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1. 发明授权

US4516982A Antimisting system for hydrocarbon fluids 失效
标题翻译：碳氢化合物流体反倾销体系
公开(公告)号：US4516982A
公开(公告)日：1985-05-14
申请号：US547905
申请日：1983-11-02
申请人： Ilan Duvdevani , Dennis G. Peiffer , John A. Eckert , Robert D. Lundberg
发明人： Ilan Duvdevani , Dennis G. Peiffer , John A. Eckert , Robert D. Lundberg
IPC分类号： B05D5/08 , C10L1/14 , C10L1/22 , C10L1/24
CPC分类号： B05D5/08 , C10L1/146 , C10L1/2368 , C10L1/2462
摘要： The present invention relates to hydrocarbon, and specifically jet fuels, solutions having dilatant properties in which the hydrocarbon solution contains a polymer complex which is the interaction product of a sulfonate containing polymer and an amine containing copolymer.
摘要翻译：本发明涉及烃，特别是喷气燃料，其具有膨胀性质的溶液，其中烃溶液含有作为含磺酸盐的聚合物和含胺共聚物的相互作用产物的聚合物配合物。

2. 发明授权

US4942189A Interfacial viscosification of aqueous solutions utilizing interpolymer complex 失效
标题翻译：使用互聚物复合物的水溶液的界面粘度
公开(公告)号：US4942189A
公开(公告)日：1990-07-17
申请号：US387184
申请日：1989-07-31
申请人： Dennis G. Peiffer , Robert D. Lundberg , Ilan Duvdevani
发明人： Dennis G. Peiffer , Robert D. Lundberg , Ilan Duvdevani
IPC分类号： C08J3/00 , C08J3/07 , C08J3/09
CPC分类号： C08J3/07 , C08J3/005 , C08J3/091 , Y10S524/924
摘要： The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 1,000 cps; forming an interpolymer complex of neutralized sulfonated polymer (water insoluble) and copolymer of styrene/vinylpyridine in the solvent system to form a solution, a concentration of the water insoluble interpolymer complex polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; the admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and interpolymer complex transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken). The large increase in viscosity of the aqueous phase is directly attributed to the formation of a large number of minute water-filled particles dispersed in the continuous aqueous phase.
摘要翻译：本发明涉及一种水性液体的增稠方法，其包括形成有机液体或油和极性助溶剂的溶剂体系的步骤，极性助溶剂小于溶剂体系的约15重量％，溶剂体系的粘度小于约1,000cps; 在溶剂体系中形成中和磺化聚合物（水不溶性）和苯乙烯/乙烯基吡啶的共聚物的互聚物络合物以形成溶液，溶液中水不溶性互聚物络合物聚合物的浓度为约0.01至约0.5重量％，粘度的溶液小于约200cps; 将所述溶液与约5至约500体积％的水混合或接触，所述水与有机液体和极性共溶剂和互聚物复合物不混溶，从有机液体转移到水相，从而使水相凝胶化（即，加粗）。水相的粘度大幅度上升直接归因于形成分散在连续水相中的大量微小水分散的颗粒。

