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    • 5. 发明授权
    • Phthalocyanines with peripheral siloxane substitution
    • 具有外围硅氧烷取代的酞菁
    • US07550586B2
    • 2009-06-23
    • US11108146
    • 2005-04-12
    • Arthur W. SnowJames S ShirkEva M MayaRichard G. S. PongSteven R. Flom
    • Arthur W. SnowJames S ShirkEva M MayaRichard G. S. PongSteven R. Flom
    • C07B47/00C07D487/22
    • C08G77/58C07F7/0838
    • The present invention is phthalocyanine compounds with peripheral siloxane substitution, as well as methods for making these compounds and various uses thereof, having the basic structure: wherein —W—X—Y—Z are peripheral groups comprising individual W, X, Y, and Z subgroups; W is a linkage represented by the formula: —D—(R1)0.1—, where D═S or O; X is: —(CH2)n—, n=2 to 8; Y is a siloxane chain; Z is an aryl or alkyl terminal cap; M is two protons or a metal ion; and forms a transparent film of high optical quality with large nonlinear absorption and thermal refraction, free of scattering from solid or liquid crystalline domains making them highly suitable for use as the active component in thin films protective eye wear, and optical data storage applications.
    • 本发明是具有外围硅氧烷取代性的酞菁化合物,以及具有以下基本结构的制备这些化合物及其各种用途的方法:其中-W-X-Y-Z是包含单独的W,X,Y和Z亚组的外围基团; W是由以下通式表示的键:-D-(R1)0.1-,其中D-S或O; X是: - (CH 2)n - ,n = 2〜8; Y是硅氧烷链; Z是芳基或烷基末端帽; M是两个质子或金属离子; 并形成具有大的非线性吸收和热折射的高光学质量的透明膜,不受固体或液晶畴的散射,使得它们非常适合用作薄膜保护眼睛磨损和光学数据存储应用中的有源成分。