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1. 发明授权

US4532120A Silane purification process 失效
标题翻译：硅烷纯化工艺
公开(公告)号：US4532120A
公开(公告)日：1985-07-30
申请号：US566279
申请日：1983-12-28
申请人： Isaac L. Smith , Gunner E. Nelson
发明人： Isaac L. Smith , Gunner E. Nelson
IPC分类号： C01B33/04 , G01N31/00 , G01N33/00
CPC分类号： C01B33/046 , G01N31/00 , G01N33/0044 , Y10T436/16
摘要： A process for the removal of and analysis of phosphine and arsine impurities in silane gas. Silane gas which normally contains the impurities of AsH.sub.3 and PH.sub.3 is contacted with a solution of NaAlH.sub.4 in dimethoxyethane, other ether or amine to remove the impurities therefrom. The dimethoxyethane or other ether solution may then be hydrolyzed with water or alcohol to evolve hydrogen gas from the NaAlH.sub.4 and to re-evolve phosphine and arsine which may then be quantitatively determined by gas chromatography, atomic absorption, or other means.
摘要翻译：一种去除和分析硅烷气体中的膦和胂杂质的方法。通常含有AsH 3和PH 3的杂质的硅烷气体与NaAlH 4在二甲氧基乙烷，其它醚或胺中的溶液接触以除去其中的杂质。然后可以用水或醇水解二甲氧基乙烷或其它醚溶液，以从NaAlH 4中释放出氢气，并重新放出膦和胂，然后可以通过气相色谱，原子吸收或其他方法定量测定。

2. 发明授权

US4683321A Preparation of dialkyldialkoxysilanes and related compounds 失效
标题翻译：二烷基二烷氧基硅烷及相关化合物的制备
公开(公告)号：US4683321A
公开(公告)日：1987-07-28
申请号：US923184
申请日：1986-10-27
申请人： Gunner E. Nelson
发明人： Gunner E. Nelson
IPC分类号： C07F7/18
CPC分类号： C07F7/1876
摘要： Alkali metal aluminum tetraalkyls can alkylate tetraalkyl silicates and alkyltrialkoxysilanes, Si(OR).sub.4 and RSi(OR).sub.3, respectively. The product in each case is predominately the dialkylate. With tetraalkyl silicates, both of the alkyl groups bonded to silicon in the dialkylate product are derived from the metal tetraalkyl. With alkyltrialkoxysilanes, the silicon atom in the dialkylate product is (a) bonded to one alkyl group detained from the metal tetraalkyl, and (b) is also bonded to an alkyl group--that was bonded to silicon--in the silicon-containing starting material. Thus, the alkyl groups in the dialkylate product that are bonded to silicon can be alike or different. The dialkyldialkoxysilane products produced by this invention can be reduced to the corresponding silanes; e.g., R.sub.2 SiH.sub.2, by using an alkyl aluminum tetrahydride as the reducing agent. The dialkyldialkoxysilanes as well as the dialkylsilanes produced are useful as chemical intermediates.
摘要翻译：碱金属铝四烷基可以分别烷基化四烷基硅酸盐和烷基三烷氧基硅烷，Si（OR）4和RSi（OR）3。每种情况下的产品主要是二烷基酯。对于四烷基硅酸盐，与二烷基化物产物中的硅键合的两个烷基都衍生自金属四烷基。对于烷基三烷氧基硅烷，二烷基化物产物中的硅原子是（a）与一个残留在金属四烷基上的烷基键合，和（b）也与含硅原料中与硅键合的烷基键合。因此，与硅键合的二烷基化物产物中的烷基可以相同或不同。本发明生产的二烷基二烷氧基硅烷产物可以还原成相应的硅烷; 例如R 2 SiH 2，通过使用四氢化烷基铝作为还原剂。二烷基二烷氧基硅烷以及所生产的二烷基硅烷可用作化学中间体。

