson , Karel Bujadoux , Francis Petit , Jean M. Fuchs , Andre Mortreux
IPC分类号： C08F4/60 , C08F4/62 , C08F4/642 , C08F4/655 , C08F10/00
CPC分类号： C08F10/00
摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.
摘要翻译：制备烯烃聚合催化组合物的方法。在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。钛化合物基本上是钛（III）化合物。钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。

6. 发明授权

US4877908A Chiral phosphorus compounds, a process for their manufacture and their application to the catalysis of enantioselective synthesis reactions 失效
公开(公告)号：US4877908A
公开(公告)日：1989-10-31
申请号：US107919
申请日：1987-10-13
申请人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono
发明人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono
IPC分类号： B01J31/18 , B01J31/00 , B01J31/24 , C07B31/00 , C07B53/00 , C07B61/00 , C07C1/00 , C07C2/32 , C07C2/42 , C07C2/46 , C07C2/52 , C07C11/02 , C07C13/20 , C07C29/136 , C07C29/88 , C07C33/22 , C07C45/49 , C07C45/50 , C07C67/00 , C07C231/00 , C07C231/12 , C07C231/20 , C07C233/47 , C07F7/18 , C07F9/46 , C07F9/50 , C07F9/53 , C07F9/572 , C07F15/00
CPC分类号： C07F15/0073 , C07C2/465 , C07C2/52 , C07C45/505 , C07F7/188 , C07F9/46 , C07F9/572 , C07C2101/16 , C07C2531/22
摘要： Chiral phosphorus-containing ligands comprising at least one amine radical and at least one dihydrocarbylphosphinoxy radical of the formula W=OP (R).sub.2, in which R is a hydrocarbon radical selected from the group consisting of alkyl, aryl, and cycloalkyl radicals, wherein the ligand is selected from the group consisting of:those of the formula ##STR1## those of the formula ##STR2## those of the formula ##STR3## those of the formula ##STR4## in which formulae: R.sub.1 and R.sub.2 are selected from the group consisting of a hydrogen atom and hydrocarbon radicals;R.sub.3 and R.sub.4, which must be different from one another, are selected from the group consisting of a hydrogen atom and hydrocarbon radicals that may or may not carry at least one functional group selected from the group consisting of the alcohol, thiol, thioether, amine, imine, acid, ester, amide, and ether functional groups; andR.sub.5 and R.sub.6 are selected from the group consisting of hydrogen atoms and hydrocarbon radicals that may or may not contain functional groups.A process for their manufacture comprises reacting an optically active amino alcohol, in a hydrocarbon solvent at a temperature between -50.degree. and 80.degree. C. and under an inert gas atmosphere, with at least one compound of the formula P(R).sub.2 Y in which Y is chosen from among the halogen atoms and amine radicals, the compound being present in a molar ratio, relative to the amino alcohol, greater than or equal to the number of P(R).sub.2 groups to be introduced into the chiral molecule.The chiral phosphorous-containing ligands are used by reacting at least one organic compound that does not possess a center of asymmetry with (A), on the one hand, at least one transition metal complex of formula MZq in which M is a metal in group VIII of the Periodic Classification, q is the coordination number of the metal M, and Z is an atom or molecule capable of complexing the metal M and (B), on the other hand, at least one ligand L.

7. 发明授权

US4593140A Process for dimerizing conjugated dienes 失效
标题翻译：二聚共轭二烯的方法
公开(公告)号：US4593140A
公开(公告)日：1986-06-03
申请号：US732544
申请日：1985-05-10
申请人： Andre Mortreux , Francis Petit , Philippe Denis , Gerard Buono , Gilbert Peiffer
发明人： Andre Mortreux , Francis Petit , Philippe Denis , Gerard Buono , Gilbert Peiffer
IPC分类号： C07C2/40 , C07C2/46 , C07C2/52 , C07C2/02
CPC分类号： C07C2/52 , C07C2/403 , C07C2/406 , C07C2/465 , C07C2531/22 , C07C2531/24
摘要： The process according to the invention consists in dimerizing a conjugated diene in the presence of a catalyst obtained by bringing together (A) at least one nickel complex of formula NiZ.sub.q in which q is the coordination number of the nickel and Z is at least one ligand capable of complexing nickel and (B) at least one phosphorus-containing ligand of general formula ##STR1## in which: R.sub.1 is chosen from a hydrogen atom and hydrocarbon radicals,R.sub.2 and R.sub.3, which may be identical or different, are chosen from a hydrogen atom and hydrocarbon radicals optionally bearing at least one group chosen from alcohol, thiol, thioether, amine, imine, acid, ester, amide and ether groups, andm is greater than or equal to 1.
摘要翻译：根据本发明的方法包括在通过将（A）至少一种式NiZq的镍络合物（其中q为镍的配位数，Z为至少一个配体）的催化剂存在下将共轭二烯二聚化能够络合镍和（B）至少一种通式为“IMAGE”的含磷配体，其中：R 1选自氢原子和烃基，R 2和R 3可以相同或不同，选自氢原子和烃基任选具有至少一个选自醇，硫醇，硫醚，胺，亚胺，酸，酯，酰胺和醚基团的基团，m大于或等于1。

