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    • 3. 发明申请
    • POLYLACTIC ACID-BASED RESIN EXPANDED BEADS AND MOLDED ARTICLE THEREOF
    • 基于聚氨酯的树脂膨胀珠及其成型品
    • US20140235741A1
    • 2014-08-21
    • US14347140
    • 2012-08-30
    • JSP CORPORATION
    • Mitsuru ShinoharaMasaharu Oikawa
    • C08G63/08
    • C08J9/12C08G63/08C08J9/122C08J9/18C08J9/232C08J2300/16C08J2333/02C08J2367/04
    • Polylactic acid-based resin expanded beads of the present invention are obtained by releasing a softened, pressurized foamable resin composition, which comprises a polylactic acid-based resin and a physical blowing agent, to a low pressure atmosphere to foam and expand the resin composition, wherein the polylactic acid-based resin satisfies the conditions (1) to (3) shown below, and exhibits excellent secondary expansion properties and fusion bonding properties. A polylactic acid-based resin expanded beads molded article obtained by in-mold molding of the polylactic acid-based resin expanded beads exhibits excellent mechanical properties. MT≦30 mN  (1) log MT≦0.93 log η−1.75  (2) CT1/2≧600 sec  (3) where MT represents a melt tension [mN] at 190° C., η represents a melt viscosity [Pa·s] at 190° C. and a shear speed of 20 sec−1, and CT1/2 represents a half crystallization time [sec] at 110° C.
    • 本发明的聚乳酸类树脂发泡珠粒通过将含有聚乳酸类树脂和物理发泡剂的软化的加压发泡树脂组合物释放到低压气氛中以使树脂组合物发泡和膨胀而获得, 其中所述聚乳酸类树脂满足下述条件(1)至(3),并且显示出优异的二次膨胀性和熔融粘合性。 通过聚乳酸类树脂发泡粒子的模内成型得到的聚乳酸类树脂发泡粒子成型体的机械特性优异。 MT≦̸ 30mN(1)log MT≦̸ 0.93log&eegr; -1.75(2)CT1 /2≥600秒(3)其中MT表示在190℃下的熔体张力[mN] 表示190℃下的熔融粘度[Pa·s],剪切速度为20秒-1,CT1 / 2表示110℃下的半结晶时间[秒]。