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1. 发明申请

US20130296450A1 METHOD FOR PRODUCING POLYETHER CARBONATE POLYOLS HAVING PRIMARY HYDROXYL END GROUPS AND POLYURETHANE POLYMERS PRODUCED THEREFROM 审中-公开
标题翻译：生产具有主要羟基末端基团的聚碳酸酯多元醇的方法和由其生产的聚氨酯聚合物
公开(公告)号：US20130296450A1
公开(公告)日：2013-11-07
申请号：US13994449
申请日：2011-12-12
申请人： Jörg Hofmann , Christoph Gürtler , Hartmut Nefzger , Norbert Hahn , Klaus Lorenz , Thomas Ernst Müller
发明人： Jörg Hofmann , Christoph Gürtler , Hartmut Nefzger , Norbert Hahn , Klaus Lorenz , Thomas Ernst Müller
IPC分类号： C08G64/34 , C08G18/48 , C08G64/02
CPC分类号： C08G64/34 , C08G18/4018 , C08G18/4261 , C08G18/44 , C08G18/4887 , C08G64/0208 , C08G64/183 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols with primary hydroxyl end groups, comprising the steps of reaction of a starter compound containing active hydrogen atoms with an epoxide and carbon dioxide under double metal cyanide catalysis, reaction of the product obtained with a cyclic carboxylic acid anhydride and reaction of this product obtained with ethylene oxide in the presence of a catalyst which contains at least one nitrogen atom per molecule, excluding non-cyclic tertiary amines with identical substituents. The invention furthermore relates to polyether carbonate polyols obtainable by this process, compositions comprising these polyether carbonate polyols and polyurethane polymers based on these polyether carbonate polyols.
摘要翻译：本发明涉及一种制备具有伯羟基端基的聚醚碳酸酯多元醇的方法，包括在双金属氰化物催化下使含有活性氢原子的起始化合物与环氧化物和二氧化碳反应的步骤，所得产物的反应与环状羧酸酐反应，并在每分子含有至少一个氮原子的催化剂存在下，与环氧乙烷反应，除去具有相同取代基的非环状叔胺。本发明还涉及通过该方法获得的聚醚碳酸酯多元醇，包含这些聚醚碳酸酯多元醇和基于这些聚醚碳酸酯多元醇的聚氨酯聚合物的组合物。

2. 发明授权

US09249259B2 Method for activating double metal cyanide catalysts for producing polyether polyols 有权
标题翻译：活化用于制备聚醚多元醇的双金属氰化物催化剂的方法
公开(公告)号：US09249259B2
公开(公告)日：2016-02-02
申请号：US14232015
申请日：2012-07-17
申请人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
发明人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
IPC分类号： C08G64/32 , C08G64/34 , C08G65/26 , C08G64/00 , C07C68/04
CPC分类号： C08G64/323 , C08G64/34 , C08G65/2603 , C08G65/2663
摘要： The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts and to a process for the preparation of polyethercarbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, characterized in that (α) (α1) the DMC catalyst and one or more H-functional starter compounds are placed in a reactor, (α2) an inert gas, an inert gas/carbon dioxide mixture or carbon dioxide is passed through the reactor at a temperature of 50 to 200° C. and at the same time a reduced pressure (absolute) of 10 mbar to 800 mbar is established in the reactor by removal of the inert gas or carbon dioxide, (β) under an atmosphere of inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, alkylene oxide is added to the mixture from step (α) at temperatures of 50 to 200° C., and (γ) one or more alkylene oxides and carbon dioxide are metered into the mixture resulting from step (β).
摘要翻译：本发明涉及一种活化双金属氰化物（DMC）催化剂的方法，以及一种由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳在存在下制备聚醚碳酸酯多元醇的方法一种双金属氰化物催化剂，其特征在于将（α）（α1）DMC催化剂和一种或多种H官能起始化合物置于反应器中，（α2）惰性气体，惰性气体/二氧化碳混合物或二氧化碳在50至200℃的温度下通过反应器，同时通过除去惰性气体或二氧化碳，在反应器中建立10毫巴至800毫巴的减压（绝对）（绝对）。）在惰性气体/二氧化碳混合物的气氛下或在纯二氧化碳气氛下，在步骤（α）的混合物中，在50〜200℃的温度下加入环氧烷，（γ）一种或多种环氧烷烃并将二氧化碳计量加入由（步骤（bgr））产生的混合物。

