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1. 发明授权

US06641761B2 Mixed PMDI/resole resin binders for the production of wood composite products 失效
标题翻译：用于生产木材复合材料的混合PMDI /树脂树脂粘合剂
公开(公告)号：US06641761B2
公开(公告)日：2003-11-04
申请号：US09773796
申请日：2001-02-01
申请人： James W. Rosthauser , William D. Detlefsen
发明人： James W. Rosthauser , William D. Detlefsen
IPC分类号： B27N300
CPC分类号： C08G18/7664 , B27N3/002 , C08G18/542 , C08G18/6492 , C08L97/02 , C08L2666/14
摘要： This invention relates to a process for the production of composite wood products. This process comprises a) applying a binder composition to wood particles, and b) molding or compressing the wood particles treated with the binder to form a composite wood product. Suitable binder compositions comprise a polymethylene poly(phenyl isocyanate) and a solid resole resin.
摘要翻译：本发明涉及生产复合木制品的方法。该方法包括a）将粘合剂组合物施用于木材颗粒，以及b）模塑或压缩用粘合剂处理的木材颗粒以形成复合木制品。合适的粘合剂组合物包含多亚甲基聚（苯基异氰酸酯）和固体甲阶酚醛树脂。

2. 发明授权

US06214265B1 Mixed PMDI/resole resin binders for the production of wood composite products 有权
标题翻译：用于生产木材复合材料的混合PMDI /树脂树脂粘合剂
公开(公告)号：US06214265B1
公开(公告)日：2001-04-10
申请号：US09213595
申请日：1998-12-17
申请人： James W. Rosthauser , William D. Detlefsen
发明人： James W. Rosthauser , William D. Detlefsen
IPC分类号： B27N300
CPC分类号： C08G18/7664 , B27N3/002 , C08G18/542 , C08G18/6492 , C08L97/02 , C08L2666/14
摘要： This invention relates to a process for the production of composite wood products. This process comprises a) applying a binder composition to wood particles, and b) molding or compressing the wood particles treated with the binder to form a composite wood product. Suitable binder compositions comprise a polymethylene poly(phenyl isocyanate) and a solid resole resin.
摘要翻译：本发明涉及生产复合木制品的方法。该方法包括a）将粘合剂组合物施用于木材颗粒，以及b）模塑或压缩用粘合剂处理的木材颗粒以形成复合木制品。合适的粘合剂组合物包含多亚甲基聚（苯基异氰酸酯）和固体甲阶酚醛树脂。

3. 发明授权

US5637374A Resorcinol-glutaraldehyde resin as an accelerator for curing phenol-formaldehyde resins 失效
公开(公告)号：US5637374A
公开(公告)日：1997-06-10
申请号：US555047
申请日：1995-11-08
申请人： David W. Shiau , William D. Detlefsen , Earl K. Phillips
发明人： David W. Shiau , William D. Detlefsen , Earl K. Phillips
IPC分类号： C08L61/06 , C08L97/02 , B32B5/12
CPC分类号： C08L61/06 , C08L97/02 , Y10T428/24099 , Y10T428/24132 , Y10T428/31946 , Y10T428/31957 , Y10T428/3196 , Y10T428/31989
摘要： The invention relates to the use of a resorcinol-glutaraldehyde reaction product as an accelerator for thermosetting phenolic resin and to a method of making the accelerator. Further, the invention relates to a resin blend comprising phenol-formaldehyde and the accelerator and a process for making cellulosic board, oriented strandboard and plywood wherein the binder for the cellulosic board, oriented strandboard and plywood in its uncured form comprises the resin blend of the invention. In another embodiment the accelerator for thermosetting resin comprises resorcinol and glutaraldehyde.

