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    • 1. 发明授权
    • Process for preparing synthetic clay minerals
    • 制备合成粘土矿物的方法
    • US06565643B2
    • 2003-05-20
    • US09747284
    • 2000-12-21
    • Jan NiemanStephan Janbroers
    • Jan NiemanStephan Janbroers
    • C04B1404
    • B01J21/16B01J35/10C01B33/40
    • The invention pertains to a process for preparing a synthetic clay mineral which comprises silicon, aluminum, and at least one octahedron ion, which clay mineral has a total content of sodium and potassium of less than 0.5 wt. %, comprising the steps of a) providing a silica-alumina with a total content of sodium and potassium of less than 2.0 wt. % b) combining the silica-alumina with an octahedron ion source in such a manner that less than 0.1 mole of the total of sodium or potassium is added per mole of octahedron ion, c) if necessary, adjusting the pH to a value of at least 7, with less than 0.1 mole of the total of sodium and potassium being added per mole of octahedron ion during the pH adjustment, d) ageing the precipitate formed in c) at a temperature of 0-350° C. in an aqueous environment; e) optionally isolating the resulting material, optionally followed by washing. The invention makes it possible to prepare a saponite with a low content of sodium and potassium without an ion-exchange on the final material being necessary.
    • 本发明涉及制备包含硅,铝和至少一种八面体离子的合成粘土矿物的方法,该粘土矿物的钠和钾的总含量小于0.5wt。 %,包括以下步骤:a)提供总钠含量低于2.0重量%的二氧化硅 - 氧化铝。 b)将二氧化硅 - 氧化铝与八面体离子源结合,使得每摩尔八面体离子加入小于0.1摩尔的钠或钾的总量,c)如果需要,将pH调节至 至少7,在pH调节期间,每摩尔八面体离子添加少于0.1摩尔的钠和钾,d)在水溶液中在0-350℃的温度下老化c)中形成的沉淀物 ; e)任选地分离所得材料,任选地随后进行洗涤。本发明使得可以在最终材料上制备不含离子交换的钠和钾含量低的皂石。
    • 2. 发明授权
    • Cogel containing oxidic compounds of tetravalent, trivalent, and divalent metallic elements
    • Cogel含有四价,三价和二价金属元素的氧化物
    • US06537442B1
    • 2003-03-25
    • US09720852
    • 2001-02-20
    • Jan NiemanStephan Janbroers
    • Jan NiemanStephan Janbroers
    • C10G4702
    • B01J37/036
    • The invention pertains to a cogel comprising oxidic compounds of one or more trivalent metallic elements selected from the group of aluminum, borium, gallium, chromium, iron, cobalt, manganese, vanadium, molybdenum, tungsten, indium, rhodium, scandium, or mixtures thereof, oxidic compounds of one or more tetravalent metallic elements selected from the group of silicon, titanium, germanium, or mixtures thereof and oxidic compounds of one or more divalent metallic elements with at least one divalent metallic element not selected from Group VIII non-noble metallic elements, wherein a) the cogel is essentially X-ray amorphous apart from saponite, if present; b) the saponite content CA of the cogel is less than 60%; c) the cogel has a surface area of at least 400 m2/g; d) the cogel has a cation-exchange capacity of at least 0.5 wt %; and e) the total of sodium and potassium contained in the cogel amounts to less than 0.5 wt %, based on the total weight of the cogel. The invention further relates to a process for preparing said cogel as well as to catalysts comprising these cogels as cracking component, a process for preparing said catalysts, and the use of these catalysts for hydroprocessing applications.
    • 本发明涉及包含选自铝,硼,镓,铬,铁,钴,锰,钒,钼,钨,铟,铑,钪或其混合物中的一种或多种三价金属元素的氧化物的共凝胶 选自硅,钛,锗或其混合物的一种或多种四价金属元素的氧化化合物和一种或多种二价金属元素的氧化化合物与至少一种未选自VIII族非贵金属的二价金属元素 元素,其中a)如果存在,共聚胶基本上是除皂石外的X射线无定形的; b)共聚胶的皂石含量CA小于60%; c)共凝胶的表面积至少为400m 2 / g; d)共聚物具有至少0.5重量%的阳离子交换容量; 基于共聚胶的总重量,共聚胶中所含的钠和钾的总量小于0.5重量%。 本发明还涉及一种制备所述共聚物的方法以及包含这些凝结剂作为裂化组分的催化剂,制备所述催化剂的方法以及这些催化剂用于加氢处理应用的方法。