3. 发明授权

US09120894B2 Method for producing polyether polyols 有权
标题翻译：聚醚多元醇的制备方法
公开(公告)号：US09120894B2
公开(公告)日：2015-09-01
申请号：US14131977
申请日：2012-07-17
申请人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
发明人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
IPC分类号： C08G85/00 , C08G65/00 , C08G65/26 , C08G64/34
CPC分类号： C08G65/2663 , C08G64/34 , C08G65/2603
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, wherein (α) the H-functional starter substance or a mixture of at least two H-functional starter substances is initially introduced into the reaction vessel, (β) for the activation, a part amount (based on the total amount of the amount of alkylene oxides employed in steps (β) and (γ)) of one or more alkylene oxides is added to the mixture resulting from step (α), it also being possible for step (β) to be carried out several times for the activation, (γ) one or more alkylene oxides and carbon dioxide are metered continuously into the mixture resulting from step (β) (“copolymerization”), the alkylene oxides employed for the copolymerization being identical to or different from the alkylene oxides employed in step (β), characterized in that in step (γ) the carbon dioxide is passed into the mixture by (i) gassing the reaction mixture in the reactor from the bottom, (ii) using a hollow shaft stirrer, (iii) a combination of the metering operations according to (i) and (ii), and/or (iv) gassing over the surface of the liquid by using stirrer units configured in several stages.
摘要翻译：本发明涉及在双金属氰化物催化剂存在下由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法，其中（α）H官能团起始物质或至少两种H功能性起始物质的混合物最初被引入反应容器（（bgr））中用于活化，部分量（基于步骤（bgr）中使用的环氧烷烃的总量（γ））和（γ））加入到由步骤（α）得到的混合物中，对于活化，（γ）一个或多个步骤（＆bgr）可以进行几次，更多的环氧烷和二氧化碳被连续地计量到由步骤（（bgr））（“共聚”）得到的混合物中，用于共聚的烯化氧与步骤（bgr）中使用的环氧烷烃相同或不同，其特征在于在步骤（γ）中，二氧化碳通过以下步骤进入混合物：（i）从底部将反应混合物放入反应器中，（ii）使用中空轴搅拌器，（iii）根据至（i）和（ii），和/或（iv）通过使用在几个阶段中配置的搅拌器单元在液体的表面上放气。

4. 发明申请

US20140228537A1 METHOD FOR ACTIVATING DOUBLE METAL CYANIDE CATALYSTS FOR PRODUCING POLYETHER POLYOLS 有权
标题翻译：用于生产聚醚多元醇的双金属氰化物催化剂的活化方法
公开(公告)号：US20140228537A1
公开(公告)日：2014-08-14
申请号：US14232015
申请日：2012-07-17
申请人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
发明人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
IPC分类号： C08G64/32
CPC分类号： C08G64/323 , C08G64/34 , C08G65/2603 , C08G65/2663
摘要： The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts and to a process for the preparation of polyethercarbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, characterized in that (α) (α1) the DMC catalyst and one or more H-functional starter compounds are placed in a reactor, (α2) an inert gas, an inert gas/carbon dioxide mixture or carbon dioxide is passed through the reactor at a temperature of 50 to 200° C. and at the same time a reduced pressure (absolute) of 10 mbar to 800 mbar is established in the reactor by removal of the inert gas or carbon dioxide, (β) under an atmosphere of inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, alkylene oxide is added to the mixture from step (α) at temperatures of 50 to 200° C., and (γ) one or more alkylene oxides and carbon dioxide are metered into the mixture resulting from step (β).
摘要翻译：本发明涉及一种活化双金属氰化物（DMC）催化剂的方法，以及一种由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳在存在下制备聚醚碳酸酯多元醇的方法一种双金属氰化物催化剂，其特征在于将（α）（α1）DMC催化剂和一种或多种H官能起始化合物置于反应器中，（α2）惰性气体，惰性气体/二氧化碳混合物或二氧化碳在50至200℃的温度下通过反应器，同时通过除去惰性气体或二氧化碳，在反应器中建立10毫巴至800毫巴的减压（绝对）（绝对）。）在惰性气体/二氧化碳混合物的气氛下或在纯二氧化碳气氛下，在步骤（α）的混合物中，在50〜200℃的温度下加入环氧烷，（γ）一种或多种环氧烷烃并将二氧化碳计量加入由（步骤（bgr））产生的混合物。