4. 发明授权

US5684114A Cross-catalyzed phenol-resorcinol adhesive 失效
标题翻译：交联催化苯酚间苯二酚粘合剂
公开(公告)号：US5684114A
公开(公告)日：1997-11-04
申请号：US487317
申请日：1995-06-07
申请人： Earl K. Phillips , William D. Detlefsen , Fred E. Carlson
发明人： Earl K. Phillips , William D. Detlefsen , Fred E. Carlson
IPC分类号： C08L61/06 , C08L97/02 , C09J161/06 , C08G8/04 , C08G14/02
CPC分类号： C09J161/06 , C08L61/06 , C08L97/02
摘要： A two-part adhesive is provided wherein the first part comprises a stable aqueous alkaline monohydroxylic phenolic resole resin solution containing a methylene donor such as oxazolidine or a methylolurea and the second part comprises a stable resorcinolic resin precondensate having a shortage of formaldehyde and optionally containing a catalyst such as an ester functional compound for the resole resin. The resin in each part exhibits viscosity stability of an unmodified resin until mixed with the other part wherein the methylene donor, of the first part catalyzes the resorcinolic resin of the second part and the catalyst, when used, of the second part catalyzes the monohydroxylic phenolic resole resin of the first part. The adhesive finds utility in the production of structural lignocellulosic panels.
摘要翻译：提供两部分粘合剂，其中第一部分包含含有亚甲基供体如恶唑烷或羟甲基脲的稳定的碱性单羟基酚醛树脂溶液，第二部分包含具有不足甲醛的稳定的间苯二酚树脂预缩合物，并且任选地含有催化剂如用于甲阶酚醛树脂的酯官能化合物。每个部件中的树脂表现出未改性树脂的粘度稳定性，直到与另一部分混合，其中第一部分的亚甲基供体在使用时催化第二部分的催化剂和催化剂，第二部分催化单羟基酚甲阶酚醛树脂的第一部分。粘合剂可用于生产结构木质纤维板。

5. 发明授权

US5057591A Foamability of phenolic resins 失效
标题翻译：酚醛树脂的可燃性
公开(公告)号：US5057591A
公开(公告)日：1991-10-15
申请号：US236379
申请日：1988-08-25
申请人： William D. Detlefsen , Lewis D. Creel , Lee R. Johnson
发明人： William D. Detlefsen , Lewis D. Creel , Lee R. Johnson
IPC分类号： C08J9/00 , B32B7/12 , C08G8/28 , C08J9/30 , C08L61/04 , C08L61/06 , C08L61/14 , C09J5/08 , C09J161/06 , C09J161/14 , C09J189/00
CPC分类号： C08J9/30 , B32B7/12 , C08G8/28 , C08L61/14 , C09J161/14 , C08J2361/14 , Y10T428/31957 , Y10T428/3196
摘要： The invention is a solution of highly advanced phenolic resin with improved inherent foamability that is made from the reaction of phenol, aldehyde, water and alkali the improved foamability being brought about by the incorporation of up to 1.0% by weight, anhydrous basis, lime (calcium hydroxide) into the early stages of the reaction mix. In another embodiment, the invention is a plywood glue composition comprising a solution of lime-containing highly advanced phenolic resin, dried animal blood and preferably an aldehyde glue viscosity-lowering agent.

6. 发明授权

US06478998B1 Hybrid phenol-formaldehyde and polymeric isocyanate based adhesive and methods of synthesis and use 有权
标题翻译：混合苯酚 - 甲醛和聚合异氰酸酯基胶粘剂及其合成和使用方法
公开(公告)号：US06478998B1
公开(公告)日：2002-11-12
申请号：US09661458
申请日：2000-09-13
申请人： Todd R. Miller , Lewis D. Creel , William D. Detlefsen
发明人： Todd R. Miller , Lewis D. Creel , William D. Detlefsen
IPC分类号： C08L6110
CPC分类号： C08L61/06 , B27N3/002 , C08G8/28 , C08G18/542 , C08G18/6492 , C08G18/7664 , C08L61/14 , C08L75/04
摘要： Hybrid resins formed of an acylated phenol-formaldehyde (PF) resin and a polymeric phenyl isocyanate (pMDI) resin have extended shelf stability, yet cure at a rate faster than any of its components when used in conventional flakeboard, strandboard or other board making processes.
摘要翻译：由酰化酚醛树脂（PF）树脂和聚合苯基异氰酸酯（pMDI）树脂形成的混合树脂具有延长的贮存稳定性，但是当用于常规的刨花板，刨花板或其他板制造工艺时，以比其任何组分更快的速率固化。