3. 发明授权

US4737534A Method for controlling viscosity of organic liquids and compositions thereof 失效
标题翻译：用于控制有机液体粘度的方法及其组合物
公开(公告)号：US4737534A
公开(公告)日：1988-04-12
申请号：US720722
申请日：1985-04-08
申请人： Robert D. Lundberg , Robert R. Phillips , Dennis G. Peiffer , Ilan Duvdevani
发明人： Robert D. Lundberg , Robert R. Phillips , Dennis G. Peiffer , Ilan Duvdevani
IPC分类号： C08J3/24 , C08L23/32 , C08L57/06 , C08K5/05 , C08K5/01 , C08L39/08 , C10M111/04
CPC分类号： C08L23/32 , C08J3/246 , C08L57/06
摘要： The instant invention relates to a process for controlling the viscosity of organic liquids by incorporating in said liquid a minor amount of polymer complex, and optionally a cosolvent for the ionic groups of said polymer. The polymer complex comprises the reaction product of a metal neutralized sulfonated polymer and a basic nitrogen-containing polymer, wherein the polymer complex is substantially soluble in said organic liquid, and pendant sulfonate groups which are substantially insoluble in said organic liquid. The optional cosolvent is selected which will solubilize the pendant sulfonate groups and provide a reasonably homogeneous mixture of solvent, cosolvent and polymer complex. The preferred compositions prepared by the method of the instant invention comprise an organic liquid having a solubility parameter of from 6 to 10.5 in combination with a polymer complex containing from 0.2 up to 10.0 mole % sulfonate groups and nitrogen-containing groups, and optionally a nonvolatile alcohol or amine cosolvent.
摘要翻译：本发明涉及通过在所述液体中加入少量聚合物络合物和任选的所述聚合物的离子基团的共溶剂来控制有机液体的粘度的方法。聚合物复合物包括金属中和的磺化聚合物和碱性含氮聚合物的反应产物，其中聚合物络合物基本上可溶于所述有机液体，以及基本上不溶于所述有机液体的侧链磺酸酯基团。选择可选的共溶剂，其将溶解磺酸侧基，并提供溶剂，共溶剂和聚合物络合物的合理均匀的混合物。通过本发明的方法制备的优选组合物包含溶解度参数为6至10.5的有机液体与含有0.2至10.0摩尔％磺酸盐基团和含氮基团的聚合物配合物以及任选的非挥发性的醇或胺助溶剂。

4. 发明授权

US4520158A Nonaqueous solvent soluble polyampholytes-viscosifier and shear thickening additive 失效
标题翻译：非水溶剂可溶性聚阴离子增稠剂和剪切增稠剂
公开(公告)号：US4520158A
公开(公告)日：1985-05-28
申请号：US638302
申请日：1984-08-06
申请人： Dennis G. Peiffer , Robert D. Lundberg , Ilan Duvdevani , Warren A. Thaler
发明人： Dennis G. Peiffer , Robert D. Lundberg , Ilan Duvdevani , Warren A. Thaler
IPC分类号： C08F8/44 , C08J3/09 , C10M151/02 , C08K5/01 , C08L39/00
CPC分类号： C08J3/091 , C08F8/44 , C10M151/02 , C08J2325/08 , C10M2205/04 , C10M2217/028 , C10M2221/02
摘要： A process for increasing the viscosity of a hydrocarbon organic liquid under increasing shear rate which includes the step of:(a) forming a solution of said hydrocarbon organic liquid and a polyampholyte having about 1 to about 500 milliequivalents of sulfonate groups per 100 gms. of said polyampholyte, wherein the concentration of said polyampholyte is about 0.01 to about 20 wt. %, said polyampholyte having the formula: ##STR1## wherein X is about 40 to about 98 mole %, y is about 1 to about 50 mole %, and z is about 1 to about 50 mole %, wherein y and z are less than 60 mole %, and M is an amine or a metal cation selected from the group consisting of aluminum, iron, lead, Groups IA, IIA, IB and IIB of the Periodic Table of Elements; and(b) subjecting said solution to increasing shear rate to increase the viscosity of said solution by at least 10% as said shear rate increases.
摘要翻译：一种在增加的剪切速率下增加烃有机液体的粘度的方法，该方法包括以下步骤：（a）形成所述烃类有机液体的溶液和每100克具有约1至约500毫当量磺酸盐基团的多聚电解质。的所述聚阴离子，其中所述聚阴离子的浓度为约0.01至约20wt。％，所述聚阴离子具有下式：其中X为约40至约98摩尔％，y为约1至约50摩尔％，z为约1至约50摩尔％，其中y和z小于 60摩尔％，M是选自元素周期表的铝，铁，铅，IA，IIA，IB和IIB族的胺或金属阳离子; 和（b）当所述剪切速率增加时，所述溶液经受所述溶液增加剪切速率以使所述溶液的粘度增加至少10％。

5. 发明授权

US4508128A Drag reduction agent for hydrocarbon liquid 失效
标题翻译：烃液减阻剂
公开(公告)号：US4508128A
公开(公告)日：1985-04-02
申请号：US547909
申请日：1983-11-02
申请人： Ralph M. Kowalik , Ilan Duvdevani , Dennis G. Peiffer , Robert D. Lundberg
发明人： Ralph M. Kowalik , Ilan Duvdevani , Dennis G. Peiffer , Robert D. Lundberg
IPC分类号： C08F8/36 , C08F8/44 , C08L25/04 , C08L25/18 , C09K3/00 , C08L79/04 , C08L81/08 , F17D1/17
CPC分类号： C09K3/00 , C08F8/44 , C08L25/04 , C08L25/18 , C08F2800/10 , Y10T137/0391
摘要： The present invention relates to improved drag reduction agents which are polymer complexes of a cationic polymer and an anionic polymer.
摘要翻译：本发明涉及作为阳离子聚合物和阴离子聚合物的聚合物配合物的改进的减阻剂。

