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    • 1. 发明授权
    • Application of refractory protective coatings, particularly on the
surface of electrolytic cell components
    • 耐火保护涂层的应用,特别是电解池组件的表面
    • US5310476A
    • 1994-05-10
    • US861513
    • 1992-04-01
    • Jainagesh SekharVittorio de Nora
    • Jainagesh SekharVittorio de Nora
    • C04B41/50C04B41/52C04B41/87C04B41/89C25C3/08C25C3/12C25D9/04C25D11/00C25D15/00
    • C04B41/507C04B41/5025C04B41/5062C04B41/52C04B41/87C04B41/89C25C3/08C25C3/085C25C3/125Y10T428/12486Y10T428/12576Y10T428/12618Y10T428/12674Y10T428/12806Y10T428/12812Y10T428/12819Y10T428/12826Y10T428/12854
    • An adherent protective coating of a refractory material is produced on the surface of carbonaceous, refractory, ceramic, metallic or other materials serving as components of electrolytic cells operating at high temperature, by applying to such surfaces a well chosen micropyretic reaction layer from a slurry, which when dried is ignited to initiate a self-sustaining micropyretic reaction, along a combustion front, to produce condensed matter forming such refractory protective adherent coating. The slurry is preferably applied in several layers, the first layer(s) to facilitate adherence and the last layer(s) to provide protection, and may contain some preformed non-reactant materials. The electrolytic cells whose components require such coatings are especially those operating at high temperature with a molten salt electrolyte, particularly those for the production of metals, aluminium being the most important. For these cells the invention provides an aluminium-wettable, adherent, refractory, protective coating for the cell-bottom carbon cathode, containing RHM material such as titanium diboride, as well as other refractory protective coatings for cell wall lining and for other cell components. Novel cell designs for the utilization of the different coatings are also provided.
    • 在碳质,耐火材料,陶瓷,金属或其他材料的表面上产生耐火材料的粘附保护涂层,其作为在高温下运行的电解池的组分,通过将这种表面从浆料中施加良好选择的微解释反应层, 当干燥时,其被点燃以开始自燃维持微反应,沿着燃烧前沿,以产生形成这种难熔保护性粘附涂层的凝聚物。 浆料优选以数层施加,第一层以促进粘附,最后一层被提供保护,并且可以含有一些预制的非反应物材料。 其组分需要这种涂层的电解槽尤其是在熔融盐电解质,特别是用于生产金属的电解液中,在高温下运行的电解槽是最重要的。 对于这些电池,本发明为含有RHM材料如二硼化钛的电池底部碳阴极以及用于电池壁衬里和其它电池组件的其它耐火保护涂层提供了铝可润湿,粘附,耐火的保护涂层。 还提供了用于不同涂层的新型电池设计。
    • 2. 发明授权
    • Aluminum electrolytic cell method with application of refractory
protective coatings on cello components
    • 铝电解槽法在电池组件上应用耐火保护涂层
    • US5340448A
    • 1994-08-23
    • US143177
    • 1993-10-26
    • Jainagesh SekharVittorio de Nora
    • Jainagesh SekharVittorio de Nora
    • C04B41/50C04B41/52C04B41/87C04B41/89C25C3/08C25C3/12C25C3/06C25D3/66
    • C04B41/507C04B41/5025C04B41/5062C04B41/52C04B41/87C04B41/89C25C3/08C25C3/085C25C3/125Y10T428/12486Y10T428/12576Y10T428/12618Y10T428/12674Y10T428/12806Y10T428/12812Y10T428/12819Y10T428/12826Y10T428/12854
    • An adherent protective coating of a refractory material is produced on the surface of carbonaceous, refractory, ceramic, metallic or other materials serving as components of electrolytic cells operating at high temperature, by applying to such surfaces a well chosen micropyretic reaction layer from a slurry, which when dried is ignited to initiate a self-sustaining micropyretic reaction, along a combustion front, to produce condensed matter forming such refractory protective adherent coating. The slurry is preferably applied in several layers, the first layer(s) to facilitate adherence and the last layer(s) to provide protection and may contain some preformed non-reactant materials. The electrolytic cells whose components require such coatings are especially those operating at high temperature with a molten salt electrolyte, particularly those for the production of metals, aluminum being the most important. For these cells the invention provides an aluminum-wettable, adherent, refractory, protective coating for the cell-bottom carbon cathode, containing RHM material such as titanium diboride, as well as other refractory protective coatings for cell wall lining and for other cell components. Novel cell designs for the utilization of the different coatings are also provided.
