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1. 发明申请

US20050171322A1 Process for the production of copolycarbonates with reduced color 有权
标题翻译：用于生产具有降低颜色的共聚碳酸酯的方法
公开(公告)号：US20050171322A1
公开(公告)日：2005-08-04
申请号：US10768575
申请日：2004-01-29
申请人： Jan Kamps , Jan Lens
发明人： Jan Kamps , Jan Lens
IPC分类号： C08G64/30 , C08G64/00
CPC分类号： C08G64/307
摘要： A method is provided for reducing the color generated during production of copolycarbonate that includes quinone-type residues. The method includes the steps preparing a reaction mixture containing precursors of monomer residues, selecting a catalyst introduction strategy and adding catalysts according to the strategy. The strategy is sufficient to result in a product copolycarbonate with improved color. The method further includes the steps of introducing the reaction mixture to a series of process units and allowing the reaction mixture to polymerize thereby forming a copolycarbonate. The resulting copolycarbonate has improved color as compared to a copolycarbonate formed in a process without the steps of selecting a catalyst introduction strategy and introducing catalysts according to the selected strategy.
摘要翻译：提供了一种减少在包括醌型残留物的共聚碳酸酯生产期间产生的颜色的方法。该方法包括制备含有单体残余物的反应混合物的步骤，选择催化剂引入策略并根据该策略加入催化剂。该策略足以产生具有改进颜色的产品共聚碳酸酯。该方法还包括将反应混合物引入一系列处理单元并使反应混合物聚合从而形成共聚碳酸酯的步骤。所得共聚碳酸酯与在不进行选择催化剂引入策略和引入催化剂的步骤的步骤中形成的方法相比，具有改进的颜色。

2. 发明申请

US20050171323A1 Process for the production of copolycarbonates with reduced color 失效
标题翻译：用于生产具有降低颜色的共聚碳酸酯的方法
公开(公告)号：US20050171323A1
公开(公告)日：2005-08-04
申请号：US10925833
申请日：2004-08-24
申请人： Jan Kamps , Jan Lens
发明人： Jan Kamps , Jan Lens
IPC分类号： C08G64/30 , C08G64/00
CPC分类号： C08G64/307
摘要： A method is provided for reducing the color generated during production of copolycarbonate that includes quinone-type residues. The method includes the steps of mixing the precursors of monomer residues, a carbonate source and a polymerization catalyst into a reaction mixture. The method further includes the steps of introducing an antioxidant such as a hydroxycarboxylic acid to the reaction mixture in an amount sufficient to reduce color formation and introducing the reaction mixture to a series of process units wherein the reaction mixture polymerizes. The resulting copolycarbonate has improved color as compared to a copolycarbonate formed in a process without the step of introducing an antioxidant to the melt polymerization process.
摘要翻译：提供了一种减少在包括醌型残留物的共聚碳酸酯生产期间产生的颜色的方法。该方法包括将单体残基前体，碳酸酯源和聚合催化剂混合到反应混合物中的步骤。该方法还包括以下步骤：将足够减少颜色形成的量的羟基羧酸的抗氧化剂引入反应混合物中，并将反应混合物引入反应混合物聚合的一系列处理单元。所得共聚碳酸酯与在不进行熔融聚合反应的抗氧化剂步骤的方法中形成的共聚碳酸酯相比具有改善的颜色。

3. 发明申请

US20050261460A1 Method of polycarbonate preparation 有权
公开(公告)号：US20050261460A1
公开(公告)日：2005-11-24
申请号：US11133827
申请日：2005-05-19
申请人： James Cella , Jan Kamps , Jan Lens , Kathryn Longley , Patrick McCloskey , Narayan Ramesh , Warren Reilly , Paul Smigelski , Marc Wisnudel
发明人： James Cella , Jan Kamps , Jan Lens , Kathryn Longley , Patrick McCloskey , Narayan Ramesh , Warren Reilly , Paul Smigelski , Marc Wisnudel
IPC分类号： C08G63/64 , C08G64/00 , C08G64/04 , C08G64/14 , C08G64/30 , C08L23/00 , C08L67/00 , C08L69/00
CPC分类号： C08G63/64 , C08G64/04 , C08G64/14 , C08G64/307 , C08L23/00 , C08L67/00 , C08L69/00 , C08L69/005 , C08L2666/18 , C08L2666/06
摘要： Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4′-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.