5. 发明授权

US09382417B2 Process for the preparation of polyether carbonate polyols 有权
标题翻译：制备聚醚碳酸酯多元醇的方法
公开(公告)号：US09382417B2
公开(公告)日：2016-07-05
申请号：US13636509
申请日：2011-03-24
申请人： Christoph Gürtler , Jörg Hofmann , Thomas Ernst Müller , Aurel Wolf , Stefan Grasser , Burkhard Köhler
发明人： Christoph Gürtler , Jörg Hofmann , Thomas Ernst Müller , Aurel Wolf , Stefan Grasser , Burkhard Köhler
IPC分类号： C08L69/00 , C08K5/13 , C08K5/47 , C08K5/32 , C08G65/26 , C08K5/3435 , C08K5/357 , C08K5/46
CPC分类号： C08L69/00 , C08G65/2603 , C08G65/2663 , C08K5/13 , C08K5/32 , C08K5/3435 , C08K5/357 , C08K5/46 , C08K5/47
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of additives A) chosen from the group consisting of sterically non-hindered phenols, catechols, pyrocatechols, thiazines, phenothiazines, thiazoles, benzothiazoles, oxazines, phenoxazines, 2,2,6,6-tetramethylpiperidine 1-oxyl and nitrostyrenes and optionally in the presence of metal salts B).
摘要翻译：本发明涉及一种通过在双金属氰化物（DMC）催化剂的帮助下，在一种或多种H官能起始物质存在下，通过二氧化碳（CO 2）与环氧烷的催化共聚制备聚醚碳酸酯多元醇的方法，在添加剂A）的存在下，选自空间非受阻酚，儿茶酚，邻苯二酚，噻嗪，吩噻嗪，噻唑，苯并噻唑，吩嗪，吩恶嗪，2,2,6,6-四甲基哌啶1-氧基和硝基苯乙烯，以及任选地在金属盐B）的存在下。

6. 发明申请

US20130072602A1 PROCESS FOR THE PREPARATION OF POLYETHER CARBONATE POLYOLS 有权
标题翻译：制备聚碳酸酯多元醇的方法
公开(公告)号：US20130072602A1
公开(公告)日：2013-03-21
申请号：US13636509
申请日：2011-03-24
申请人： Christoph Gürtler , Jörg Hofmann , Thomas Ernst Müller , Aurel Wolf , Stefan Grasser , Burkhard Köhler
发明人： Christoph Gürtler , Jörg Hofmann , Thomas Ernst Müller , Aurel Wolf , Stefan Grasser , Burkhard Köhler
IPC分类号： C08L69/00 , C08K5/13 , C08K5/47 , C08K5/357 , C08K5/3435 , C08K5/32 , C08K5/46
CPC分类号： C08L69/00 , C08G65/2603 , C08G65/2663 , C08K5/13 , C08K5/32 , C08K5/3435 , C08K5/357 , C08K5/46 , C08K5/47
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances with the aid of double metal cyanide (DMC) catalysts and in the presence of additives A) chosen from the group consisting of sterically non-hindered phenols, catechols, pyrocatechols, thiazines, phenothiazines, thiazoles, benzothiazoles, oxazines, phenoxazines, 2,2,6,6-tetramethylpiperidine 1-oxyl and nitrostyrenes and optionally in the presence of metal salts B).
摘要翻译：本发明涉及一种通过在双金属氰化物（DMC）催化剂的帮助下，在一种或多种H官能起始物质存在下，通过二氧化碳（CO 2）与环氧烷的催化共聚制备聚醚碳酸酯多元醇的方法，在添加剂A）的存在下，选自空间非受阻酚，儿茶酚，邻苯二酚，噻嗪，吩噻嗪，噻唑，苯并噻唑，吩嗪，吩恶嗪，2,2,6,6-四甲基哌啶1-氧基和硝基苯乙烯，以及任选地在金属盐B）的存在下。