    • 在碳质,耐火材料,陶瓷,金属或其他材料的表面上产生耐火材料的粘附保护涂层,其作为在高温下运行的电解池的组分,通过将这种表面从浆料中施加良好选择的微解释反应层, 当干燥时,其被点燃以开始自燃维持微反应,沿着燃烧前沿,以产生形成这种难熔保护性粘附涂层的凝聚物。 浆料优选以几层施加,第一层以促进粘合,最后一层提供保护,并且可以含有一些预先形成的非反应物材料。 其组分需要这种涂层的电解槽尤其是在熔融盐电解质,特别是用于生产金属的电解液中,在高温下运行的电解槽是最重要的。 对于这些电池,本发明为含有RHM材料如二硼化钛的电池底部碳阴极以及用于电池壁衬里和其它电池组件的其它耐火保护涂层提供了铝可润湿,粘附,耐火的保护涂层。 还提供了用于不同涂层的新型电池设计。
    • 3. 发明授权
    • Aluminium electrowinning cells having a V-shaped cathode bottom and method of producing aluminium
    • 具有V形阴极底的铝电解冶金电池和生产铝的方法
    • US06682643B2
    • 2004-01-27
    • US09978160
    • 2001-10-16
    • Vittorio de Nora
    • Vittorio de Nora
    • C25C308
    • C25C3/08
    • A cell for the electrowinning of aluminium comprises a plurality of metal-based anodes facing and spaced part from an aluminium-wettable drained cathode surface on which aluminium is produced. The drained cathode surface is formed along the cell by upper surfaces of juxtaposed carbon cathode blocks, the cathode blocks extending across the cell. The drained cathode surface is divided into quadrants by a longitudinal aluminium collection groove along the cell and by a central aluminium collection reservoir across the cell. Pairs of quadrants across the cell are inclined in a V-shape relationship, the collection groove being located along the bottom of the V-shape and arranged to collect molten aluminium draining from the drained cathode surface and evacuate it into the aluminium collection reservoir during cell operation.
    • 用于电解铝的电池包括多个金属阳极,其面对并与其上产生铝的铝可润湿排出的阴极表面间隔开。 排出的阴极表面沿着电池通过并置的碳阴极块的上表面形成,阴极块延伸穿过电池。 排出的阴极表面通过沿着电池的纵向铝收集槽和穿过电池的中央铝收集容器分成象限。 跨越电池的象限的对象以V形关系倾斜,收集槽沿V形底部定位,并布置成收集从排出的阴极表面排出的熔融铝,并在电池单元期间将其排空到铝收集容器中 操作。
    • 4. 发明授权
    • Nickel-iron alloy-based anodes for aluminium electrowinning cells
    • 用于铝电解冶金电池的基于镍 - 铁合金的阳极
    • US06521115B2
    • 2003-02-18
    • US09772285
    • 2001-01-29
    • Jean-Jacques DuruzVittorio de NoraOlivier Crottaz
    • Jean-Jacques DuruzVittorio de NoraOlivier Crottaz
    • C25C308
    • C25C3/12C25C3/06
    • An anode of a cell for the electrowinning of aluminium comprises an iron-nickel alloy body or layer whose surface is oxidised to form a coherent and adherent outer iron oxide-based layer, in particular hematite, the surface of which is electrochemically active for the oxidation of oxygen ions and which reduces diffusion of oxygen from the electrochemically active surface into the iron-nickel alloy body or layer. The anode may be kept dimensionally stable during cell operation by maintaining a sufficient amount of dissolved alumina and iron species in the electrolyte to prevent dissolution of the outer oxide layer of the or each anode and by reducing the electrolyte operating temperature to limit dissolution of iron and by reducing the electrolyte operating temperature to limit dissolution of iron species in the electrolyte.