8. 发明授权

US5356848A Catalytic composition for the polymerization of olefins and its process of preparation 失效
标题翻译：用于烯烃聚合的催化组合物及其制备方法
公开(公告)号：US5356848A
公开(公告)日：1994-10-18
申请号：US117319
申请日：1993-09-07
申请人： Jean M. Brusson , Karel Bujadoux , Francis Petit , Jean M. Fuchs , Andre Mortreux
发明人： Jean M. Brusson , Karel Bujadoux , Francis Petit , Jean M. Fuchs , Andre Mortreux
IPC分类号： C08F4/60 , C08F4/62 , C08F4/642 , C08F4/655 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00
摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.
摘要翻译：制备烯烃聚合催化组合物的方法。在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。钛化合物基本上是钛（III）化合物。钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。

9. 发明授权

US5210202A Chiral phosphorous compounds, a process for their manufacture and their application to the catalysis of enantioselective synthesis reactions 失效
标题翻译：手性磷化合物，其制备方法及其在催化对映选择性合成反应中的应用
公开(公告)号：US5210202A
公开(公告)日：1993-05-11
申请号：US811673
申请日：1991-12-23
申请人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
发明人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
IPC分类号： B01J31/18 , B01J31/00 , B01J31/24 , C07B31/00 , C07B53/00 , C07B61/00 , C07C1/00 , C07C2/32 , C07C2/42 , C07C2/46 , C07C2/52 , C07C11/02 , C07C13/20 , C07C29/136 , C07C29/88 , C07C33/22 , C07C45/49 , C07C45/50 , C07C67/00 , C07C231/00 , C07C231/12 , C07C231/20 , C07C233/47 , C07F7/18 , C07F9/46 , C07F9/50 , C07F9/53 , C07F9/572 , C07F15/00
CPC分类号： C07F15/0073 , C07C2/465 , C07C2/52 , C07C45/505 , C07F7/188 , C07F9/46 , C07F9/572 , C07C2101/16 , C07C2531/22
摘要： Chiral phosphorus-containing ligands comprising at least one amine radical and at least one dihydrocarbylphosphinoxy radical of the formula W=OP (R).sub.2, in which R is a hydrocarbon radical selected from the group consisting of alkyl, aryl, and cycloalkyl radicals, wherein the ligand is selected from the group consisting of:those of the formula ##STR1## those of the forumula ##STR2## those of the formula ##STR3## those of the formula ##STR4##
摘要翻译：包含至少一个胺基团和至少一个式W = OP（R）2的二烃基次膦基的手性含磷配体，其中R是选自烷基，芳基和环烷基的烃基，其中该配体选自：式（I）的化合物（I）的化合物的组合（II）的那些式

10. 发明授权

US5099077A Chiral phosphorus compounds, a process for their manufacture and their application to the catalysis of enantioselective synthesis reactions 失效
标题翻译： CHIRAL PHOSPHORUS化合物，其制备方法及其应用于催化合成反应的应用
公开(公告)号：US5099077A
公开(公告)日：1992-03-24
申请号：US398539
申请日：1989-10-11
申请人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
发明人： Michele Petit , Andre Mortreux , Francis Petit , Gerard Buono , Gilbert Peiffer
IPC分类号： B01J31/18 , B01J31/00 , B01J31/24 , C07B31/00 , C07B53/00 , C07B61/00 , C07C1/00 , C07C2/32 , C07C2/42 , C07C2/46 , C07C2/52 , C07C11/02 , C07C13/20 , C07C29/136 , C07C29/88 , C07C33/22 , C07C45/49 , C07C45/50 , C07C67/00 , C07C231/00 , C07C231/12 , C07C231/20 , C07C233/47 , C07F7/18 , C07F9/46 , C07F9/50 , C07F9/53 , C07F9/572 , C07F15/00
CPC分类号： C07F15/0073 , C07C2/465 , C07C2/52 , C07C45/505 , C07F7/188 , C07F9/46 , C07F9/572 , C07C2101/16 , C07C2531/22
摘要： A method of using a chiral phosphorus-containing ligands comprising at least one amine radical and at least one dihydrocarbylphosphioxy radical of the formula W=OP (R).sub.2 ; from the group consisting of:those of the formula ##STR1## those of the formula ##STR2## those of the formula ##STR3## those of the formula ##STR4## in a hydrogenation reaction for the synthesis of optically active organic compounds comprising reacting at least one organic compound that does not possess a center of asymmetry with (A), on the one hand, at least one transition metal complex of the formula MZq in which M is a metal in group VIII of the Periodic Classification, q is the coordination number of the metal M, and Z is an atom or molecule capable of complexing the metal M and (B), on the other hand, at least one ligand L.

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