3. 发明授权

US4512966A Hydride production at moderate pressure 失效
标题翻译：中等压力下的氢化物生产
公开(公告)号：US4512966A
公开(公告)日：1985-04-23
申请号：US557206
申请日：1983-12-02
申请人： Gunner E. Nelson
发明人： Gunner E. Nelson
IPC分类号： C01B6/24 , C01B6/26
CPC分类号： C01B6/243
摘要： An effective two stage process for the production of sodium aluminum tetrahydride which facilitates use of equipment at moderate hydrogen pressure of 700-1500 psig. An aluminum alkyl is added to provide a catalyst species in a hydrocarbon reaction medium containing aluminum and sodium reactants. A reaction at about 130.degree.-170.degree. C. is carried out to form Na.sub.3 AlH.sub.6. The reaction temperature is then lowered to about 80.degree.-120.degree. C. and the hydrogen pressure is continued to convert the Na.sub.3 AlH.sub.6 to NaAlH.sub.4.
摘要翻译：用于生产四氢化钠铝的有效的两阶段方法，其有助于在中等氢气压力为700-1500psig的条件下使用设备。加入烷基铝以在含有铝和钠反应物的烃反应介质中提供催化剂种类。在约130℃-170℃进行反应，形成Na 3 AlH 6。然后将反应温度降至约80-120℃，并继续氢气压力将Na 3 AlH 6转化为NaAlH 4。

4. 发明授权

US4322539A Conversion of ethers to thioamines 失效
标题翻译：醚转化为硫胺
公开(公告)号：US4322539A
公开(公告)日：1982-03-30
申请号：US253168
申请日：1981-04-13
申请人： Gunner E. Nelson , Michael J. Dagani
发明人： Gunner E. Nelson , Michael J. Dagani
IPC分类号： C07D233/54 , C07D233/64
CPC分类号： C07D233/64
摘要： Bis-(imidazolylmethyl)-ether hydrochloride conversion to the corresponding amino-alkylene-thiomethyl imidazoles by reaction with amino alkylene thiols.
摘要翻译：通过与氨基亚烷基硫醇反应，将双 - （咪唑基甲基） - 醚盐酸盐转化成相应的氨基 - 亚烷基 - 硫代甲基咪唑。

5. 发明授权

US4107064A Metal sequestering method 失效
标题翻译：金属螯合法
公开(公告)号：US4107064A
公开(公告)日：1978-08-15
申请号：US824401
申请日：1977-08-15
申请人： Gunner E. Nelson , Tillmon H. Pearson
发明人： Gunner E. Nelson , Tillmon H. Pearson
IPC分类号： C02F5/10 , C11D3/00 , C11D3/20 , C11D1/86
CPC分类号： C11D3/2089 , C02F5/10
摘要： A method for sequestering metal ions using .alpha.,.alpha.'-carboxyalkoxy succinic acid or salts thereof in combination with a surfactant. SPCROSS-REFERENCE TO RELATED APPLICATIONSThis application is a division of application Ser. No. 682,320, filed May 3, 1976, now U.S. Pat. No. 4,066,687, which is a division of application Ser. No. 385,545, filed Aug. 3, 1973, now U.S. Pat. No. 3,980,578, which in turn is a continuation-in-part of application Ser. No. 153,816, filed June 16, 1971, now U.S. Pat. No. 3,784,486.
摘要翻译：使用α，α'-羧甲氧基琥珀酸或其盐与表面活性剂组合来螯合金属离子的方法。

6. 发明授权

US4031143A Reduction using NaAlEt.sub.2 H.sub.2 失效
标题翻译：使用NaAlEt {hd 2 {b H {HD 2
公开(公告)号：US4031143A
公开(公告)日：1977-06-21
申请号：US337902
申请日：1973-03-05
申请人： Gunner E. Nelson
发明人： Gunner E. Nelson
IPC分类号： C07B31/00 , C07C29/00
CPC分类号： C07B31/00
摘要： It is disclosed that a process wherein a reducible compound is reduced by an addition reaction to aluminum dihydrocarbon dihydrides of sodium, potassium or lithium followed by hydrolysis to remove the aluminum is improved by subjecting to oxidation with molecular oxygen the product from the aluminum addition prior to the hydrolysis operation. The intervening oxidation operation converts al--R bonds in the addition product into al-O-R bonds, R being hydrocarbon, preferably alkyl, the result being that upon hydrolysis an alcohol is produced from those groups rather than a hydrocarbon. The by-product alcohol thus produced is easier to dispose of without serious ecological disadvantages which is a significant improvement over the situation that exists when hydrocarbon is released.
摘要翻译：公开了通过对钠，钾或锂的二氢二氢二氢化铝的加成反应还原可还原化合物，然后水解除去铝的方法，通过用分子氧氧化来自铝添加的产物，水解操作。中间氧化操作将加成产物中的α-R键转化为α-O-R键，R为烃，优选为烷基，其结果是在水解时，由这些基团而不是烃产生醇。如此生产的副产物醇更容易处理而没有严重的生态缺陷，这是与释放碳氢化合物时存在的情况相比有显着改善的。

