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1. 发明申请

US20100329921A1 NICKEL BASE SUPERALLOY COMPOSITIONS AND SUPERALLOY ARTICLES 审中-公开
标题翻译：镍基超级合金组合物和超级合金文章
公开(公告)号：US20100329921A1
公开(公告)日：2010-12-30
申请号：US12794244
申请日：2010-06-04
申请人： JOSHUA LEIGH MILLER , Brian Thomas Hazel , Douglas Gerard Konitzer , Paul John Fink
发明人： JOSHUA LEIGH MILLER , Brian Thomas Hazel , Douglas Gerard Konitzer , Paul John Fink
IPC分类号： C22C19/05
CPC分类号： F01D5/28 , C22C19/057 , F01D9/041
摘要： A superalloy composition comprising, in weight percent: about 6.2-6.6 Al, about 6.5-7.0 Ta, about 6.0-7.0 Cr, about 6.25-7.0 W, about 1.5-2.5 Mo, about 0.15-0.60 Hf, 0.0-1.0 Re, 6.5-9.0 Co, optionally, 0.03-0.06 C, optionally, up to about 0.004 B, optionally up to about 0.03 total of one or more rare earth elements selected from yttrium (Y), lanthanum (La), or cerium (Ce), balance nickel, such that the superalloy composition exhibits a stress rupture capability improvement of at least 15% over a base stress rupture capability of a base composition nominally comprising, in weight percent: 6.5 Al, 6.6 Ta, 6.0 Cr, 6.25 W, 1.5 Mo, 0.15 Hf, 0.0 Re, 7.5 Co. Articles incorporating the superalloy composition include a gas turbine engine component such as a high pressure turbine nozzle or nozzle segment.
摘要翻译：一种超合金组合物，其包含重量百分比：约6.2-6.6Al，约6.5-7.0Ta，约6.0-7.0Cr，约6.25-7.0W，约1.5-2.5Mo，约0.15-0.60Hd，0.0-1.0Re， 6.5-9.0Co，任选地，0.03-0.06℃，任选地，至多约0.004B，任选地最多约0.03个总计选自钇（Y），镧（La）或铈（Ce）的一种或多种稀土元素，，使得镍合金组合物表现出基本组合物的基本应力断裂能力至少15％的应力断裂能力改善，该基础组合物名义上包含重量百分比：6.5Al，6.6Ta，6.0Cr，6.25W，1.5 Mo，0.15 Hf，0.0 Re，7.5Co。含有超合金组合物的制品包括燃气轮机发动机部件，例如高压涡轮喷嘴或喷嘴段。

2. 发明申请

US20110280716A1 GAS TURBINE ENGINE COMPRESSOR COMPONENTS COMPRISING THERMAL BARRIERS, THERMAL BARRIER SYSTEMS, AND METHODS OF USING THE SAME 审中-公开
标题翻译：包含热障碍物，热障碍系统的气体涡轮发动机压缩机组件及其使用方法
公开(公告)号：US20110280716A1
公开(公告)日：2011-11-17
申请号：US12870315
申请日：2010-08-27
申请人： DOUGLAS GERARD KONITZER , Eric Scott Huron , Brian Thomas Hazel
发明人： DOUGLAS GERARD KONITZER , Eric Scott Huron , Brian Thomas Hazel
IPC分类号： F04D29/58
CPC分类号： F01D5/06 , F05C2201/0463 , F05C2201/0466 , F05D2230/90 , F05D2260/95 , F05D2300/11 , F05D2300/611 , Y02T50/67 , Y02T50/6765
摘要： Gas turbine engine compressor disks having a hot flowpath side; a shaft having a first surface positioned in the hot flowpath side; and a thermal barrier applied to at least the first surface of the shaft where the thermal barrier is operable to maintain the temperature of the shaft below about 700° C. (1300° F.) when the hot flowpath side experiences a service operating temperature of from about 700° C. (1300° F.) to about 788° C. (1450° F.).
摘要翻译：具有热流路侧的燃气涡轮发动机压缩机盘; 轴，其具有位于所述热流路侧的第一表面; 以及施加到至少轴的第一表面的热障，其中热障可操作以在热流动侧经历使用操作温度时保持轴的温度低于约700℃（1300°F）从约700℃（1300°F）至约788℃（1450°F）。