6. 发明授权

US4738997A Asphalt blends based on polymer complexes 失效
标题翻译：基于聚合物配合物的沥青混合料
公开(公告)号：US4738997A
公开(公告)日：1988-04-19
申请号：US807674
申请日：1985-12-11
申请人： Robert D. Lundberg , Ilan Duvdevani , Dennis G. Peiffer
发明人： Robert D. Lundberg , Ilan Duvdevani , Dennis G. Peiffer
IPC分类号： C08L95/00
CPC分类号： C08L95/00
摘要： A bitumen-containing composition which comprises;(a) bitumen;(b) about 0.5 to about 30 parts by weight of a polymer complex per 100 parts by weight of the bitumen; and(c) about 0 to about 100 parts by weight of a filler per 100 parts by weight of the bitumen.
摘要翻译：含有沥青的组合物，其包含：（a）沥青; （b）每100重量份沥青约0.5至约30重量份的聚合物复合物; 和（c）每100重量份沥青约0至约100重量份的填料。

7. 发明授权

US4656204A Process for use of drag reduction agent in a hydrocarbon liquid 失效
标题翻译：在烃液中使用减阻剂的方法
公开(公告)号：US4656204A
公开(公告)日：1987-04-07
申请号：US547929
申请日：1983-11-02
申请人： Ilan Duvdevani , Robert D. Lundberg , Ralph M. Kowalik , Dennis G. Peiffer
发明人： Ilan Duvdevani , Robert D. Lundberg , Ralph M. Kowalik , Dennis G. Peiffer
IPC分类号： B05D5/08 , C09K3/00 , C10L1/14 , C10L1/22 , C10L1/24
CPC分类号： B05D5/08 , C09K3/00 , C10L1/146 , C10L1/2368 , C10L1/2462
摘要： The present invention relates to an improved process for the use of drag reduction agents, which are polymer complexes of a cationic polymer and an anionic polymer.
摘要翻译：本发明涉及使用作为阳离子聚合物和阴离子聚合物的聚合物配合物的减阻剂的改进方法。

8. 发明授权

US4497923A Shear thickening of organic diluents via interpolymer complexes 失效
标题翻译：通过互聚物络合物剪切有机稀释剂的增稠
公开(公告)号：US4497923A
公开(公告)日：1985-02-05
申请号：US547904
申请日：1983-11-02
申请人： Robert D. Lundberg , Dennis G. Peiffer , Ilan Duvdevani , Robert R. Phillips
发明人： Robert D. Lundberg , Dennis G. Peiffer , Ilan Duvdevani , Robert R. Phillips
IPC分类号： B01J13/00 , B05D5/08 , C08J3/00 , C08J3/09 , C09K3/00 , C10L7/02 , C08J3/08 , C08J3/10 , C08K5/01 , C08K5/04
CPC分类号： B05D5/08 , B01J13/0082 , C08J3/005 , C08J3/091 , C09K3/00 , C10L7/02 , Y10S524/924
摘要： The present invention relates to a process for the viscosification of an organic liquid which comprises the steps of forming a first solution of an anionic polymer dissolved in the organic liquid; forming a second solution of a cationic polymer dissolved in the organic liquid; and mixing the first and the second solutions together to form an interpolymer complex of the anionic and cationic polymer in the organic liquid, wherein the organic liquid containing the interpolymer complex has improved viscosification properties. This solution possesses higher viscosity than the mean of the separate viscosities of the starting solutions at relatively low solids content. Moreover, these interpolymer complexes, in hydrocarbon solutions, can be formulated to exhibit shear thickening at increased shear rates. This property is useful in such technological applications as antimisting of the solvent.
摘要翻译：本发明涉及有机液体的增粘方法，其包括以下步骤：形成溶解在有机液体中的阴离子聚合物的第一溶液; 形成溶解在有机液体中的阳离子聚合物的第二溶液; 并将第一和第二溶液混合在一起形成有机液体中阴离子和阳离子聚合物的互聚物络合物，其中含有互聚物络合物的有机液体具有改进的增粘性能。该溶液具有比起始溶液在相对较低固体含量下分开的粘度的平均值更高的粘度。此外，在烃溶液中的这些互聚物配合物可以配制成在增加的剪切速率下显示剪切增稠。该特性在溶剂的抗溶剂等技术应用中是有用的。

