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    • 6. 发明授权
    • Aqueous suspension of bentonite and its use for coating thermal
insulating molded articles
    • 膨润土的水悬浮液及其用于涂覆绝热模制品的用途
    • US4670101A
    • 1987-06-02
    • US749480
    • 1985-06-27
    • Sabine SchmidtPeter KleinschmitRudolf Schwarz
    • Sabine SchmidtPeter KleinschmitRudolf Schwarz
    • C04B30/02D21F11/00
    • C04B30/02
    • There is prepared an aqueous suspension which in addition to water, consists of 2 to 50 weight % of a mixture of bentonite and inorganic fibers, with the portion of inorganic fiber being 1 to 30 weight % and the portion of bentonite being 1 to 30 weight % and wherein the total amount of solids does not exceed 50 weight %. With the suspension there is attained an improvement of the mechanical properties of thermal insulating molded objects which are employed for thermal insulation and which for example, contain pyrogenically produced silica as a filler by delivery of this suspension on the thermal insulating plate. The suspension can also be delivered on thermal insulating molded bodies on which there is pressed a fiber net or a fiber felt. After applying the suspension several thermal insulating molded bodies can be joined together where the coating formed consisting of bentonite and inorganic fibers acts as binder. The heat insulating molded article in addition to this layer, can have one or more additional coatings based on organic or inorganic lacquer systems, silicone compositions or low melting glazes.
    • 制备水性悬浮液,除了水之外,由2〜50重量%的膨润土和无机纤维​​的混合物组成,无机纤维的比例为1〜30重量%,膨润土的比例为1〜30重量% %,其中固体的总量不超过50重量%。 通过悬浮液,绝热成型体的机械性能得到改善,其用于隔热,并且例如通过将该悬浮液输送到绝热板上而含有热解法生产的二氧化硅作为填料。 该悬浮液也可以在其上挤压纤维网或纤维毡的隔热成型体上输送。 应用悬浮液后,几个绝热成型体可以结合在一起,其中由膨润土和无机纤维​​组成的涂层作为粘合剂。 除了该层之外,绝热模制品可以具有一种或多种基于有机或无机漆系统,硅酮组合物或低熔点釉料的附加涂层。
    • 7. 发明授权
    • Bis-(silylethyl)-oligosulphides and process for their production
    • 双(甲硅烷基乙基) - 二硫化物及其生产方法
    • US4444936A
    • 1984-04-24
    • US461432
    • 1983-01-27
    • Rudolf SchwarzPeter KleinschmitChrista LiedtkeSiegfried Wolff
    • Rudolf SchwarzPeter KleinschmitChrista LiedtkeSiegfried Wolff
    • C08L7/00C07F7/08C07F7/12C07F7/18C08G75/02C08G75/14C08K5/5425C08K5/548C08L21/00C08L23/00C08L33/00C08L33/02C08L101/00C08K5/06
    • C08K5/548C07F7/12C07F7/182C08G75/02C08G75/14
    • Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m --SiR.sub.n.sup.1 R.sub.4--(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 --C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 --C.sub.3 -alkyl, phenyl or C.sub.5 --C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.
    • 通过使式(CH2 = CH)m-SiRn1R4-(m + n)的乙烯基硅烷(其中R表示氯,溴,碘,C1-C3-烷氧基,2-甲基苯基) 甲氧基乙氧基,2-乙氧基乙氧基或羟基,R1代表C1-C3-烷基,苯基或C5-C7-环烷基,n是0,1或2,m是1或2,m + n是1,2或3, 以及在给定情况下,在约100至200℃的温度下,乙烯基硅烷与硫的摩尔比为1:2.5至1:10的硫化氢和乙烯基硅烷至硫化氢的摩尔比为1:0至1:5 在1至25巴(反应总压力)温度的压力下,在本身已知的硫化催化剂的存在下,在给定的情况下,随后水解或部分水解反应产物。 双(甲硅烷基乙基) - 二硫化物用作含有硅酸盐填料的交联性橡胶混合物中的增强添加剂(粘合剂),在给定情况下用于炭黑以及在给定情况下硫和其它常规组分。
    • 8. 发明授权
    • Form body for heat insulation and vacuum insulation panel with
asymmetric design
    • 隔热型绝热面板和非对称设计的真空绝热面板
    • US5316816A
    • 1994-05-31
    • US7129
    • 1993-01-22
    • Gerhard SextlHans StrackRoland ReuterIlona FussPeter KleinschmitRudolf Schwarz
    • Gerhard SextlHans StrackRoland ReuterIlona FussPeter KleinschmitRudolf Schwarz
    • F16L59/02B32B1/06B32B5/16
    • F16L59/028Y10T428/231Y10T428/237Y10T428/238Y10T428/239
    • A shaped body, preferably plate-shaped, for use as heat insulation, formed of (a) a finely distributed, powdery or fibrous substance, (b) a microporous casing, and (c) a gastight and watertight, metal-free casing. The shaped body is produced by drying a powdery or fibrous substance if necessary, optionally placing it into a microporous casing, optionally pressing and then optionally drying. Thereafter, the powdery substance is placed with the microporous casing into a gastight and watertight, metal-free casing. This gastight and watertight casing is optionally evacuated and sealed. Furthermore, a shaped article, preferably plate-shaped, for use as heat insulation, produced from (a) a finely distributed, powdery or fibrous substance with a water absorption capacity of 4 to 50% by weight at 23.degree. C. and 85% relative humidity, (b) a casing of two parts with asymmetric design which contains this finely distributed, powdery or fibrous substance, the first part of the casing being metal-free and concave in such a manner that it is completely filled by the preferably plate-like shaped article and the second part being metal-free or metallic and planar and connected to the trough in such a manner that a gastight and water-vapor-tight seal is assured and both parts having water-vapor-permeabilities between 0 and 0.2 g/m.sup.2 /d at 23.degree. C. and 85% relative humidity and gas permeabilities for N.sub.2, O.sub.2 and CO.sub.2 of in sum 0 to 0.5 cm.sup.3 /m.sup.2 d/bar at 23.degree. C.; the shaped article having the property of absorbing water up to an amount of 2 to 15% by weight without its thermal conductivity deteriorating more than 25%.
    • 由(a)精细分布的粉状或纤维状物质形成的成型体,优选为板状,(b)微孔外壳,(c)气密和水密的无金属外壳。 如果需要,通过干燥粉末或纤维状物质,任选地将其置于微孔套管中,任选地按压然后任选地干燥而制成成形体。 此后,将粉状物质与微孔套管一起置于气密和防水,无金属的外壳中。 这种气密和防水外壳可选择地抽真空并密封。 此外,用作绝热的成型制品,优选为板状,由(a)精细分布的粉末状或纤维状物质制成,其吸水量在23℃下为4〜50重量%,85重量% 相对湿度,(b)具有不对称设计的两部分的壳体,其包含这种精细分布的粉状或纤维状物质,壳体的第一部分是无金属和凹入的,使得其被优选板完全填充 并且第二部分是无金属的或金属的和平面的,并且以这样的方式连接到槽,使得保证气密和水蒸气密封,并且两个部分的水蒸汽渗透性在0和0.2之间 在23℃和85%相对湿度下的g / m 2 / d和在23℃下为0至0.5cm 3 / m 2d / bar的N 2,O 2和CO 2的气体渗透性。 该成型制品具有吸水量至多2至15重量%的特性,而其导热率不会降低25%以上。