3. 发明授权

US08658291B2 CMAS mitigation compositions, environmental barrier coatings comprising the same, and ceramic components comprising the same 有权
标题翻译： CMAS缓释组合物，包含其的环境屏障涂层和包含其的陶瓷组分
公开(公告)号：US08658291B2
公开(公告)日：2014-02-25
申请号：US12339974
申请日：2008-12-19
申请人： Glen Harold Kirby , Brett Allen Boutwell , Ming Fu , Bangalore Aswatha Nagaraj , Brian Thomas Hazel
发明人： Glen Harold Kirby , Brett Allen Boutwell , Ming Fu , Bangalore Aswatha Nagaraj , Brian Thomas Hazel
IPC分类号： B32B9/00 , B32B19/00 , B32B9/04 , B32B13/04 , F03B3/12 , F03B7/00 , F03D11/02
CPC分类号： C04B41/52 , C04B41/009 , C04B41/89 , C23C28/042 , F01D5/288 , F05D2300/611 , C04B41/5096 , C04B41/5035 , C04B41/5024 , C04B41/5037 , C04B41/522 , C04B41/524 , C04B41/5025 , C04B41/4582 , C04B35/10 , C04B35/00 , C04B35/14 , C04B35/18 , C04B35/185 , C04B35/565 , C04B35/584 , C04B35/806 , C04B35/803
摘要： Calcium magnesium aluminosilicate (CMAS) mitigation compositions selected from rare earth elements, rare earth oxides, zirconia, hafnia partially or fully stabilized with alkaline earth or rare earth elements, zirconia partially or fully stabilized with alkaline earth or rare earth elements, magnesium oxide, cordierite, aluminum phosphate, magnesium silicate, and combinations thereof when the CMAS mitigation composition is included as a separate CMAS mitigation layer in an environmental barrier coating for a high temperature substrate component.
摘要翻译：选自稀土元素，稀土氧化物，氧化锆，部分或完全用碱土金属或稀土元素稳定的镁铝硅酸钙（CMAS）缓蚀组合物，用碱土金属或稀土元素部分或完全稳定的氧化锆，氧化镁，堇青石，当将CMAS缓和组合物作为单独的CMAS缓解层包含在高温底物组分的环境屏障涂层中时，可以使用磷酸铝，硅酸镁及其组合。

4. 发明授权

US07919187B2 Environmental barrier coating for silicon-containing substrates and process therefor 失效
标题翻译：含硅基材的环境阻隔涂层及其工艺
公开(公告)号：US07919187B2
公开(公告)日：2011-04-05
申请号：US11616361
申请日：2006-12-27
申请人： Brian Thomas Hazel , Christine Walston , Irene Spitsberg
发明人： Brian Thomas Hazel , Christine Walston , Irene Spitsberg
IPC分类号： B32B13/04 , B05D3/02
CPC分类号： C04B41/85 , C04B35/195 , C04B41/009 , C04B41/5024 , C04B41/52 , C04B41/89 , C04B2235/3213 , C04B2235/3215 , C04B2235/3217 , C04B2235/3481 , C04B2235/79 , C04B2235/80 , C23C4/11 , C23C4/18 , C23C28/04 , C23C30/00 , F01D5/288 , F05D2230/90 , F05D2300/211 , F05D2300/2112 , F23M2900/05004 , F23R3/007 , Y02T50/67 , Y02T50/672 , C04B41/4527 , C04B41/5096 , C04B41/5037 , C04B41/5042 , C04B35/565 , C04B35/584 , C04B35/806 , C04B41/0072 , C04B41/4519 , C04B2111/0025
摘要： A protective coating for use on a silicon-containing substrate, and deposition methods therefor. The coating has a strontium-aluminosilicate (SAS) composition that is less susceptible to degradation by volatilization and in corrosive environments as a result of having at least an outer surface region that consists essentially of one or more stoichiometric crystalline phases of SAS and is substantially free of a nonstoichiometric second crystalline phase of SAS that contains a substoichiometric amount of silica. The coating can be produced by carrying out deposition and heat treatment steps that result in the entire coating or just the outer surface region of the coating consisting essentially of the stoichiometric celsian phase.
摘要翻译：用于含硅基材的保护涂层及其沉积方法。涂层具有锶 - 硅铝酸盐（SAS）组合物，其通过挥发和腐蚀性环境中较不易于降解，因为至少具有由SAS的一个或多个化学计量结晶相组成的至少一个外表面区域，并且基本上没有的非化学计量的第二结晶相的SAS，其含有亚化学计量的二氧化硅。可以通过进行沉积和热处理步骤来产生涂层，所述沉积和热处理步骤导致整个涂层或仅基本上由化学计量的凝胶相组成的涂层的外表面区域。

