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1. 发明授权

US5051111A Whitener dispersion 失效
标题翻译：增白剂分散体
公开(公告)号：US5051111A
公开(公告)日：1991-09-24
申请号：US275231
申请日：1988-11-22
申请人： Italo Anceschi , Werner Fringeli , Martin Jollenbeck , Georges Mahler , Willy Schurings
发明人： Italo Anceschi , Werner Fringeli , Martin Jollenbeck , Georges Mahler , Willy Schurings
IPC分类号： C09B57/00 , C09B57/02 , C09B67/20 , C09B67/22 , D06L3/12
CPC分类号： D06L3/1264 , D06L3/125 , Y10S8/922
摘要： There are disclosed aqueous dispersions comprising water-insoluble or sparingly soluble fluorescent whitening agents, water-soluble fluorescent whitening agents, dispersants, optional solubilizers, further optional assistants and a copolymer of 2-vinylpyrrolidone and 3-vinylpropionic acid, their preparation and the use thereof for whitening polyester/cellulose fiber material. These novel dispersions are storage-stable and temperature-stable.
摘要翻译：公开了包含水不溶性或微溶性荧光增白剂，水溶性荧光增白剂，分散剂，任选的增溶剂，其它任选助剂和2-乙烯基吡咯烷酮和3-乙烯基丙酸的共聚物的水分散体，其制备及其用途用于增白聚酯/纤维素纤维材料。这些新型分散体是储存稳定和温度稳定的。

2. 发明授权

US5053055A Whitener dispersion 失效
标题翻译：白色分散
公开(公告)号：US5053055A
公开(公告)日：1991-10-01
申请号：US275236
申请日：1988-11-22
申请人： Werner Fringeli , Martin Jollenbeck
发明人： Werner Fringeli , Martin Jollenbeck
IPC分类号： C09B57/00 , C09B57/02 , C09B57/08 , C09K11/06 , D06L3/12 , E21B43/247
CPC分类号： E21B43/247 , D06L3/125 , D06L3/1264 , Y10S8/922
摘要： There are disclosed aqueous dispersions comprising water-insoluble or sparingly soluble fluorescent whitening agents, dispersants, further optional assistants and a copolymer of 2-vinylpyrrolidone and 3-vinylpropionic acid, their preparation and the use thereof for whitening textile fibre materials. These novel dispersions are storage-stable.
摘要翻译：公开了包含水不溶性或微溶性荧光增白剂，分散剂，其它任选的助剂和2-乙烯基吡咯烷酮和3-乙烯基丙酸的共聚物的水分散体，它们的制备及其用于增白织物纤维材料的用途。这些新型分散体是储存稳定的。

3. 发明授权

US5009669A Aqueous dispensions of 2-(2'-hydroxyphenyl)benzotriazoles 失效
标题翻译： 2-（2'-羟基苯基）苯并三唑的水分散体
公开(公告)号：US5009669A
公开(公告)日：1991-04-23
申请号：US358910
申请日：1989-05-30
申请人： Martin Jollenbeck , Hans-Ulrich Berendt , Werner Fringeli
发明人： Martin Jollenbeck , Hans-Ulrich Berendt , Werner Fringeli
IPC分类号： C09K3/00 , C09K15/30 , D06P1/642
CPC分类号： C09K15/30 , D06P1/6426 , Y10S8/90
摘要： Aqueous stable dispersion of UV-absorbing 2-(2'-hydroxyphenyl)benzotriazole compounds containing(a) 15 to 50 per cent by weight of a benzotriazole compound of the formula ##STR1## where R is halogen, C.sub.1 -C.sub.12 alkyl, lower alkoxy, lower alkoxycarbonyl, cycloalkyl, aryl, C.sub.1 -C.sub.12 alkylaryl or aralkyl, and the rings A and B can be further substituted independently of one another by halogen, hydroxyl, lower alkyl, lower alkoxy or lower alkoxycarbonyl, and(b) 2 to 20 per cent by weight of an acid ester, or salt thereof, of an alkylene oxide adduct of the formula ##STR2## where X is the acid radical of an inorganic oxygen-containing acid, or else the radical of an organic acid and Y is C.sub.1 -C.sub.12 alkyl, aryl or aralkyl, "Alkylen" is the ethylene radical or propylene radical, and m is from 1 to 4 and n from 4 to 50.These dispersions are excellent agents for improving the light fastness of dyeings of synthetic fibres, in particular polyester fibres or acid-modified polyester fibres.
摘要翻译：含有（a）15至50重量％的下式的苯并三唑化合物（1）的UV-吸收的2-（2'-羟基苯基）苯并三唑化合物的水性稳定分散体其中R是卤素，C 1 -C 12烷基，低级烷氧基，低级烷氧基羰基，环烷基，芳基，C 1 -C 12烷基芳基或芳烷基，并且环A和B可以被卤素，羟基，低级烷基，低级烷氧基或低级烷氧基羰基彼此独立地取代，和（b）2至 20重量％的式（2）的烯化氧加成物的酸酯或其盐，其中X是无机含氧酸的酸根，或有机酸的基团 Y为C1-C12烷基，芳基或芳烷基，“烷基”为亚乙基或丙烯基，m为1至4，n为4至50.这些分散体是提高合成染色剂耐光性的优良剂纤维，特别是聚酯纤维或酸改性聚酯纤维。