7. 发明申请

US20140155559A1 METHOD FOR PRODUCING POLYETHER POLYOLS 有权
标题翻译：生产聚醚多元醇的方法
公开(公告)号：US20140155559A1
公开(公告)日：2014-06-05
申请号：US14131977
申请日：2012-07-17
申请人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
发明人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
IPC分类号： C08G65/26
CPC分类号： C08G65/2663 , C08G64/34 , C08G65/2603
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, wherein (α) the H-functional starter substance or a mixture of at least two H-functional starter substances is initially introduced into the reaction vessel, (β) for the activation, a part amount (based on the total amount of the amount of alkylene oxides employed in steps (β) and (γ)) of one or more alkylene oxides is added to the mixture resulting from step (α), it also being possible for step (β) to be carried out several times for the activation, (γ) one or more alkylene oxides and carbon dioxide are metered continuously into the mixture resulting from step (β) (“copolymerization”), the alkylene oxides employed for the copolymerization being identical to or different from the alkylene oxides employed in step (β), characterized in that in step (γ) the carbon dioxide is passed into the mixture by (i) gassing the reaction mixture in the reactor from the bottom, (ii) using a hollow shaft stirrer, (iii) a combination of the metering operations according to (i) and (ii), and/or (iv) gassing over the surface of the liquid by using stirrer units configured in several stages.
摘要翻译：本发明涉及在双金属氰化物催化剂存在下由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法，其中（α）H官能团起始物质或至少两种H功能性起始物质的混合物最初被引入反应容器（（bgr））中用于活化，部分量（基于步骤（bgr）中使用的环氧烷烃的总量（γ））和（γ））加入到由步骤（α）得到的混合物中，对于活化，（γ）一个或多个步骤（＆bgr）可以进行几次，更多的环氧烷和二氧化碳被连续地计量到由步骤（（bgr））（“共聚”）得到的混合物中，用于共聚的烯化氧与步骤（bgr）中使用的环氧烷烃相同或不同，其特征在于在步骤（γ）中，二氧化碳通过以下步骤进入混合物：（i）从底部将反应混合物放入反应器中，（ii）使用中空轴搅拌器，（iii）根据至（i）和（ii），和/或（iv）通过使用在几个阶段中配置的搅拌器单元在液体的表面上放气。

8. 发明申请

US20140221602A1 METHOD FOR ACTIVATING DOUBLE METAL CYANIDE CATALYSTS FOR THE PRODUCTION OF POLYETHER CARBONATE POLYOLS 有权
标题翻译：用于生产聚碳酸酯多元醇的双金属氰化物催化剂的活化方法
公开(公告)号：US20140221602A1
公开(公告)日：2014-08-07
申请号：US14232633
申请日：2012-07-16
申请人： Thomas Ernst Müller , Christoph Gürtler , Yvonne Dienes , Julien Barruet , Burkhard Köhler , Walter Leitner
发明人： Thomas Ernst Müller , Christoph Gürtler , Yvonne Dienes , Julien Barruet , Burkhard Köhler , Walter Leitner
IPC分类号： C08G64/32
CPC分类号： C08G64/323 , C08G64/34 , C08G65/2603 , C08G65/2663
摘要： The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts with heterocumulenes for the preparation of polyether carbonate polyols by catalytic copolymerization of carbon dioxide (CO2) with alkylene oxides in the presence of one or more H-functional starter substances, and to a process for the preparation of polyether carbonate polyols from one or more H-functional starter substances, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, characterized in that (α) under an inert gas atmosphere, under an atmosphere of an inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, at temperatures of from 90 to 150° C., the DMC catalyst is mixed with a heterocumulene and H-functional starter substance, (β) alkylene oxide is added at temperatures of from 100 to 150° C. to the mixture from step (α) under an inert gas atmosphere, under an atmosphere of an inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, and (γ) one or more alkylene oxides and carbon dioxide are metered continuously into the mixture resulting from step (β).
摘要翻译：本发明涉及一种用于通过在一种或多种H功能性起始剂存在下通过二氧化碳（CO 2）与氧化烯的催化共聚来制备聚醚碳酸酯多元醇的异氰脲酸双金属氰化物（DMC）催化剂的活化方法以及在双金属氰化物催化剂存在下从一种或多种H官能起始物质，一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法，其特征在于（α）在惰性气体气氛中，在惰性气体/二氧化碳混合气氛下或在纯二氧化碳气氛下，在90〜150℃的温度下，将DMC催化剂与杂多烯和H官能起始物质（＆bgr ;）在惰性气体气氛下，在惰性气体/二氧化碳气氛下，将氧化烯在100至150℃的温度下加入步骤（α）的混合物中或者在纯二氧化碳气氛下，将（γ）一种或多种烯化氧和二氧化碳连续计量到由步骤（bgr）得到的混合物中。

