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    • 1. 发明授权
    • Layers used to prevent reticulation in photographic elements
    • US4056396A
    • 1977-11-01
    • US578069
    • 1975-05-16
    • Ikutaro HorieTakushi MiyazakoShinji SakaguchiNobuo TsujiNagao Kameji
    • Ikutaro HorieTakushi MiyazakoShinji SakaguchiNobuo TsujiNagao Kameji
    • G03C1/04C08F16/00C08F16/14C08F20/00C08F20/52G03C1/053G03C1/76G03C3/00
    • G03C1/7614G03C1/053
    • A photographic light-sensitive material including a support, a non-light sensitive uppermost layer consisting of at least one organic synthetic high polymer compound as a film forming material and at least one light-sensitive layer between the support and the uppermost layer, said organic high polymer compound being selected from the group consisting of the following polymers (A) to (F):polymer (A) comprising repeating units a.sub.1 and a.sub.2 ;______________________________________ a.sub.1 : ##STR1## 80 - 97 mol% a.sub.2 : ##STR2## 3 - 20 mol% ______________________________________ Wherein M represents a cation, and m represents 0, 3 or 4;Polymer (B) comprising repeating units b.sub.1, b.sub.2 and b.sub.3 ;______________________________________ b.sub.1 : ##STR3## 5 - 30 mol% b.sub.2 : ##STR4## 5 - 75 mol% b.sub.3 : ##STR5## 20 - 65 mol% ______________________________________ Wherein R.sub.1 and R.sub.2 each represents --CH.sub.3 or --C.sub.2 H.sub.5, R.sub.3 and R.sub.5 each represents --H or --CH.sub.3, and R.sub.4 represents --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7 or --C.sub.4 H.sub.9 ;polymer (C) comprising repeating units c.sub.1 and c.sub.2 ;______________________________________ c.sub.1 : ##STR6## 10 - 40 mol% c.sub.2 : ##STR7## 60 - 90 mol% ______________________________________ Wherein R.sub.6 represents --H or --CH.sub.3, and Z represents --COOH, --COOCH.sub.3, --COOC.sub.2 H.sub.5, --COOC.sub.3 H.sub.7, --COOC.sub.4 H.sub.9 or --CONH.sub.2 ;polymer (D) comprising repeating units d.sub.1 and d.sub.2 ;______________________________________ d.sub.1 : ##STR8## 10 - 40 mol% d.sub.2 : ##STR9## 60 - 90 mol% ______________________________________ Wherein R.sub.7 represents --H or --CH.sub.3 ;polymer (E) comprising repeating units e.sub.1 and e.sub.2 ;______________________________________ e.sub.1 : ##STR10## 20 - 60 mol% e.sub.2 : ##STR11## 40 - 80 mol% ______________________________________ wherein R.sub.8 and R.sub.9 each represents --H or --CH.sub.3, and X represents --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7 or --C.sub.4 H.sub.9 ; andpolymer (F) comprising repeating unit f.sub.1 ;______________________________________ f.sub.1 : ##STR12## wherein Y represents --CH.sub.3 or --COCH.sub.3, R.sub.10 represents --H or --C.sub.n H.sub.2n+1, n being an integer of 1 to 12, said organic synthetic high polymer compound being insoluble to a processing solutions
    • 7. 发明授权
    • Color photographic light-sensitive material
    • 彩色摄影感光材料
    • US4120725A
    • 1978-10-17
    • US771704
    • 1977-02-24
    • Kiyoshi NakazyoShinji SakaguchiNobuo Tsuji
    • Kiyoshi NakazyoShinji SakaguchiNobuo Tsuji
    • G03C7/26G03C1/053G03C7/388G03C1/10G03C1/40
    • G03C7/3882G03C1/053
    • A color photographic light-sensitive material having at least one silver halide photographic emulsion layer containing a hydrophobic coupler, in which the color photographic material additionally contains both a polymer having a recurring unit represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group and R.sup.2 and R.sup.3 each represents a hydrogen atom, an aliphatic hydrocarbon group, an aromatic hydrocarbon group, an alkyl-substituted amino group or an aryl-substituted amino group, with the proviso that both of R.sup.2 and R.sup.3 are not simultaneously hydrogen atoms, the total number of carbon atoms in R.sup.2 and R.sup.3 is 4 to 12, R.sup.2 and R.sup.3 do not contain an acidic group, and R.sup.2 and R.sup.3 can combine to form a ring;And a polymer having a recurring unit represented by the following general formula (II); ##STR2## wherein R.sup.4 has the same meaning as R.sup.1 ; and Q represents (1) --(CH.sub.2).sub.p OH, wherein p represents 0 or 1, ##STR3## wherein q represents an integer of 2 to 4, ##STR4## wherein R.sup.5 represents an alkyl group; and R.sup.6 represents a hydrogen atom or an alkyl group, ##STR5## wherein Z.sup.1 represents the atoms necessary to form a lactam ring, an oxazolidone ring or a pyridone ring, or ##STR6## wherein Z.sup.2 represents the atoms necessary to form a morpholine ring.