4. 发明授权

US5518657A Storage-stable formulation of fluorescent whitening mixtures 失效
标题翻译：储存稳定的荧光增白剂配方
公开(公告)号：US5518657A
公开(公告)日：1996-05-21
申请号：US278708
申请日：1994-07-22
申请人： Werner Fringeli , Josef Zelger
发明人： Werner Fringeli , Josef Zelger
IPC分类号： C07D251/54 , C07C309/32 , C07C309/39 , C09B67/46 , C11D3/42 , D06L3/12 , C09K11/06
CPC分类号： D06L3/1214 , C11D3/42 , D06L3/1264
摘要： Storage-stable formulations of whitening mixtures comprising at least two anionic fluorescent whiteners, which preferably contain at least one sulfonic acid radical; an anionic polysaccharide; dispersants and water, and if appropriate auxiliaries. These formulations are particularly suitable for the preparation of liquid washing agents.
摘要翻译：含有至少两种阴离子荧光增白剂的美白混合物的储存稳定配方，其优选含有至少一个磺酸基; 阴离子多糖; 分散剂和水，以及适当的助剂。这些制剂特别适用于制备液体洗涤剂。

5. 发明授权

US5423905A Moth- and beetle-proofing formulation 失效
标题翻译：蛾类和防甲虫制剂
公开(公告)号：US5423905A
公开(公告)日：1995-06-13
申请号：US276282
申请日：1994-07-18
申请人： Werner Fringeli
发明人： Werner Fringeli
IPC分类号： A01N31/02 , A01N47/30 , C14C9/00 , D06M16/00 , A01N47/28 , C09D5/00
CPC分类号： D06M16/006 , A01N47/30 , C14C9/00
摘要： The invention relates to a formulation for protecting keratinous material from attack by pests that feed on keratin, comprising (A) at least one diphenylurea of formula ##STR1## wherein R.sub.1 is hydrogen or 4-chlorophenoxy-6-sulfonate,R.sub.2 is hydrogen or chloro,R.sub.3 is chloro or trifluoromethyl,R.sub.4 is hydrogen or chloro, andR.sub.5 is hydrogen or trifluoromethyl, and(B) at least one glycol, and to a process for protecting keratinous material against attack by pests that feed on keratin with the novel formulation.
摘要翻译：本发明涉及一种用于保护角质材料免于受角蛋白侵袭的害虫的制剂，其包含（A）至少一种式（1）的二苯基脲，其中R1是氢或4-氯苯氧基-6-磺酸盐，R2是氢或氯，R 3是氯或三氟甲基，R 4是氢或氯，R 5是氢或三氟甲基，和（B）至少一种二醇，以及保护角质材料免受害虫攻击的方法，新颖的配方。

6. 发明授权

US4605511A Stable stilbene fluorescent brightener solution 失效
标题翻译：稳定的芪类荧光增白剂溶液
公开(公告)号：US4605511A
公开(公告)日：1986-08-12
申请号：US397273
申请日：1982-07-12
申请人： Werner Fringeli
发明人： Werner Fringeli
IPC分类号： C09B67/44 , C09B69/04 , D06L3/12 , C09K11/06
CPC分类号： D06L3/1264 , C09B69/04
摘要： Stilbene fluorescent brightener solutions which are stable to metal ions and metal catalysts and contain a stilbene fluorescent brightener substituted by sulfo groups and a fatty amine oxyalkylation product of the formula ##STR1## in which Q is an aliphatic hydrocarbon radical having 12 to 22 carbon atoms, M is hydrogen or an alkali metal ion, ammonium ion or amine salt ion and m and n are integers, the sum of m and n being at least 2 and not more than 50, and their use for the fluorescent brightening of natural and synthetic fibrous materials.
摘要翻译：对金属离子和金属催化剂稳定并含有被磺基取代的茋荧光增白剂和式为“IMAGE”的脂肪胺烷氧基化产物的二苯乙烯荧光增白剂溶液，其中Q是具有12-22个碳原子的脂族烃基， M是氢或碱金属离子，铵离子或胺盐离子，m和n是整数，m和n之和至少为2并且不大于50，它们用于天然和合成纤维的荧光增白材料