7. 发明授权

US5124502A Method of preparation of phenylalkylsilanes 失效
标题翻译：苯基烷基硅烷的制备方法
公开(公告)号：US5124502A
公开(公告)日：1992-06-23
申请号：US636756
申请日：1991-01-02
申请人： Gunner E. Nelson , John G. Loop
发明人： Gunner E. Nelson , John G. Loop
IPC分类号： C07F7/08 , C10M105/76
CPC分类号： C10M105/76 , C10M2227/04 , C10N2240/08
摘要： New methods of producing phenylalkylsilanes having a desired ration of phenyldialkylsilanes to phenyltrialkylsilanes using effective control of temperature in the reaction of sodium trialkylaluminum and phenyltrihalosilanes are disclosed.
摘要翻译：公开了在三烷基铝和苯基三卤硅烷的反应中有效控制温度来生产苯基二烷基硅烷对苯基三烷基硅烷的所需比例的苯基烷基硅烷的新方法。

8. 发明授权

US5097052A Preparation of sodium aluminum alkyls 失效
标题翻译：烷基铝钠的制备
公开(公告)号：US5097052A
公开(公告)日：1992-03-17
申请号：US695446
申请日：1991-05-03
申请人： Gunner E. Nelson
发明人： Gunner E. Nelson
IPC分类号： C07F5/06
CPC分类号： C07F5/062
摘要： Novel methods for the preparation of sodium aluminum tetraalkyls have been discovered comprising the reaction of sodium aluminum tri-isobutyl hydride and olefins. The methods avoid the use of sodium aluminum hydrides and permit in one step both the substitution of isobutyl groups and additions at hydride hydrogens to produce sodium aluminum tetraalkyls.

9. 发明授权

US4916245A Preparation of alkyl silanes 失效
标题翻译：烷基硅烷的制备
公开(公告)号：US4916245A
公开(公告)日：1990-04-10
申请号：US198514
申请日：1988-05-25
申请人： Gunner E. Nelson
发明人： Gunner E. Nelson
IPC分类号： C07F7/08
CPC分类号： C07F7/0827
摘要： Olefins and metal aluminum tetralkyls react with alkylhalosilanes to yield mixtures of tetraalkyls silanes which may be employed as functional fluids. For example, decene-1 and sodium aluminum tetraoctyl, NaAl(C.sub.8 H.sub.17).sub.4, react with methyltrichlorosilane. The mole ratio of sodium aluminum tetraalkyl to halosilane is from about 0.75:1.0, to about 1:1, and the ratio of olefin to the metal aluminate is selected to confer in the product mixture, the desired concentration of alkyl radicals derived from the olefin.

10. 发明授权

US4845260A Preparation of alkyl silanes 失效
标题翻译：烷基硅烷的制备
公开(公告)号：US4845260A
公开(公告)日：1989-07-04
申请号：US129001
申请日：1987-12-03
申请人： Gunner E. Nelson
发明人： Gunner E. Nelson
IPC分类号： C07F7/08
CPC分类号： C07F7/0809 , C07F7/0827
摘要： Silahydrocarbons having the formula RSiR'.sub.3 are prepared by a three step process. In the first step in a preferred embodiment, sodium, aluminum, hydrogen and olefin (corresponding to the radical R') are reacted in the presence of a triorganoaluminum catalyst. In a second step, fresh catalyst is added and reaction continued. In a third step, the product of the second step is reacted with a trihaloalkylsilane to produce the RSiR'.sub.3 product. Such products are useful as functional fluids.
摘要翻译：具有式RSiR'3的硅烷通过三步法制备。在优选实施方案的第一步中，钠，铝，氢和烯烃（对应于R'基团）在三有机铝催化剂的存在下反应。在第二步中，加入新鲜的催化剂并继续反应。在第三步骤中，将第二步的产物与三卤代烷基硅烷反应以产生RSiR'3产物。这些产品可用作功能性液体。

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