9. 依法登记的发明

USH1077H Interfacial viscosification of aqueous solutions utilizing interpolymer complexes 失效
公开(公告)号：USH1077H
公开(公告)日：1992-07-07
申请号：US527232
申请日：1990-05-21
申请人： Dennis G. Peiffer , Robert D. Lundberg , Ilan Duvdevani
发明人： Dennis G. Peiffer , Robert D. Lundberg , Ilan Duvdevani
IPC分类号： C08J3/00 , C08J3/07
CPC分类号： C08J3/07 , C08J3/005
摘要： The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 1,000 cps; forming an interpolymer complex of neutralized sulfonated polymer (water insoluble) and copolymer of styrene/vinylpyridine in the solvent system to form a solution, a concentration of the water insoluble interpolymer complex polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and interpolymer complex transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken). The large increase in viscosity of the aqueous phase is directly attributed to the formation of a large number of minute water-filled particles dispersed in the continuous aqueous phase.

10. 发明授权

US4904722A Method for controlling viscosity of organic liquids and compositions thereof 失效
标题翻译：用于控制有机液体粘度的方法及其组合物
公开(公告)号：US4904722A
公开(公告)日：1990-02-27
申请号：US788963
申请日：1985-10-18
申请人： Robert D. Lundberg , Robert R. Phillips , Dennis G. Peiffer , Ilan Duvdevani
发明人： Robert D. Lundberg , Robert R. Phillips , Dennis G. Peiffer , Ilan Duvdevani
IPC分类号： C08J3/24 , C08L23/32 , C08L57/06
CPC分类号： C08L23/32 , C08J3/246 , C08L57/06
摘要： A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of less than 9.5, a viscosity, as measured at 25.degree. C., of less than 200 centipoises and said organic liquid is selected from the group consisting of mineral oils, synthetic oils, naphthanes, alkanes, cycloalkanes and aromatics and mixtures thereof, which comprises incorporating in said organic liquid about 0.01 to 20 grams of polymer complex per 100 ml. of said organic liquid, said polymer complex being formed "in situ" in said organic liquid or dissolved in said organic liquid, said complex being comprised of polymer A, containing about 4 meq. to 500 meq. of neutralized sulfonate groups, and polymer B, containing basic nitrogen groups, both functional groups being present at a level of from about 4 to 500 meq. per 100 g. of polymer, wherein polymer B has the formula: ##STR1## wherein x is about 50.0 to 99.8 weight percent and y is about 0.2 to about 50.0 weight percent, wherein said sulfonate groups of said polymer A being neutralized with basic compounds selected from the group consisting of transition elements, said polymer A having a polymeric backbone substantially soluble in said organic liquid and said polymer having a molecular weight of about 1,000 to 10,000,000.
摘要翻译：一种用于控制有机液体的粘度的方法，所述有机液体的溶解度参数小于9.5，在25℃下测得的小于200厘泊的粘度和所述有机液体选自矿物质油，合成油，萘烷，烷烃，环烷烃和芳族化合物及其混合物，其包括在每一100ml中在所述有机液体中加入约0.01至20克聚合物复合物。的所述有机液体，所述聚合物复合物在所述有机液体中“原位”形成或溶解在所述有机液体中，所述复合物由聚合物A组成，含有约4meq。至500毫克的中和磺酸盐基团和含有碱性氮基团的聚合物B，两个官能团的存在量为约4至500meq。每100克的聚合物，其中聚合物B具有下式：其中x为约50.0至99.8重量％，y为约0.2至约50.0重量％，其中所述聚合物A的所述磺酸盐基团用碱性化合物中和，所述碱性化合物选自由过渡元素组成，所述聚合物A具有基本上可溶于所述有机液体的聚合物骨架，所述聚合物的分子量为约1,000至10,000,000。

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