7. 发明授权

US4298490A Process for the production of washing powders of stabilized or enhanced appearance which contain fluorescent whitening agents 失效
标题翻译：用于生产含有荧光增白剂的稳定或增强外观的洗衣粉的方法
公开(公告)号：US4298490A
公开(公告)日：1981-11-03
申请号：US102056
申请日：1979-12-10
申请人： Burkhart Lange , Suresh C. Agarwal , Werner Fringeli , Franz Gunter
发明人： Burkhart Lange , Suresh C. Agarwal , Werner Fringeli , Franz Gunter
IPC分类号： C11D3/42 , C09K11/02 , C09K11/06 , C11D11/00
CPC分类号： C11D3/42
摘要： The invention relates to the production of washing powders of stabilized or enhanced appearance which contain a fluorescent whitening agent of the formula ##STR1## wherein X.sub.1 is hydrogen, chlorine, bromine, alkyl or alkoxy, X.sub.2 is hydrogen or alkyl and M is hydrogen, an alkali metal or ammonium ion. The stabilizing or enhancement of the appearance is effected by first dissolving or dispersing the fluorescent whitening agent in a mixture of water and a polyvinyl alcohol or polyvinyl pyrrolidone which is soluble or is able to swell in water, adding this solution or dispersion to the washing powder slurry and drying the slurry. The solution or dispersion can also be subsequently sprayed onto the dried residual washing powder. The appearance can be further enhanced by employing a polyethylene glycol, a surfactant containing ethyleneoxy and/or propyleneoxy groups, and/or a cellulose ether, in addition to the polymer in the solution or dispersion. The solution or dispersion comprising fluorescent whitening agent and polymer can also alternatively be dried, preferably by spray drying, to produce a preparation which, after it has been suspended in water, can also be added to the washing powder slurry. The slurry is then dried, preferably by spray drying.
摘要翻译：本发明涉及具有稳定或增强外观的洗涤粉的制备，其含有下式的荧光增白剂，其中X 1是氢，氯，溴，烷基或烷氧基，X 2是氢或烷基，M是氢，碱金属或铵离子。通过首先将荧光增白剂溶解或分散在水和聚乙烯醇或聚乙烯吡咯烷酮的混合物中，使其溶解或能够在水中溶胀，将该溶液或分散体加入到洗涤粉末中来实现外观的稳定或增强浆料和干燥浆料。溶液或分散体也可随后喷洒到干燥的残留洗涤粉末上。除了溶液或分散体中的聚合物之外，还可以通过使用聚乙二醇，含有乙烯氧基和/或丙烯氧基的表面活性剂和/或纤维素醚来进一步增强外观。包含荧光增白剂和聚合物的溶液或分散体也可以干燥，优选通过喷雾干燥来制备在悬浮在水中之后也可以加入洗涤粉末浆料中的制剂。然后将浆料干燥，优选通过喷雾干燥。

8. 发明授权

US4339238A Stable aqueous formulations of stilbene fluorescent whitening agents 失效
标题翻译：稳定的芪类荧光增白剂水性制剂
公开(公告)号：US4339238A
公开(公告)日：1982-07-13
申请号：US223173
申请日：1981-01-07
申请人： Werner Fringeli , Alain Lauton
发明人： Werner Fringeli , Alain Lauton
IPC分类号： D06L3/12 , D21H21/30 , C09K11/06 , D06P3/852 , D21D3/00 , D21H3/80
CPC分类号： D06L3/1264 , D21H21/30
摘要： The invention relates to formulations which are stable to metal ions and contain a stilbene fluorescent whitening agent which is substituted by sulfo groups, and an acid phosphoric acid ester of an oxyalkylated fatty amine of the formula ##STR1## wherein R is an aliphatic hydrocarbon radical of 8 to 22 carbon atoms, Y.sub.1 and Y.sub.2 are preferably hydrogen, X is the acid radical of phosphoric acid and the sum of n+m is 2 to 30, preferably 4 to 20. The formulations can additionally contain various assistants such as non-ionic or anionic surfactants and/or organic solvents or polar compounds. The formulations are used for whitening natural and synthetic fabrics, e.g. made from polyamide, cellulose and blended fabrics, as well as paper.
摘要翻译：本发明涉及对金属离子稳定并含有被磺基取代的茋荧光增白剂的制剂，以及下式的烷氧基化脂肪胺的酸式磷酸酯，其中R是脂族烃基 8〜22个碳原子，Y1和Y2优选为氢，X为磷酸的酸基，n + m的和为2〜30，优选为4〜20。配方可另外含有各种辅助剂，如非离子型或阴离子表面活性剂和/或有机溶剂或极性化合物。该制剂用于增白天然和合成织物，例如，由聚酰胺，纤维素和混纺织物制成，以及纸。

