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    • 4. 发明授权
    • Use of polycationic condensates as color transfer inhibiting and color release reducing additive to detergents and fabric conditioners
    • 使用聚阳离子缩合物作为颜色转移抑制和减色添加剂到洗涤剂和织物调理剂
    • US06465415B2
    • 2002-10-15
    • US09833623
    • 2001-04-13
    • Dieter BoeckhHans-Ulrich JägerJürgen Alfred Lux
    • Dieter BoeckhHans-Ulrich JägerJürgen Alfred Lux
    • C11D337
    • C11D3/37C11D3/0021C11D3/3723C11D3/3776
    • Polycationic condensates obtainable by condensing (a) piperazine, 1-alkylpiperazines having 1 to 25 carbon atoms in the alkyl group, 1,4-dialkylpiperazines having 1 to 25 carbon atoms in the alkyl group, 1,4-bis(3-aminopropyl)piperazine, 1-(2-aminoethyl)piperazine, 1-(2-hydroxyalkyl)piperazines having 2 to 25 carbon atoms in the alkyl group, imidazole, C1-C25-alkylimidazoles or mixtures of said compounds with (b) alkylene dihalides, epihalohydrins and/or bisepoxides in the molar ratio from 1:0.8 to 1:1.1 and, where appropriate, quaternization of the condensates with C4-C25-alkylating agents or by heating triethanolamine or triisopropanolamine in the presence of acidic catalysts and quaternizing the condensates with C4-C25-alkylating agents as color-fixing additive to detergents and fabric conditioners, and detergents which comprise (i) 1-50% by weight of at least one nonionic surfactant, (ii) 0-4.0% by weight of an anionic surfactant and (iii) 0.05-2.5% by weight of the polycationic condensate are used as color transfer inhibiting and color release reducing additive, and fabric conditioners which comprise a fabric softener, a nonionic surfactant and 0.1-2.5% by weight of said polycationic condensates.
    • 通过缩合(a)在烷基中具有1至25个碳原子的哌嗪,1-烷基哌嗪,在烷基中具有1至25个碳原子的1,4-二烷基哌嗪,1,4-双(3-氨基丙基) 哌嗪,1-(2-氨基乙基)哌嗪,烷基中具有2至25个碳原子的1-(2-羟基烷基)哌嗪,咪唑,C 1 -C 25烷基咪唑或所述化合物与(b)亚烷基二卤化物的混合物,表卤代醇 和/或双过氧化物,摩尔比为1:0.8至1:1.1,并且在适当时,缩合物与C 4 -C 25烷基化剂季铵化,或通过在酸性催化剂存在下加热三乙醇胺或三异丙醇胺,并用C4- C25烷基化剂作为洗涤剂和织物调理剂的着色添加剂,以及洗涤剂,其包含(i)1-50重量%的至少一种非离子表面活性剂,(ii)0-4.0重量%的阴离子表面活性剂和( iii)0.05-2.5重量%的聚阳离子冷凝物 用作转色抑制和减色添加剂的红茶,以及包含织物柔软剂,非离子表面活性剂和0.1-2.5重量%的所述聚阳离子缩合物的织物调理剂。
    • 5. 发明授权
    • Polycationic condensates as color transfer inhibiting and color release reducing additive to detergents and fabric conditioners
    • 聚阳离子缩合物作为转印抑制剂和减色添加剂到洗涤剂和织物调理剂中
    • US06262011B1
    • 2001-07-17
    • US09467239
    • 1999-12-20
    • Dieter BoeckhHans-Ulrich JägerJürgen Alfred Lux
    • Dieter BoeckhHans-Ulrich JägerJürgen Alfred Lux
    • C11D337
    • C11D3/37C11D3/0021C11D3/3723C11D3/3776
    • Polycationic condensates obtainable by condensing (a) piperazine, 1-alkylpiperazines having 1 to 25 carbon atoms in the alkyl group, 1,4-dialkylpiperazines having 1 to 25 carbon atoms in the alkyl group, l,4-bis(3-aminopropyl)piperazine, 1-(2-aminoethyl)piperazine, 1-(2-hydroxyalkyl)piperazines having 2 to 25 carbon atoms in the alkyl group, imidazole, C1-C25-alkylimidazoles or mixtures of said compounds with (b) alkylene dihalides, epihalohydrins and/or bisepoxides in the molar ratio from 1:0.8 to 1:1.1 and, where appropriate, quaternization of the condensates with C4-C25-alkylating agents or by heating triethanolamine or triisopropanolamine in the presence of acidic catalysts and quaternizing the condensates with C4-C25-alkylating agents as color-fixing additive to detergents and fabric conditioners, and detergents which comprise (i) 1-50% by weight of at least one nonionic surfactant, (ii) 0-4.0% by weight of an anionic surfactant and (iii) 0.05-2.5% by weight of the polycationic condensate are used as color transfer inhibiting and color release reducing additive, and fabric conditioners which comprise a fabric softener, a nonionic surfactant and 0.1-2.5% by weight of said polycationic condensates.
    • 通过缩合(a)在烷基中具有1至25个碳原子的哌嗪,1-烷基哌嗪,在烷基中具有1至25个碳原子的1,4-二烷基哌嗪,1,4-双(3-氨基丙基) 哌嗪,1-(2-氨基乙基)哌嗪,烷基中具有2至25个碳原子的1-(2-羟基烷基)哌嗪,咪唑,C 1 -C 25烷基咪唑或所述化合物与(b)亚烷基二卤化物的混合物,表卤代醇 和/或双过氧化物,摩尔比为1:0.8至1:1.1,并且在适当的情况下,缩合物与C 4 -C 25烷基化剂季铵化,或在酸性催化剂存在下加热三乙醇胺或三异丙醇胺,并用C4- C25烷基化剂作为洗涤剂和织物调理剂的着色添加剂,以及洗涤剂,其包含(i)1-50重量%的至少一种非离子表面活性剂,(ii)0-4.0重量%的阴离子表面活性剂和( iii)0.05-2.5重量%的聚阳离子冷凝物 用作转色抑制和减色添加剂的红茶,以及包含织物柔软剂,非离子表面活性剂和0.1-2.5重量%的所述聚阳离子缩合物的织物调理剂。