    • 用于电解电解铝的电池的阳极包括铁 - 镍合金体或其表面被氧化以形成相干和粘附的外部氧化铁基层,特别是赤铁矿的表面,其表面对于氧化具有电化学活性 的氧离子,并且其将氧从电化学活性表面扩散到铁 - 镍合金体或层中。 阳极可以在电池操作期间保持尺寸稳定,通过在电解质中保持足够量的溶解的氧化铝和铁物质以防止阳极的外部氧化物层的溶解和通过降低电解液的操作温度来限制铁的溶解和 通过降低电解液的操作温度来限制铁物质在电解质中的溶解。
    • 5. 发明授权
    • Aluminium production cell with an insulating cover having individually removable sections
    • 具有绝缘盖的铝生产单元具有单独的可移除部分
    • US06402928B1
    • 2002-06-11
    • US09446925
    • 2000-03-31
    • Vittorio de NoraJainagesh A. Sekhar
    • Vittorio de NoraJainagesh A. Sekhar
    • C25C308
    • C25C3/08
    • A cell of advanced design for production aluminum by the electrolysis of an aluminum compound dissolve in a molten ectrolyte, has a cathode (30) of drained configuration, and at least one non-carbon anode (10) facing the cathode both covered by the electrolyte (54). The upper part of the cell contains a removable thermic insulating cover (60) placed just above the level of the electrolyte (54). Preferably, the cathode (30) comprises a cathode mass (32) supported by a cathode carrier (31) made of electrically conductive material which serves also for the uniform distribution of electric current feeders (42) which connect the cathode carrier (31) to the negative busbars.
    • 一种用于通过电解铝化合物的铝化合物生产铝的先进设计的电池溶解在熔融的电解质中,具有排出构型的阴极(30),并且至少一个面向阴极的非碳阳极(10)都被电解质覆盖 (54)。 电池的上部包含位于电解质(54)的正上方的可移除的热绝缘盖(60)。 优选地,阴极(30)包括由导电材料制成的阴极载体(31)支撑的阴极块(32),其也用于均匀分布连接阴极载体(31)的电流馈送器(42) 负母线。
    • 6. 发明授权
    • Application of refractory protective coatings on the surface of electrolytic cell components
    • 耐火保护涂层在电解槽组件表面的应用
    • US06402926B1
    • 2002-06-11
    • US08666870
    • 1996-06-17
    • Jaihagesh A. SekharVittorio de Nora
    • Jaihagesh A. SekharVittorio de Nora
    • C25C300
    • C04B41/507C04B41/5025C04B41/5062C04B41/52C04B41/87C04B41/89C25C3/08C25C3/085C25C3/125Y10T428/12486Y10T428/12576Y10T428/12618Y10T428/12674Y10T428/12806Y10T428/12812Y10T428/12819Y10T428/12826Y10T428/12854
    • An adherent protective coating of a refractory material is produced on the surface of carbonaceous, refractory, ceramic, metallic or other materials serving as components of electrolytic cells operating at high temperature, by applying to such surfaces a well chosen micropyretic reaction layer from a slurry, which when dried is ignited to initiate a self-sustaining micropyretic reaction, along a combustion front, to produce condensed matter forming such refractory protective adherent coating. The slurry is preferably applied in several layers, the first layer(s) to facilitate adherence and the last layer(s) to provide protection, and may contain some preformed non-reactant materials. The electrolytic cells whose components require such coatings are especially those operating at high temperature with a molten salt electrolyte, particularly those for the production of metals, aluminium being the most important. For these cells the invention provides an aluminium-wettable, adherent, refractory, protective coating for the cell-bottom carbon cathode, containing RHM material such as titanium diboride, as well as other refractory protective coatings for cell wall lining and for other cell components. Novel cell designs for the utilization of the different coatings are also provided.
