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    • 1. 发明申请
    • Self-crosslinking polyurethane dispersions and a process for their preparation
    • 自交联聚氨酯分散体及其制备方法
    • US20070004856A1
    • 2007-01-04
    • US11475691
    • 2006-06-27
    • Jan MazanekDorota Greszta-FranzSebastian DorrJurgen MeixnerReinhard HalpaapHelmut MullerOlaf FleckHeino Muller
    • Jan MazanekDorota Greszta-FranzSebastian DorrJurgen MeixnerReinhard HalpaapHelmut MullerOlaf FleckHeino Muller
    • C08G18/08
    • C08G18/8064C08G18/0823C08G18/4219C08G18/8048C08G18/807C08G18/8077C09D175/06
    • The present invention relates to a process for preparing self-crosslinking polyurethane dispersions by I) reacting a1) polyisocyanates with a2) at least one hydroxyl component having an average OH functionality of ≧2 and a number average molecular weight of 62 to 2500 g/mol, wherein the hydroxyl component contains at least one acid-functional compound containing at least one isocyanate-reactive group, to form an NCO-functional and optionally OH-functional prepolymer, II) then reacting the NCO-functional and optionally OH-functional prepolymer with a3) a hydroxyl component having an average OH functionality of >1 and a4) optionally another polyisocyanate component, which may be the same as or different from a1), to form an OH-functional and NCO-free polyurethane, III) adding a blocked polyisocyanate either before, during or after the reaction of steps I) and II), or forming a blocked polyisocyanate in situ from a polyisocyanate and a blocking agent after the reaction of step II) has taken place, IV) neutralizing the acid groups of the resulting composition by adding a5) a neutralizing agent, and V) dispersing the resulting composition in water. The present invention also relates to the dispersions prepared by the present invention and to their use in coating, adhesive and sealant compositions.
    • 本发明涉及一种制备自交联聚氨酯分散体的方法,其方法是使a1)多异氰酸酯与a2)至少一种平均OH官能度> = 2,数均分子量为62〜2500g / mol,其中所述羟基组分含有至少一种含有至少一个异氰酸酯反应性基团的酸官能化合物,以形成NCO-官能和任选的OH-官能预聚物,II)然后使所述NCO-官能和任选的OH-官能预聚物 其中a3)具有平均OH官能度> 1的羟基组分和a4)任选地可以与a1)相同或不同的另一种多异氰酸酯组分,以形成OH-官能和无NCO的聚氨酯,III)加入 在步骤I)和II)的反应之前,期间或之后封闭的多异氰酸酯,或在步骤II)的反应之后由多异氰酸酯和封闭剂原位形成封端多异氰酸酯具有ta 呃地方,IV)通过添加a)中和剂中和所得组合物的酸基,和V)将得到的组合物分散在水中。 本发明还涉及由本发明制备的分散体及其在涂料,粘合剂和密封剂组合物中的用途。
    • 3. 发明申请
    • Self-crosslinking polyurethane dispersions
    • 自交联聚氨酯分散体
    • US20050075470A1
    • 2005-04-07
    • US10953386
    • 2004-09-29
    • Jan MazanekJurgen MeixnerOlaf FleckHeino Muller
    • Jan MazanekJurgen MeixnerOlaf FleckHeino Muller
    • C08G18/08C08G18/12C08G18/40C08G18/76C08G18/00
    • C08G18/12C08G18/0823C08G18/4018C08G18/76C08G18/2805
    • A process for preparing self-crosslinking polyurethane polymers including i) reacting an aromatic isocyanate component (A) or a mixture of aromatic, aliphatic and/or cycloaliphatic isocyanate component having an isocyanate group functionality of greater than or equal to 2 with an at least difunctional polyol component (B1) with an average molecular weight of from 62 to 2500, which includes at least one acid-functional compound (C), to give a prepolymer containing isocyanate groups or containing hydroxyl groups, ii) adding one or more polyol components (B2) having an OH functionality of greater than or equal to 1, and optionally, an isocyanate component (A′), which may be identical to or different from (A), iii) mixing the resulting NCO-functional product with a blocking agent (D), and iv) adding a polyol component (B3). Self-crosslinking polyurethane polymers prepared as described above can be used in paint, varnish or adhesive compositions.
    • 一种制备自交联聚氨酯聚合物的方法,其包括:使异氰酸酯组分(A)或具有大于或等于2的异氰酸酯基官能度的芳族,脂族和/或脂环族异氰酸酯组分的混合物与至少二官能 平均分子量为62〜2500的多元醇成分(B1),其包含至少一种酸官能化合物(C),得到含异氰酸酯基或含羟基的预聚物,ii)添加一种或多种多元醇成分( B2),以及任选地,可以与(A)相同或不同的异氰酸酯组分(A'),iii)将所得的NCO-官能产物与封闭剂 (D),和iv)添加多元醇成分(B3)。 如上所述制备的自交联聚氨酯聚合物可用于油漆,清漆或粘合剂组合物中。