7. 发明授权

US5498647A Resorcinol glutaraldehyde resin as an accelerator for curing phenolic formaldehyde resins 失效
标题翻译：间苯二酚戊二醛树脂作为固化酚醛树脂的促进剂
公开(公告)号：US5498647A
公开(公告)日：1996-03-12
申请号：US487337
申请日：1995-06-07
申请人： David W. Shiau , William D. Detlefsen , Earl K. Phillips
发明人： David W. Shiau , William D. Detlefsen , Earl K. Phillips
IPC分类号： C08L61/06 , C08L97/02 , C08K11/00
CPC分类号： C08L61/06 , C08L97/02 , Y10T428/24099 , Y10T428/24132 , Y10T428/31946 , Y10T428/31957 , Y10T428/3196 , Y10T428/31989
摘要： The invention relates to the use of a resorcinol-glutaraldehyde reaction product as an accelerator for thermosetting phenolic resin and to a method of making the accelerator. Further, the invention relates to a resin blend comprising phenol-formaldehyde and the accelerator and a process for making cellulosic board, oriented strandboard and plywood wherein the binder for the cellulosic board, oriented strandboard and plywood in its uncured form comprises the resin blend of the invention. In another embodiment the accelerator for thermosetting resin comprises resorcinol and glutaraldehyde.
摘要翻译：本发明涉及间苯二酚 - 戊二醛反应产物作为热固性酚醛树脂的促进剂的用途及其制备方法。此外，本发明涉及包含苯酚 - 甲醛和促进剂的树脂共混物以及用于制备纤维素板，定向刨花板和胶合板的方法，其中用于纤维素板，定向刨花板和未固化形式的胶合板的粘合剂包括：发明。在另一个实施方案中，热固性树脂促进剂包括间苯二酚和戊二醛。

8. 发明授权

US5446089A Resorcinol-glutaraldehyde resin as an accelerator for curing phenol-formaldehyde resins 失效
标题翻译：间苯二酚 - 戊二醛树脂作为固化酚醛树脂的促进剂
公开(公告)号：US5446089A
公开(公告)日：1995-08-29
申请号：US269111
申请日：1994-06-30
申请人： David W. Shiau , William D. Detlefsen , Earl K. Phillips
发明人： David W. Shiau , William D. Detlefsen , Earl K. Phillips
IPC分类号： C08L61/06 , C08L97/02 , C09J161/12
CPC分类号： C08L61/06 , C08L97/02 , Y10T428/24099 , Y10T428/24132 , Y10T428/31946 , Y10T428/31957 , Y10T428/3196 , Y10T428/31989
摘要： The invention relates to the use of a resorcinol-glutaraldehyde reaction product as an accelerator for thermosetting phenolic resin and to a method of making the accelerator. Further, the invention relates to a resin blend comprising phenol-formaldehyde and the accelerator and a process for making cellulosic board, oriented strandboard and plywood wherein the binder for the cellulosic board, oriented strandboard and plywood in its uncured form comprises the resin blend of the invention. In another embodiment the accelerator for thermosetting resin comprises resorcinol and glutaraldehyde.
摘要翻译：本发明涉及间苯二酚 - 戊二醛反应产物作为热固性酚醛树脂的促进剂的用途及其制备方法。此外，本发明涉及包含苯酚 - 甲醛和促进剂的树脂共混物以及用于制备纤维素板，定向刨花板和胶合板的方法，其中用于纤维素板，定向刨花板和未固化形式的胶合板的粘合剂包括：发明。在另一个实施方案中，热固性树脂促进剂包括间苯二酚和戊二醛。