5. 发明申请

US20100330295A1 METHOD FOR PROVIDING DUCTILE ENVIRONMENTAL COATING HAVING FATIGUE AND CORROSION RESISTANCE 审中-公开
标题翻译：提供具有耐疲劳性和耐腐蚀性的耐腐蚀环氧涂层的方法
公开(公告)号：US20100330295A1
公开(公告)日：2010-12-30
申请号：US12494813
申请日：2009-06-30
申请人： Brian Thomas Hazel , Ming Fu
发明人： Brian Thomas Hazel , Ming Fu
IPC分类号： C23C4/08 , B05D3/02 , C23C16/44 , C23C14/34
CPC分类号： C23C28/028 , C23C4/073 , C23C10/56 , C23C28/021 , C23C30/00
摘要： Method includes providing a superalloy substrate such as a turbine disk, a turbine seal, a turbine blade, a turbine nozzle, a turbine shroud, or a turbine frame or case having an under platform or non-gas path region; and providing a predominantly gamma-prime nickel aluminide intermetallic ductile corrosion and oxidation resistant coating disposed on at least a portion of the substrate. The coating comprises from about 15 to about 30 atomic % aluminum, up to about 20 atomic % chromium, optionally, up to about 30 atomic % of at least one platinum group metal, optionally, up to about 4 atomic % of at least one reactive element, and optionally, up to about 15 atomic % of at least one strengthening element, and a balance being essentially nickel or nickel and at least one of cobalt, iron, or cobalt and iron. A coating precursor composition may be applied to the substrate before or after optional plating with one or more platinum group metals.
摘要翻译：方法包括提供诸如涡轮盘，涡轮密封件，涡轮叶片，涡轮喷嘴，涡轮机罩或具有下平台或非气体路径区域的涡轮机框架或壳体的超级合金基板; 并且提供主要是γ-基铝酸镍金属间金属延性腐蚀和抗氧化涂层，其设置在所述基底的至少一部分上。涂层包含约15至约30原子％的铝，至多约20原子％的铬，任选的至多约30原子％的至少一种铂族金属，任选的至多约4原子％的至少一种反应性元素和任选地至多约15原子％的至少一种强化元素，余量基本上为镍或镍以及钴，铁或钴和铁中的至少一种。涂覆前体组合物可以在用一种或多种铂族金属任选镀覆之前或之后施加到基材上。

6. 发明申请

US20100159150A1 METHODS FOR MAKING ENVIRONMENTAL BARRIER COATINGS AND CERAMIC COMPONENTS HAVING CMAS MITIGATION CAPABILITY 有权
标题翻译：制备环境阻隔涂层的方法和具有CMAS缓解能力的陶瓷组件
公开(公告)号：US20100159150A1
公开(公告)日：2010-06-24
申请号：US12340013
申请日：2008-12-19
申请人： GLEN HAROLD KIRBY , Brett Allen Boutwell , Ming Fu , Bangalore Aswatha Nagaraj , Brian Thomas Hazel
发明人： GLEN HAROLD KIRBY , Brett Allen Boutwell , Ming Fu , Bangalore Aswatha Nagaraj , Brian Thomas Hazel
IPC分类号： C23C4/10 , B32B9/04 , B05D1/36 , C23C14/34
CPC分类号： C23C28/042 , C04B41/009 , C04B41/4584 , C04B41/52 , C04B41/89 , C23C4/11 , C04B41/5096 , C04B41/5035 , C04B41/5024 , C04B41/5037 , C04B41/4539 , C04B41/5027 , C04B41/4582 , C04B41/4531 , C04B41/4537 , C04B35/195 , C04B35/565 , C04B35/584 , C04B35/806
摘要： Methods of making components having calcium magnesium aluminosilicate (CMAS) mitigation capability involving providing a component; applying an environmental barrier coating to the component, the environmental barrier coating having a separate CMAS mitigation layer including a CMAS mitigation composition selected from rare earth elements, rare earth oxides, zirconia, hafnia partially or fully stabilized with alkaline earth or rare earth elements, zirconia partially or fully stabilized with alkaline earth or rare earth elements, magnesium oxide, cordierite, aluminum phosphate, magnesium silicate, and combinations thereof.
摘要翻译：制备具有钙镁铝硅酸盐（CMAS）减轻能力的组分的方法涉及提供组分; 将环境屏障涂层施加到部件上，环境屏障涂层具有单独的CMAS缓解层，其包括选自稀土元素，稀土氧化物，氧化锆，部分或完全用碱土金属或稀土元素稳定的半导体材料的CMAS缓和组合物，氧化锆部分或完全用碱土金属或稀土元素稳定，氧化镁，堇青石，磷酸铝，硅酸镁及其组合。