9. 发明授权

US4212763A Bis-triazinylaminostilbene compounds and their use as fluorescent brightening agents 失效
标题翻译：双三嗪基氨基芪化合物及其作为荧光增白剂的用途
公开(公告)号：US4212763A
公开(公告)日：1980-07-15
申请号：US919115
申请日：1978-06-26
申请人： Werner Fringeli
发明人： Werner Fringeli
IPC分类号： C07D251/38 , C07D251/52 , C08K5/00 , C08K5/34 , C08K5/3477 , C08L33/00 , C08L33/02 , C08L77/00 , C09B57/00 , D06L3/12 , D21H19/10 , D21H21/28 , C07D403/06 , C07D401/14
CPC分类号： C07D251/52 , C07D251/38
摘要： Bis-triazinylaminostilbene compounds of the formula ##STR1## in which R.sub.1 is alkyl, alkenyl, cyclohexyl or phenylalkyl, R.sub.2 is hydrogen, alkyl, cyclohexyl, benzyl, alkyl which is substituted by hydroxyl, cyano, sulpho or carbamoyl, alkoxyalkyl or hydroxyalkoxyalkyl or alkoxyalkoxyalkyl or mono- or di-alkylaminoalkyl, and R.sub.3 is hydrogen, alkyl, alkyl which is substituted by hydroxyl, cyano or sulpho, or alkoxyalkyl or hydroxyalkoxyalkyl or R.sub.2 and R.sub.3 together with the nitrogen atom to which they are bonded are a morpholine ring or a pyrrolidine, piperidine, hexamethyleneimine or piperazine ring which is unsubstituted or substituted by 1 or 2 alkyl groups, and M is hydrogen or an alkali metal, ammonium or amine ion, and, if R.sub.2 or R.sub.3 is hydroxyalkyl, R.sub.1 is methyl, cyclohexyl or alkenyl only, and their use as fluorescent brightening agents for organic material of high molecular weight are disclosed.
摘要翻译：其中R 1为烷基，链烯基，环己基或苯基烷基，R 2为氢，烷基，环己基，苄基，被羟基，氰基，磺基或氨基甲酰基取代的烷基，烷氧基烷基或羟基烷氧基烷基或烷氧基烷氧基烷基或单 - 或二 - 烷基氨基烷基，R3为氢，烷基，被羟基，氰基或磺基取代的烷基，或烷氧基烷基或羟基烷氧基烷基或R2和R3与它们所键合的氮原子一起取代吗啉环或吡咯烷，哌啶，六亚甲基亚胺或哌嗪环，其未被取代或被1或2个烷基取代，M为氢或碱金属，铵或胺离子，如果R2或R3为羟烷基，R1为甲基，环己基或烯基，并且它们用作高分子量有机材料的荧光增白剂。

10. 发明授权

US4364845A Concentrated aqueous solutions of sulfo group-containing fluorescent brighteners which are stable on storage 失效
标题翻译：储存稳定的含磺基荧光增白剂的浓缩水溶液
公开(公告)号：US4364845A
公开(公告)日：1982-12-21
申请号：US55417
申请日：1979-07-06
申请人： Werner Fringeli
发明人： Werner Fringeli
IPC分类号： C09B67/44 , D06L3/12 , D21H21/30 , C09K11/06
CPC分类号： D06L3/1264 , D21H21/30
摘要： Concentrated aqueous solutions of sulfo group-containing fluorescent brighteners, which are stable on storage, containing a stilbene fluorescent brightener substituted by sulfo groups and a lactam of the formula ##STR1## in which m is 0 or an integer between 1 and 9, and their use for the fluorescent brightening of high molecular weight organic material.
摘要翻译：含有磺基的荧光增白剂的浓缩水溶液在储存时稳定，含有被磺基取代的芪荧光增白剂和式为“IMAGE”的内酰胺，其中m为0或1至9之间的整数，并且它们用于高分子量有机材料的荧光增白。

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