9. 发明授权

US4961795A Composition and process for bonding lignocellulosic material 失效
标题翻译：用于粘合木质纤维素材料的组合物和方法
公开(公告)号：US4961795A
公开(公告)日：1990-10-09
申请号：US149102
申请日：1988-01-27
申请人： William D. Detlefsen , Earl K. Phillips , Richard V. Norton
发明人： William D. Detlefsen , Earl K. Phillips , Richard V. Norton
IPC分类号： B27D1/04 , B27N3/00 , C08L61/06 , C08L97/02
CPC分类号： C08L61/06 , B27D1/04 , B27N3/002 , C08L97/02
摘要： A composition and a process for bonding lignocellulosic material under heat and pressure is disclosed. According to the process, a curing agent is combined with a binder which is an alkaline phenol-formaldehyde resin. In one aspect the combination is by injection into a line carrying the binder to application apparatus, followed by in-line mixing of the curing agent and binder and application of the mixture to the lignocellulosic material. The lignocellulosic material is then compressed and the binder cured. The curing agent may be an ester, a lactone or an organic carbonate. The effect of the curing agent may be moderated with an aliphatic mono or polyhydric alcohol.
摘要翻译：公开了一种用于在热和压力下粘合木质纤维素材料的组合物和方法。根据该方法，将固化剂与作为碱性酚醛树脂的粘合剂组合。在一个方面，组合是通过注入到携带粘合剂的施用装置的管线中，随后将固化剂和粘合剂在线混合并将混合物施用于木质纤维素材料。然后将木质纤维素材料压缩并使粘合剂固化。固化剂可以是酯，内酯或有机碳酸酯。固化剂的效果可以用脂肪族单或多元醇调节。

10. 发明授权

US6150492A Cross-catalyzed phenol-resorcinol adhesive 失效
标题翻译：交联催化苯酚间苯二酚粘合剂
公开(公告)号：US6150492A
公开(公告)日：2000-11-21
申请号：US192077
申请日：1994-02-04
申请人： Earl K. Phillips , William D. Detlefsen , Fred E. Carlson
发明人： Earl K. Phillips , William D. Detlefsen , Fred E. Carlson
IPC分类号： C08L61/06 , C08L97/02 , C09J161/06 , C08G14/04 , C08G8/04
CPC分类号： C09J161/06 , C08L61/06 , C08L97/02
摘要： A two-part adhesive is provided wherein the first part comprises a stable aqueous alkaline monohydroxylic phenolic resole resin solution containing a methylene donor such as oxazolidine or a methylolurea and the second part comprises a stable resorcinolic resin precondensate having a shortage of formaldehyde and optionally containing a catalyst such as an ester functional compound for the resole resin. The resin in each part exhibits viscosity stability of an unmodified resin until mixed with the other part wherein the methylene donor, of the first part catalyzes the resorcinolic resin of the second part and the catalyst, when used, of the second part catalyzes the monohydroxylic phenolic resole resin of the first part. The adhesive finds utility in the production of structural lignocellulosic panels.
摘要翻译：提供两部分粘合剂，其中第一部分包含含有亚甲基供体如恶唑烷或羟甲基脲的稳定的碱性单羟基酚醛树脂溶液，第二部分包含具有不足甲醛的稳定的间苯二酚树脂预缩合物，并且任选地含有催化剂如用于甲阶酚醛树脂的酯官能化合物。每个部件中的树脂表现出未改性树脂的粘度稳定性，直到与另一部分混合，其中第一部分的亚甲基供体在使用时催化第二部分的催化剂和催化剂，第二部分催化单羟基酚甲阶酚醛树脂的第一部分。粘合剂可用于生产结构木质纤维板。

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