9. 发明申请

US20120148478A1 PROCESS FOR THE PREPARATION OF CHLORINE BY GAS PHASE OXIDATION ON NANOSTRUCTURED SUPPORTED RUTHENIUM CATALYSTS 审中-公开
标题翻译：通过气相氧化在纳米结构支持的钌催化剂上制备氯的方法
公开(公告)号：US20120148478A1
公开(公告)日：2012-06-14
申请号：US13384792
申请日：2010-07-14
申请人： Timm Schmidt , Christoph Gürtler , Jürgen Kintrup , Thomas Ernst Müller , Tim Loddenkemper , Frank Gerhartz , Walther Müller
发明人： Timm Schmidt , Christoph Gürtler , Jürgen Kintrup , Thomas Ernst Müller , Tim Loddenkemper , Frank Gerhartz , Walther Müller
IPC分类号： C01B7/04 , B01J35/10 , B01J21/02 , B01J21/06 , B01J23/62 , B01J23/14 , B01J27/13 , B01J23/89 , B01J23/755 , B01J23/18 , B01J23/644 , B01J37/08 , B01J23/46 , B82Y30/00 , B82Y40/00
CPC分类号： C01B7/04 , B01J21/12 , B01J23/462 , B01J23/626 , B01J23/63 , B01J23/6445 , B01J23/6447 , B01J23/892 , B01J35/0013 , B01J35/006 , B01J35/023 , B01J35/04 , B01J35/1014 , B01J35/1042 , B01J35/108 , B01J37/0203 , B01J37/0211 , B01J37/349
摘要： The present invention relates to a process for the preparation of chlorine by gas phase oxidation using a supported catalyst based on ruthenium, characterised in that the catalyst support has a plurality of pores having a pore diameter>50 nm and carries nanoparticles containing ruthenium and/or ruthenium compounds as catalytically active components.
摘要翻译：本发明涉及一种使用基于钌的负载型催化剂通过气相氧化制备氯的方法，其特征在于催化剂载体具有多个孔径> 50nm的孔，并载有含钌和/或钌化合物作为催化活性组分。

10. 发明授权

US08987446B2 Bimetallic complexes and the use thereof in producing diaryl carbonate 有权
标题翻译：双金属络合物及其在制备碳酸二芳酯中的用途
公开(公告)号：US08987446B2
公开(公告)日：2015-03-24
申请号：US13515710
申请日：2010-12-09
申请人： Christoph Gürtler , Thomas Ernst Müller , Pieter Ooms , Johann Rechner , Friedhelm Risse , Angelina Prokofieva , Franco Doro , Burkhard Köhler , Walter Leitner , Aurel Wolf
发明人： Christoph Gürtler , Thomas Ernst Müller , Pieter Ooms , Johann Rechner , Friedhelm Risse , Angelina Prokofieva , Franco Doro , Burkhard Köhler , Walter Leitner , Aurel Wolf
IPC分类号： C07D241/46 , C07F15/00 , C07C68/00
CPC分类号： C07F15/0066 , C07C68/005 , C07C69/96
摘要： The invention relates to bimetallic complexes in which the ligand contains a salophen unit which complexes copper, manganese or cobalt and a phenanthroline unit which complexes palladium and the two systems are linked by a continuous conjugated system. The invention further relates to the use of these bimetallic complexes as catalysts for the oxidative carbonylation of aromatic hydroxy compounds to form diaryl carbonates, a process for preparing diaryl carbonates using the bimetallic complex as catalyst and also diaryl carbonates prepared by oxidative carbonylation of aromatic hydroxy compounds using the bimetallic complexes of the invention as catalysts.
摘要翻译：本发明涉及双金属络合物，其中配体包含络合铜，锰或钴的盐酸单体和络合钯并且两种体系通过连续共轭体系连接的菲咯啉单元。本发明还涉及这些双金属络合物作为用于芳族羟基化合物的氧化羰基化以形成碳酸二芳基酯的催化剂的使用，使用双金属络合物作为催化剂制备碳酸二芳基酯的方法，以及通过芳族羟基化合物的氧化羰基化制备的碳酸二芳基酯使用本发明的双金属络合物作为催化剂。

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