4. 发明申请

US20070100156A1 POLYCYCLIC DIHYDROXY COMPOUNDS AND METHODS FOR PREPARATION 有权
标题翻译：多环二羟基化合物及其制备方法
公开(公告)号：US20070100156A1
公开(公告)日：2007-05-03
申请号：US11261720
申请日：2005-10-28
申请人： Jan Kamps , Jan-Pleun Lens , A.S. Radhakrishna , T. Raj , Ravindra Singh
发明人： Jan Kamps , Jan-Pleun Lens , A.S. Radhakrishna , T. Raj , Ravindra Singh
IPC分类号： C07C69/76
CPC分类号： C07C45/69 , C07C45/74 , C07C67/343 , C07C67/347 , C07C69/757 , C07C2601/14 , C07C49/223
摘要： A dihydroxy aromatic compound having a Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4.
摘要翻译：具有式（I）的二羟基芳族化合物，其中R 1选自氰基官能团，硝基官能团，具有1至10个碳的脂族官能团，具有2个具有4至10个碳的脂环族酯官能团和具有4至10个碳原子的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团至10个碳; 并且每次出现时，每个R 3和R 4可以相同或不同，并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团具有3至10个碳，“n”是0至4的整数，“m”是0至4的整数。

5. 发明申请

US20070100113A1 Polymers, polymer compositions and method of preparation 有权
标题翻译：聚合物，聚合物组合物和制备方法
公开(公告)号：US20070100113A1
公开(公告)日：2007-05-03
申请号：US11261279
申请日：2005-10-28
申请人： Jan Kamps , Jan-Pleun Lens , James Mahood , A.S. Radhakrishna , T. Raj , Ravindra Singh
发明人： Jan Kamps , Jan-Pleun Lens , James Mahood , A.S. Radhakrishna , T. Raj , Ravindra Singh
IPC分类号： C08G18/00 , C08G64/00
CPC分类号： C08G64/14 , C08G63/64 , C08G64/06 , C08G64/24 , C08G64/28
摘要： A polycarbonate comprises structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and R3 and R4 are independently at each occurrence a hydrogen, an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons.
摘要翻译：聚碳酸酯包括衍生自式（I）的多环二羟基化合物的结构单元，其中R 1选自氰基官能团，硝基官能团，具有1至10个碳的脂族官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团至10个碳; R 3和R 4在每次出现时独立地为氢，具有1至10个碳的脂族官能团或具有3至10个碳的脂环族官能团。

6. 发明申请

US20070260033A1 METHODS OF POLYMER PREPARATION USING POLYCYCLIC DIHYDROXY COMPOUNDS 有权
标题翻译：使用多环二羟基化合物制备聚合物的方法
公开(公告)号：US20070260033A1
公开(公告)日：2007-11-08
申请号：US11693314
申请日：2007-03-29
申请人： Jan Kamps , Jan-Pleun Lens , James Mahood , Arakali Radhakrishna , T. Raj , Ravindra Singh
发明人： Jan Kamps , Jan-Pleun Lens , James Mahood , Arakali Radhakrishna , T. Raj , Ravindra Singh
IPC分类号： C08G64/04
CPC分类号： C07C69/757 , C07C45/69 , C07C45/74 , C07C67/343 , C07C67/347 , C07C2601/14 , C08G64/14 , C07C49/223
摘要： Disclosed herein is a process for preparing a polymer comprising structural units derived from polycyclic dihydroxy compound having Formula (I), wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4. The process comprises subjecting a polycyclic dihydroxy compound of Formula (I) to polymerization.
摘要翻译：本文公开了一种制备包含衍生自具有式（I）的多环二羟基化合物的结构单元的聚合物的方法，其中R 1选自氰基官能团，硝基官能团，脂族基团具有1至10个碳的官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团至10个碳; 并且每次出现时，每个R 3和R 4可以相同或不同，并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团具有3至10个碳，“n”是0至4的整数，“m”是0至4的整数。该方法包括使式（I）的多环二羟基化合物进行聚合。

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