7. 发明授权

US07442444B2 Bond coat for silicon-containing substrate for EBC and processes for preparing same 有权
标题翻译：用于EBC的含硅基材的粘合剂涂层及其制备方法
公开(公告)号：US07442444B2
公开(公告)日：2008-10-28
申请号：US11150098
申请日：2005-06-13
申请人： Brian Thomas Hazel , Irene Spitsberg , Brett Allen Boutwell
发明人： Brian Thomas Hazel , Irene Spitsberg , Brett Allen Boutwell
IPC分类号： B32B15/04 , B32B18/00 , F01D5/14
CPC分类号： C04B35/806 , C04B35/16 , C04B35/185 , C04B35/195 , C04B35/573 , C04B35/58085 , C04B35/584 , C04B35/62863 , C04B41/52 , C04B41/89 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3225 , C04B2235/3427 , C04B2235/3463 , C04B2235/3481 , C04B2235/5244 , C04B2235/5248 , C23C4/02 , C23C28/042 , C23C28/048 , C23C28/322 , C23C28/345 , C23C28/3455 , C23C28/36 , C23C30/00 , F01D5/288 , F05D2230/90 , F05D2260/95 , F05D2300/222 , F05D2300/611 , Y10T428/12611 , Y10T428/12674 , Y10T428/264 , C04B41/5071 , C04B41/53 , C04B41/0072 , C04B41/4558 , C04B41/5035 , C04B41/5024 , C04B41/5037 , C04B41/4529 , C04B41/5031 , C04B41/4527 , C04B41/5042 , C04B41/522
摘要： An article comprising a silicon-containing substrate, a silicide-containing bond coat layer overlying the substrate, and typically an environmental barrier coating overlaying the bond coat layer. An article is also provided wherein the environmental barrier coating comprises: (1) an optional inner silica scale layer overlaying the bond coat layer; (2) intermediate layer overlaying the inner silica scale layer, or the bond coat layer in the absence of the inner silica scale layer, and comprising mullite, or a combination of mullite with a barium strontium aluminosilicate, a yttrium silicate, or a calcium aluminosilicate; and (3) an outer steam-resistant barrier layer overlaying the intermediate layer and consisting essentially of an alkaline earth silicate/aluminosilicate. Processes are also provided for forming the silicide-containing bond coat layer over the substrate, followed by forming the environmental barrier coating over the bond coat layer.
摘要翻译：包括含硅基材，覆盖在基材上的含硅化物粘合涂层的物品，通常是覆盖粘合涂层的环境阻挡涂层。还提供了一种制品，其中所述环境保护涂层包括：（1）覆盖所述粘合涂层的任选的内部二氧化硅刻度层; （2）覆盖内部二氧化硅刻度层的中间层或不存在内部二氧化硅刻度层的粘合涂层，并且包含莫来石或莫来石与铝酸钡锶钡，硅酸钇或硅铝酸钙的组合 ; 和（3）覆盖中间层并基本上由碱土金属硅酸盐/硅铝酸盐组成的外部耐蒸汽阻挡层。还提供了用于在衬底上形成含硅化物粘合涂层的工艺，然后在粘合涂层上形成环境阻挡涂层。

8. 发明申请

US20080220172A1 Sintering resistant, low conductivity, high stability thermal barrier coating/environmental barrier coating system for a ceramic-matrix composite (CMC) article to improve high temperature capability 有权
公开(公告)号：US20080220172A1
公开(公告)日：2008-09-11
申请号：US11977336
申请日：2007-10-23
申请人： Brett Allen Rohrer Boutwell , Irene Spitsberg , Christine Govern , Bangalore A. Nagaraj , Brian Thomas Hazel
发明人： Brett Allen Rohrer Boutwell , Irene Spitsberg , Christine Govern , Bangalore A. Nagaraj , Brian Thomas Hazel
IPC分类号： B05D1/36
CPC分类号： C04B41/009 , C04B41/52 , C04B41/89 , C23C28/042 , F01D5/288 , F05D2230/90 , F05D2300/2118 , F05D2300/50211 , F05D2300/611 , C04B41/4527 , C04B41/5096 , C04B41/5024 , C04B41/5037 , C04B41/5042 , C04B41/5031 , C04B41/522 , C04B41/4529 , C04B35/565 , C04B35/584 , C04B35/806 , C04B35/597
摘要： In accordance with an embodiment of the invention, a thermal barrier coating (TBC) for inclusion in a thermal barrier coating/environmental barrier coating system (TBC/EBC system) for use on a silicon containing material substrate is provided. The TBC comprises a compound having a primary constituent portion and a stabilizer portion stabilizing said primary constituent. The primary constituent portion of the TBC comprises hafnia present in an amount of at least about 5 mol % of the primary constituent. The stabilizer portion of said thermal barrier coating comprises at least one metal oxide comprised of cations with a +2 or +3 valence present in the amount of about 10 to about 40 mol % of the thermal barrier coating.

