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1. 发明授权

US07976953B2 Low NMP aqueous polyurethane composition 有权
标题翻译：低NMP水性聚氨酯组合物
公开(公告)号：US07976953B2
公开(公告)日：2011-07-12
申请号：US11630367
申请日：2005-06-28
申请人： Ilse Van Casteren , Marc Roelands , Gerardus Cornelis Overbeek , Ronald Tennebroek
发明人： Ilse Van Casteren , Marc Roelands , Gerardus Cornelis Overbeek , Ronald Tennebroek
IPC分类号： B32B27/40 , C08L75/04 , C08L55/00
CPC分类号： C08G18/0823 , C08G18/0852 , C08G18/12 , C08G18/283 , C08G18/6692 , C08G18/724 , C08G18/7607 , C08L33/10 , C08L75/04 , Y10T428/31551 , Y10T428/31591 , Y10T428/31598 , Y10T428/31601 , Y10T428/31605 , Y10T428/31609 , C08G18/3231 , C08L2666/04
摘要： An aqueous composition with a sediment content ≦5%, comprising a polyurethane dispersion wherein the polyurethane has an acid value in the range of from 25 to 65 mgKOH/g and comprises (i) 36 to 60 wt % of at least one aromatic polyisocyanate and where the polyurethane is prepared in the presence of (a) ≦5 wt % of 1-methyl-2-pyrrolidinone by weight of the polyurethane, (b) 5 to 100 wt % of 1-ethyl-2-pyrrolidinone by weight of polyurethane and (c) water.
摘要翻译：含有沉淀物含量的水性组合物，其含量为5％，包括聚氨酯分散体，其中所述聚氨酯的酸值在25至65mgKOH / g范围内，并且包含（i）36至60wt％的至少一种芳族多异氰酸酯（a）＆nlE; 5重量％的1-甲基-2-吡咯烷酮占聚氨酯重量的情况下制备聚氨酯，（b）按重量计5-100重量％的1-乙基-2-吡咯烷酮的聚氨酯和（c）水。

2. 发明申请

US20110091653A1 COATING COMPOSITION COMPRISING AUTOXIDISABLE COMPONENT 审中-公开
标题翻译：包含可自动化组分的涂料组合物
公开(公告)号：US20110091653A1
公开(公告)日：2011-04-21
申请号：US12920386
申请日：2009-03-31
申请人： Gerardus Cornelis Overbeek , Ilse Van Casteren , Ronald Tennebroek , Jelle Bernardus Otto Van Der Werf
发明人： Gerardus Cornelis Overbeek , Ilse Van Casteren , Ronald Tennebroek , Jelle Bernardus Otto Van Der Werf
IPC分类号： B05D3/02 , C08L63/00 , C08G59/00
CPC分类号： C09D133/14 , C08F8/14 , C08F8/44 , C08F220/28 , C08F220/32 , C08F2810/30 , C08F2810/50 , C09D133/068 , Y10T428/31855 , C08F120/06 , C08F2220/325 , C08F220/14 , C08F2220/1825 , C08F212/08
摘要： There is described (pref. non-adhesive) coating compositions (which may be either water or solvent borne) that comprise an autoxidisable vinyl polymer, the autoxidisable polymer having a vinyl polymer backbone 25% to 75% by wt of the autoxidisable polymer; fatty acid residue 25% to 75% by wt of the autoxidisable polymer; Tg from −6O° C. to +2O° C., Mw from 3500 to 50000 g/mol; and polydispersity from 2 to 10; the autoxidisable polymer obtained by a process of: (A) polymerising ethylenically unsaturated vinyl monomers comprising: at least one epoxy functional vinyl monomer 15% to 100% by wt total monomers in (A); 0 to 85% of at least one other ethylenically unsaturated vinyl monomer, (preferably other than styrenic monomers) by wt total monomers in (A); (B) reacting the epoxy functional polymer from (A) with fatty acids having an average iodine value from 30 to 250 g I2/100 g fatty acid; where composition has: a) a opt. co-solvent content ≦40% by wt of the composition; b) a solids content either ≧30% (aqueous) ≧60% (solvent based) by wt of the composition, the composition as a coating film having a telegraphing value of less than 10 gloss units (difference between an initial smooth gloss minus an initial rough gloss of the film).
摘要翻译：描述了包含可自动氧化的乙烯基聚合物的（优先非粘性）涂料组合物（其可以是水或溶剂载体），所述可自动氧化聚合物具有25重量％至75重量％的可自动氧化聚合物的乙烯基聚合物主链; 脂肪酸残基25％至75％重量的可自动氧化聚合物; Tg为-60℃至+ 20℃，Mw为3500至50000g / mol; 多分散性为2〜10; 通过以下方法获得的可自动氧化聚合物：（A）烯键式不饱和乙烯基单体的聚合，包括：（A）中至少一种15重量％至100重量％的单体的至少一种环氧官能乙烯基单体; 0至85％的（A）中的总单体的至少一种其它烯属不饱和乙烯基单体（优选不同于苯乙烯类单体）; （B）使来自（A）的环氧官能聚合物与平均碘值为30-250g I2 / 100g脂肪酸的脂肪酸反应; 其中组合有：a）选择。共溶剂含量＆nlE; 40重量％的组合物; b）以组合物重量计≥30％（水性）≥30％（水性）≥60％（溶剂基）的固体含量，具有小于10个光泽单位的透印值的涂膜的组成（初始平滑光泽度减去初始粗糙的光泽度）。