    • 在碳质,耐火材料,陶瓷,金属或其他材料的表面上产生耐火材料的粘附保护涂层,其作为在高温下运行的电解池的组分,通过将这种表面从浆料中施加良好选择的微解释反应层, 当干燥时,其被点燃以开始自燃维持微反应,沿着燃烧前沿,以产生形成这种难熔保护性粘附涂层的凝聚物。 浆料优选以数层施加,第一层以促进粘合,最后一层被提供保护,并且可以含有一些预制的非反应物材料。 其组分需要这种涂层的电解槽尤其是在熔融盐电解质,特别是用于生产金属的电解液中,在高温下运行的电解槽是最重要的。 对于这些电池,本发明为含有RHM材料如二硼化钛的电池底部碳阴极以及用于电池壁衬里和其它电池组件的其它耐火保护涂层提供了铝可润湿,粘附,耐火的保护涂层。 还提供了用于不同涂层的新型电池设计。
    • 7. 发明授权
    • Aluminium electrowinning cell with sidewalls resistant to molten electrolyte
    • 具有抵抗熔融电解质的侧壁的铝电解冶金电池
    • US06258246B1
    • 2001-07-10
    • US09431023
    • 1999-11-01
    • Jean-Jacques DuruzVittorio de NoraGeorges Berclaz
    • Jean-Jacques DuruzVittorio de NoraGeorges Berclaz
    • C25C308
    • C25C3/085C25C3/08
    • A drained cathode cell for the electrowinning of aluminium comprises a cell bottom (20) arranged to collect product aluminium and thermic insulating sidewalls (40) lined with a molten electrolyte resistant sidewall lining (50), in particular containing silicon carbide, silicon nitride or boron nitride. The thermic insulating sidewalls (40) inhibit formation of an electrolyte crust on the lining (50), whereby the lining (50) is exposed to molten electrolyte. The cell bottom (20) has a peripheral zone from which the insulating sidewalls (40) extend generally vertically to form, with the cell bottom, a trough for containing molten electrolyte and aluminium produced on at least one drained cathode (32). The peripheral zone of the cell bottom (20) is arranged to keep the product aluminium from contacting and reacting with the molten electrolyte resistant sidewall lining 50).
    • 用于电解铝的排水阴极单元包括:细胞底部(20),其布置成收集产品铝和热绝缘侧壁(40),衬里衬有耐熔融电解质侧壁衬里(50),特别是含有碳化硅,氮化硅或硼 氮化物。 热绝缘侧壁(40)阻止在衬里(50)上形成电解质外壳,由此将衬里(50)暴露于熔融电解质。 电池底部(20)具有外围区域,绝缘侧壁(40)从该周边区域大致垂直延伸,以便在电池底部形成用于容纳在至少一个排出的阴极(32)上产生的熔融电解质和铝的槽。 电池底部(20)的周边区域布置成使产品铝不与耐熔融电解质侧壁衬垫50接触并反应。
    • 8. 发明授权
    • Hard and abrasion resistant surfaces protecting cathode blocks of aluminium electrowinning
    • 硬和耐磨表面保护铝电解沉积阴极块
    • US06180182B2
    • 2001-01-30
    • US09117063
    • 1998-05-29
    • Jainagesh A. SekharVittorio de Nora
    • Jainagesh A. SekharVittorio de Nora
    • B05D108
    • C04B41/009C04B41/507C04B41/52C04B41/87C04B41/89C04B2111/00879C25C3/08Y10T428/252Y10T428/30C04B41/4519C04B41/4539C04B41/4556C04B41/4578C04B41/5057C04B41/455C04B41/4523C04B41/5155C04B41/4517C04B41/5027C04B41/5031C04B35/52
    • A component of an aluminium production cell, in particular a cathode or a cell lining of an electrolytic cell for the production of aluminium by the electrolysis of alumina in cryolite, having an aluminium-wettable refractory coating on a heat-stable baked carbon-containing body, is produced from a part-manufactured cell component which is a layered composite of two precursors. A precursor layer of the aluminium-wettable refractory coating contains at least one aluminium-wettable refractory material in particulate form, or a particulate micropyretic reaction mixture which when ignited reacts to form at least one aluminium-wettable refractory material, or a mixture thereof, and non-carbon fillers and binders. A non-baked or part-baked precursor of the heat-stable carbon-containing body comprises particulate carbon compacted with a heat-convertible binder which when subjected to heat treatment binds the particulate carbon into the heat-stable carbon-containing body of the fully-manufactured cell component. This layered composite is convertible to the fully-manufactured cell component by heat treatment to form the aluminium-wettable refractory coating and simultaneously bind and heat-stabilize the carbon-containing body.