9. 发明授权

US07364807B2 Thermal barrier coating/environmental barrier coating system for a ceramic-matrix composite (CMC) article to improve high temperature capability 有权
公开(公告)号：US07364807B2
公开(公告)日：2008-04-29
申请号：US11006292
申请日：2004-12-06
申请人： Brett Allen Rohrer Boutwell , Irene Spitsberg , Christine Govern , Bangalore A. Nagaraj , Brian Thomas Hazel , Ramgopal Darolia , Curtis Alan Johnson , Yan Gao , Mark Daniel Gorman
发明人： Brett Allen Rohrer Boutwell , Irene Spitsberg , Christine Govern , Bangalore A. Nagaraj , Brian Thomas Hazel , Ramgopal Darolia , Curtis Alan Johnson , Yan Gao , Mark Daniel Gorman
IPC分类号： B32B15/04 , B32B18/00
CPC分类号： C04B41/009 , C04B41/52 , C04B41/89 , C04B2111/0025 , C23C28/042 , C23C28/322 , C23C28/345 , C23C28/3455 , F01D5/288 , F05D2230/90 , F05D2300/2118 , F05D2300/50211 , F05D2300/611 , C04B41/4527 , C04B41/5096 , C04B41/5035 , C04B41/522 , C04B41/5024 , C04B41/5037 , C04B41/5031 , C04B41/5042 , C04B41/5044 , C04B41/4529 , C04B35/565 , C04B35/584 , C04B35/806
摘要： In accordance with an embodiment of the invention, an article is provided. The article comprises a substrate comprised of silicon containing material, an environmental barrier coating (EBC) overlying the substrate and a thermal barrier coating (TBC) on the environmental barrier coating. The thermal barrier coating comprising a compound having a rhombohedral phase.

10. 发明授权

US07357994B2 Thermal/environmental barrier coating system for silicon-containing materials 有权
标题翻译：含硅材料的热/环境屏障涂层系统
公开(公告)号：US07357994B2
公开(公告)日：2008-04-15
申请号：US11160212
申请日：2005-06-14
申请人： Brian Thomas Hazel , Irene Spitsberg
发明人： Brian Thomas Hazel , Irene Spitsberg
IPC分类号： B32B9/04
CPC分类号： C04B41/89 , C04B41/009 , C04B41/52 , C04B2111/00405 , C09D1/00 , C09D5/18 , C23C28/042 , C23C28/048 , C23C28/324 , C23C28/34 , C23C28/341 , C23C28/345 , C23C28/3455 , C23C28/36 , C04B41/4527 , C04B41/5096 , C04B41/5024 , C04B41/5037 , C04B41/5032 , C04B41/5042 , C04B41/4529 , C04B41/522 , C04B35/565 , C04B35/584 , C04B35/806
摘要： A coating system for Si-containing materials, particularly those for articles exposed to high temperatures. The coating system exhibits improved resistance to corrosion from sea salt and CMAS as a result of using aluminate compounds to protect silicate-containing layers of the coating system. The coating system includes an environmental barrier coating, a thermal barrier coating overlying the environmental barrier coating and formed of a thermal-insulating material, and a transition layer between the environmental barrier coating and thermal barrier coating, wherein the transition layer contains at least one aluminate compound and/or alumina.
摘要翻译：用于含Si材料的涂层系统，特别是用于暴露于高温的制品。由于使用铝酸盐化合物来保护涂层体系中的含硅酸盐层，涂层体系表现出对海盐和CMAS的耐腐蚀性的改善。涂层系统包括环境屏障涂层，覆盖环境屏障涂层并由绝热材料形成的热障涂层，以及环境阻隔涂层和热障涂层之间的过渡层，其中过渡层包含至少一种铝酸盐化合物和/或氧化铝。

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