3. 发明申请

US20110118407A1 COATING COMPOSITION COMPRISING AUTOXIDISABLE COMPONENT 审中-公开
标题翻译：包含可自动化组分的涂料组合物
公开(公告)号：US20110118407A1
公开(公告)日：2011-05-19
申请号：US12919278
申请日：2009-03-31
申请人： Ilse Van Casteren , Gerardus Cornelis Overbeek , Ronald Tennebroek
发明人： Ilse Van Casteren , Gerardus Cornelis Overbeek , Ronald Tennebroek
IPC分类号： C08L63/00 , C08F265/04 , B05D3/00
CPC分类号： C09D137/00 , C08F8/14 , C08F8/44 , C08F120/06 , C08F212/08 , C08F220/28 , C08F220/32 , C08F2220/325 , C08F2810/30 , C08F2810/50 , C08J5/18 , C09D139/06 , Y10T428/31938
摘要： An aqueous emulsion coating composition comprising an autoxidisable vinyl oligomer having ≧20 wt % of unsaturated fatty acid residue; Tg from −50 to +15° C.; Mw from 2,500 to 40,000 g/mol; polydispersity from 2 to 12, said composition having ≦15% co-solvent by weight of solids, ≦13% NMP by weight of solids ≧38% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.
摘要翻译：一种水性乳液涂料组合物，其包含具有≥20重量％的不饱和脂肪酸残基的可自动氧化的乙烯基低聚物; Tg为-50〜+ 15℃。 Mw为2,500至40,000g / mol; 所述组合物具有≥11％的固体，15％的固体重量的共溶剂，固体重量的13％的NMP，固体重量的固体含量≥38％; 所述组合物当以具有透光值形式的涂层的形式时，所述透射值定义为在粗糙PVC上铸造的膜和在10个光泽单元的光滑PVC上铸造的膜之间的20°角的光泽差。

4. 发明申请

US20110118394A1 COATING COMPOSITION COMPRISING AUTOXIDISABLE COMPONENT 审中-公开
标题翻译：包含可自动化组分的涂料组合物
公开(公告)号：US20110118394A1
公开(公告)日：2011-05-19
申请号：US12919322
申请日：2009-03-31
申请人： Ilse Van Casteren , Gerardus Cornelis Overbeek , Ronald Tennebroek , Tijs Nabuurs , Richard George Coogan
发明人： Ilse Van Casteren , Gerardus Cornelis Overbeek , Ronald Tennebroek , Tijs Nabuurs , Richard George Coogan
IPC分类号： C09D123/30 , C08F10/00 , C08K5/3415 , B05D3/00
CPC分类号： C09D133/14 , C08G18/283 , C08G18/4211 , C08G18/423 , C08G18/4233 , C08G18/606 , C08G18/755 , C09D167/08 , C09D175/04 , C09D177/12 , Y10T428/31511
摘要： An aqueous solution coating composition comprising an autoxidisable polyvinyl polymer having ≧20% of fatty acid residue by weight of polymer; Tg from −60 to +15° C.; acid value of 15 to 75 mg KOH/g, Mw from 2500 to 100000 g/mol; polydispersity ≦30, said composition having ≦25% co-solvent by weight of solids, ≧30% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.
摘要翻译：一种水溶液涂料组合物，其包含具有≥20％的聚合物重量的脂肪酸残基的可自动氧化的聚乙烯基聚合物; Tg从-60到+ 15℃。酸值为15至75mg KOH / g，Mw为2500至100000g / mol; 多分散性; 30，所述组合物具有＆lt; NlE; 25重量％的固体重量的共溶剂，≥30重量％组合物的固体; 所述组合物当以具有透光值形式的涂层的形式时，所述透射值定义为在粗糙PVC上铸造的膜和在10个光泽单元的光滑PVC上浇铸的膜之间的20°角的光泽差。

5. 发明申请

US20100144915A1 RADIATION CURABLE AQUEOUS COMPOSITION FOR LOW GLOSS COATINGS 审中-公开
标题翻译：低光泽涂料的辐射可固化水性组合物
公开(公告)号：US20100144915A1
公开(公告)日：2010-06-10
申请号：US12527494
申请日：2008-02-19
申请人： Ilse Van Casteren , Roland Tennebroek , Mario Cornelis Schoondermark , Paul De Kok
发明人： Ilse Van Casteren , Roland Tennebroek , Mario Cornelis Schoondermark , Paul De Kok
IPC分类号： C09D175/04
CPC分类号： C09D175/08 , C08G18/0823 , C08G18/672 , C08L75/04 , C08L75/16 , C09D175/04 , C09D175/16 , C08L2666/20
摘要： A radiation curable aqueous coating composition having a 85° gloss of ≦60 upon drying comprising (A) 10 to 99 wt % of a polyurethane, (B) 1 to 90 wt % of a radiation curable component; (C) 0.1 to 10 wt % of an associative thickener; wherein at least 80 wt % of (A)+(B)+(C) has a particle size greater than 500 nm and wherein the C═C bond concentration of the composition is 0.2 to 5.0 mmol per g of (A)+(B)+(C).
摘要翻译：干燥后具有85°光泽度的可辐射固化水性涂料组合物; 60（A）10至99重量％的聚氨酯，（B）1至90重量％的可辐射固化组分; （C）0.1〜10重量％的缔合增稠剂; 其中（A）+（B）+（C）的至少80重量％具有大于500nm的粒度，并且其中组合物的C = C键浓度为每摩尔（A）+（ B）+（C）。

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