    • 通过电解冰晶石中的氧化铝来生产铝的电解池的阴极或电解槽的一个部件,特别是在热稳定的含有烘烤的含碳体上具有铝可润湿耐火涂层的铝生产电池的组件 是由作为两种前体的层状复合材料的部分制造的电池部件制成的。 铝可润湿耐火涂层的前体层包含至少一种颗粒形式的铝可湿性耐火材料,或微粒微溶剂反应混合物,当点燃反应形成至少一种铝可润湿耐火材料或其混合物时,以及 非碳填料和粘合剂。 热稳定性含碳体的未烘烤或部分焙烧的前体包括用可热转化粘合剂压实的颗粒状碳,当进行热处理时,将颗粒碳结合到完全的热稳定性含碳体中 - 制造单元组件。 该层状复合物通过热处理可转化为完全制造的电池组件,以形成铝可润湿耐火涂层,同时结合和热稳定含碳体。
    • 10. 发明授权
    • Electrocatalytically active non-carbon metal-based anodes for aluminium
production cells
    • 用于铝生产电池的电催化活性非碳金属基阳极
    • US6103090A
    • 2000-08-15
    • US126114
    • 1998-07-30
    • Vittorio de NoraJean-Jacques Duruz
    • Vittorio de NoraJean-Jacques Duruz
    • C25C3/12C25C7/02C25C3/08C25C3/18
    • C25C7/025C25C3/12
    • A non-carbon, metal-based high temperature resistant anode of a cell for the production of aluminium has a metal-based substrate coated with one or more electrically conductive adherent applied layers, at least one electrically conductive layer being electrochemically active. The electrochemically active layer contains one or more electrocatalysts fostering the oxidation of oxygen ions as well as fostering the formation of biatomic molecular gaseous oxygen to inhibit ionic and/or monoatomic oxygen attack of the metal-based substrate. The electrocatalyst can be iridium, palladium, platinum, rhodium, ruthenium, silicon, tin, zinc, Mischmetal oxides and metals of the Lanthanide series. The applied layer may further comprise electrochemically active constituents from oxides, oxyfluorides, phosphides, carbides, in particular spinels such as ferrites.
    • 用于生产铝的电池的非碳金属基耐高温阳极具有涂覆有一个或多个导电粘附施加层的金属基底层,至少一个导电层是电化学活性的。 电化学活性层包含一种或多种促进氧离子氧化的电催化剂,以及促进生物原子分子气态氧的形成以抑制金属基底层的离子和/或单原子氧侵蚀。 电催化剂可以是镧系元素的铱,钯,铂,铑,钌,硅,锡,锌,稀土氧化物和金属。 施加的层还可以包含来自氧化物,氟氧化物,磷化物,碳化物,特别是尖晶石如铁氧体的电化学活性成分。