    • 一种彩色照相感光材料,其具有含有疏水性成色剂的至少一种卤化银照相乳剂层,其中彩色照相材料另外含有具有由以下通式(I)表示的重复单元的聚合物:( I)其中R1表示氢原子或低级烷基,R2和R3各自表示氢原子,脂族烃基,芳香族烃基,烷基取代氨基或芳基取代氨基,条件是 R2和R3都不是氢原子,R2和R3中的碳原子总数为4〜12,R2和R3不含酸性基团,R2和R3可以结合形成环; 和具有下列通用公式(II)所表示的转换单元的聚合物; (II)其中R 4具有与R 1相同的含义; (2)其中q表示2〜4的整数,(3)其中R 5表示烷基;(3)其中, (4)其中Z1表示形成内酰胺环所必需的原子,恶唑烷酮环或吡啶酮环,或者其中Z2表示必要的原子,其中Z 2表示氢原子或烷基, 形成吗啉环。
    • 9. 发明授权
    • Magnetic recording material
    • 磁记录材料
    • US4657817A
    • 1987-04-14
    • US558673
    • 1983-12-06
    • Tsutomu OkitaKyoichi NaruoNobuo TsujiTeruo NakagawaKiyoshi MuraseTakahisa Ogasawara
    • Tsutomu OkitaKyoichi NaruoNobuo TsujiTeruo NakagawaKiyoshi MuraseTakahisa Ogasawara
    • C08F290/00C08F299/06C08G18/42C08G18/67C08L75/16C09D5/23C09D175/04C09D175/14G11B5/702G11B5/70
    • G11B5/7026C08G18/42C08G18/672C08L75/16G11B5/7021Y10S428/90Y10T428/31609
    • There is provided a magnetic recording material produced by coating on a support a magnetic coating composition which contains as main components a magnetic powder and a binder, the binder comprising an urethane acrylate synthesized using a polyester polyol having a particular structure, and by irradiating the resulting magnetic coat with electron beams to harden it. The polyester polyol contains polyhydric alcohol component, 50 mole % or more of which is a dihydric alcohol selected from the class (A) described below, and/or polybasic acid component, 50 mole % or more of which is a dibasic acid selected from the class (B) described below. The urethane acrylate is synthesized under such a condition that it may have two or more of (meth)acryloyl groups per molecule. Thus, improvements in electromagnetic properties and in durability are attained.Class (A): Alkyl-substituted aliphatic dihydric alcohols, alicyclic dihydric alcohols, and dihydric alcohols made by addition of alkylene oxides to alicyclic or aromatic dihydric alcohols.Class (B): Alicyclic dicarboxylic acids and aromatic dicarboxylic acids.
    • 提供了一种通过在载体上涂覆磁性涂料组合物而制备的磁记录材料,磁性涂料组合物含有作为主要组分的磁性粉末和粘合剂,所述粘合剂包含使用具有特定结构的聚酯多元醇合成的聚氨酯丙烯酸酯,并且通过照射所得到的 磁性涂层用电子束硬化。 聚酯多元醇含有多元醇成分,其中50摩尔%以上是选自下述(A)的二元醇,和/或多元酸成分,50摩尔%以上的二元酸选自 (B)类。 氨基甲酸酯丙烯酸酯在每分子可以具有两个以上(甲基)丙烯酰基的条件下合成。 因此,获得了电磁特性和耐久性的改善。 (A)类:烷基取代的脂族二元醇,脂环族二元醇和通过将环氧烷烃加成到脂环族或芳族二元醇中制得的二元醇。 类(B):脂环族二羧酸和芳族二羧酸。